GROUND-WATER QUALITY IN THE PIEDMONTIBLUE RIDGE UNCONFINED AQUIFER
SYSTEM OF GEORGIA
John C. Donahue and Susan R. Kibler
GEORGIA DEPARTMENT OF NATURAL RESOURCES ENVIRONMENTAL PROTECTION DIVISION WATERSHED PROTECTION BRANCH REGULATORY SUPPORT PROGRAM
ATLANTA 2007
CIRCULAR 12U

GROUND-WATER QUALITY IN THE PlEDMONTlBLUE RIDGE UNCONFINED AQUIFER
SYSTEM OF GEORGIA
John C. Donahue and Susan R. Kibler
Thepreparation of this report wasfunded inpart through a grant from the U S . Environmental Protection Agency under the provisions of Section 106 of the Federal Water Pollution Control Act of 1972, as amended.
GEORGIA DEPARTMENT OF NATURAL RESOURCES Noel Holcomb, Commissioner
ENVIRONMENTAL PROTECTION DIVISION Carol A. Couch, Director
WATERSHED PROTECTION BRANCH Linda MacGregor, Branch Chief
ATLANTA 2007
CIRCULAR 12U

TABLE OF CONTENTS
Section CHAPTER 1 INTRODUCTION
1.1 Purpose and Scope 1.2 PiedmontlBlue Ridge Ground-Water Monitoring Network 1.3 Population Characteristics
1.3.1 High-Growth Counties 1.3.2 Low Income and Minority Areas
CHAPTER 2 HYDROGEOLOGIC FRAMEWORK 2.1 PiedmontlBlue Ridge Aquifer System 2.1.I Regolith 2.1.2 Fractured Bedrock 2.2 Favorable Scenarios for Obtaining Ground Water
CHAPTER 3 METHODS 3.1 Field Methods 3.2 Laboratory Methods
CHAPTER 4 RESULTS 4.1 pH 4.2 Conductivity 4.3 Anions and Non-Metals 4.3.1 Chloride 4.3.2 Sulfate 4.3.3 NitrateINitrite 4.3.4 Dissolved Oxygen 4.3.5 Total Phosphorus 4.4 Metals 4.4.1 Alkali Metals 4.4.2 Alkaline Earth Metals 4.4.3 Copper, Lead, Zinc 4.4.4 Iron, Manganese, Nickel, Chromium 4.4.5 Molybdenum, Uranium, Vanadium 4.4.6 Aluminum, Titanium 4.4.7 Volatile Organic Compounds 4.5 Gamma Radiation
CHAPTER 5 SUMMARY AND CONCLUSIONS 5.1 Field Parameters 5.2 Anions and Non-Metals 5.3 Metals 5.4 Paired Samples

Page 1-1 1-1 1-2 1-5 1-5 1-6
2-1 2-1 2-1 2-1 2-2
3-2

Section 5.5
5.6

Occurrences of Nutrients and VOCs According to County Class 5.5.1 VOCS 5.5.2 Nutrients Overall Quality of Ground Water in the PiedmontIBlue Ridge Region

CHAPTER 6 LlST OF REFERENCES

APPENDIX Laboratory and Well Data

LlST OF FIGURES Figure 1-1. Map of Georgia, Showing the Counties that Lie
Within the Study Area. Figure 1-2. Location Map Showing Sampling Stations.

LlST OF TABLES Table 3-1 Analytical Methods. Table A - I Georgia PiedmontlBlue Ridge Counties,
Population Growth and Densities. Table A-2 Ground-Water Quality Analyses for the
PiedmontlBlue Ridge Unconfined Aquifer System Table A-3 Chemical Components and Reporting Limits

