1998 ambient air surveillance report [1998]

GEORGIA DEPARTMENT OF NATURAL RESOURCES
ENVIRONMENTAL PROTECTION DIVISION
Air Protection Branch
1998 Ambient Air Surveillance Report 1997 PAMS Network 1997 Toxic Network

2

TABLE OF CONTENTS
Georgia Ambient Air Standards 1998 Georgia Air Sampling Network
Criteria Pollutants
PM-10 Sulfur Dioxide (SO2 ) Ozone (O3 ) Carbon Monoxide ( CO ) Nitrogen Dioxide ( NO2 ) Lead ( Pb )
Non-Criteria Pollutants
PAMS PAMS Carbonyl Air Toxics METALS Air Toxics VOC'S Air Toxics SEMI-VOC'S Acid Precipiatation Oxides of Nitrogen ( NOx ) Nitric Oxide ( NO ) Reactive Oxides of Nitrogen

PAGE 6 7
9 12 14 17 19 21
23 48 50 52 54 55 56 57 58

3

APPENDICIES

Types of Sampling Methods ( Appendix A )

59

Abbreviations ( Appendix B )

61

4

Ambient Air Monitoring Ambient air monitoring in Georgia provides information on measured concentrations of criteria and non-criteria pollutants at selected locations. Criteria pollutants are those which a standard has been adopted by the U.S. Environmental Protection Agency. Non-criteria pollutants, while having no standard, provide useful information on the quality and content of ambient air.
The current Georgia Air Sampling Network (G.A.S.N.), is comprised of 58 monitors at 46 locations in 23 counties. Monitoring takes place year round with the exception of ozone, which is sampled from April through October.
The monitoring network is composed of State and Local Air Monitoring Stations (SLAMS), National Air Monitoring Stations (NAMS), Special Purpose Monitoring (SPM), and Photochemical Assessment Monitoring Stations (PAMS). During 1996 the network contained 14 NAMS, 25 SLAMS, 19 SPM stations and 4 PAMS stations.
The number and location of the individual sites vary from year to year, depending on a variety of reasons that include: availability of long term space allocation; citizen complaint; regulatory need; etc. Once the site is established, it is our intention to monitor for long term trends.
In general, the basic monitoring objectives that govern the selection of sites are: 1) to determine the highest concentration expected to occur; 2) to determine representative concentrations in areas of high population density; 3) to determine the impact on ambient pollution levels of significant sources or source categories; 4) to determine the general background concentration levels; and 5) to determine the concentration of a number of compounds which may aid in the generation of ground level ozone.
5

GEORGIA AMBIENT AIR STANDARDS SUMMARY Criteria Pollutants

Compound Sulfur Dioxide
Particulate Matter (PM-10)

Standard 0.50 0.14 0.03
50.0
150.0

Units ppm
micrograms per cubic meter

Time Interval 3 Hour 24 Hour
Annual Mean Annual Arithmetic
Mean
24 Hour

Carbon Monoxide Ozone
Nitrogen Dioxide

35.0 9.0 0.125 0.85 .05

ppm ppm ppm

1 Hour
8 Hour Average
1 Hour
(Atlanta 13 County Non-Attainment Area)
8 Hour Average
(4th Max)
Statewide
Annual Mean

Lead

1.5

micrograms per Calendar Quarter

cubic meter

Average

6

1998 GEORGIA AIR MONITORING NETWORK
7

STATE OF GEORGIA 1998 AMBIENT AIR MONITORING NETWORK
FOR CRITERIA POLLUTANTS

SITE ID
130090001 130150002 130210007
130210012
130510019 130510014
130510021
130511002
130550001 130850001 130891002
130890002
130890003 130892001
130893001
130950006 130950007 130970003 130970004 131110094 131110091 131130001 131150003 131150005 131210001 131210032 131210039

CITY
Milledgeville Stilesboro
Macon
Port Wentworth
Savannah
Summerville Dawsonville Clarkston
Decatur
Doraville Tucker
Albany
Douglasville Cohutta Wilderness McCaysville Fayetteville Rome

131210048 Atlanta

131210055
131210099 131270004 131270006 131350002 132150008 132150009 132150010
132150011
132151003
132230003
132450003
132450091

Brunswick Lawrenceville
Columbus
Yorkville Augusta

132470001
132550002 132611001 132950002 133030001

Conyers
Griffin Leslie Rossville Sandersville

COUNTY
Baldwin Bartow Bibb
Chatham
Chattooga Dawson
DeKalb
Dougherty Douglas Fannin Fayette Floyd
Fulton
Glynn Gwinnett
Muscogee
Paulding Richmond Rockdale Spalding Sumpter W alker W ashington

SITE NAME
Baldwin County Airport Stilesboro Allied Chemical
Macon SE
Farmers Market Shuman Jr. High School
E. President St.
W. Lathrop & Augusta Ave.
DNR Fish Hatchery Forestry Commission DeKalb Tech.
South DeKalb
D.M.R.C. Health Center
Idlewild Road
Dougherty Middle School Turner Elementary Sch. Beulah Pump Station Douglas Co. Water Auth. Jacks River Road McCaysville Elem. School DOT Coosa Elementary School Coosa High School Fulton Co. Health Dept. E. Rivers School Fire Station # 8
GA. Tech
Confederate Ave.
Roswell Road Arco Pump Station Risley Middle School Gwinnett Tech. Airport S.E. Site Fort Benning Junction
Cussetta Road School
Crime Lab
King Farm
Regional YDC.
Bungalow Road School
Monastery
UGA Experiment Station Community Center Health Center Heath Center

POLLUTANT
Sulfur Dioxide Sulfur Dioxide PM-10 Ozone Sulfur Dioxide Sulfur Dioxide PM-10 Ozone Sulfur Dioxide PM-10 Sulfur Dioxide PM-10 Ozone Carbon Monoxide Ozone Nitrogen Dioxide Lead PM-10 Ozone Nitrogen Dioxide Sulfur Dioxide PM-10 PM-10 Ozone Ozone Sulfur Dioxide Ozone Sulfur Dioxide PM-10 PM-10 PM-10 PM-10 PM-10 Sulfur Dioxide Nitrogen Dioxide Ozone Sulfur Dioxide Carbon Monoxide PM-10 Ozone Ozone Ozone Lead Lead PM-10 Lead Ozone Ozone Nitrogen Dioxide Sulfur Dioxide Ozone PM-10 Ozone Nitrogen Dioxide PM-10 Ozone PM-10 PM-10

8

PARTICULATE MATTER (PM-10)
Sources: Particulate matter (PM) is solid matter or liquid droplets from smoke, dust, fly ash, or condensing vapors that can be suspended in the air for long periods of time. It represents a broad class of chemically diverse particles that range in size from molecular clusters of 0.005 micrometers (m) to coarse particles of 50-100 m in diameter (100 m is about the thickness of an average human hair). PM results from all types of combustion. The carbon-based particles that result from incomplete burning of diesel fuel in buses, trucks and cars are of particular concern. Another important combustion source is the burning of wood in stoves and fireplaces in residential settings. Also of concern are the sulfate and nitrate particles that are formed as a byproduct of SO2 and NO2 emissions, primarily from fossil fuel-burning power plants and vehicular exhausts.
The U.S. national ambient air quality standard was originally based on particles up to 25-45 m in size, termed "total suspended particles" (TSP). In 1987, EPA replaced TSP with an indicator that includes only those particles smaller than 10 m, termed PM10. These smaller particles cause most of the adverse health effects because of their ability to penetrate deeply into the lungs. Health effects. The observed human health effects of PM include breathing and respiratory symptoms, aggravation of existing respiratory and cardiovascular disease, alterations in the body's defense system against inhaled materials and organisms, and damage to lung tissue. Groups that appear to be most sensitive to the effects of PM include individuals with chronic lung or cardiovascular disease, individuals with influenza, asthmatics, elderly people, and children.
Health Effects: Marked increases in daily mortality have been statistically associated with very high 24-hour concentrations of PM10, with some increased risk of mortality at lower concentrations. Small increases in mortality appear to exist at even lower levels. Risks to sensitive individuals increase with consecutive, multi-day exposures to elevated PM concentrations. The research also indicates that aggravation of bronchitis occurs with elevated 24-hour PM10 levels, and small decreases in lung function take place when children are exposed to lower 24-hour peak PM10 levels. Lung function impairment persists for 2-3 weeks following exposure to PM.
National Primary and Secondary Ambient Air Quality Standards for Particulate Matter.
(a) The annual primary and secondary PM-10 standards are met when the annual arithmetic mean concentration, as determined in accordance with appendix N of this part, is less than or equal to 50 micrograms per cubic meter. (b) The 24-hour primary and secondary PM-10 standards are met when the 99th percentile 24-hour concentration, is less than or equal to 150 micrograms per cubic meter. [62 FR 38711, July 18, 1997]
9

Units: micrograms per cubic meter

Site ID

City

County

130210007 Macon

Bibb

STATE OF GEORGIA PARTICULATE MATTER (PM-10) 1ST MAX & ANNUAL ARITHMETIC MEAN

Site Name Allied Chem.

Number Measured
(days)
61

1st Max 60

# Values > 150

Annual

#

Arithmetic Values

Mean

> 50

0

30

0

130510014 Savannah Chatham

Shuman Sch

53

130511002 Savannah Chatham

Lathrop & Augusta

162

130550001 Summerville Chattooga

Fish Hatchery

55

76

0

88

0

115

0

26

0

31

0

24

0

130892001 Doraville

DeKalb

Health Center

56

58

0

30

0

130950007 Albany

Dougherty

Turner Sch.

48

130970003 Douglasville Douglas

Beulah Pump Station

60

131150005 Rome

Floyd

Coosa High School

45

66

0

60

0

70

0

28

0

22

0

24

0

10

Site ID

City

County

131210001 Atlanta

Fulton

131210032 Atlanta

Fulton

131210039 Atlanta

Fulton

131210048 Atlanta

Fulton

131270004 Brunswick Glynn

132150011 Columbus Muscogee

132450091 Augusta

Richmond

132550002 Griffin

Spalding

132950002 Rossville

Walker

Site Name
Fulton Co. Health Dept.
E. Rivers School
Fire Station # 8

Number Measured
(days) 54
49
59

Ga. Tech.

183

Arco Pump Station

49

Cussetta Rd. School

57

Bungalow Rd. School

51

UGA

Experiment

59

Station

Health Dept.

50

1st Max 56

# Values > 150

Annual

#

Arithmetic Values

Mean

> 50

0

28

0

64

0

25

0

73

0

31

0

80

0

30

0

134

0

33

0

54

0

23

0

68

0

28

0

55

0

24

0

55

0

25

0

133030001 Sandersville Washington Health Center

60

110

0

29

0

11

SULFUR DIOXIDE
Sources: Sulfur dioxide (SO2) is a colorless reactive gas that is ordorless at low concentrations, but pungent at very high concentrations. It is emitted primarily when fossil fuels and ores that contain sulfur are burned or processed. Major sources of SO2 are fossil fuel-burning power plants and industrial boilers.
Health Effects: Exposure to SO2 can cause impairment of respiratory function, aggravation of existing respiratory disease (especially bronchitis), and a decrease in the ability of the lungs to clear foreign particles. It can also lead to increased mortality, especially if elevated levels of particulate matter (PM) are also present. Groups that appear most sensitive to the effects of SO2 include asthmatics and other individuals with hyperactive airways, and individuals with chronic obstructive lung or cardiovascular disease. Elderly people and children are also likely to be sensitive to SO2.
Effects of short-term peak exposures have been evaluated in controlled human exposure studies. These studies show that SO2 generally increases airway resistance in the lungs, and can cause significant constriction of air passages in sensitive asthmatics. These impacts have been observed in subjects engaged in moderate to heavy exercise while exposed to relatively high peak concentrations. These changes in lung function are accompanied by perceptible symptoms such as wheezing, shortness of breath, and coughing in these sensitive groups.
The presence of PM appears to aggravate the impact of SO2 pollution. Several studies of chronic effects have found that people living in areas with high PM and SO2 levels have a higher incidence of respiratory illnesses and symptoms than people living in areas without such a synergistic combination of pollutants.
National Primary Ambient Air Quality Standards for Sulfur Oxides (Sulfur Dioxide).
(a) The level of the annual standard is 0.030 parts per million (ppm), not to be exceeded in a calendar year. The annual arithmetic mean shall be rounded to three decimal places (fractional parts equal to or greater than 0.0005 ppm shall be rounded up).
(b) The level of the 24-hour standard is 0.14 parts per million (ppm), not to be exceeded more than once per calendar year. The 24-hour averages shall be determined from successive nonoverlapping 24-hour blocks starting at midnight each calendar day and shall be rounded to two decimal places (fractional parts equal to or greater than 0.005 ppm shall be rounded up).
(c) Sulfur oxides shall be measured in the ambient air as sulfur dioxide by the reference method described in appendix A to this part or by an equivalent method designated in accordance with part 53 of this chapter.
(d) To demonstrate attainment, the annual arithmetic mean and the second-highest 24hour averages must be based upon hourly data that are at least 75 percent complete in each calendar quarter. A 24-hour block average shall be considered valid if at least 75 percent of the hourly averages for the 24-hour period are available. In the event that only 18, 19, 20, 21, 22, or 23 hourly averages are available, the 24-hour block average shall be computed as the sum of the available hourly averages using 18, 19, etc. as the divisor. If fewer than 18 hourly averages are available, but the 24-hour average would exceed the level of the standard when zeros are substituted for the missing values, subject to the rounding rule of paragraph (b) of this section, then this shall be considered a valid 24-hour average. In this case, the 24-hour block average shall be computed as the sum of the available hourly averages divided by 24. [61 FR 25579, May 22, 1996]
12

STATE OF GEORGIA SULFUR DIOXIDE
24 & 3 HOUR MAXIMUM OBSERVATIONS

Units: parts per million

Site ID 130090001 130150002 130210012 130510019
130510021
130511002
130950006 131110091 131150003 131210048 131210055 132450003

City
Milledgeville Stilesboro Macon Port Wentworth Savannah
Savannah
Albany McCaysville Rome Atlanta Atlanta Augusta

County Baldwin Bartow Bibb Chatham
Chatham
Chatham
Dougherty Fannin Floyd Fulton Fulton Richmond

Site Name
Airport Stilesboro Forestry Farmer's Market E. President St. Lathrop & Augusta Dougherty Middle Sch. Elem. School Coosa Elem. Sch. GA Tech Confederate Ave. YDC

# Obs. (hours)
8314 8335 8661 7703
8651
3502
8324 8551 8697 7591 8224 7962

Max 24 - Hour

1st

2nd

0.016

0.015

0.015

0.014

0.019

0.019

0.012

0.010

0.030

0.027

0.001

0.001

0.007 0.061 0.016 0.033 0.018 0.021

0.006 0.052 0.016 0.019 0.016 0.011

Obs > Std.
0 0 0 0
0
0
0 0 0 0 0 0

Max 3 - Hour

1st

2nd

0.075

0.066

0.160

0.069

0.052

0.039

0.037

0.037

0.142

0.061

0.001

0.001

0.028 0.127 0.091 0.118 0.063 0.040

0.021 0.115 0.072 0.062 0.042 0.036

Obs > Std.
0 0 0 0
0
0
0 0 0 0 0 0

13

OZONE
Sources: Ozone (O3), a colorless gas, is the major constituent of smog. It is produced by the chemical reaction of nitrogen dioxide with reactive organic substances such as hydrocarbons in automobile exhaust or vapors from cleaning solvents - in the presence of sunlight. This type of pollution first gained attention in the 1940's as Los Angeles "smog." Since then, photochemical smog has been observed frequently in many cities as well. (Note: In the upper atmosphere, naturally occurring ozone is beneficial in protecting us from the harmful solar rays.) Health Effects: Ozone and other photochemical oxidants such as peroxyacyl nitrates and aldehydes are associated with health effects in humans. Peroxyacyl nitrates and aldehydes cause the irritation that is characteristic of photochemical pollution. Ozone has a greater impact on the respiratory system, where it irritates the mucous membranes of the nose, throat and airways; ninety percent of the ozone inhaled into the lungs is never exhaled. Symptoms associated with exposure include cough, chest pain, and throat irritation. Ozone can also increase susceptibility to respiratory infections. In addition, ozone impairs normal functioning of the lungs and reduces the ability to perform physical exercise. Recent studies also suggest that even at lower ozone concentrations some healthy individuals engaged in moderate exercise for 6 to 8 hours may experience symptoms. All of these effects are more severe in individuals with sensitive respiratory systems, and studies show that moderate levels may impair the ability of individuals with asthma or respiratory disease to engage in normal daily activities. The potential chronic effects of repeated exposure to ozone are of even greater concern. Laboratory studies show that people exposed over a 6 to 8 hour period to relatively low ozone levels develop lung inflammation. Animal studies suggest that if exposures are repeated over a long period (e.g. months, years, lifetime), inflammation of this type may lead to permanent scarring of lung tissue, loss of lung function, and reduced lung elasticity. Air Quality Levels: EPA recently revised the ozone standard for areas of the state which are outside the Atlanta non-attainment area. For these areas, the 1-hour ozone standard was replaced with an 8-hour average ozone standard. The air quality standard for ozone, which is designed to protect public health with an adequate margin of safety, is 0.08 ppm, averaged over eight hours. EPD is required to issue a public alert when ozone levels reach 0.12 ppm, a public warning when ozone levels reach 0.40 ppm, and a declaration of public emergency at 0.50 ppm. The significant harm level, at which serious and widespread health effects occur among the general population, is 0.60 ppm of ozone, averaged over two hours.
14

