- Towson, W.E.1
- Tyler, Gary R.1
- Tyler, John, 1790-18621
- Upshur, A. P. (Abel Parker), 1790-18441
- Van Buren, John, 1810-18661
- Van Dusen, Elizabeth--Correspondence1
- Vrooman, Carl Schurz, 1872-1966--Correspondence1
- Watson, Thomas E. (Thomas Edward), 1856-19221
- Wells, Jere A.1
- West, James E. (James Edward), 1876-1948--Correspondence1
- Wheeler, John H. (John Hervey)1
- White, Edward Douglass, 1845-1921--Death and burial1
- Whitehead, William A. (William Adee), 1810-18841
- Wilson, Edith Bolling Galt, 1872-19611
- Wilson, Edith Bolling Galt, 1872-1961--Correspondence1
- Wilson, Ellen Axson--Correspondence1
- Winchester, James, 1752-18261
- Windsor, Edward, Duke of, 1894-1972--Correspondence1
- Wisner, Benjamin B. (Benjamin Blydenburg), 1794-18351
- Withers, John W. (John William), 1868-1961--Correspondence1