Page 5-5 5-5 5-5 5-6
Page

CHAPTER 1. INTRODUCTION
1.1 PURPOSE AND SCOPE
This report, covering the period December 2005 through December 2006, is the second in a series of summaries to examine potential ground-water impairment within specific areas of Georgia or involving specific types of wells. The previous series of summaries of the Circular 12 series, nineteen in all, dealt with the chemical quality of ground water Statewide.
These summaries are among the tools used by the Georgia Environmental Protection Division (EPD) to assess trends in the quality of the State's ground-water resources. EPD is the State organization with regulatory responsibility for maintaining and, where possible, improving ground-water quality and availability. EPD has implemented a comprehensive statewide ground-water management policy of anti-degradation (EPD, 1991; 1998). Five components comprise EPD's current ground-water quality assessment program:
1. The Georgia Ground-Water Monitoring Network. The Georgia Geologic Survey Branch (GGS) of EPD and its successor, the Regulatory Support Program of the Watershed Protection Branch, maintain this program. Early in calendar year 2004, a three-part monitoring program replaced the Statewide aquifer-specific monitoring network. The new program examines ground-water: a) in the coastal area for influx of connate brines, sea water, or low-quality surface water; b) in the Piedmont and Blue Ridge for impacts from development and rural land use as well as to gain a more thorough understanding of the area's ambient ground water; and c) from small public water systems to spot check for intermittent contamination that might escape detection under item 2) below. The current report summarizes findings for part b) of the program, the Piedmont/Blue Ridge Monitoring Project.
2. Sampling of public drinking water wells as part of the Safe Drinking Water Program, also of the Watershed Protection Branch. This program provides data on the quality of ground water that the residents of Georgia are using.
3. Special studies addressing specific water quality issues. Examples of these types of studies include a survey of nitritelnitrate levels in shallow wells located throughout the State of Georgia (Shellenberger, et al., 1996; Stuart, et al., 1995), operation of a Pesticide Monitoring Network conducted jointly by the GGS and the Georgia Department of Agriculture (GDA) (Tolford, 1999; Glen, 2001), and the Domestic Well Pesticide Sampling

Project conducted jointly by the GGS and the GDA (Overacre, 2004, Berry, 2005).
4. Ground-water sampling at environmental facilities such as municipal solid waste landfills, RCRA facilities, and sludge disposal facilities. The primary branches responsible for monitoring these facilities are EPD's Land Protection, Watershed Protection, and Hazardous Waste Management Branches.
5. The wellhead protection program (WHP), which is designed to protect the area surrounding a municipal drinking water well from contaminants. The U.S. Environmental Protection Agency (EPA) approved Georgia's WHP Plan on September 30, 1992. The WHP Plan became a part of the Georgia Safe Drinking Water Rules, effective July 1, 1993. The protection of public water supply wells from contaminants is important not only for maintaining ground-water quality, but also for ensuring that public water supplies meet health standards.
1.2 PIEDMONTIBLUE RIDGE GROUND-WATER MONITORING NETWORK
The study area for the PiedmontlBlue Ridge Monitoring Project encompassed 74 counties lying wholly or partly within the Piedmont or the Blue Ridge physiographic provinces (Fig. 1-1). The Cartersville-Great Smoky fault system bounds the area to the northwest, and the Fall Line bounds the area to the southeast (Figure 1-1). The northeastern and southwestern boundaries are the South Carolina and Alabama State lines, respectively. The sole aquifer system in the area is the PiedmontlBlue Ridge unconfined aquifer system.
The current project sampled 120 wells, preferably shallow and as evenly distributed as possible throughout the study area (Figure 1-2). Sixty of the wells and springs are public water sources.
Waters from the sampled wells and springs were field tested for pH, conductivity, temperature, and dissolved oxygen. The sampled wells and springs were located using a global positioning system (GPS) receiver. Laboratory testing for the project included analyses for chloride, sulfate, nitratelnitrite, total phosphorus, sulfide, and metals, including uranium. Sulfide testing later ceased after laboratory capacity became a concern and no detections occurred. Testing for radionuclides in addition to uranium was considered, but the project budget could not accommodate the additional analyses.
Project testing also included analyses for volatile organic compounds (VOCs) in high-growth counties. VOC testing was later extended to lowgrowth counties having urban core area (e.g., Fulton County) or established industrial towns (e.g. Upson County). Per request of the US EPA, Region 4, sample waters from two stations, Lin-I and Mwr-I, were sent to a graduate student at

Figure 1-1. Map of Georgia, Showing the Counties that Lie Within the Study Area. Also Shown Are the Cartersville-Great Smoky Fault System and Fall Line.
1-3