UNITS: PARTS PER MILLION

Site ID 130890002 130893001 130970004
131130001
131210055 131350002 132230003 132470001

City Decatur Tucker Douglasville
Fayetteville
Atlanta Lawrenceville Yorkville Conyers

County DeKalb DeKalb Douglas
Fayette
Fulton Gwinnett Paulding Rockdale

STATE OF GEORGIA OZONE
1 HR AVERAGES

Site Name
So. DeKalb Idlewild Road Douglas Co. Water Authority Dept. of Transportation Confederate Ave. Gwinnett Tech. King Farm Monastery

Number Measured (days) 159 176
212
213
207
190 212 214

1st Max 0.166 0.135 0.157
0.149
0.158 0.142 0.157 0.140

2nd Max 0.142 0.134 0.133
0.141
0.157 0.139 0.138 0.134

# of Values > 0.12 5 6 8
7
11 4 3 6

15

Site ID

City

County

130210012
130510021
130850001 130890002 130893001 130970004

Macon
Savannah
Dawsonville Decatur Tucker Douglasville

Bibb
Chatham
Dawson DeKalb DeKalb Douglas

131110094 Cohutta

Fannin

131130001
131210055
131270006 131350002 132150008 132151003 132230003
132450091
132470001
132611001

Fayetteville
Atlanta
Brunswick Lawrenceville Columbus Columbus Yorkville
Augusta
Conyers
Leslie

Fayette
Fulton
Glynn Gwinnett Muscogee Muscogee Paulding
Richmond
Rockdale
Sumpter

STATE OF GEORGIA OZONE
8 HR AVERAGES

Site Name
Forestry Comm. E. President Street Forestry Comm. S. DeKalb Idlewild Road Douglas Co. Water Authority Cohutta Wilderness Area Dept. of Transportation Confederate Ave. Risley School Gwinnett Tech. Airport Crime Lab King Farm Bungalow Road School Monastery Union High School

Number Measured
(days) 201
212
214 159 176 212
214
213
207 183 190 199 210 212 213 214 213

1st Max
0.110
0.080
0.102 0.117 0.114 0.141
0.093
0.126
0.138 0.101 0.116 0.102 0.104 0.123 0.116 0.120 0.090

2nd Max
0.108
0.080
0.099 0.115 0.113 0.116
0.088
0.114
0.134 0.092 0.112 0.097 0.095 0.122 0.108 0.118 0.084

3rd Max
0.106
0.078
0.098 0.113 0.112 0.115
0.086
0.112
0.130 0.083 0.111 0.095 0.094 0.112 0.100 0.118 0.083

4th Max

# of 4th Max Values $ 0.085

0.106

18

0.075

0

0.096

12

0.112

21

0.111

19

0.110

35

0.081

3

0.111

34

0.126

41

0.082

2

0.111

27

0.091

8

0.089

8

0.104

26

0.099

13

0.113

38

0.081

1

16

CARBON MONOXIDE Sources: Carbon Monoxide (CO) is an odorless, colorless gas that is a by-product of the incomplete burning of fuels. Industrial processes contribute to CO pollution levels, but the principal source of CO pollution in most large urban areas is the automobile. Cigarettes and other sources of incomplete burning in the indoor environment also produce CO. CO is inhaled and enters the blood stream; there it binds chemically to hemoglobin, the substance that carries oxygen to the cells, thereby reducing the amount of oxygen delivered to all tissues of the body. The percentage of hemoglobin inactivated by CO depends on the amount of air breathed, the concentration of CO in air, and length of exposure; this is indexed by the percentage of carboxyhemoglobin found in the blood. Health Effects: CO weakens the contractions of the heart, thus reducing the amount of blood pumped to various parts of the body and, therefore, the oxygen available to the muscles and various organs. In a healthy person, this effect significantly reduces the ability to perform physical exercises. In persons with chronic heart diseases, these effects can threaten the overall quality of life, since their systems are unable to compensate for the decrease in oxygen. CO pollution is also likely to cause such individuals to experience angina during exercise. Adverse effects have also been observed in individuals with heart conditions who are exposed to CO pollution in heavy freeway traffic for 1 to 2 hours or more. In addition, fetuses, young infants, pregnant women, elderly people, and individuals with anemia or emphysema are likely to be more susceptible to the effects of CO. For these individuals, the effects are more pronounced when exposure takes place at high altitude locations, where oxygen concentration is lower. CO can also affect mental function, visual activity, and alertness of healthy individuals, even at relatively low concentrations. Air Quality Levels: The air quality standard for CO, which is designed to protect public health with an adequate margin of safety, is 9 parts per million, averaged over 8 hours. EPD is required to issue a public alert when CO levels reach 15 ppm, a public warning when CO levels reach 30 ppm, and a public declaration of emergency at the level of 40 ppm. The significant harm level, at which serious and widespread health effects occur to the general population, is 50 ppm of CO.
17

Units: parts per million

SITE ID 130891002 131210099

City County Clarkston DeKalb Atlanta Fulton

Site Name
DeKalb Tech Roswell Road

STATE OF GEORGIA CARBON MONOXIDE 1 & 8 HOUR OBSERVATIONS

# Observations (hours) 8433
8641

Max 1 - Hour

1st

2nd

6.4

4.8

5.1

5.0

Obs. > 35 0 0

Max 8 -Hour

1st

2nd

4.1

4.1

3.1

3.1

Obs. > 9 0 0

18

NITROGEN DIOXIDE
Sources: Nitrogen dioxide (NO2) is a light brown gas that can become an important component of urban haze. Nitrogen oxides usually enter the air as the result of high-temperature combustion processes, such as those occurring in automobiles and power plants. NO2 plays an important role in the atmospheric reactions that generate ozone. Home heaters and gas stoves also produce substantial amounts of NO2.
Health Effects: Healthy individuals experience respiratory problems when exposed to high levels of NO2 for short durations (less than three hours). Asthmatics are especially sensitive, and changes in airway responsiveness have been observed in some studies of exercising asthmatics exposed to relatively low levels of NO2. Studies also indicate a relationship between indoor NO2 exposures and increased respiratory illness rates in young children, but definitive results are still lacking. Many animal studies suggest that NO2 impairs respiratory defense mechanisms and increases susceptibility to infection.
Several studies also show that chronic exposure to relatively low NO2 pollution levels may cause structural changes in the lungs of animals. These studies suggest that chronic exposure to NO2 could lead to adverse health effects in humans, but specific levels and durations likely to cause such effects have not yet been determined.
National Primary and Secondary Ambient Air Quality Standards for Nitrogen Dioxide
(a) The level of the national primary ambient air quality standard for nitrogen dioxide is 0.053 parts per million (100 micrograms per cubic meter), annual arithmetic mean concentration. (b) The level of national secondary ambient air quality standard for nitrogen dioxide is 0.053 parts per million (100 micrograms per cubic meter), annual arithmetic mean concentration. (c) The levels of the standards shall be measured by:
(1) A reference method based on appendix F and designated in accordance with part 53 of this chapter, or (2) An equivalent method designated in accordance with part 53 of this chapter. (d) The standards are attained when the annual arithmetic mean concentration in a calendar year is less than or equal to 0.053 ppm, rounded to three decimal places (fractional parts equal to or greater than 0.0005 ppm must be rounded up). To demonstrate attainment, an annual mean must be based upon hourly data that are at least 75 percent complete or upon data derived from manual methods that are at least 75 percent complete for the scheduled sampling days in each calendar quarter. [50 FR 25544, June 19, 1985]
19

State of Georgia Nitrogen Dioxide Annual Arithmetic Means

Units: parts per million

Site ID
130890002 130893001 131210048 132230003 132470001

City
Decatur Tucker Atlanta Yorkville Conyers

County
DeKalb DeKalb Fulton Paulding Rockdale

Site Name
South DeKalb Idlewild Road Ga. Tech. King Farm Monastery

Number Measured (hours) 3691 5798 7886 8060 8196

Annual Arithmetic Mean
0.020 0.016 0.024 0.006 0.042

# of Values > 0.053 0 0 0 0 0

20

LEAD
Nature and Sources of the Pollutant: In the past, automotive sources were the major contributor of Pb emissions to the atmosphere. As a result of EPA's regulatory efforts to reduce the content of Pb in gasoline, the contribution from the transportation sector has declined over the past decade. Today, metals processing is the major source of Pb emissions to the atmosphere. The highest air concentrations of Pb are found in the vicinity of nonferrous and ferrous smelters, and battery manufacturers. Health and Environmental Effects: Exposure to Pb occurs mainly through inhalation of air and ingestion of Pb in food, water, soil, or dust. It accumulates in the blood, bones, and soft tissues. Lead can adversely affect the kidneys, liver, nervous system, and other organs. Excessive exposure to Pb may cause neurological impairments, such as seizures, mental retardation, and behavioral disorders. Even at low doses, Pb exposure is associated with damage to the nervous systems of fetuses and young children, resulting in learning deficits and lowered IQ. Recent studies also show that Pb may be a factor in high blood pressure and subsequent heart disease. Lead can also be deposited on the leaves of plants, presenting a hazard to grazing animals. Air Quality Levels: National primary and secondary ambient air quality standards for lead and its compounds, measured as elemental, are: 1.5 micrograms per cubic meter, maximum arithmetic mean averaged over a calendar quarter. (Secs. 109, 301(a) Clean Air Act as amended (42 U.S.C. 7409, 7601(a))) [43 FR 46258, Oct. 5, 1978]
21

STATE OF GEORGIA LEAD
QUARTERLY COMPOSITE AVERAGES

UNITS: MICROGRAMS PER CUBIC METER

Site ID

City

County

130890003 132150009
132150010

Atlanta Columbus
Columbus

DeKalb Muscogee
Muscogee

132150011 Columbus Muscogee

Site Name
D.M.R.C. S.E. Site Ft. Benning Jct. Cussetta School

Number Observations
(months) 12 12
12

1st Quarter Composite
Avg. 0.01 0.53
0.22

2nd Quarter Composite
Avg. 0.01 0.31
0.19

12

0.06

0.03

3rd Quarter Composite
Avg. 0.01 0.22
0.29
0.05

4th Quarter Composite
Avg. 0.01 0.58
0.22
0.16

# of Values > 1.50 ug/M3 0 0
0
0

22

PAMS The Environmental Protection Agency (EPA) has revised the ambient air quality surveillance regulations in Title 40 Part 58 of the Code of Federal Regulations (40 CFR Part 58) to include provisions for enhanced monitoring of ozone, oxides of nitrogen, volatile organic compounds (VOCs), selected carbonyl compounds, and monitoring of meteorological parameters. The revisions require States to establish Photochemical Assessment Monitoring Stations (PAMS) as part of their existing State Implementation Plan (SIP) monitoring networks in ozone non-attainment areas classified as serious, severe, or extreme. The principal reasons for requiring the collection of additional ambient air pollutant and meteorological data are the lack of successful attainment of the National Ambient Air Quality Standard (NAAQS) for ozone, and the need to obtain a more comprehensive air quality data base for ozone and its precursors. Analysis of the data will help the EPD understand the underlying causes of ozone pollution, devise effective controls, and measure improvement.
23

SITE NAME
S. Dekalb (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 132230003 132470001

PINENE/P-ETHYLTOLUEN

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

240

1997

1926

43188
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
7.600 1.960 5.800

2ND MAX
7.100 1.740 5.700

ARITH. MEAN
1.255 0.439 1.254

SITE NAME
S. Dekalb (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 132230003 132470001

BPINENE/1,2,3- TRIME

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

240

1997

1926

43189
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
10.20 3.940 11.80

2ND MAX
9.300 3.840 11.30

ARITH. MEAN
1.806 0.876 2.162

24

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ETHANE AKA-METHYLMET

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

107

1997

1927

1997

53

43202
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
24.10 80.00 8.500 5.980 13.20 18.40

2ND MAX
23.00 20.90 5.500 5.620 12.90 14.80

ARITH. MEAN
5.620 7.354 2.780 2.895 4.602 4.673

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ETHYLENE AKA-ETHENE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43203
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
32.40 23.10 6.090 0.005 6.900 10.20

2ND MAX
31.10 21.80 2.600 0.005 5.700 7.400

ARITH. MEAN
4.442 4.542 1.772 0.005 1.080 2.079

25

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

PROPANE AKA-DIMETHYL

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43204
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
46.50 50.00 7.000 10.10 28.00 15.00

2ND MAX
42.40 24.70 5.900 9.230 14.50 12.50

ARITH. MEAN
6.371 6.550 2.067 3.007 3.494 4.094

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

PROPYLENE AKA-PROPEN

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43205
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
16.60 8.000 1.500 0.005 3.200 1.700

2ND MAX
15.90 8.000 1.500 0.005 3.200 1.700

ARITH. MEAN
2.402 1.815 0.670 0.005 0.721 0.543

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ACETYLENE AKA-ETHYNE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

52

43206
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
19.80 80.00 4.600 0.005 5.900 8.800

2ND MAX
14.70 19.10 3.300 0.005 4.400 7.100

ARITH. MEAN
4.266 5.040 1.309 1.268 1.589 2.903

26

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-BUTANE AKA-BUTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43212
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
37.60 34.30 4.900 2.620 7.900 11.70

2ND MAX
25.00 30.70 4.300 2.580 7.000 10.700

ARITH. MEAN
4.266 5.040 1.309 1.268 1.589 2.903

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ISOBUTANE AKA-2-METH

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

51

1997

15

1997

108

1997

1927

1997

53

43214
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
14.30 7.000 1.700 4.490 3.100 3.600

2ND MAX
13.40 4.600 1.000 2.010 3.100 3.000

ARITH. MEAN
2.165 1.330 0.273 0.366 0.745 0.827

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

TRANS-2-BUTENE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

52

43216
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.600 1.100 0.050 0.005 1.200 0.300

2ND MAX
2.600 1.100 0.050 0.005 0.600 0.300

ARITH. MEAN
0.388 0.128 0.050 0.005 0.077 0.071

27

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

CIS-2-BUTENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1825 53 15 108
1927 53

43217
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.000 0.080 0.050 0.005 17.60 0.500

2ND MAX
2.300 0.060 0.050 0.005 0.800 0.400

ARITH. MEAN
0.235 0.085 0.050 0.005 0.045 0.065

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-PENTANE AKA-AMYL H

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43220
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
40.50 11.00 8.100 1.600 13.60 4.100

2ND MAX
26.90 9.100 5.800 1.480 13.60 4.100

ARITH. MEAN
3.877 2.755 2.903 4.313 1.373 1.693

SITE NAME
S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130890002 130893001 132230003 132470001 132470001

ISOPENTANE AKA-2-MET

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

108

1997

1927

1997

53

43221
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
50.00 11.60 4.070 18.80 10.20

2ND MAX
30.30 11.10 3.360 17.90 7.900

ARITH. MEAN
7.425 6.023 1.344 3.343 3.571

28

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

1-PENTENE AKA-PROPYL

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

53

43224
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
4.200 1.500 0.500 0.005 0.800 2.200

2ND MAX
3.400 1.100 0.400 0.005 0.600 0.900

ARITH. MEAN
0.533 0.249 0.103 0.005 0.101 0.125

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

TRANS-2-PENTENE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

53

43226
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.200 6.500 0.800 0.005 2.800 1.400

2ND MAX
5.500 2.200 0.300 0.005 0.800 1.100

ARITH. MEAN
0.558 0.317 0.117 0.005 0.053 0.095

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

CIS-2-PENTENE AKA-CI

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

53

43227
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.300 5.500 0.050 0.005 1.800 0.400

2ND MAX
3.100 0.700 0.050 0.005 0.600 0.050

ARITH. MEAN
0.290 0.186 0.050 0.005 0.023 0.057

29

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

3-METHYLPENTANE AKA-

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

63

1997

1927

1997

53

43230
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
15.30 4.600 1.900 0.760 4.900 3.400

2ND MAX
14.30 4.500 1.800 0.550 3.400 1.500

ARITH. MEAN
1.953 1.086 0.907 0.100 0.360 0.337

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-HEXANE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1825 53 15 240
1927 53

43231
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
9.700 3.800 1.700 0.490 17.50 5.300

2ND MAX
9.700 3.800 1.700 0.490 17.50 5.300

ARITH. MEAN
1.637 1.166 1.070 0.098 0.446 0.557

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-HEPTANE AKA-DIPROP

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

240

1997

1927

1997

53

43232
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.100 1.900 1.800 0.360 3.600 1.600

2ND MAX
5.000 1.000 0.800 0.330 2.100 1.200

ARITH. MEAN
0.550 0.322 0.403 0.020 0.225 0.148

30

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-OCTANE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1825 53 15 240
1927 53

43233
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.000 2.800 2.000 3.380 4.700 2.100

2ND MAX
2.700 2.400 1.300 0.230 1.100 1.500

ARITH. MEAN
0.376 0.269 0.333 0.022 0.162 0.129

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-NONANE AKA-NONYL H

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

240

1997

1927

1997

53

43235
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.200 0.800 0.300 0.330 4.500 4.000

2ND MAX
2.000 0.800 0.300 0.310 2.200 1.100

ARITH. MEAN
0.176 0.101 0.093 0.011 0.156 0.161

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132470001 132470001

N-DECANE SAMPLING
PERIOD
1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15
1926 53

43238
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.100 1.100 5.100 3.100 4.100

2ND MAX
3.000 1.000 3.200 2.400 0.800

ARITH. MEAN
0.218 0.166 1.147 0.158 0.168

31

SITE NAME
S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130890002 130893001 132230003 132470001 132470001

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

CYCLOPENTANE AKA-PEN

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

108

1997

1927

1997

53

ISOPRENE AKA-3-METHY

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

41

1997

1788

1997

53

43242
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
1.400 0.050 0.005 1.700 1.400

43243
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
71.70 7.800 0.900 12.01 61.50 11.40

2ND MAX
1.100 0.050 0.005 1.700 1.400

ARITH. MEAN
0.291 0.050 0.005 0.133 0.392

2ND MAX
55.80 6.900 0.800 10.72 40.40 8.800

ARITH. MEAN
7.308 1.265 0.367 3.731 5.407 1.765

SITE NAME
S. Dekalb (2) Tucker (2) Conyers (2)

SITE NUMBER
130890002 130893001 132470001

2-METHYL-1-PENTENE A

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

53

43246
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
1.500 0.050 0.700

2ND MAX
0.300 0.050 0.500

ARITH. MEAN
0.082 0.050 0.077

32

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2,4-DIMETHYLPENTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

CYCLOHEXANE AKA-HEXA

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

52

1997

15

1997

240

1997

1926

1997

53

43247
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon
43248
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.000 1.100 0.500 0.350 1.300 0.200
1ST MAX
2.300 4.100 0.300 0.380 2.200 0.300

2ND MAX
5.700 1.000 0.500 0.005 1.300 0.050

ARITH. MEAN
0.494 0.174 0.110 0.006 0.112 0.053

2ND MAX
2.200 0.500 0.050 0.260 1.900 0.200

ARITH. MEAN
0.096 0.148 0.067 0.008 0.040 0.058

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

3-METHYLHEXANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

52

43249
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.200 2.600 1.100 0.590 2.500 1.100

2ND MAX
7.600 2.400 1.000 0.540 2.000 0.900

ARITH. MEAN
0.952 0.513 0.347 0.044 0.514 0.152

33

SITE NAME
S. Dekalb (1) S. Dekalb (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 132230003 132470001 132470001

2,2,4-TRIMETHYLPENTA

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

38

1997

240

1997

1926

1997

35

43250
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
26.60 7.300 1.320 5.300 3.600

2ND MAX
25.80 6.700 1.240 4.900 2.200

ARITH. MEAN
2.998 2.050 0.110 0.836 0.570

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2,3,4-TRIMETHYLPENTA

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

52

1997

15

1997

240

1997

1926

1997

53

3-METHYLHEPTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

52

1997

15

1997

240

1997

1926

1997

53

43252
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon
43253
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.900 2.600 1.100 0.450 1.900 1.000
1ST MAX
3.100 5.700 0.300 0.290 1.700 0.500

2ND MAX
8.900 2.500 0.600 0.410 1.600 0.700

ARITH. MEAN
1.046 0.526 0.283 0.023 0.285 0.119

2ND MAX
2.900 0.700 0.050 0.200 1.100 0.400

ARITH. MEAN
0.202 0.204 0.067 0.010 0.094 0.070

34

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

METHYLCYCLOHEXANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

43261
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
4.800 0.900 0.200 0.270 2.500 1.200

2ND MAX
4.000 0.900 0.005 0.240 1.300 0.900

ARITH. MEAN
0.415 0.140 0.018 0.011 0.202 0.099

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

METHYLCYCLOPENTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

43262
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.200 2.600 0.900 0.490 1.190 1.100

2ND MAX
6.100 2.500 0.900 0.430 1.500 1.100

ARITH. MEAN
0.490 0.479 0.407 0.025 0.202 0.182

35

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2-METHYLHEXANE

SAMPLING PERIOD

NO. OF OBS.

1997

1240

1997

53

1997

15

1997

240

1997

1926

1997

53

43263
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.600 2.200 1.000 0.540 2.100 0.800

2ND MAX
6.100 2.100 0.900 0.490 1.500 0.700

ARITH. MEAN
0.671 0.366 0.293 0.019 0.280 0.091

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

1-BUTENE SAMPLING
PERIOD
1997 1997 1997 1997 1997
1997

NO. OF OBS.
1825 53 15 108
1927 53

43280
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.600 7.000
0.005 1.100 2.900

2ND MAX
3.300 6.300
0.005 1.000 2.900

ARITH. MEAN
0.651 0.705 0.010 0.005 0.297 0.271

36

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2,3-DIMETHYLBUTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

52

43284
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.800 2.200 0.800 0.430 5.700 1.500

2ND MAX
8.200 2.100 0.700 0.005 2.400 0.500

ARITH. MEAN
1.113 0.374 0.217 0.009 0.175 0.099

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2-METHYLPENTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43285
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
22.20 7.900 3.200 1.260 3.800 4.100

2ND MAX
20.20 6.800 2.900 0.690 3.000 2.400

ARITH. MEAN
2.707 1.439 1.400 0.188 0.472 0.488

37

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2,3-DIMETHYLPENTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

43291
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.100 8.600 0.800 0.710 2.000 0.700

2ND MAX
7.700 4.100 0.700 0.420 1.700 0.600

ARITH. MEAN
0.771 0.542 0.160 0.013 0.194 0.108

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

ISOPENTANE & CYCLOPE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

43341 UNITS
ppb carbon

1ST MAX
129.5

2ND MAX ARITH. MEAN

90.30

11.27

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

FORMALDEHYDE AKA-OXY

SAMPLING PERIOD

NO. OF OBS.

1997

506

43502 UNITS
ppb carbon

1ST MAX
5.140

2ND MAX ARITH. MEAN

4.880

0.863

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

ACETALDEHYDE AKA-ACE

SAMPLING PERIOD

NO. OF OBS.

1997

503

43503 UNITS
ppb carbon

1ST MAX
10.78

2ND MAX ARITH. MEAN

8.910

1.103

38

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

ACETONE AKA-DIMETHYL

SAMPLING PERIOD

NO. OF OBS.

1997

506

43551 UNITS
ppb carbon

1ST MAX
18.18

2ND MAX ARITH. MEAN

18.18

1.405

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132470001 132470001

N-UNDECANE SAMPLING
PERIOD
1997 1997 1997 1997 1997

NO. OF OBS.
1895 53 15
1926 53

43954
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.700 40.00 18.30 3.300 0.600

2ND MAX
2.700 0.700 11.20 3.100 0.600

ARITH. MEAN
0.229 0.870 3.600 0.168 0.111

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2-METHYLHEPTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

43960
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.800 0.800 0.300 0.120 3.300 0.700

2ND MAX
2.400 0.700 0.050 0.120 1.400 0.600

ARITH. MEAN
0.165 0.093 0.068 0.006 0.092 0.077

39

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132230003 132470001 132470001

M/P XYLENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15 240
1926 53

45109
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
29.70 13.60 8.100 2.790 9.000 4.700

2ND MAX
29.00 12.40 7.100 2.190 7.600 4.600

ARITH. MEAN
3.474 3.334 4.130 0.218 1.040 1.446

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

BENZENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15 240
1926 52

45201
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
21.00 8.600 4.400 1.580 5.300 6.100

2ND MAX
19.80 8.300 3.000 1.440 4.700 3.800

ARITH. MEAN
2.398 2.449 2.173 0.404 1.020 1.436

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

TOLUENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15 240
1926 53

45202
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
56.40 21.60 18.40 4.750 16.80 9.100

2ND MAX
53.60 20.60 15.60 4.390 14.00 7.800

ARITH. MEAN
6.797 5.271 10.00 0.729 2.305 2.928

40

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ETHYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45203
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.200 3.800 2.400 0.810 2.400 1.200

2ND MAX
7.500 3.400 2.200 0.720 2.100 1.200

ARITH. MEAN
1.028 0.783 1.240 0.081 0.401 0.266

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132470001 132470001

O-XYLENE SAMPLING
PERIOD
1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15
1926 53

45204
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
12.70 5.100 2.800 3.000 2.700

2ND MAX
12.20 4.700 2.500 2.800 2.100

ARITH. MEAN
1.422 1.210 1.353 0.444 0.556

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

1,3,5-TRIMETHYLBENZE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45207
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
5.400 1.800 0.800 0.420 2.200 0.600

2ND MAX
5.300 1.700 0.600 0.390 1.300 0.300

ARITH. MEAN
0.441 0.270 0.173 0.180 0.169 0.073

41

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

1,2,4-TRIMETHYLBENZE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45208
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
14.60 129.7 2.700 10.32 4.400 63.10

2ND MAX
14.60 16.30 2.000 9.900 3.900 24.00

ARITH. MEAN
1.614 5.480 1.247 7.532 0.588 3.941

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-PROPYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45209
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.500 3.100 3.300 0.230 1.000 0.900

2ND MAX
2.100 1.100 0.400 0.170 0.700 0.900

ARITH. MEAN
0.132 0.229 0.290 0.009 0.096 0.119

SITE NAME
S. Dekalb (1) S. Dekalb (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 132230003 132470001 132470001

ISOPROPYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

38

1997

240

1997

1926

1997

35

45210
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
1.900 0.050 0.005 0.500 0.050

2ND MAX
1.400 0.050 0.005 0.500 0.050

ARITH. MEAN
0.044 0.050 0.005 0.028 0.050

42

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132230003 132470001 132470001

O-ETHYLTOLUENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45211
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.500 1.400 0.500 0.350 2.100 0.400

2ND MAX
3.200 1.200 0.400 0.330 1.200 0.300

ARITH. MEAN
0.376 0.185 0.130 0.045 0.156 0.066

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132230003 132470001 132470001

M-ETHYLTOLUENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45212
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.500 4.400 1.800 0.820 1.700 1.500

2ND MAX
8.300 3.700 1.300 0.690 1.000 1.200

ARITH. MEAN
0.604 0.838 0.677 0.027 0.021 0.242

SITE NAME
S. Dekalb (2) Tucker (2) Conyers (2)

SITE NUMBER
130891002 130893001 132470001

P-ETHYLTOLUENE

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

53

45213
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
7.000 0.900 10.80

2ND MAX
4.700 0.800 10.80

ARITH. MEAN
1.251 0.287 1.556

43

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132470001 132470001

M-DIETHYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1895

1997

53

1997

15

1997

1926

1997

53

45218
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.500 0.300 1.600 0.600 0.300

2ND MAX
1.700 0.200 0.050 0.500 0.050

ARITH. MEAN
0.103 0.058 0.153 0.023 0.055

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132470001 132470001

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

P-DIETHYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1895

1997

53

1997

15

1997

1926

1997

53

STYRENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1917 51 15 240
1926 53

45219
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.500 1.500 0.700 1.500 0.700

45220
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.800 1.800 0.500 0.340 1.100 1.500

2ND MAX
3.500 1.400 0.300 1.100 0.300

ARITH. MEAN
0.322 0.228 0.110 0.114 0.072

2ND MAX
2.800 1.000 0.400 0.280 0.900 1.300

ARITH. MEAN
0.300 0.317 0.120 0.099 0.273 0.317

44

SITE NAME
S. Dekalb (2) Tucker (2) Conyers (2)

SITE NUMBER
130891002 130893001 132470001

1,2,3-TRIMETHYLBENZE

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

53

45225
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
13.10 8.300 9.200

2ND MAX
3.900 3.200 3.200

ARITH. MEAN
1.242 1.497 0.905

SITE NAME
S. Dekalb (1) Tucker (2) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

WIND SPEED SAMPLING
PERIOD
1997 1997 1997 1997

NO. OF OBS.
8674 8547 8438 8642

61101
UNITS
Knots Knots Knots Knots

1ST MAX
12.8 9.9 19.4 12.2

2ND MAX
11.5 9.9 17.3 12.0

ARITH. MEAN
2.67 2.77 5.59 2.36

SITE NAME
S. Dekalb (1) Tucker (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

OUTDOOR TEMPERATURE

SAMPLING PERIOD

NO. OF OBS.

1997

7857

1997

8549

1997

8338

1997

8535

62101
UNITS
Deg. C. Deg. C. Deg. C. Deg. C.

1ST MAX
34 35 33 35

2ND MAX
34 35 32 35

ARITH. MEAN
14.8 15.7 15.0 15.3

45

SITE NAME
S. Dekalb (1) Tucker (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

RELATIVE HUMIDITY

SAMPLING PERIOD

NO. OF OBS.

1997

8726

1997

8541

1997

7254

1997

8436

62201
UNITS
% % % %

1ST MAX
100 100 100 100

2ND MAX
100 100 100 100

ARITH. MEAN
80.1 73.4 72.8 80.3

SITE NAME
S. Dekalb (1) Tucker (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

SOLAR RADIATION

SAMPLING PERIOD

NO. OF OBS.

1997

8140

1997

8480

1997

8630

1997

8488

63301
UNITS
Lang./min Lang./min Lang./min Lang./min

1ST MAX
1.56 1.38 1.42 0.94

2ND MAX
1.54 1.38 1.42 0.92

ARITH. MEAN
0.253 0.231 0.248 0.176

SITE NAME
S. Dekalb (1) Tucker (1) Yorkville (1)

SITE NUMBER
130891002 130893001 132230003

ULTRAVIOLET RADIATION

SAMPLING PERIOD

NO. OF OBS.

1997

7903

1997

6872

1997

5147

63302
UNITS
Watts/sq m Watts/sq m Watts/sq m

1ST MAX
0.06 0.06 0.05

2ND MAX
0.06 0.06 0.05

ARITH. MEAN
0.009 0.011 0.009

46

SITE NAME
S. Dekalb (1) Tucker (2) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

BAROMETRIC PRESSURE

SAMPLING PERIOD

NO. OF OBS.

1997

8590

1997

8550

1997

8355

1997

8613

64101
UNITS
Millibars Millibars Millibars Millibars

1ST MAX
1006 994.0 991.0 1009

2ND MAX
1006 993.0 991.0 1009

ARITH. MEAN
989.9 978.7 970.2 991.9

47

PHOTOCHEMICAL ASSESSMENT MONITORING Carbonyl Compounds
Determination of ambient concentrations of carbonyl compounds is a requirement of 40 CFR Part 58, Subpart E, enhanced ozone network monitoring programs. Carbonyl compounds have been shown to contribute to the formation of photochemical ozone. Formaldehyde, acetaldehyde, and acetone are specifically required target compounds for PAMS; however, other carbonyl compounds may be added to the target list consistent with individual program objectives. The methodology used to accomplish carbonyl compounds monitoring provides sensitive and accurate measurements of carbonyl compounds and involves sample collection and analysis procedures. In this method, a cartridge(s) containing a solid sorbent is used to capture the target compounds.
48

CARBONYL DATA

ACETONE SITE NAME
S. Dekalb (1)

43551 SITE NUMBER
130891002

SAMPLING PERIOD
1997

NO. OF OBS.
506

UNITS
ppb carbon

1ST MAX
18.18

2ND MAX ARITH. MEAN

18.18

1.405

FORMALDEHYDE

43502

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

SAMPLING PERIOD
1997

NO. OF OBS.
506

UNITS
ppb carbon

1ST MAX
5.14

2ND MAX ARITH. MEAN

4.88

0.863

ACETALDEHYDE

43503

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

SAMPLING PERIOD
1997

NO. OF OBS.
503

UNITS
ppb carbon

1ST MAX
10.78

2ND MAX ARITH. MEAN

8.91

1.103

Observations are 3 hours in duration

49

Toxic Metals 1997 Monitoring Results

Toxic air pollutants are also referred to as air toxics or hazardous air pollutants (HAPs). They are generally defined as those pollutants that are known or suspected to cause serious health problems. "Routine" toxic air pollutants are emitted by a variety of industrial sources and motor vehicles. In addition to routine releases, sudden accidental air releases of toxics potentially threaten many Americans. In response to public concern over the quality of Georgia's air, the Environmental Protection Division began an ambitious project to establish, over the course of five years, twenty sites to monitor non-criteria metals which include arsenic, cadmium, chromium, nickel, and zinc. In 1997 beryllium, cobalt, lead, and selenium were added. There are six sites in six counties in the 1997 network. Currently there are no ambient standards established for these metals.