Sampling station
Figure 1-2. Location Map Showing Sampling Stations. 1-4

the University of CaliforniaIRiverside to be analyzed for perchlorate as part of a nation-wide ground-water perchlorate study. No results have been forthcoming on the perchlorate analyses.
The State has established limits, termed Maximum Contaminant Levels (MCLs), on the concentrations of certain substances in water made available to the public. Primary MCLs apply to substances which pose a threat to health. Secondary MCLs apply to substances which, though not ordinarily a threat to health nevertheless impart an offensive quality to the water, such as bad taste or ability to stain. Although these standards apply only to treated water made available to the public, they are useful guidelines for evaluating the quality of raw (untreated) water.
Assembling the candidate wells and springs began in December 2005 and continued through much of the length of the project. Candidate wells came from a variety of sources. Lists of public water system licensees and public water sources provided the largest group of candidates. Other candidates came by way of the Georgia Forestry Commission (GFC). Many GFC offices are located in rural areas and depend on wells for drinking water or wash water. Employees at these offices, many living in rural areas themselves, offered the use of their private wells and gave referrals to other private well owners. The Georgia Department of Natural Resources (DNR) Wildlife Resources Division (WRD) made available wells or springs supplying water to work stations and hunting check stations. Some WRD employees were also able to offer their private wells or to provide references to other private well owners. The DNR Parks and Historic Sites Division also provided candidates. Most park wells are public water sources, but staff house wells and certain other park water sources are non-public. Employees of the EPDIWatershed Protection BranchIRegulatory Support Program offered a few private wells or references to private well owners.
1.3 POPULATION CHARACTERISTICS
1.3.1 High-Growth Counties
According to data available from the US Census Bureau (USCB) website at www.fedstats.govlgflstatesll3000lhtml (Feb. 6, 2007 edition), Georgia's population has grown from an estimated 8,230,155 to an estimated 8,918,129 between July 1, 2000 and July 1, 2004. This is an increase of about 8.36 percent. The lower limit for "high-growth" counties in the current study was, therefore, set at 8 percent. All counties with a population growth rate equal to or greater than the lower limit were considered high-growth counties (see Table A-I in the Appendix).
Low-growth counties generally fall into three categories: rural, urban, and rural-industrial (see Table A - I in the Appendix). Rural counties generally have relatively low population densities, about 50 people per square mile or less.

Rural-industrial counties usually have population densities of about I 0 0 to 200 people per square mile and have long-established industrial centers (commonly, these are or used to be textile mill towns). Urban counties have population densities in excess of 500 people per square mile.
1.3.2 Low Income and Minority Areas
The minority and low-income data for this study was obtained by comparing the geographic location of each sampling station to data and maps from the 2000 United States Decennial Census Survey (2000 Survey), which is available on the USCB website at www.census.gov. Data from the 2000 Survey were used, as the 2005 US Census American Community Survey (2005 Survey) was not complete for all areas.
For the 2000 Survey, the USCB used a combination of income thresholds to establish the number of people living in poverty. The number is reported as a percentage of individuals living below the poverty level. More information as to how the income thresholds and the poverty level are established can be found on the USCB website. In the US, the percentage of people living below the poverty level is reported as 12.4 percent. Of the 120 sites that were sampled for this study, 40 sites (33 percent) were located in areas where the level of poverty exceeded the national average.
The sampling locations were also compared to the USCB data for two minority populations: Hispanic or Latino and Black or African American. The percentage of the population in the US that self-identify as Hispanic or Latino is reported as 12.5 percent. Of the 120 sites that were sampled for this study, two sites (2 percent) were located in areas that exceeded the 12.5 percent national average. The percentage of the population in the US that self-identify as Black or African American is reported as 12.3 percent. Of the 120 sites that were sampled for this study, 57 sites (48 percent) were located in areas that exceeded the 12.3 percent national average.