Compound

Site

Augusta Brunswick

Arsenic

Dawsonville Gainesville

Savannah Utoy Creek-co

Augusta

Brunswick

Berylium

Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Brunswick

Cadmium

Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Brunswick

Cobalt

Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Chromium

Brunswick Dawsonville Gainesville

Savannah Utoy Creek-co

Toxic Metals

ug/m3

No of Obs. 1st Max 2nd Max Mean

14

0.0083

0.006 0.004

10

0.0091

0.0066 0.0031

8

0.0057

0.005 0.0027

12

0.018

0.01 0.0047

7

0.012

0.008 0.0039

22

0.0074

0.007 0.0014

4 0.000078

0.00007 0.0002

3

0.0001 0.000021 0.0002

4

0.0005

0.0001 0.0003

4

0.0017

0.0002 0.0003

2

0.0021

0.0003 0.0006

5

0.0003

0.00023 0.0003

4

0.0084

0.0062 0.0008

1

0.0021

ND

0.0003

3

0.0032

0.0024 0.0008

2

0.0042

0.00071 0.0007

1

0.0016

ND

0.0004

11

0.0059

0.0058 0.0011

4

0.0012

0.001 0.0008

2

0.0036

0.0008 0.0008

2

0.0086

0.0016 0.0017

4

0.0023

0.0017 0.0012

2

0.0018

0.0015 0.0009

7

0.0038

0.0028 0.0014

14

0.0088

0.0071 0.0031

19

0.0044

0.004 0.0014

14

0.006

0.0052 0.0019

17

0.0062

0.0054 0.0025

17

0.034

0.013 0.0055

26

0.0091

0.0089 0.0042

50

Compound

Site

Augusta

Brunswick

Lead

Dawsonville Gainesville

Savannah Utoy Creek-co

Augusta

Brunswick

Manganese

Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Brunswick

Nickel

Dawsonville Gainesville Savannah

Utoy Creek-co

Augusta

Selenium

Brunswick Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Brunswick

Dawsonville

Zinc

Gainesville

Savannah

Utoy Creek-co

No of Obs. 18 13 10 8 10 28 12 12 10 11 9 17 7 11 8 3 13 21 12 12 10 11 9 17 23 25 22 20 19 41

1st Max 0.028
0.0078 0.0083
0.017 0.011
0.06 0.04 0.0062 0.011 0.022 0.01 0.066 0.041 0.0065 0.027 0.0028 0.0051 0.0083 0.032 0.026 0.095 0.22 0.012 0.026 0.092 0.092 0.1078 0.14 0.12 0.131

2nd Max 0.027
0.0076 0.0076 0.0071
0.01 0.0092
0.025 0.0049
0.011 0.014 0.0091 0.053 0.0045 0.004 0.0068 0.0027 0.0046 0.0066 0.027 0.024 0.089
0.14 0.048 0.021 0.089 0.085 0.074
0.12 0.059 0.116

Mean 0.011
0.0041 0.0042 0.0047 0.0064 0.0095
0.015 0.0039 0.0065 0.0085 0.0073
0.026 0.0027 0.0018 0.0025 0.0014 0.0024 0.0029
0.019 0.019 0.058 0.074 0.041 0.013 0.038 0.029 0.025 0.042 0.034 0.039

51

Compound 1,1,1-Trichloroethane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 2-Bromopentane Benzene
Chloromethane
Cyclohexane Dichlorodifluoromethane
Freon 11 Hexachlorobutadiene Methane, chlorodifluoro Methylene Chloride o-Dimethylbenzene p,m-Dimethylbenzene
Styrene Tetrachloroethylene Toluene
Trichloroethylene

Air Toxic Volatile Organic Compounds (VOC)
1997 Monitoring Results

Volatile Organic Compounds ug/m3

Site

No. of Obs. 1st Max 2nd Max

Utoy Creek-Co Gainesville gainesville Utoy Creek-Co Gainesville Augusta Dawsonville Gainesville Utoy Creek-Co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-Co Augusta Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-Co Brunswick Dawsonville Gainesville Gainesville Gainesville Brunswick Gainesville Utoy Creek-Co Utoy Creek-Co

2

24

23.5

1

15 ND

1

2.9 ND

1

2.9 ND

1

3.8 NA

4

2.6

2.2

1

1.6 ND

3

2.6

1.6

8

3.5

3.2

8

1.4

1.2

10

3.8

2.5

14

1.9

1.8

4

1.4

1.2

3

1.7

1.3

14

1.4

1.2

4

6.9

5.2

2

3.5

2.5

4

4

3.5

4

4

3

2

3.5

2.5

3

3.5

3

7

4

4

3

3.4

3.4

1

2.8 ND

1

3.9 ND

1

7.5 ND

1

2.5 NA

3

18.8

4.9

2

46.9

3.8

27

17

10.4

1

2.6 ND

Augusta Brunswick Dawsonville Gainesville Utoy Creek-Co Gainesville Utoy Creek-Co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-Co Augusta

3

4.3

3.9

1

2.2 ND

1

2.6 ND

3

5.2

3

10

6.1

5.2

2

0.9

0.2

1

8.8 ND

7

6.4

6

11

10.2

7.9

1

1.9 ND

11

7.2

4.1

4

12.8

7.2

30

10.6

10.6

1

3.2 ND

Mean
2.26 2.95 1.33 1.28
3.8 1.16 0.83 0.82
0.8 0.85 1.36 0.98 0.65 0.84 0.69 1.76 1.48 1.83 1.32 1.47 1.92 1.56 1.67 1.45 1.51 2.88
2.5 2.02 3.19 2.56 1.13
1.57 1.3
1.16 1.44 1.63 0.38 1.85 2.25 3.05
1 2.12 3.45 2.87 1.47

52

Air Toxic Volatile Organic Compounds (VOC)
1997 Monitoring Results (continued)

Compound
1,2,3-Trimethyl benzene* 1,3-Butadiene, 2-methyl-* 1-Butene * 1-Ethyl-2-Methyl Benzene* 1-Ethyl-3-Methyl Benzene* 1-Ethyl-4-Methyl Benzene* 1-Pentene* 2,2,4-Trimethylpentane* 2,2-Dimethylbutane* 2,3,4-Trimethylpentane* 2,3-Dimethylbutane* 2,3-Dimethylpentane * 2-Methyl-1,3-Butadiene * 2-methyl-1-pentene * 2-Methyl-1-Propene* 2-Methylheptane* 2-Methylhexane* 2-Methylpentane* 3-Methylhexane* 3-Methylpentane* 4-Methyl-1-Hexene* 4-Methylpentan-2-one* Acetylene* Butane* Butane, 2-methyl- * Ethane* Ethylene* Heptane * Hexane* Isobutane* Isopentane* Methylcyclohexane* Methylcyclopentane* n-Butane* n-Decane* n-Heptane* n-Hexane* n-Nonane* n-Octane* n-Pentane* n-Propylbenzene* Pentane* Propane* Propane, 2-methyl- * Propylene* trans-2-Butene* Trans-2-Pentene*

Volatile Organic Compounds ug/m3

Site

No. of Obs.

Gainesville

2

Gainesville

1

Gainesville

2

Gainesville

1

Gainesville

2

Gainesville

1

Gainesville

1

Gainesville

2

Gainesville

1

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

1

Gainesville

1

Gainesville

1

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

1

Gainesville

1

Gainesville

3

Gainesville

3

Gainesville

1

Gainesville

3

Gainesville

3

Gainesville

1

Gainesville

2

Gainesville

3

Gainesville

4

Gainesville

2

Gainesville

3

Gainesville

3

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

1

Gainesville

1

Gainesville

3

Gainesville

1

Gainesville

2

Gainesville

3

Gainesville

1

Gainesville

3

Gainesville

1

Gainesville

2

1st Max 2nd Max

0.6

0.3

1.4 NA

0.2

0.2

0.1 ND

0.9

0.7

0.8 ND

0.4 ND

1.8

1

0.5 ND

0.7

0.3

0.8

0.7

0.2

0.2

1.1

0.8

0.2 ND

1.5 ND

0.2 ND

0.6

0.3

3

1

0.8

0.5

1.9

0.6

0.4 NA

5.3

2

3.6

1.9

1.4 NA

7.9

5.5

5.5

2.3

2.4 NA

6

4.9

2.6

1.3

20.4

6.2

0.2

0.1

1.7

1

8.6

4.9

0.2

0.2

0.5

0.4

4.3

1.8

0.2 ND

0.2 ND

7.6

3.4

0.3 ND

13.3

9.1

7.8

3.2

1.2 NA

2.2

0.9

0.2 ND

0.2

0.1

Mean
0.35 1.4
0.17 0.067
0.55 0.58 0.17 0.95 0.23 0.35 0.53 0.12
1.2 0.1 3.1 0.1 0.32 1.35 0.32 0.85 0.4
3 2.3 1.4 5.36 2.93 2.4 5.45 1.53 3.7 0.15 0.89 5.2 0.15 0.32 2.05 0.1 0.13
4 0.17 11.2 4.67
1.2 1.1 0.1 0.1

53

Compound a-BHC Acenapthene
Acenapthylene
Benzo(a)anthracene Benzo(b)fluoranthene
Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Fluoranthene
Fluorene Hexachlorobenzene Indeno(1,2,3-cd)pyrene Naphthalene
Phenanthrene
Pyrene

Air Toxic Semi-Volatile Organic Compounds 1997 Monitoring Results

Semi-Volatile Organic Compounds ug/m3

Site

No. of Obs.

1st Max

Brunswick Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Augusta Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Utoy Creek-co Dawsonville Gainesville Utoy Creek-co Augusta Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Dawsonville Gainesville Savannah Utoy Creek-co Augusta Savannah Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Utoy Creek-co

1 0.00008

1 0.0003

1

0.1

3

0.15

1

0.01

2

0.06

3

0.08

8

0.2

2

0.03

1

0.04

1

0.02

3

0.03

11

0.1

1 0.0007

3

0.003

2 0.0001

2 0.00007

3 0.0002

2 0.00004

2 0.0002

6

0.002

5 0.0007

1 0.00006

2 0.00006

7 0.00009

1

0.002

5

0.005

7

0.001

4 0.0005

5

0.002

8

0.01

20

0.01

1

0.009

1

0.04

1

0.03

3

0.011

1 0.00009

1 0.0001

2 0.0003

3

0.08

9

0.2

5

0.04

12

0.07

10

0.1

24

0.26

4

0.004

6

0.003

3

0.003

4

0.004

6

0.004

13

0.2

1

0.002

5

0.005

2

0.002

1

0.02

9

0.012

2nd Max Mean

ND ND ND 0.015 ND 0.01 0.03 0.1 0.03 ND ND 0.02 0.1 ND 0.002 0.00003 0.00003 0.00009 0.00003 0.0002 0.0005 0.0007 ND 0.00003 0.00009 ND 0.0008 0.001 0.0002 0.001 0.002 0.005 ND ND ND 0.007 ND ND 0.0003 0.05 0.05 0.03 0.06 0.07 0.23 0.003 0.003 0.003 0.003 0.004 0.02 ND 0.002 0.001 ND 0.005

0.00002 0.00002
0.01 0.01 0.007 0.008 0.01 0.02 0.004 0.008 0.007 0.009 0.02 0.0004 0.0006 0.00002 0.00002 0.00003 0.00001 0.00003 0.0001 0.0001 0.00001 0.00002 0.00002 0.0004 0.0006 0.0002 0.0001 0.0003 0.0007 0.001 0.002 0.0031 0.002 0.002 0.00004 0.00004 0.0001 0.02 0.02 0.01 0.03 0.02 0.07 0.001 0.0007 0.0007 0.001 0.001 0.006 0.0003 0.0008 0.0005 0.001 0.001

54

Acid Precipitation 1998 Network

Acid precipitation was monitored in 6 counties in 1998. The Air Protection Branch operated 3 of these sites and the Georgia Forestry Commission and University of Georgia operated the remainder. There are no national or state standards for acid precipitation. A fiveyear analysis reveals no obvious trends.

Site Hiawassee Summerville Dawsonville McDuffie Co. Athens Eatonton

Acid Precipitation Weighted Average

Reported as pH

1994 - 1998

1994

1995

1996

1997

4.55

4.73

4.55

4.53

4.52

4.62

4.62

4.52

4.62

4.71

4.58

4.70

4.86

4.95

4.49

4.49

4.67

4.63

4.55

4.59

4.69

4.64

4.63

4.70

1998 4.73 4.62 4.65 4.90 4.58 4.70

pH

5.60 5.40 5.20 5.00 4.80 4.60 4.40 4.20

Natural Rainfall
1994 1995

1996 Year

1997

1998

Hiawassee Summerville Dawsonville McDuffie Co. Athens Eatonton

55

Units: parts per million

State of Georgia Oxides of Nitrogen

Site ID
130890002 130893001 131210048 132230003 132470001

City
Decatur Tucker Atlanta Yorkville Conyers

County
DeKalb DeKalb Fulton Paulding Rockdale

Site Name
South DeKalb Idlewild Road Ga. Tech. King Farm Monastery

Number Measured (hours) 3690 5799 5953 8059 8197

1st Max
0.501 0.387 0.484 0.091 0.169

Annual Arithmetic Mean
0.073 0.022 0.047 0.008 0.011

56

State of Georgia Nitric Oxide

Units: parts per million

Site ID
130890002 130893001 131210048 132230003 132470001

City
Decatur Tucker Atlanta Yorkville Conyers

County
DeKalb DeKalb Fulton Paulding Rockdale

Site Name
South DeKalb Idlewild Road Ga. Tech. King Farm Monastery

Number Measured (hours) 3691 5799 5973 8060 8197

1st Max
0.487 0.382 0.500 0.063 0.136

Annual Arithmetic Mean
0.055 0.009 0.027 0.005 0.007

57

State of Georgia Reative Oxides of Nitrogen

Units: parts per million

Site ID
130890002 130893001 132470001

City
Decatur Tucker Conyers

County
DeKalb DeKalb Rockdale

Site Name
South DeKalb Idlewild Road Monastery

Number Measured (hours) 554 2792 5039

1st Max
0.200 0.200 0.120

Annual Arithmetic Mean
0.043 0.037 0.012

58

Appendix " A"

TYPES OF SAMPLING METHODS

LEAD (Manual) Samples are collected on 8" x 10" pre-weighed fiberglass filters with a high-volume sampler for 24 hours. Atomic absorption analysis is then performed on the samples SULFUR DIOXIDE (Continuous) Continuous analysis for sulfur dioxide is accomplished with the use of pulsed fluorescence (U.V. Light) method. NITROGEN DIOXIDE (Continuous) Continuous analysis for nitrogen dioxide is accomplished with the use of ozone phase chemiluminescent method. CARBON MONOXIDE (Continuous) Continuous analysis for carbon monoxide is accomplished with the use of non-dispersive infrared analysis and gas filter correlation methods
OZONE (Continuous) Continuous analysis for ozone is accomplished with the use of U.V. photometric method
PARTICULATE MATTER 10 MICRON (PM-10) Samples are collected on microquartz fiber filters with a PM-10 sampler for 24 hours. Gravimetric analysis is performed on all samples after collection
NITRIC OXIDE Continuous analysis for nitric oxide is accomplished with the use of ozone phase chemiluminescent method.
OXIDES OF NITROGEN Continuous analysis for oxides of nitrogen is accomplished with the use of ozone phase chemiluminescent method. (method number 074)

59

ACID PRECIPITATION Samples are collected weekly and analyzed gravimetrically and also for acidity and conductivity. Further analyses are performed for selected compounds. VOC ANALYSIS During June, July, and August samples are analyzed hourly using a gas chromatography unit using a Flame Ionization Detector (FID). Throughout the year a 24 hour integrated sample is taken and analyzed in a State Laboratory. CARBONYL During July and August samples are taken for three hours and analyzed at a State Laboratory. Throughout the year a 24 hour integrated sample is taken and analyzed in a State Laboratory.
60

Appendix " B "
AM AQCR ARITH MEAN CO EPA GEO MEAN Pb NO Nox NO2 NUM OBS O3 PM-10
PPM QTR SO2 TSP
g/M3 UV

ABBREVIATIONS
Annual mean Air Quality Control Region Arithmetic mean Carbon monoxide Environmental Protection Agency Geometric Mean Lead Nitric Oxide Oxides of nitrogen Nitrogen Dioxide Number of observations Ozone Particles with an aerodynamic diameter of 10 microns or less Parts Per Million Calendar quarter Sulfur dioxide Total Suspended particulate Micrograms per Cubic Meter Ultraviolet

61

REFERENCES: http://www.epa.gov/oar/aqtrnd97/brochure/pb.html http://www.epa.gov/ttn/uatw/basicfac.html [Code of Federal Regulations] [Title 40, Volume 2, Parts 50 to 51] [Revised as of July 1, 1998] Measuring Air Quality: The Pollutant Standards Index; Office of Air Quality Planning and Standards, US EPA; EPA 451/K-94-001; February 1994.
62

GEORGIA DEPARTMENT OF NATURAL RESOURCES
ENVIRONMENTAL PROTECTION DIVISION
Air Protection Branch
1998 Ambient Air Surveillance Report 1997 PAMS Network 1997 Toxic Network

2

TABLE OF CONTENTS
Georgia Ambient Air Standards 1998 Georgia Air Sampling Network
Criteria Pollutants
PM-10 Sulfur Dioxide (SO2 ) Ozone (O3 ) Carbon Monoxide ( CO ) Nitrogen Dioxide ( NO2 ) Lead ( Pb )
Non-Criteria Pollutants
PAMS PAMS Carbonyl Air Toxics METALS Air Toxics VOC'S Air Toxics SEMI-VOC'S Acid Precipiatation Oxides of Nitrogen ( NOx ) Nitric Oxide ( NO ) Reactive Oxides of Nitrogen

PAGE 6 7
9 12 14 17 19 21
23 48 50 52 54 55 56 57 58

3

APPENDICIES

Types of Sampling Methods ( Appendix A )

59

Abbreviations ( Appendix B )

61

4

Ambient Air Monitoring Ambient air monitoring in Georgia provides information on measured concentrations of criteria and non-criteria pollutants at selected locations. Criteria pollutants are those which a standard has been adopted by the U.S. Environmental Protection Agency. Non-criteria pollutants, while having no standard, provide useful information on the quality and content of ambient air.
The current Georgia Air Sampling Network (G.A.S.N.), is comprised of 58 monitors at 46 locations in 23 counties. Monitoring takes place year round with the exception of ozone, which is sampled from April through October.
The monitoring network is composed of State and Local Air Monitoring Stations (SLAMS), National Air Monitoring Stations (NAMS), Special Purpose Monitoring (SPM), and Photochemical Assessment Monitoring Stations (PAMS). During 1996 the network contained 14 NAMS, 25 SLAMS, 19 SPM stations and 4 PAMS stations.
The number and location of the individual sites vary from year to year, depending on a variety of reasons that include: availability of long term space allocation; citizen complaint; regulatory need; etc. Once the site is established, it is our intention to monitor for long term trends.
In general, the basic monitoring objectives that govern the selection of sites are: 1) to determine the highest concentration expected to occur; 2) to determine representative concentrations in areas of high population density; 3) to determine the impact on ambient pollution levels of significant sources or source categories; 4) to determine the general background concentration levels; and 5) to determine the concentration of a number of compounds which may aid in the generation of ground level ozone.
5

GEORGIA AMBIENT AIR STANDARDS SUMMARY Criteria Pollutants

Compound Sulfur Dioxide
Particulate Matter (PM-10)

Standard 0.50 0.14 0.03
50.0
150.0

Units ppm
micrograms per cubic meter

Time Interval 3 Hour 24 Hour
Annual Mean Annual Arithmetic
Mean
24 Hour

Carbon Monoxide Ozone
Nitrogen Dioxide

35.0 9.0 0.125 0.85 .05

ppm ppm ppm

1 Hour
8 Hour Average
1 Hour
(Atlanta 13 County Non-Attainment Area)
8 Hour Average
(4th Max)
Statewide
Annual Mean

Lead

1.5

micrograms per Calendar Quarter

cubic meter

Average

6

1998 GEORGIA AIR MONITORING NETWORK
7

STATE OF GEORGIA 1998 AMBIENT AIR MONITORING NETWORK
FOR CRITERIA POLLUTANTS

SITE ID
130090001 130150002 130210007
130210012
130510019 130510014
130510021
130511002
130550001 130850001 130891002
130890002
130890003 130892001
130893001
130950006 130950007 130970003 130970004 131110094 131110091 131130001 131150003 131150005 131210001 131210032 131210039

CITY
Milledgeville Stilesboro
Macon
Port Wentworth
Savannah
Summerville Dawsonville Clarkston
Decatur
Doraville Tucker
Albany
Douglasville Cohutta Wilderness McCaysville Fayetteville Rome

131210048 Atlanta

131210055
131210099 131270004 131270006 131350002 132150008 132150009 132150010
132150011
132151003
132230003
132450003
132450091

Brunswick Lawrenceville
Columbus
Yorkville Augusta

132470001
132550002 132611001 132950002 133030001

Conyers
Griffin Leslie Rossville Sandersville

COUNTY
Baldwin Bartow Bibb
Chatham
Chattooga Dawson
DeKalb
Dougherty Douglas Fannin Fayette Floyd
Fulton
Glynn Gwinnett
Muscogee
Paulding Richmond Rockdale Spalding Sumpter W alker W ashington

SITE NAME
Baldwin County Airport Stilesboro Allied Chemical
Macon SE
Farmers Market Shuman Jr. High School
E. President St.
W. Lathrop & Augusta Ave.
DNR Fish Hatchery Forestry Commission DeKalb Tech.
South DeKalb
D.M.R.C. Health Center
Idlewild Road
Dougherty Middle School Turner Elementary Sch. Beulah Pump Station Douglas Co. Water Auth. Jacks River Road McCaysville Elem. School DOT Coosa Elementary School Coosa High School Fulton Co. Health Dept. E. Rivers School Fire Station # 8
GA. Tech
Confederate Ave.
Roswell Road Arco Pump Station Risley Middle School Gwinnett Tech. Airport S.E. Site Fort Benning Junction
Cussetta Road School
Crime Lab
King Farm
Regional YDC.
Bungalow Road School
Monastery
UGA Experiment Station Community Center Health Center Heath Center

POLLUTANT
Sulfur Dioxide Sulfur Dioxide PM-10 Ozone Sulfur Dioxide Sulfur Dioxide PM-10 Ozone Sulfur Dioxide PM-10 Sulfur Dioxide PM-10 Ozone Carbon Monoxide Ozone Nitrogen Dioxide Lead PM-10 Ozone Nitrogen Dioxide Sulfur Dioxide PM-10 PM-10 Ozone Ozone Sulfur Dioxide Ozone Sulfur Dioxide PM-10 PM-10 PM-10 PM-10 PM-10 Sulfur Dioxide Nitrogen Dioxide Ozone Sulfur Dioxide Carbon Monoxide PM-10 Ozone Ozone Ozone Lead Lead PM-10 Lead Ozone Ozone Nitrogen Dioxide Sulfur Dioxide Ozone PM-10 Ozone Nitrogen Dioxide PM-10 Ozone PM-10 PM-10

8

PARTICULATE MATTER (PM-10)
Sources: Particulate matter (PM) is solid matter or liquid droplets from smoke, dust, fly ash, or condensing vapors that can be suspended in the air for long periods of time. It represents a broad class of chemically diverse particles that range in size from molecular clusters of 0.005 micrometers (m) to coarse particles of 50-100 m in diameter (100 m is about the thickness of an average human hair). PM results from all types of combustion. The carbon-based particles that result from incomplete burning of diesel fuel in buses, trucks and cars are of particular concern. Another important combustion source is the burning of wood in stoves and fireplaces in residential settings. Also of concern are the sulfate and nitrate particles that are formed as a byproduct of SO2 and NO2 emissions, primarily from fossil fuel-burning power plants and vehicular exhausts.
The U.S. national ambient air quality standard was originally based on particles up to 25-45 m in size, termed "total suspended particles" (TSP). In 1987, EPA replaced TSP with an indicator that includes only those particles smaller than 10 m, termed PM10. These smaller particles cause most of the adverse health effects because of their ability to penetrate deeply into the lungs. Health effects. The observed human health effects of PM include breathing and respiratory symptoms, aggravation of existing respiratory and cardiovascular disease, alterations in the body's defense system against inhaled materials and organisms, and damage to lung tissue. Groups that appear to be most sensitive to the effects of PM include individuals with chronic lung or cardiovascular disease, individuals with influenza, asthmatics, elderly people, and children.
Health Effects: Marked increases in daily mortality have been statistically associated with very high 24-hour concentrations of PM10, with some increased risk of mortality at lower concentrations. Small increases in mortality appear to exist at even lower levels. Risks to sensitive individuals increase with consecutive, multi-day exposures to elevated PM concentrations. The research also indicates that aggravation of bronchitis occurs with elevated 24-hour PM10 levels, and small decreases in lung function take place when children are exposed to lower 24-hour peak PM10 levels. Lung function impairment persists for 2-3 weeks following exposure to PM.
National Primary and Secondary Ambient Air Quality Standards for Particulate Matter.
(a) The annual primary and secondary PM-10 standards are met when the annual arithmetic mean concentration, as determined in accordance with appendix N of this part, is less than or equal to 50 micrograms per cubic meter. (b) The 24-hour primary and secondary PM-10 standards are met when the 99th percentile 24-hour concentration, is less than or equal to 150 micrograms per cubic meter. [62 FR 38711, July 18, 1997]
9

Units: micrograms per cubic meter

Site ID

City

County

130210007 Macon

Bibb

STATE OF GEORGIA PARTICULATE MATTER (PM-10) 1ST MAX & ANNUAL ARITHMETIC MEAN

Site Name Allied Chem.

Number Measured
(days)
61

1st Max 60

# Values > 150

Annual

#

Arithmetic Values

Mean

> 50

0

30

0

130510014 Savannah Chatham

Shuman Sch

53

130511002 Savannah Chatham

Lathrop & Augusta

162

130550001 Summerville Chattooga

Fish Hatchery

55

76

0

88

0

115

0

26

0

31

0

24

0

130892001 Doraville

DeKalb

Health Center

56

58

0

30

0

130950007 Albany

Dougherty

Turner Sch.

48

130970003 Douglasville Douglas

Beulah Pump Station

60

131150005 Rome

Floyd

Coosa High School

45

66

0

60

0

70

0

28

0

22

0

24

0

10

Site ID

City

County

131210001 Atlanta

Fulton

131210032 Atlanta

Fulton

131210039 Atlanta

Fulton

131210048 Atlanta

Fulton

131270004 Brunswick Glynn

132150011 Columbus Muscogee

132450091 Augusta

Richmond

132550002 Griffin

Spalding

132950002 Rossville

Walker

Site Name
Fulton Co. Health Dept.
E. Rivers School
Fire Station # 8

Number Measured
(days) 54
49
59

Ga. Tech.

183

Arco Pump Station

49

Cussetta Rd. School

57

Bungalow Rd. School

51

UGA

Experiment

59

Station

Health Dept.

50

1st Max 56

# Values > 150

Annual

#

Arithmetic Values

Mean

> 50

0

28

0

64

0

25

0

73

0

31

0

80

0

30

0

134

0

33

0

54

0

23

0

68

0

28

0

55

0

24

0

55

0

25

0

133030001 Sandersville Washington Health Center

60

110

0

29

0

11

SULFUR DIOXIDE
Sources: Sulfur dioxide (SO2) is a colorless reactive gas that is ordorless at low concentrations, but pungent at very high concentrations. It is emitted primarily when fossil fuels and ores that contain sulfur are burned or processed. Major sources of SO2 are fossil fuel-burning power plants and industrial boilers.
Health Effects: Exposure to SO2 can cause impairment of respiratory function, aggravation of existing respiratory disease (especially bronchitis), and a decrease in the ability of the lungs to clear foreign particles. It can also lead to increased mortality, especially if elevated levels of particulate matter (PM) are also present. Groups that appear most sensitive to the effects of SO2 include asthmatics and other individuals with hyperactive airways, and individuals with chronic obstructive lung or cardiovascular disease. Elderly people and children are also likely to be sensitive to SO2.
Effects of short-term peak exposures have been evaluated in controlled human exposure studies. These studies show that SO2 generally increases airway resistance in the lungs, and can cause significant constriction of air passages in sensitive asthmatics. These impacts have been observed in subjects engaged in moderate to heavy exercise while exposed to relatively high peak concentrations. These changes in lung function are accompanied by perceptible symptoms such as wheezing, shortness of breath, and coughing in these sensitive groups.
The presence of PM appears to aggravate the impact of SO2 pollution. Several studies of chronic effects have found that people living in areas with high PM and SO2 levels have a higher incidence of respiratory illnesses and symptoms than people living in areas without such a synergistic combination of pollutants.
National Primary Ambient Air Quality Standards for Sulfur Oxides (Sulfur Dioxide).
(a) The level of the annual standard is 0.030 parts per million (ppm), not to be exceeded in a calendar year. The annual arithmetic mean shall be rounded to three decimal places (fractional parts equal to or greater than 0.0005 ppm shall be rounded up).
(b) The level of the 24-hour standard is 0.14 parts per million (ppm), not to be exceeded more than once per calendar year. The 24-hour averages shall be determined from successive nonoverlapping 24-hour blocks starting at midnight each calendar day and shall be rounded to two decimal places (fractional parts equal to or greater than 0.005 ppm shall be rounded up).
(c) Sulfur oxides shall be measured in the ambient air as sulfur dioxide by the reference method described in appendix A to this part or by an equivalent method designated in accordance with part 53 of this chapter.
(d) To demonstrate attainment, the annual arithmetic mean and the second-highest 24hour averages must be based upon hourly data that are at least 75 percent complete in each calendar quarter. A 24-hour block average shall be considered valid if at least 75 percent of the hourly averages for the 24-hour period are available. In the event that only 18, 19, 20, 21, 22, or 23 hourly averages are available, the 24-hour block average shall be computed as the sum of the available hourly averages using 18, 19, etc. as the divisor. If fewer than 18 hourly averages are available, but the 24-hour average would exceed the level of the standard when zeros are substituted for the missing values, subject to the rounding rule of paragraph (b) of this section, then this shall be considered a valid 24-hour average. In this case, the 24-hour block average shall be computed as the sum of the available hourly averages divided by 24. [61 FR 25579, May 22, 1996]
12

STATE OF GEORGIA SULFUR DIOXIDE
24 & 3 HOUR MAXIMUM OBSERVATIONS

Units: parts per million

Site ID 130090001 130150002 130210012 130510019
130510021
130511002
130950006 131110091 131150003 131210048 131210055 132450003

City
Milledgeville Stilesboro Macon Port Wentworth Savannah
Savannah
Albany McCaysville Rome Atlanta Atlanta Augusta

County Baldwin Bartow Bibb Chatham
Chatham
Chatham
Dougherty Fannin Floyd Fulton Fulton Richmond

Site Name
Airport Stilesboro Forestry Farmer's Market E. President St. Lathrop & Augusta Dougherty Middle Sch. Elem. School Coosa Elem. Sch. GA Tech Confederate Ave. YDC

# Obs. (hours)
8314 8335 8661 7703
8651
3502
8324 8551 8697 7591 8224 7962

Max 24 - Hour

1st

2nd

0.016

0.015

0.015

0.014

0.019

0.019

0.012

0.010

0.030

0.027

0.001

0.001

0.007 0.061 0.016 0.033 0.018 0.021

0.006 0.052 0.016 0.019 0.016 0.011

Obs > Std.
0 0 0 0
0
0
0 0 0 0 0 0

Max 3 - Hour

1st

2nd

0.075

0.066

0.160

0.069

0.052

0.039

0.037

0.037

0.142

0.061

0.001

0.001

0.028 0.127 0.091 0.118 0.063 0.040

0.021 0.115 0.072 0.062 0.042 0.036

Obs > Std.
0 0 0 0
0
0
0 0 0 0 0 0

13

OZONE
Sources: Ozone (O3), a colorless gas, is the major constituent of smog. It is produced by the chemical reaction of nitrogen dioxide with reactive organic substances such as hydrocarbons in automobile exhaust or vapors from cleaning solvents - in the presence of sunlight. This type of pollution first gained attention in the 1940's as Los Angeles "smog." Since then, photochemical smog has been observed frequently in many cities as well. (Note: In the upper atmosphere, naturally occurring ozone is beneficial in protecting us from the harmful solar rays.) Health Effects: Ozone and other photochemical oxidants such as peroxyacyl nitrates and aldehydes are associated with health effects in humans. Peroxyacyl nitrates and aldehydes cause the irritation that is characteristic of photochemical pollution. Ozone has a greater impact on the respiratory system, where it irritates the mucous membranes of the nose, throat and airways; ninety percent of the ozone inhaled into the lungs is never exhaled. Symptoms associated with exposure include cough, chest pain, and throat irritation. Ozone can also increase susceptibility to respiratory infections. In addition, ozone impairs normal functioning of the lungs and reduces the ability to perform physical exercise. Recent studies also suggest that even at lower ozone concentrations some healthy individuals engaged in moderate exercise for 6 to 8 hours may experience symptoms. All of these effects are more severe in individuals with sensitive respiratory systems, and studies show that moderate levels may impair the ability of individuals with asthma or respiratory disease to engage in normal daily activities. The potential chronic effects of repeated exposure to ozone are of even greater concern. Laboratory studies show that people exposed over a 6 to 8 hour period to relatively low ozone levels develop lung inflammation. Animal studies suggest that if exposures are repeated over a long period (e.g. months, years, lifetime), inflammation of this type may lead to permanent scarring of lung tissue, loss of lung function, and reduced lung elasticity. Air Quality Levels: EPA recently revised the ozone standard for areas of the state which are outside the Atlanta non-attainment area. For these areas, the 1-hour ozone standard was replaced with an 8-hour average ozone standard. The air quality standard for ozone, which is designed to protect public health with an adequate margin of safety, is 0.08 ppm, averaged over eight hours. EPD is required to issue a public alert when ozone levels reach 0.12 ppm, a public warning when ozone levels reach 0.40 ppm, and a declaration of public emergency at 0.50 ppm. The significant harm level, at which serious and widespread health effects occur among the general population, is 0.60 ppm of ozone, averaged over two hours.
14

UNITS: PARTS PER MILLION

Site ID 130890002 130893001 130970004
131130001
131210055 131350002 132230003 132470001

City Decatur Tucker Douglasville
Fayetteville
Atlanta Lawrenceville Yorkville Conyers