CHAPTER 2. HYDROGEOLOGIC FRAMEWORK
2.1 PIEDMONTIBLUE RIDGE AQUIFER SYSTEM
The Piedmont/Blue Ridge aquifer system in Georgia is part of the general Piedmont and mountain aquifer system that extends from New Jersey into Alabama (Daniel and Harned, 1997). The system is unconfined or semi-confined and is composed of two major hydrogeologic units: regolith and fractured igneous and metamorphic bedrock (Heath, 1980; Daniel and Harned, 1997).
2.1.IRegolith
Typical regolith is composed of a surficial veneer of soil or, near stream bottoms and former stream bottoms, alluvium, underlain by saprolite (Heath, 1980). Saprolite is bedrock that has undergone extensive chemical weathering in place. Many of the structures and textures of the original bedrock are commonly preserved, with the saprolite appearing as a "rotten" version of the original rock. Saprolitization involves the leaching of alkali metals, alkaline earth and other divalent metals by downward percolating, typically acidic ground water from micas, feldspars, and other minerals composing the original rock, leaving behind a residual material rich in clay minerals.
The regolith possesses a high degree of porosity, mostly primary (35-55 percent) void space between mineral grains (Daniel and Harned, 1998), and constitutes the main reservoir holding ground water. The saprolite typically grades downward through a transition zone into unweathered fractured bedrock. The transition zone contains a mix of saprolite, partially weathered bedrock, and lumps of fresh bedrock. This zone commonly exhibits greater permeability than the overlying or underlying materials (Daniel and Harned, 1998). However, Williams et al. (2004) found areas of poor hydraulic communication between the bedrock and the regolith at Lawrenceville, Georgia.
The regolith serves as a reservoir that feeds ground water downward into the underlying fractured bedrock (Heath, 1980). The water table usually lies within the regolith and, at rest, is a subdued imitation of the topography, with flow proceeding from high areas to valleys. Streams can be viewed as outcroppings of the water table. Williams et al. (2004), however, found that pumping at the City of Lawrenceville's Rhodes Jordan Park well field influenced a water level station about a mile and a half away, across a locally major watershed divide.
2.1.2 Fractured Bedrock
The bedrock is igneous and metamorphic and comprises granitic rocks, a lesser amount of mafic and ultramafic rocks (diabase is the most common), gneisses, schists, amphibolites, quartzites, phyllites, marbles, granulites, and

mylonites and other cataclastic rocks. Unlike the regolith, these rocks have almost no primary porosity, i.e., void space between mineral grains. Nearly all the ground water in these rocks is stored in fractures and solution voids (secondary porosity). In the North Carolina Piedmont, Daniel and Harned (1998) found 1-3'3, porosity typical for bedrock.
Fractures consist of faults, breaks in the rock with differential displacement, and joints, breaks in the rock with little differential displacement (Heath, 1980). Fractures generally are more numerous and wider near the bedrock surface. At about 600 feet, pressure from the overlying rock column becomes too great and fractures are held shut (Daniel and Harned, 1998). Fractures also serve to open the rock to weathering, which, in turn, can enlarge the fractures and alter the rock to saprolite. Large fractures in bedrock function as conduits, thus wells tapping bedrock can have larger yields than those tapping the regolith. Fractures can be concentrated along fault zones, shear zones, late-generation fold axes, foliation planes, lithologic contacts, compositional layers, or intrusion boundaries. Stressrelief fractures, nearly horizontal inverted saucer-shaped structures, may form in certain scenarios as the bedrock rebounds from the erosive removal of overlying material (Cressler et al., 1983). These structures may be on the order of a few inches in thickness and may range from about a hundred feet to a quarter mile in diameter. Schists contain dense networks of fine hairline fractures along foliations and have the best developed regolithlbedrock transition zones (Daniel and Harned, 1998). They are not good producers of water, as the fine fractures do not accommodate conduit flow. Fractures in more massive rocks tend to be wider and are more conducive to conduit flow.
2.2 FAVORABLE SCENARIOS FOR OBTAINING GROUND WATER
The regolith itself has been used as a ground-water source for small-scale purposes. The high-yielding wells (Cressler et al., 1988; Williams et al., 2004) derive water from bedrock fractures. Cressler et al. (1988) and Khallouf and Williams (2003) identified scenarios where one can obtain large amounts of ground water in the Piedmont and the Blue Ridge:
1) contact zones between rocks of contrasting character as between a massive granitic gneiss and a deep weathering feldspathic schist;
2) contact zones in multilayered rocks, as the compositionally layered gneisses in Rockdale County;
3) fault zones;
4) stress-relief fractures;
5) zones of fracture concentration, more applicable to massive rocks than to schists or phyllites;

6) small-scale structures that localize drainage;
7) late generation folds, those that post-date peak metamorphism and
have fractured rocks in their hinges;
8) shear zones.

CHAPTER 3. METHODS
3.1 FIELD METHODS
Conductivity, pH, temperature, and, if possible, dissolved oxygen were monitored in the field with a Horiba Model U-10 water quality meter. A Garmin 8 eTrex Legend GPS receiver was used to measure latitude and longitude at the sampling station. At most stations, gamma radiation readings were taken both over a five-gallon plastic bucket filled with sample water (sample reading) and over ground at a distance from the bucket (background reading) (Table A-2, Part A). Gamma radiation readings were taken utilizing a Mount Sopris Instrument Co., Model SC-132 handheld scintillation detector.
In mbst cases, wells had dedicated pumps with plumbing downstream of the wellhead that included spigots or other outlets. The outlet nearest the wellhead was typically used as the monitoring and collection point. A Y-tube formed of garden hose was fitted to the outlet. The Y-tube had a plastic pitcher fitted on one branch to accommodate the water quality meter probe; the other branch of the Y-tube was left open to be used for sampling. The meter probe was inserted into the pitcher and the wellhead pump was turned on to initiate the purging process. Every five minutes, conductivity, pH, dissolved oxygen, and temperature readings were taken and recorded. Monitoring continued until these parameters stabilized, which typically occurred after 15 to 20 minutes of continuous purging. The final recorded readings of pH, conductivity, dissolved oxygen, and temperature are reported in (Table A-2). For springs and for wells with outsized raw water outlets (such as four-inch purge pipes) where the Y-tube connection could not be made, the water quality meter's calibration cup was used to draw aliquots for monitoring. At some springs, a suitable container, such as the half-gallon plastic jug used for chloride and sulfate analyses (see below), was employed to draw sample water and to fill various other sample containers.
Once the field parameters stabilized, a metals sample was collected in a half-liter plastic bottle containing a nitric acid preservative; a nitratelnitrite and phosphorus sample was collected in a plastic 125 milliliter bottle containing a sulfuric acid preservative; and a chloride and sulfate sample was collected in a half-gallon (approx. 2 liter) plastic jug. Where called for, VOC samples were collected in a triplet of septum vials containing a hydrochloric acid preservative.
When sampling was completed, the sample bottles, except for the halfgallon jug, were placed in doubled plastic bags. The bagged samples and the jug were then placed in ice water in a cooler. A trip blank, a septum vial containing clean water and a hydrochloric acid preservative prepared by EPD laboratory personnel, accompanied the VOC samples during transport.

Four wells underwent dual sampling: Fay-2, Ful-2, Hll-2, and Grn-2. The first three were resampled due to reported Primary MCL exceedances or synthetic organic chemical detections. At the last well, one sample was collected at the wellhead and another was collected at a spigot about 600 feet to the west of the wellhead.
3.2 LABORATORY METHODS
Laboratory measurements of the concentrations of VOCs, chloride, nitrate1 nitrite, total phosphorus, and metals took place at the EPD laboratory. The US EPA has approved and assigned identification numbers to various testing procedures, termed EPA methods, used in environmental venues. The EPD lab used the methods given in the table below.

Table 3-1. Analytical Methods

Analyte
Metals (1)
Metals (2) Chloride and Sulfate
T o t a l 1 NitrateINitrite
Sulfide
. VOCs

EPA Method

200.7

ICP

1 ICPIMS

300.0

Ion Chromatography

353.2

Colorimetric

376

Titrimetric

The reporting limit is the lowest concentration of a substance that can be accurately measured. These limits are given in Table A-3 in the Appendix. The typical reporting limits for calcium, nitratelnitrite, and sulfate are 1000 parts per billion (ppb), 0.02 parts per million (ppm) as nitrogen, and 10 ppm, respectively. During the current project, the high concentrations of these substances in some samples caused the reporting limits to be raised.
The ICP (inductively-coupled plasma spectrometry) method is generally the better method for analyzing major metals and abundant minor metals: calcium, magnesium, sodium, iron, manganese, and, to a degree, potassium. The values reported for calcium, cobalt, iron, potassium, magnesium, manganese, sodium, titanium, and vanadium were derived from ICP analysis.
The ICP method is subject to interferences when used for analyzing trace metals. These interferences can result in spuriously high reported concentrations for some metals. During this study, ICP analyses for zinc and nickel proved to be particularly vulnerable to interference. As a result, the values reported for chromium, nickel, copper, zinc, arsenic selenium, molybdenum, silver, cadmium, tin, antimony, barium, thallium, lead, and uranium were derived from ICPlMS

(inductively-coupled plasma spectrometrylmass spectrometry) analysis. The lCPl MS method provides results for trace metals that are more accurate.
Chloride and sulfate were analyzed using ion chromatography, which depends on the affinity of the analyte for an ion-exchange medium. Nitratelnitrite and total phosphorus were analyzed using colorimetric techniques. These methods involve converting the analyte to a strongly colored substance, which can then be compared with a color standard. The method used to test for sulfide is titrimetric, which involves embedding the analyte in a colored solution and then adding a solution with a substance of a known concentration that reacts with the analyte causing the color to disappear. VOCs were analyzed with the GCIMS (gas chromatographylmass spectrometry) technique.