County DeKalb DeKalb Douglas
Fayette
Fulton Gwinnett Paulding Rockdale

STATE OF GEORGIA OZONE
1 HR AVERAGES

Site Name
So. DeKalb Idlewild Road Douglas Co. Water Authority Dept. of Transportation Confederate Ave. Gwinnett Tech. King Farm Monastery

Number Measured (days) 159 176
212
213
207
190 212 214

1st Max 0.166 0.135 0.157
0.149
0.158 0.142 0.157 0.140

2nd Max 0.142 0.134 0.133
0.141
0.157 0.139 0.138 0.134

# of Values > 0.12 5 6 8
7
11 4 3 6

15

Site ID

City

County

130210012
130510021
130850001 130890002 130893001 130970004

Macon
Savannah
Dawsonville Decatur Tucker Douglasville

Bibb
Chatham
Dawson DeKalb DeKalb Douglas

131110094 Cohutta

Fannin

131130001
131210055
131270006 131350002 132150008 132151003 132230003
132450091
132470001
132611001

Fayetteville
Atlanta
Brunswick Lawrenceville Columbus Columbus Yorkville
Augusta
Conyers
Leslie

Fayette
Fulton
Glynn Gwinnett Muscogee Muscogee Paulding
Richmond
Rockdale
Sumpter

STATE OF GEORGIA OZONE
8 HR AVERAGES

Site Name
Forestry Comm. E. President Street Forestry Comm. S. DeKalb Idlewild Road Douglas Co. Water Authority Cohutta Wilderness Area Dept. of Transportation Confederate Ave. Risley School Gwinnett Tech. Airport Crime Lab King Farm Bungalow Road School Monastery Union High School

Number Measured
(days) 201
212
214 159 176 212
214
213
207 183 190 199 210 212 213 214 213

1st Max
0.110
0.080
0.102 0.117 0.114 0.141
0.093
0.126
0.138 0.101 0.116 0.102 0.104 0.123 0.116 0.120 0.090

2nd Max
0.108
0.080
0.099 0.115 0.113 0.116
0.088
0.114
0.134 0.092 0.112 0.097 0.095 0.122 0.108 0.118 0.084

3rd Max
0.106
0.078
0.098 0.113 0.112 0.115
0.086
0.112
0.130 0.083 0.111 0.095 0.094 0.112 0.100 0.118 0.083

4th Max

# of 4th Max Values $ 0.085

0.106

18

0.075

0

0.096

12

0.112

21

0.111

19

0.110

35

0.081

3

0.111

34

0.126

41

0.082

2

0.111

27

0.091

8

0.089

8

0.104

26

0.099

13

0.113

38

0.081

1

16

CARBON MONOXIDE Sources: Carbon Monoxide (CO) is an odorless, colorless gas that is a by-product of the incomplete burning of fuels. Industrial processes contribute to CO pollution levels, but the principal source of CO pollution in most large urban areas is the automobile. Cigarettes and other sources of incomplete burning in the indoor environment also produce CO. CO is inhaled and enters the blood stream; there it binds chemically to hemoglobin, the substance that carries oxygen to the cells, thereby reducing the amount of oxygen delivered to all tissues of the body. The percentage of hemoglobin inactivated by CO depends on the amount of air breathed, the concentration of CO in air, and length of exposure; this is indexed by the percentage of carboxyhemoglobin found in the blood. Health Effects: CO weakens the contractions of the heart, thus reducing the amount of blood pumped to various parts of the body and, therefore, the oxygen available to the muscles and various organs. In a healthy person, this effect significantly reduces the ability to perform physical exercises. In persons with chronic heart diseases, these effects can threaten the overall quality of life, since their systems are unable to compensate for the decrease in oxygen. CO pollution is also likely to cause such individuals to experience angina during exercise. Adverse effects have also been observed in individuals with heart conditions who are exposed to CO pollution in heavy freeway traffic for 1 to 2 hours or more. In addition, fetuses, young infants, pregnant women, elderly people, and individuals with anemia or emphysema are likely to be more susceptible to the effects of CO. For these individuals, the effects are more pronounced when exposure takes place at high altitude locations, where oxygen concentration is lower. CO can also affect mental function, visual activity, and alertness of healthy individuals, even at relatively low concentrations. Air Quality Levels: The air quality standard for CO, which is designed to protect public health with an adequate margin of safety, is 9 parts per million, averaged over 8 hours. EPD is required to issue a public alert when CO levels reach 15 ppm, a public warning when CO levels reach 30 ppm, and a public declaration of emergency at the level of 40 ppm. The significant harm level, at which serious and widespread health effects occur to the general population, is 50 ppm of CO.
17

Units: parts per million

SITE ID 130891002 131210099

City County Clarkston DeKalb Atlanta Fulton

Site Name
DeKalb Tech Roswell Road

STATE OF GEORGIA CARBON MONOXIDE 1 & 8 HOUR OBSERVATIONS

# Observations (hours) 8433
8641

Max 1 - Hour

1st

2nd

6.4

4.8

5.1

5.0

Obs. > 35 0 0

Max 8 -Hour

1st

2nd

4.1

4.1

3.1

3.1

Obs. > 9 0 0

18

NITROGEN DIOXIDE
Sources: Nitrogen dioxide (NO2) is a light brown gas that can become an important component of urban haze. Nitrogen oxides usually enter the air as the result of high-temperature combustion processes, such as those occurring in automobiles and power plants. NO2 plays an important role in the atmospheric reactions that generate ozone. Home heaters and gas stoves also produce substantial amounts of NO2.
Health Effects: Healthy individuals experience respiratory problems when exposed to high levels of NO2 for short durations (less than three hours). Asthmatics are especially sensitive, and changes in airway responsiveness have been observed in some studies of exercising asthmatics exposed to relatively low levels of NO2. Studies also indicate a relationship between indoor NO2 exposures and increased respiratory illness rates in young children, but definitive results are still lacking. Many animal studies suggest that NO2 impairs respiratory defense mechanisms and increases susceptibility to infection.
Several studies also show that chronic exposure to relatively low NO2 pollution levels may cause structural changes in the lungs of animals. These studies suggest that chronic exposure to NO2 could lead to adverse health effects in humans, but specific levels and durations likely to cause such effects have not yet been determined.
National Primary and Secondary Ambient Air Quality Standards for Nitrogen Dioxide
(a) The level of the national primary ambient air quality standard for nitrogen dioxide is 0.053 parts per million (100 micrograms per cubic meter), annual arithmetic mean concentration. (b) The level of national secondary ambient air quality standard for nitrogen dioxide is 0.053 parts per million (100 micrograms per cubic meter), annual arithmetic mean concentration. (c) The levels of the standards shall be measured by:
(1) A reference method based on appendix F and designated in accordance with part 53 of this chapter, or (2) An equivalent method designated in accordance with part 53 of this chapter. (d) The standards are attained when the annual arithmetic mean concentration in a calendar year is less than or equal to 0.053 ppm, rounded to three decimal places (fractional parts equal to or greater than 0.0005 ppm must be rounded up). To demonstrate attainment, an annual mean must be based upon hourly data that are at least 75 percent complete or upon data derived from manual methods that are at least 75 percent complete for the scheduled sampling days in each calendar quarter. [50 FR 25544, June 19, 1985]
19

State of Georgia Nitrogen Dioxide Annual Arithmetic Means

Units: parts per million

Site ID
130890002 130893001 131210048 132230003 132470001

City
Decatur Tucker Atlanta Yorkville Conyers

County
DeKalb DeKalb Fulton Paulding Rockdale

Site Name
South DeKalb Idlewild Road Ga. Tech. King Farm Monastery

Number Measured (hours) 3691 5798 7886 8060 8196

Annual Arithmetic Mean
0.020 0.016 0.024 0.006 0.042

# of Values > 0.053 0 0 0 0 0

20

LEAD
Nature and Sources of the Pollutant: In the past, automotive sources were the major contributor of Pb emissions to the atmosphere. As a result of EPA's regulatory efforts to reduce the content of Pb in gasoline, the contribution from the transportation sector has declined over the past decade. Today, metals processing is the major source of Pb emissions to the atmosphere. The highest air concentrations of Pb are found in the vicinity of nonferrous and ferrous smelters, and battery manufacturers. Health and Environmental Effects: Exposure to Pb occurs mainly through inhalation of air and ingestion of Pb in food, water, soil, or dust. It accumulates in the blood, bones, and soft tissues. Lead can adversely affect the kidneys, liver, nervous system, and other organs. Excessive exposure to Pb may cause neurological impairments, such as seizures, mental retardation, and behavioral disorders. Even at low doses, Pb exposure is associated with damage to the nervous systems of fetuses and young children, resulting in learning deficits and lowered IQ. Recent studies also show that Pb may be a factor in high blood pressure and subsequent heart disease. Lead can also be deposited on the leaves of plants, presenting a hazard to grazing animals. Air Quality Levels: National primary and secondary ambient air quality standards for lead and its compounds, measured as elemental, are: 1.5 micrograms per cubic meter, maximum arithmetic mean averaged over a calendar quarter. (Secs. 109, 301(a) Clean Air Act as amended (42 U.S.C. 7409, 7601(a))) [43 FR 46258, Oct. 5, 1978]
21

STATE OF GEORGIA LEAD
QUARTERLY COMPOSITE AVERAGES

UNITS: MICROGRAMS PER CUBIC METER

Site ID

City

County

130890003 132150009
132150010

Atlanta Columbus
Columbus

DeKalb Muscogee
Muscogee

132150011 Columbus Muscogee

Site Name
D.M.R.C. S.E. Site Ft. Benning Jct. Cussetta School

Number Observations
(months) 12 12
12

1st Quarter Composite
Avg. 0.01 0.53
0.22

2nd Quarter Composite
Avg. 0.01 0.31
0.19

12

0.06

0.03

3rd Quarter Composite
Avg. 0.01 0.22
0.29
0.05

4th Quarter Composite
Avg. 0.01 0.58
0.22
0.16

# of Values > 1.50 ug/M3 0 0
0
0

22

PAMS The Environmental Protection Agency (EPA) has revised the ambient air quality surveillance regulations in Title 40 Part 58 of the Code of Federal Regulations (40 CFR Part 58) to include provisions for enhanced monitoring of ozone, oxides of nitrogen, volatile organic compounds (VOCs), selected carbonyl compounds, and monitoring of meteorological parameters. The revisions require States to establish Photochemical Assessment Monitoring Stations (PAMS) as part of their existing State Implementation Plan (SIP) monitoring networks in ozone non-attainment areas classified as serious, severe, or extreme. The principal reasons for requiring the collection of additional ambient air pollutant and meteorological data are the lack of successful attainment of the National Ambient Air Quality Standard (NAAQS) for ozone, and the need to obtain a more comprehensive air quality data base for ozone and its precursors. Analysis of the data will help the EPD understand the underlying causes of ozone pollution, devise effective controls, and measure improvement.
23

SITE NAME
S. Dekalb (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 132230003 132470001

PINENE/P-ETHYLTOLUEN

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

240

1997

1926

43188
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
7.600 1.960 5.800

2ND MAX
7.100 1.740 5.700

ARITH. MEAN
1.255 0.439 1.254

SITE NAME
S. Dekalb (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 132230003 132470001

BPINENE/1,2,3- TRIME

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

240

1997

1926

43189
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
10.20 3.940 11.80

2ND MAX
9.300 3.840 11.30

ARITH. MEAN
1.806 0.876 2.162

24

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ETHANE AKA-METHYLMET

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

107

1997

1927

1997

53

43202
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
24.10 80.00 8.500 5.980 13.20 18.40

2ND MAX
23.00 20.90 5.500 5.620 12.90 14.80

ARITH. MEAN
5.620 7.354 2.780 2.895 4.602 4.673

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ETHYLENE AKA-ETHENE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43203
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
32.40 23.10 6.090 0.005 6.900 10.20

2ND MAX
31.10 21.80 2.600 0.005 5.700 7.400

ARITH. MEAN
4.442 4.542 1.772 0.005 1.080 2.079

25

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

PROPANE AKA-DIMETHYL

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43204
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
46.50 50.00 7.000 10.10 28.00 15.00

2ND MAX
42.40 24.70 5.900 9.230 14.50 12.50

ARITH. MEAN
6.371 6.550 2.067 3.007 3.494 4.094

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

PROPYLENE AKA-PROPEN

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43205
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
16.60 8.000 1.500 0.005 3.200 1.700

2ND MAX
15.90 8.000 1.500 0.005 3.200 1.700

ARITH. MEAN
2.402 1.815 0.670 0.005 0.721 0.543

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ACETYLENE AKA-ETHYNE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

52

43206
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
19.80 80.00 4.600 0.005 5.900 8.800

2ND MAX
14.70 19.10 3.300 0.005 4.400 7.100

ARITH. MEAN
4.266 5.040 1.309 1.268 1.589 2.903

26

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-BUTANE AKA-BUTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43212
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
37.60 34.30 4.900 2.620 7.900 11.70

2ND MAX
25.00 30.70 4.300 2.580 7.000 10.700

ARITH. MEAN
4.266 5.040 1.309 1.268 1.589 2.903

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ISOBUTANE AKA-2-METH

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

51

1997

15

1997

108

1997

1927

1997

53

43214
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
14.30 7.000 1.700 4.490 3.100 3.600

2ND MAX
13.40 4.600 1.000 2.010 3.100 3.000

ARITH. MEAN
2.165 1.330 0.273 0.366 0.745 0.827

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

TRANS-2-BUTENE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

52

43216
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.600 1.100 0.050 0.005 1.200 0.300

2ND MAX
2.600 1.100 0.050 0.005 0.600 0.300

ARITH. MEAN
0.388 0.128 0.050 0.005 0.077 0.071

27

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

CIS-2-BUTENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1825 53 15 108
1927 53

43217
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.000 0.080 0.050 0.005 17.60 0.500

2ND MAX
2.300 0.060 0.050 0.005 0.800 0.400

ARITH. MEAN
0.235 0.085 0.050 0.005 0.045 0.065

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-PENTANE AKA-AMYL H

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43220
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
40.50 11.00 8.100 1.600 13.60 4.100

2ND MAX
26.90 9.100 5.800 1.480 13.60 4.100

ARITH. MEAN
3.877 2.755 2.903 4.313 1.373 1.693

SITE NAME
S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130890002 130893001 132230003 132470001 132470001

ISOPENTANE AKA-2-MET

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

108

1997

1927

1997

53

43221
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
50.00 11.60 4.070 18.80 10.20

2ND MAX
30.30 11.10 3.360 17.90 7.900

ARITH. MEAN
7.425 6.023 1.344 3.343 3.571

28

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

1-PENTENE AKA-PROPYL

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

53

43224
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
4.200 1.500 0.500 0.005 0.800 2.200

2ND MAX
3.400 1.100 0.400 0.005 0.600 0.900

ARITH. MEAN
0.533 0.249 0.103 0.005 0.101 0.125

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

TRANS-2-PENTENE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

53

43226
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.200 6.500 0.800 0.005 2.800 1.400

2ND MAX
5.500 2.200 0.300 0.005 0.800 1.100

ARITH. MEAN
0.558 0.317 0.117 0.005 0.053 0.095

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

CIS-2-PENTENE AKA-CI

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

52

1997

15

1997

108

1997

1927

1997

53

43227
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.300 5.500 0.050 0.005 1.800 0.400

2ND MAX
3.100 0.700 0.050 0.005 0.600 0.050

ARITH. MEAN
0.290 0.186 0.050 0.005 0.023 0.057

29

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

3-METHYLPENTANE AKA-

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

63

1997

1927

1997

53

43230
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
15.30 4.600 1.900 0.760 4.900 3.400

2ND MAX
14.30 4.500 1.800 0.550 3.400 1.500

ARITH. MEAN
1.953 1.086 0.907 0.100 0.360 0.337

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-HEXANE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1825 53 15 240
1927 53

43231
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
9.700 3.800 1.700 0.490 17.50 5.300

2ND MAX
9.700 3.800 1.700 0.490 17.50 5.300

ARITH. MEAN
1.637 1.166 1.070 0.098 0.446 0.557

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-HEPTANE AKA-DIPROP

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

240

1997

1927

1997

53

43232
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.100 1.900 1.800 0.360 3.600 1.600

2ND MAX
5.000 1.000 0.800 0.330 2.100 1.200

ARITH. MEAN
0.550 0.322 0.403 0.020 0.225 0.148

30

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-OCTANE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1825 53 15 240
1927 53

43233
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.000 2.800 2.000 3.380 4.700 2.100

2ND MAX
2.700 2.400 1.300 0.230 1.100 1.500

ARITH. MEAN
0.376 0.269 0.333 0.022 0.162 0.129

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-NONANE AKA-NONYL H

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

240

1997

1927

1997

53

43235
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.200 0.800 0.300 0.330 4.500 4.000

2ND MAX
2.000 0.800 0.300 0.310 2.200 1.100

ARITH. MEAN
0.176 0.101 0.093 0.011 0.156 0.161

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132470001 132470001

N-DECANE SAMPLING
PERIOD
1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15
1926 53

43238
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.100 1.100 5.100 3.100 4.100

2ND MAX
3.000 1.000 3.200 2.400 0.800

ARITH. MEAN
0.218 0.166 1.147 0.158 0.168

31

SITE NAME
S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130890002 130893001 132230003 132470001 132470001

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

CYCLOPENTANE AKA-PEN

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

108

1997

1927

1997

53

ISOPRENE AKA-3-METHY

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

41

1997

1788

1997

53

43242
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
1.400 0.050 0.005 1.700 1.400

43243
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
71.70 7.800 0.900 12.01 61.50 11.40

2ND MAX
1.100 0.050 0.005 1.700 1.400

ARITH. MEAN
0.291 0.050 0.005 0.133 0.392

2ND MAX
55.80 6.900 0.800 10.72 40.40 8.800

ARITH. MEAN
7.308 1.265 0.367 3.731 5.407 1.765

SITE NAME
S. Dekalb (2) Tucker (2) Conyers (2)

SITE NUMBER
130890002 130893001 132470001

2-METHYL-1-PENTENE A

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

53

43246
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
1.500 0.050 0.700

2ND MAX
0.300 0.050 0.500

ARITH. MEAN
0.082 0.050 0.077

32

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2,4-DIMETHYLPENTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

CYCLOHEXANE AKA-HEXA

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

52

1997

15

1997

240

1997

1926

1997

53

43247
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon
43248
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.000 1.100 0.500 0.350 1.300 0.200
1ST MAX
2.300 4.100 0.300 0.380 2.200 0.300

2ND MAX
5.700 1.000 0.500 0.005 1.300 0.050

ARITH. MEAN
0.494 0.174 0.110 0.006 0.112 0.053

2ND MAX
2.200 0.500 0.050 0.260 1.900 0.200

ARITH. MEAN
0.096 0.148 0.067 0.008 0.040 0.058

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

3-METHYLHEXANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

52

43249
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.200 2.600 1.100 0.590 2.500 1.100

2ND MAX
7.600 2.400 1.000 0.540 2.000 0.900

ARITH. MEAN
0.952 0.513 0.347 0.044 0.514 0.152

33

SITE NAME
S. Dekalb (1) S. Dekalb (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 132230003 132470001 132470001

2,2,4-TRIMETHYLPENTA

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

38

1997

240

1997

1926

1997

35

43250
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
26.60 7.300 1.320 5.300 3.600

2ND MAX
25.80 6.700 1.240 4.900 2.200

ARITH. MEAN
2.998 2.050 0.110 0.836 0.570

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2,3,4-TRIMETHYLPENTA

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

52

1997

15

1997

240

1997

1926

1997

53

3-METHYLHEPTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

52

1997

15

1997

240

1997

1926

1997

53

43252
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon
43253
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.900 2.600 1.100 0.450 1.900 1.000
1ST MAX
3.100 5.700 0.300 0.290 1.700 0.500

2ND MAX
8.900 2.500 0.600 0.410 1.600 0.700

ARITH. MEAN
1.046 0.526 0.283 0.023 0.285 0.119

2ND MAX
2.900 0.700 0.050 0.200 1.100 0.400

ARITH. MEAN
0.202 0.204 0.067 0.010 0.094 0.070

34

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

METHYLCYCLOHEXANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

43261
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
4.800 0.900 0.200 0.270 2.500 1.200

2ND MAX
4.000 0.900 0.005 0.240 1.300 0.900

ARITH. MEAN
0.415 0.140 0.018 0.011 0.202 0.099

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

METHYLCYCLOPENTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

43262
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.200 2.600 0.900 0.490 1.190 1.100

2ND MAX
6.100 2.500 0.900 0.430 1.500 1.100

ARITH. MEAN
0.490 0.479 0.407 0.025 0.202 0.182

35

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2-METHYLHEXANE

SAMPLING PERIOD

NO. OF OBS.

1997

1240

1997

53

1997

15

1997

240

1997

1926

1997

53

43263
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
6.600 2.200 1.000 0.540 2.100 0.800

2ND MAX
6.100 2.100 0.900 0.490 1.500 0.700

ARITH. MEAN
0.671 0.366 0.293 0.019 0.280 0.091

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

1-BUTENE SAMPLING
PERIOD
1997 1997 1997 1997 1997
1997

NO. OF OBS.
1825 53 15 108
1927 53

43280
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.600 7.000
0.005 1.100 2.900

2ND MAX
3.300 6.300
0.005 1.000 2.900

ARITH. MEAN
0.651 0.705 0.010 0.005 0.297 0.271

36

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2,3-DIMETHYLBUTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

52

43284
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.800 2.200 0.800 0.430 5.700 1.500

2ND MAX
8.200 2.100 0.700 0.005 2.400 0.500

ARITH. MEAN
1.113 0.374 0.217 0.009 0.175 0.099

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2-METHYLPENTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

1997

53

1997

15

1997

108

1997

1927

1997

53

43285
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
22.20 7.900 3.200 1.260 3.800 4.100

2ND MAX
20.20 6.800 2.900 0.690 3.000 2.400

ARITH. MEAN
2.707 1.439 1.400 0.188 0.472 0.488

37

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2,3-DIMETHYLPENTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

43291
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.100 8.600 0.800 0.710 2.000 0.700

2ND MAX
7.700 4.100 0.700 0.420 1.700 0.600

ARITH. MEAN
0.771 0.542 0.160 0.013 0.194 0.108

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

ISOPENTANE & CYCLOPE

SAMPLING PERIOD

NO. OF OBS.

1997

1825

43341 UNITS
ppb carbon

1ST MAX
129.5

2ND MAX ARITH. MEAN

90.30

11.27

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

FORMALDEHYDE AKA-OXY

SAMPLING PERIOD

NO. OF OBS.

1997

506

43502 UNITS
ppb carbon

1ST MAX
5.140

2ND MAX ARITH. MEAN

4.880

0.863

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

ACETALDEHYDE AKA-ACE

SAMPLING PERIOD

NO. OF OBS.

1997

503

43503 UNITS
ppb carbon

1ST MAX
10.78

2ND MAX ARITH. MEAN

8.910

1.103

38

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

ACETONE AKA-DIMETHYL

SAMPLING PERIOD

NO. OF OBS.

1997

506

43551 UNITS
ppb carbon

1ST MAX
18.18

2ND MAX ARITH. MEAN

18.18

1.405

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132470001 132470001

N-UNDECANE SAMPLING
PERIOD
1997 1997 1997 1997 1997

NO. OF OBS.
1895 53 15
1926 53

43954
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.700 40.00 18.30 3.300 0.600

2ND MAX
2.700 0.700 11.20 3.100 0.600

ARITH. MEAN
0.229 0.870 3.600 0.168 0.111

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

2-METHYLHEPTANE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

43960
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.800 0.800 0.300 0.120 3.300 0.700

2ND MAX
2.400 0.700 0.050 0.120 1.400 0.600

ARITH. MEAN
0.165 0.093 0.068 0.006 0.092 0.077

39

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132230003 132470001 132470001

M/P XYLENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15 240
1926 53

45109
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
29.70 13.60 8.100 2.790 9.000 4.700

2ND MAX
29.00 12.40 7.100 2.190 7.600 4.600

ARITH. MEAN
3.474 3.334 4.130 0.218 1.040 1.446

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

BENZENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15 240
1926 52

45201
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
21.00 8.600 4.400 1.580 5.300 6.100

2ND MAX
19.80 8.300 3.000 1.440 4.700 3.800

ARITH. MEAN
2.398 2.449 2.173 0.404 1.020 1.436

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

TOLUENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15 240
1926 53

45202
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
56.40 21.60 18.40 4.750 16.80 9.100

2ND MAX
53.60 20.60 15.60 4.390 14.00 7.800

ARITH. MEAN
6.797 5.271 10.00 0.729 2.305 2.928

40

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

ETHYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45203
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.200 3.800 2.400 0.810 2.400 1.200

2ND MAX
7.500 3.400 2.200 0.720 2.100 1.200

ARITH. MEAN
1.028 0.783 1.240 0.081 0.401 0.266

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132470001 132470001

O-XYLENE SAMPLING
PERIOD
1997 1997 1997 1997 1997

NO. OF OBS.
1917 53 15
1926 53

45204
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
12.70 5.100 2.800 3.000 2.700

2ND MAX
12.20 4.700 2.500 2.800 2.100

ARITH. MEAN
1.422 1.210 1.353 0.444 0.556

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

1,3,5-TRIMETHYLBENZE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45207
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
5.400 1.800 0.800 0.420 2.200 0.600

2ND MAX
5.300 1.700 0.600 0.390 1.300 0.300

ARITH. MEAN
0.441 0.270 0.173 0.180 0.169 0.073

41

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

1,2,4-TRIMETHYLBENZE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45208
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
14.60 129.7 2.700 10.32 4.400 63.10

2ND MAX
14.60 16.30 2.000 9.900 3.900 24.00

ARITH. MEAN
1.614 5.480 1.247 7.532 0.588 3.941

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

N-PROPYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45209
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.500 3.100 3.300 0.230 1.000 0.900

2ND MAX
2.100 1.100 0.400 0.170 0.700 0.900

ARITH. MEAN
0.132 0.229 0.290 0.009 0.096 0.119

SITE NAME
S. Dekalb (1) S. Dekalb (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 132230003 132470001 132470001

ISOPROPYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

38

1997

240

1997

1926

1997

35

45210
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
1.900 0.050 0.005 0.500 0.050

2ND MAX
1.400 0.050 0.005 0.500 0.050

ARITH. MEAN
0.044 0.050 0.005 0.028 0.050

42

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132230003 132470001 132470001

O-ETHYLTOLUENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45211
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.500 1.400 0.500 0.350 2.100 0.400

2ND MAX
3.200 1.200 0.400 0.330 1.200 0.300

ARITH. MEAN
0.376 0.185 0.130 0.045 0.156 0.066

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132230003 132470001 132470001

M-ETHYLTOLUENE

SAMPLING PERIOD

NO. OF OBS.

1997

1917

1997

53

1997

15

1997

240

1997

1926

1997

53

45212
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
8.500 4.400 1.800 0.820 1.700 1.500

2ND MAX
8.300 3.700 1.300 0.690 1.000 1.200

ARITH. MEAN
0.604 0.838 0.677 0.027 0.021 0.242

SITE NAME
S. Dekalb (2) Tucker (2) Conyers (2)

SITE NUMBER
130891002 130893001 132470001

P-ETHYLTOLUENE

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

53

45213
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
7.000 0.900 10.80

2ND MAX
4.700 0.800 10.80

ARITH. MEAN
1.251 0.287 1.556

43

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132470001 132470001

M-DIETHYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1895

1997

53

1997

15

1997

1926

1997

53

45218
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.500 0.300 1.600 0.600 0.300

2ND MAX
1.700 0.200 0.050 0.500 0.050

ARITH. MEAN
0.103 0.058 0.153 0.023 0.055

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130891002 130893001 132470001 132470001

SITE NAME
S. Dekalb (1) S. Dekalb (2) Tucker (2) Yorkville (1) Conyers (1) Conyers (2)

SITE NUMBER
130891002 130890002 130893001 132230003 132470001 132470001

P-DIETHYLBENZENE

SAMPLING PERIOD

NO. OF OBS.

1997

1895

1997

53

1997

15

1997

1926

1997

53

STYRENE SAMPLING
PERIOD
1997 1997 1997 1997 1997 1997

NO. OF OBS.
1917 51 15 240
1926 53

45219
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
3.500 1.500 0.700 1.500 0.700

45220
UNITS
ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon ppb carbon

1ST MAX
2.800 1.800 0.500 0.340 1.100 1.500

2ND MAX
3.500 1.400 0.300 1.100 0.300

ARITH. MEAN
0.322 0.228 0.110 0.114 0.072

2ND MAX
2.800 1.000 0.400 0.280 0.900 1.300

ARITH. MEAN
0.300 0.317 0.120 0.099 0.273 0.317

44

SITE NAME
S. Dekalb (2) Tucker (2) Conyers (2)

SITE NUMBER
130891002 130893001 132470001

1,2,3-TRIMETHYLBENZE

SAMPLING PERIOD

NO. OF OBS.

1997

53

1997

15

1997

53

45225
UNITS
ppb carbon ppb carbon ppb carbon

1ST MAX
13.10 8.300 9.200

2ND MAX
3.900 3.200 3.200

ARITH. MEAN
1.242 1.497 0.905

SITE NAME
S. Dekalb (1) Tucker (2) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

WIND SPEED SAMPLING
PERIOD
1997 1997 1997 1997

NO. OF OBS.
8674 8547 8438 8642

61101
UNITS
Knots Knots Knots Knots

1ST MAX
12.8 9.9 19.4 12.2

2ND MAX
11.5 9.9 17.3 12.0

ARITH. MEAN
2.67 2.77 5.59 2.36

SITE NAME
S. Dekalb (1) Tucker (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

OUTDOOR TEMPERATURE

SAMPLING PERIOD

NO. OF OBS.

1997

7857

1997

8549

1997

8338

1997

8535

62101
UNITS
Deg. C. Deg. C. Deg. C. Deg. C.

1ST MAX
34 35 33 35

2ND MAX
34 35 32 35

ARITH. MEAN
14.8 15.7 15.0 15.3

45

SITE NAME
S. Dekalb (1) Tucker (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

RELATIVE HUMIDITY

SAMPLING PERIOD

NO. OF OBS.

1997

8726

1997

8541

1997

7254

1997

8436

62201
UNITS
% % % %

1ST MAX
100 100 100 100

2ND MAX
100 100 100 100

ARITH. MEAN
80.1 73.4 72.8 80.3

SITE NAME
S. Dekalb (1) Tucker (1) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

SOLAR RADIATION

SAMPLING PERIOD

NO. OF OBS.

1997

8140

1997

8480

1997

8630

1997

8488

63301
UNITS
Lang./min Lang./min Lang./min Lang./min

1ST MAX
1.56 1.38 1.42 0.94

2ND MAX
1.54 1.38 1.42 0.92

ARITH. MEAN
0.253 0.231 0.248 0.176

SITE NAME
S. Dekalb (1) Tucker (1) Yorkville (1)

SITE NUMBER
130891002 130893001 132230003

ULTRAVIOLET RADIATION

SAMPLING PERIOD

NO. OF OBS.

1997

7903

1997

6872

1997

5147

63302
UNITS
Watts/sq m Watts/sq m Watts/sq m

1ST MAX
0.06 0.06 0.05

2ND MAX
0.06 0.06 0.05

ARITH. MEAN
0.009 0.011 0.009

46

SITE NAME
S. Dekalb (1) Tucker (2) Yorkville (1) Conyers (1)

SITE NUMBER
130891002 130893001 132230003 132470001

BAROMETRIC PRESSURE

SAMPLING PERIOD

NO. OF OBS.

1997

8590

1997

8550

1997

8355

1997

8613

64101
UNITS
Millibars Millibars Millibars Millibars

1ST MAX
1006 994.0 991.0 1009

2ND MAX
1006 993.0 991.0 1009

ARITH. MEAN
989.9 978.7 970.2 991.9

47

PHOTOCHEMICAL ASSESSMENT MONITORING Carbonyl Compounds
Determination of ambient concentrations of carbonyl compounds is a requirement of 40 CFR Part 58, Subpart E, enhanced ozone network monitoring programs. Carbonyl compounds have been shown to contribute to the formation of photochemical ozone. Formaldehyde, acetaldehyde, and acetone are specifically required target compounds for PAMS; however, other carbonyl compounds may be added to the target list consistent with individual program objectives. The methodology used to accomplish carbonyl compounds monitoring provides sensitive and accurate measurements of carbonyl compounds and involves sample collection and analysis procedures. In this method, a cartridge(s) containing a solid sorbent is used to capture the target compounds.
48

CARBONYL DATA

ACETONE SITE NAME
S. Dekalb (1)

43551 SITE NUMBER
130891002

SAMPLING PERIOD
1997

NO. OF OBS.
506

UNITS
ppb carbon

1ST MAX
18.18

2ND MAX ARITH. MEAN

18.18

1.405

FORMALDEHYDE

43502

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

SAMPLING PERIOD
1997

NO. OF OBS.
506

UNITS
ppb carbon

1ST MAX
5.14

2ND MAX ARITH. MEAN

4.88

0.863

ACETALDEHYDE

43503

SITE NAME SITE NUMBER

S. Dekalb (1)

130891002

SAMPLING PERIOD
1997

NO. OF OBS.
503

UNITS
ppb carbon

1ST MAX
10.78

2ND MAX ARITH. MEAN

8.91

1.103

Observations are 3 hours in duration

49

Toxic Metals 1997 Monitoring Results

Toxic air pollutants are also referred to as air toxics or hazardous air pollutants (HAPs). They are generally defined as those pollutants that are known or suspected to cause serious health problems. "Routine" toxic air pollutants are emitted by a variety of industrial sources and motor vehicles. In addition to routine releases, sudden accidental air releases of toxics potentially threaten many Americans. In response to public concern over the quality of Georgia's air, the Environmental Protection Division began an ambitious project to establish, over the course of five years, twenty sites to monitor non-criteria metals which include arsenic, cadmium, chromium, nickel, and zinc. In 1997 beryllium, cobalt, lead, and selenium were added. There are six sites in six counties in the 1997 network. Currently there are no ambient standards established for these metals.