CHAPTER 4. RESULTS
One hundred and twenty six pH measurements were made on all 120 stations tapping the PiedmontlBlue Ridge aquifer system. The pHs ranged from 4.58 to 8.60. The sample water was acidic at 83 stations, basic at 36 stations, and fluctuated at one station. Three stations underwent follow-up sampling because of a reported Primary MCL exceedance or chlorinated hydrocarbon detection. One of these, the fluctuating station well Hll-2, gave basic water for the original sampling and acidic water for the follow-up sampling. At the other two stations, wells Fay-2 and Ful-2, the sample water remained basic although the pH declined. For station Grn-2, another of the dually sampled wells, the wellhead sample registered a lower pH than the sample at the distant spigot.
4.2 CONDUCTIVITY
One hundred and twenty six conductivity measurements were made covering all 120 stations. The conductivity measurements ranged from 6 microsiemenses per centimeter (uS1cm) to 563 uSlcm, with a little over half the stations producing waters with conductivities of 100 uS/cm or less. The two lowest conductivity measurements recorded for this study were made on waters drawn from quartzites: 6 uSlcm for well Mwr-2 tapping the Hollis Quartzite in Meriwether County (Hewitt and Crickmay, 1937) and 9 uS1cm for well Chk-I, drilled into the Pine Log Mountain Quartzite in Cherokee County (John Costello, personal communication). Inspection of Table A-2 shows that sample waters with lower conductivities generally tend to have acidic pHs and lower contents of sulfate and chloride and of the major metals calcium, magnesium, and sodium.
Concerning the four dually sampled wells, conductivities were higher in the second samples from Fay-2 and Hll-2, lower in the second sample from Ful2, and identical in both samples from Grn-2.
4.3 ANIONS AD NON-METALS
Samples from all 120 stations received testing for chloride, sulfate, nitratel nitrite, and total phosphorus. Due to an oversight, the original samples for stations Lin-I and Wik-I did not include the aliquot for nitratelnitrite and total phosphorus. This aliquot was collected in a later sampling. On-site dissolved oxygen measurements are available for 82 stations. Samples from 26 stations underwent analyses for sulfide. Because of a lack of detections and concerns about laboratory capacity, sulfide testing was suspended in mid-June, 2006. Sulfide analyses are not further discussed. By request from a student at the University of California at Riverside via EPA Region 4, two samples (from wells

Lin-I and Mwr-I) were forwarded to that university to be tested for perchlorate. No results have been forthcoming.
4.3.1 Chloride
The chloride contents of sampled waters ranged from undetectable to 22 ppm, far below the Secondary MCL of 250 ppm. Detectable chloride occurred in samples from 15 stations.
4.3.2 Sulfate
Analyses detected sulfate in samples from 41 stations. In the case of dually sampled well Hll-2, testing the initial sample did not detect sulfate, however, testing the follow-up sample resulted in a detection. For dually sampled well Fay-2, the sulfate content of the initial sample exceeded that of the follow-up by one ppm. Sulfate concentrations ranged from undetected to 180 ppm, all below the Secondary MCL of 250 ppm. Although waters with detectable sulfate constituted only about a third of the samples, these waters accounted for half or more of the detections of molybdenum, uranium, and manganese. The two-thirds of the samples with no detectable sulfate accounted for about 80% each of the lead and copper detections.
4.3.3 NitratelNitrite
Nitratelnitrite was detected in samples from 88 stations. Nitratelnitrite ranged from undetected to 16 pprn as nitrogen. The sample with the 16 pprn level, taken from well Sph-I, is the only case in which the level exceeded the Primary MCL of 10 pprn as nitrogen. Well Sph-I is a domestic well located adjacent to a kennel, with another kennel and a now-unused chicken house within a distance of a few hundred feet. Three other samples had nitratelnitrite levels above the 5 pprn level, the level above which the Drinking Water Compliance Program can require intensive monitoring of treated water in a public water supply: domestic well Jak-I (9 pprn), municipal supply well Jak-2 (5.5 pprn), and public restaurant well Mad-2 (5.3 pprn). Likely sources of nitratelnitrite for these three stations were not immediately obvious. Samples from 113 stations contained nitratelnitrite as nitrogen at levels below the 3 pprn level considered the minimum likely reflective of human influence (Madison and Brunett, 1985).
For the multiply sampled wells Fay-2, Ful-2, HII-2, and Grn-I, nitratelnitrite levels remained the same or nearly the same for both samplings at each station.
4.3.4 Dissolved Oxygen
Dissolved oxygen measurements are available for 82 stations. Dissolved oxygen was detected in sample waters from 77 stations and ranged up to 9.63 ppm. Sample waters with basic pHs commonly have low dissolved oxygen