Compound

Site

Augusta Brunswick

Arsenic

Dawsonville Gainesville

Savannah Utoy Creek-co

Augusta

Brunswick

Berylium

Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Brunswick

Cadmium

Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Brunswick

Cobalt

Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Chromium

Brunswick Dawsonville Gainesville

Savannah Utoy Creek-co

Toxic Metals

ug/m3

No of Obs. 1st Max 2nd Max Mean

14

0.0083

0.006 0.004

10

0.0091

0.0066 0.0031

8

0.0057

0.005 0.0027

12

0.018

0.01 0.0047

7

0.012

0.008 0.0039

22

0.0074

0.007 0.0014

4 0.000078

0.00007 0.0002

3

0.0001 0.000021 0.0002

4

0.0005

0.0001 0.0003

4

0.0017

0.0002 0.0003

2

0.0021

0.0003 0.0006

5

0.0003

0.00023 0.0003

4

0.0084

0.0062 0.0008

1

0.0021

ND

0.0003

3

0.0032

0.0024 0.0008

2

0.0042

0.00071 0.0007

1

0.0016

ND

0.0004

11

0.0059

0.0058 0.0011

4

0.0012

0.001 0.0008

2

0.0036

0.0008 0.0008

2

0.0086

0.0016 0.0017

4

0.0023

0.0017 0.0012

2

0.0018

0.0015 0.0009

7

0.0038

0.0028 0.0014

14

0.0088

0.0071 0.0031

19

0.0044

0.004 0.0014

14

0.006

0.0052 0.0019

17

0.0062

0.0054 0.0025

17

0.034

0.013 0.0055

26

0.0091

0.0089 0.0042

50

Compound

Site

Augusta

Brunswick

Lead

Dawsonville Gainesville

Savannah Utoy Creek-co

Augusta

Brunswick

Manganese

Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Brunswick

Nickel

Dawsonville Gainesville Savannah

Utoy Creek-co

Augusta

Selenium

Brunswick Dawsonville Gainesville

Savannah

Utoy Creek-co

Augusta

Brunswick

Dawsonville

Zinc

Gainesville

Savannah

Utoy Creek-co

No of Obs. 18 13 10 8 10 28 12 12 10 11 9 17 7 11 8 3 13 21 12 12 10 11 9 17 23 25 22 20 19 41

1st Max 0.028
0.0078 0.0083
0.017 0.011
0.06 0.04 0.0062 0.011 0.022 0.01 0.066 0.041 0.0065 0.027 0.0028 0.0051 0.0083 0.032 0.026 0.095 0.22 0.012 0.026 0.092 0.092 0.1078 0.14 0.12 0.131

2nd Max 0.027
0.0076 0.0076 0.0071
0.01 0.0092
0.025 0.0049
0.011 0.014 0.0091 0.053 0.0045 0.004 0.0068 0.0027 0.0046 0.0066 0.027 0.024 0.089
0.14 0.048 0.021 0.089 0.085 0.074
0.12 0.059 0.116

Mean 0.011
0.0041 0.0042 0.0047 0.0064 0.0095
0.015 0.0039 0.0065 0.0085 0.0073
0.026 0.0027 0.0018 0.0025 0.0014 0.0024 0.0029
0.019 0.019 0.058 0.074 0.041 0.013 0.038 0.029 0.025 0.042 0.034 0.039

51

Compound 1,1,1-Trichloroethane 1,2,4-Trichlorobenzene 1,2,4-Trimethylbenzene 2-Bromopentane Benzene
Chloromethane
Cyclohexane Dichlorodifluoromethane
Freon 11 Hexachlorobutadiene Methane, chlorodifluoro Methylene Chloride o-Dimethylbenzene p,m-Dimethylbenzene
Styrene Tetrachloroethylene Toluene
Trichloroethylene

Air Toxic Volatile Organic Compounds (VOC)
1997 Monitoring Results

Volatile Organic Compounds ug/m3

Site

No. of Obs. 1st Max 2nd Max

Utoy Creek-Co Gainesville gainesville Utoy Creek-Co Gainesville Augusta Dawsonville Gainesville Utoy Creek-Co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-Co Augusta Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-Co Brunswick Dawsonville Gainesville Gainesville Gainesville Brunswick Gainesville Utoy Creek-Co Utoy Creek-Co

2

24

23.5

1

15 ND

1

2.9 ND

1

2.9 ND

1

3.8 NA

4

2.6

2.2

1

1.6 ND

3

2.6

1.6

8

3.5

3.2

8

1.4

1.2

10

3.8

2.5

14

1.9

1.8

4

1.4

1.2

3

1.7

1.3

14

1.4

1.2

4

6.9

5.2

2

3.5

2.5

4

4

3.5

4

4

3

2

3.5

2.5

3

3.5

3

7

4

4

3

3.4

3.4

1

2.8 ND

1

3.9 ND

1

7.5 ND

1

2.5 NA

3

18.8

4.9

2

46.9

3.8

27

17

10.4

1

2.6 ND

Augusta Brunswick Dawsonville Gainesville Utoy Creek-Co Gainesville Utoy Creek-Co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-Co Augusta

3

4.3

3.9

1

2.2 ND

1

2.6 ND

3

5.2

3

10

6.1

5.2

2

0.9

0.2

1

8.8 ND

7

6.4

6

11

10.2

7.9

1

1.9 ND

11

7.2

4.1

4

12.8

7.2

30

10.6

10.6

1

3.2 ND

Mean
2.26 2.95 1.33 1.28
3.8 1.16 0.83 0.82
0.8 0.85 1.36 0.98 0.65 0.84 0.69 1.76 1.48 1.83 1.32 1.47 1.92 1.56 1.67 1.45 1.51 2.88
2.5 2.02 3.19 2.56 1.13
1.57 1.3
1.16 1.44 1.63 0.38 1.85 2.25 3.05
1 2.12 3.45 2.87 1.47

52

Air Toxic Volatile Organic Compounds (VOC)
1997 Monitoring Results (continued)

Compound
1,2,3-Trimethyl benzene* 1,3-Butadiene, 2-methyl-* 1-Butene * 1-Ethyl-2-Methyl Benzene* 1-Ethyl-3-Methyl Benzene* 1-Ethyl-4-Methyl Benzene* 1-Pentene* 2,2,4-Trimethylpentane* 2,2-Dimethylbutane* 2,3,4-Trimethylpentane* 2,3-Dimethylbutane* 2,3-Dimethylpentane * 2-Methyl-1,3-Butadiene * 2-methyl-1-pentene * 2-Methyl-1-Propene* 2-Methylheptane* 2-Methylhexane* 2-Methylpentane* 3-Methylhexane* 3-Methylpentane* 4-Methyl-1-Hexene* 4-Methylpentan-2-one* Acetylene* Butane* Butane, 2-methyl- * Ethane* Ethylene* Heptane * Hexane* Isobutane* Isopentane* Methylcyclohexane* Methylcyclopentane* n-Butane* n-Decane* n-Heptane* n-Hexane* n-Nonane* n-Octane* n-Pentane* n-Propylbenzene* Pentane* Propane* Propane, 2-methyl- * Propylene* trans-2-Butene* Trans-2-Pentene*

Volatile Organic Compounds ug/m3

Site

No. of Obs.

Gainesville

2

Gainesville

1

Gainesville

2

Gainesville

1

Gainesville

2

Gainesville

1

Gainesville

1

Gainesville

2

Gainesville

1

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

1

Gainesville

1

Gainesville

1

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

1

Gainesville

1

Gainesville

3

Gainesville

3

Gainesville

1

Gainesville

3

Gainesville

3

Gainesville

1

Gainesville

2

Gainesville

3

Gainesville

4

Gainesville

2

Gainesville

3

Gainesville

3

Gainesville

2

Gainesville

2

Gainesville

2

Gainesville

1

Gainesville

1

Gainesville

3

Gainesville

1

Gainesville

2

Gainesville

3

Gainesville

1

Gainesville

3

Gainesville

1

Gainesville

2

1st Max 2nd Max

0.6

0.3

1.4 NA

0.2

0.2

0.1 ND

0.9

0.7

0.8 ND

0.4 ND

1.8

1

0.5 ND

0.7

0.3

0.8

0.7

0.2

0.2

1.1

0.8

0.2 ND

1.5 ND

0.2 ND

0.6

0.3

3

1

0.8

0.5

1.9

0.6

0.4 NA

5.3

2

3.6

1.9

1.4 NA

7.9

5.5

5.5

2.3

2.4 NA

6

4.9

2.6

1.3

20.4

6.2

0.2

0.1

1.7

1

8.6

4.9

0.2

0.2

0.5

0.4

4.3

1.8

0.2 ND

0.2 ND

7.6

3.4

0.3 ND

13.3

9.1

7.8

3.2

1.2 NA

2.2

0.9

0.2 ND

0.2

0.1

Mean
0.35 1.4
0.17 0.067
0.55 0.58 0.17 0.95 0.23 0.35 0.53 0.12
1.2 0.1 3.1 0.1 0.32 1.35 0.32 0.85 0.4
3 2.3 1.4 5.36 2.93 2.4 5.45 1.53 3.7 0.15 0.89 5.2 0.15 0.32 2.05 0.1 0.13
4 0.17 11.2 4.67
1.2 1.1 0.1 0.1

53

Compound a-BHC Acenapthene
Acenapthylene
Benzo(a)anthracene Benzo(b)fluoranthene
Benzo(g,h,i)perylene Benzo(k)fluoranthene Chrysene Fluoranthene
Fluorene Hexachlorobenzene Indeno(1,2,3-cd)pyrene Naphthalene
Phenanthrene
Pyrene

Air Toxic Semi-Volatile Organic Compounds 1997 Monitoring Results

Semi-Volatile Organic Compounds ug/m3

Site

No. of Obs.

1st Max

Brunswick Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Augusta Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Utoy Creek-co Dawsonville Gainesville Utoy Creek-co Augusta Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Dawsonville Gainesville Savannah Utoy Creek-co Augusta Savannah Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Savannah Utoy Creek-co Augusta Brunswick Dawsonville Gainesville Utoy Creek-co

1 0.00008

1 0.0003

1

0.1

3

0.15

1

0.01

2

0.06

3

0.08

8

0.2

2

0.03

1

0.04

1

0.02

3

0.03

11

0.1

1 0.0007

3

0.003

2 0.0001

2 0.00007

3 0.0002

2 0.00004

2 0.0002

6

0.002

5 0.0007

1 0.00006

2 0.00006

7 0.00009

1

0.002

5

0.005

7

0.001

4 0.0005

5

0.002

8

0.01

20

0.01

1

0.009

1

0.04

1

0.03

3

0.011

1 0.00009

1 0.0001

2 0.0003

3

0.08

9

0.2

5

0.04

12

0.07

10

0.1

24

0.26

4

0.004

6

0.003

3

0.003

4

0.004

6

0.004

13

0.2

1

0.002

5

0.005

2

0.002

1

0.02

9

0.012

2nd Max Mean

ND ND ND 0.015 ND 0.01 0.03 0.1 0.03 ND ND 0.02 0.1 ND 0.002 0.00003 0.00003 0.00009 0.00003 0.0002 0.0005 0.0007 ND 0.00003 0.00009 ND 0.0008 0.001 0.0002 0.001 0.002 0.005 ND ND ND 0.007 ND ND 0.0003 0.05 0.05 0.03 0.06 0.07 0.23 0.003 0.003 0.003 0.003 0.004 0.02 ND 0.002 0.001 ND 0.005

0.00002 0.00002
0.01 0.01 0.007 0.008 0.01 0.02 0.004 0.008 0.007 0.009 0.02 0.0004 0.0006 0.00002 0.00002 0.00003 0.00001 0.00003 0.0001 0.0001 0.00001 0.00002 0.00002 0.0004 0.0006 0.0002 0.0001 0.0003 0.0007 0.001 0.002 0.0031 0.002 0.002 0.00004 0.00004 0.0001 0.02 0.02 0.01 0.03 0.02 0.07 0.001 0.0007 0.0007 0.001 0.001 0.006 0.0003 0.0008 0.0005 0.001 0.001

54

Acid Precipitation 1998 Network

Acid precipitation was monitored in 6 counties in 1998. The Air Protection Branch operated 3 of these sites and the Georgia Forestry Commission and University of Georgia operated the remainder. There are no national or state standards for acid precipitation. A fiveyear analysis reveals no obvious trends.

Site Hiawassee Summerville Dawsonville McDuffie Co. Athens Eatonton

Acid Precipitation Weighted Average

Reported as pH

1994 - 1998

1994

1995

1996

1997

4.55

4.73

4.55

4.53

4.52

4.62

4.62

4.52

4.62

4.71

4.58

4.70

4.86

4.95

4.49

4.49

4.67

4.63

4.55

4.59

4.69

4.64

4.63

4.70

1998 4.73 4.62 4.65 4.90 4.58 4.70

pH

5.60 5.40 5.20 5.00 4.80 4.60 4.40 4.20

Natural Rainfall
1994 1995

1996 Year

1997

1998

Hiawassee Summerville Dawsonville McDuffie Co. Athens Eatonton

55

Units: parts per million

State of Georgia Oxides of Nitrogen

Site ID
130890002 130893001 131210048 132230003 132470001

City
Decatur Tucker Atlanta Yorkville Conyers

County
DeKalb DeKalb Fulton Paulding Rockdale

Site Name
South DeKalb Idlewild Road Ga. Tech. King Farm Monastery

Number Measured (hours) 3690 5799 5953 8059 8197

1st Max
0.501 0.387 0.484 0.091 0.169

Annual Arithmetic Mean
0.073 0.022 0.047 0.008 0.011

56

State of Georgia Nitric Oxide

Units: parts per million

Site ID
130890002 130893001 131210048 132230003 132470001

City
Decatur Tucker Atlanta Yorkville Conyers

County
DeKalb DeKalb Fulton Paulding Rockdale

Site Name
South DeKalb Idlewild Road Ga. Tech. King Farm Monastery

Number Measured (hours) 3691 5799 5973 8060 8197

1st Max
0.487 0.382 0.500 0.063 0.136

Annual Arithmetic Mean
0.055 0.009 0.027 0.005 0.007

57

State of Georgia Reative Oxides of Nitrogen

Units: parts per million

Site ID
130890002 130893001 132470001

City
Decatur Tucker Conyers

County
DeKalb DeKalb Rockdale

Site Name
South DeKalb Idlewild Road Monastery

Number Measured (hours) 554 2792 5039

1st Max
0.200 0.200 0.120

Annual Arithmetic Mean
0.043 0.037 0.012

58

Appendix " A"

TYPES OF SAMPLING METHODS

LEAD (Manual) Samples are collected on 8" x 10" pre-weighed fiberglass filters with a high-volume sampler for 24 hours. Atomic absorption analysis is then performed on the samples SULFUR DIOXIDE (Continuous) Continuous analysis for sulfur dioxide is accomplished with the use of pulsed fluorescence (U.V. Light) method. NITROGEN DIOXIDE (Continuous) Continuous analysis for nitrogen dioxide is accomplished with the use of ozone phase chemiluminescent method. CARBON MONOXIDE (Continuous) Continuous analysis for carbon monoxide is accomplished with the use of non-dispersive infrared analysis and gas filter correlation methods
OZONE (Continuous) Continuous analysis for ozone is accomplished with the use of U.V. photometric method
PARTICULATE MATTER 10 MICRON (PM-10) Samples are collected on microquartz fiber filters with a PM-10 sampler for 24 hours. Gravimetric analysis is performed on all samples after collection
NITRIC OXIDE Continuous analysis for nitric oxide is accomplished with the use of ozone phase chemiluminescent method.
OXIDES OF NITROGEN Continuous analysis for oxides of nitrogen is accomplished with the use of ozone phase chemiluminescent method. (method number 074)

59

ACID PRECIPITATION Samples are collected weekly and analyzed gravimetrically and also for acidity and conductivity. Further analyses are performed for selected compounds. VOC ANALYSIS During June, July, and August samples are analyzed hourly using a gas chromatography unit using a Flame Ionization Detector (FID). Throughout the year a 24 hour integrated sample is taken and analyzed in a State Laboratory. CARBONYL During July and August samples are taken for three hours and analyzed at a State Laboratory. Throughout the year a 24 hour integrated sample is taken and analyzed in a State Laboratory.
60

Appendix " B "
AM AQCR ARITH MEAN CO EPA GEO MEAN Pb NO Nox NO2 NUM OBS O3 PM-10
PPM QTR SO2 TSP
g/M3 UV

ABBREVIATIONS
Annual mean Air Quality Control Region Arithmetic mean Carbon monoxide Environmental Protection Agency Geometric Mean Lead Nitric Oxide Oxides of nitrogen Nitrogen Dioxide Number of observations Ozone Particles with an aerodynamic diameter of 10 microns or less Parts Per Million Calendar quarter Sulfur dioxide Total Suspended particulate Micrograms per Cubic Meter Ultraviolet

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REFERENCES: http://www.epa.gov/oar/aqtrnd97/brochure/pb.html http://www.epa.gov/ttn/uatw/basicfac.html [Code of Federal Regulations] [Title 40, Volume 2, Parts 50 to 51] [Revised as of July 1, 1998] Measuring Air Quality: The Pollutant Standards Index; Office of Air Quality Planning and Standards, US EPA; EPA 451/K-94-001; February 1994.
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Locations