contents; 14 out of 21 stations with basic waters registered dissolved oxygen below 1 ppm. No MCLs exist for dissolved oxygen.
Though the monitoringlsampling apparatus is intended to minimize contact between the atmosphere and the sample water, air can nevertheless enter the sample water upstream of the apparatus and interfere with dissolved oxygen measurements. Jet pumps frequently admit air to the pump water column. Water can begin cascading in open-hole wells when the water level is pumped considerably below a productive fracture. In low recovery wells with small water columns, the water level can be pumped near to or at the pump's intake level and air can be entrained.
4.3.5 Total Phosphorus
Total phosphorus data are available for all 120 stations. Phosphorus was detected in samples from 81 stations. Phosphorus concentrations ranged from undetected to 1.3 pprn, though most are below 0.1 ppm. No obvious association between phosphorus and nitratelnitrite was apparent. Samples with basic pHs, as a rule, had lower phosphorus contents than acidic samples. Excepting vanadium, no obvious association between phosphorus and metals was apparent. Vanadium was analyzed by the ICP method, and, if the analyses are accurate, all samples containing detectable vanadium also contained detectable phosphorus. No MCLs are assigned to phosphorus.
4.4 METALS
The metals analyzed for this project are given in Table A-2 in the Appendix. Analyses failed to detect arsenic, selenium, silver, cadmium, antimony, thallium, beryllium, and cobalt. These metals are not further discussed. Samples from all 120 stations received metals analysis.
4.4.1 Alkali Metals
The EPD laboratory tested for the alkali metals sodium and potassium using the ICP method. Owing to low analytical sensitivity (reporting limit 5,000 ppb), potassium was detected in samples from only three stations. The highest level was 6,400 ppb. No MCLs apply to sodium or potassium.
Sodium concentrations ranged from undetected to 41,000 ppb. Detectable levels of the metal occurred in samples from 116 stations. Two of the stations giving waters with no detectable sodium were wells drilled into quartzite, one deriving water from the Hollis Quartzite (station Mwr-2) and the other from the Pine Log Mountain Quartzite (station Chk-2). Two stations, Bts-I and Ctn-I, tied for the highest sodium concentration, 41,000 ppb. Bts-I, Indian Spring, is a historical mineral spring in Butts County and the site of Indian Springs State Park. Ctn-I, the Pates Creek Well, is a 610-foot deep public well belonging to

the Clayton County Water Authority. Water from this well showed the highest conductivity and the second-highest calcium and sulfate levels encountered in the study. As a general rule, waters with basic pHs and higher conductivities tend to have higher alkali metal contents.
For the dually sampled wells, the sodium levels were noticeably lower in the follow-up sample for Ful-2 but were equal or nearly so for follow-up samples for Fay-2 and Hll-2. For Grn-2, the sodium content of the wellhead sample was higher than of the distant sample. None of these samples had detectable potassium.
4.4.2 Alkaline Earth Metals
The current study examined ground-water levels of the alkaline earth metals calcium, magnesium, and barium. The EPD laboratory determined calcium and magnesium by the ICP method. The laboratory used the ICPIMS method to test for barium. A Primary MCL of 2,000 ppb applies to barium; no MCLs apply to calcium or magnesium.
Calcium was detected in samples from 115 stations, with the maximum level being 100,000 ppb in the sample from well Bwn-2, a public supply well serving a subdivision. This well also produced water with the highest sulfate level and the second highest conductivity observed during the study. The concentration of this metal tends to be depressed in waters with the lowest pHs (below about 6.00).
Magnesium was detected in samples from 95 stations. Two stations tied for the highest level of 16,000 ppb: Tbt-I, a domestic well in Talbot County, and Bib-I, a golf-course irrigation well in Bibb County. Both had conductivities in the moderate 200-300 uSlcm range. The high concentration of magnesium in the Bib-I sample might be due in part to fertilizers used on the golf course. The concentration of this metal tends to be lower in waters at the lowest pHs (below about 6.00).
Barium was detected in samples from 114 stations. The analytical sensitivity afforded by ICPIMS testing for barium showed the metal to be a nearly ubiquitous trace element. The highest concentration of the metal, 590 ppb, was found in water from a domestic well Sph-I in Stephens County. The water from this well, at 4.80, was in the lower range of pHs encountered in this project and contained excessive nitratelnitrite (above 10 ppm as nitrogen) and manganese (above 50 ppb).
For the dually sampled stations Fay-2, Ful-2, Hll-2, and Grn-2, the concentrations of calcium, magnesium, and barium in each sample pair was the same or nearly so.

4.4.3 Copper, Lead, and Zinc
Copper was detected in samples at 24 stations, lead at 25 stations, and zinc at 58 stations. Copper concentrations ranged up to 90 ppb. This level is well below the Secondary MCL of 1,000 ppb and the action level of 1,300 ppb that apply for copper in treated public water. The maximum lead concentration found was 9.4 ppb. This level is below the 15 ppb action level established for lead in treated public water. The highest zinc level encountered was 1,600 ppb, below the 5,000 ppb Secondary MCL for that metal. The highest lead and copper levels occurred in samples from stations Ogr-I and Ful-3, both domestic wells, and the highest zinc concentration occurred in Rok-I, an irrigation well in Rockdale County. Detectable copper and zinc concentrations seem slightly more likely to occur in acid waters, while detectable lead seems about equally likely to occur in acid waters as in basic waters. Detections of two or all three of these metals in a single sample were common.
For the dually sampled stations, only samples from Fay-2 and Grn-2 showed any copper, lead, or zinc. For Fay-2, the zinc and lead levels declined for the second sample and the copper level fell below detection. For Grn-2, zinc declined below detection in the distant sample.
4.4.4 Iron, Manganese, Nickel, Chromium
The EPD laboratory analyzed for these metals using the ICP method. Since they usually are trace metals, the laboratory also used the ICPlMS method for analyzing nickel and chromium. Secondary MCLs of 300 ppb and 50 ppb apply respectively to iron and manganese. Primary MCLs of 100 ppb apply to nickel and to chromium.
lron was detected in samples from 67 stations, with exceedances at 25 stations, 14 of these stations being public supplies. Manganese was found in samples from 63 stations, with exceedances at 36 stations, of which 22 are public supplies. The ICP method returned a spurious nickel exceedance of 200 ppb for the sample from station Hll-2, resulting in a follow-up sampling being conducted. A later check of the ICPIMS results for that station led to the ICP nickel value being discarded. Nickel was accurately detected at three stations, with a high concentration of 18 ppb. Chromium was detected at a level below the Primary MCL at one station. Detectable iron or manganese do not necessarily accompany detectable nickel or chromium.
lron levels in the samples ranged up to 5,600 ppb. Acid waters are somewhat more favorable for iron detections than basic waters, particularly if the iron concentration exceeds the Secondary MCL. For twelve stations where notes comment on sediment in the raw water, excessive iron was detected in samples from ten of those stations. The appearances of the sediments are as follows:

I) general cloudiness (Dws-I , Spd-I);
2) sand and silt-sized particles of weathered rock plus or minus clay (Btw-I, Fay-2, Gmr-I, Jsp-I, Trp-2), including in some cases weathered biotite (Bts-2, Ful-I, Rbn-I);
3) reddish to yellowish brown sludge (Lpk-2, New-2).
Concerning the dually sampled wells, the samples from Grn-2 contained no detectable iron. All samples from Fay-2, Ful-2, and Hll-2 contained excessive iron. For Ful-2, the iron level in the second sample increased, while, for Hll-2 and Fay-2, iron levels in the second samples decreased.
Manganese levels ranged up to 360 ppb. As with iron, acid waters were more favorable for manganese detections and manganese Secondary MCL exceedances than basic waters. For the above-mentioned twelve stations with sediment problems, manganese was detected at ten stations (no detections at Spd-I and Btw-I) and was excessive at six (Trp-2, Rbn-I, New-2, Lpk-2, Jsp-I, Fay-2 - highest level). Manganese occurred along with iron in samples from 47 stations. For the dually sampled wells, the samples from Grn-2 and Ful-2 showed no detectable manganese. The manganese levels for Hll-2 decreased from slightly excessive for the first sampling to not detectable for the second, and, the manganese level at Fay-2 declined for the second sample.
4.4.5 Molybdenum, Uranium, Vanadium
The EPD laboratory found molybdenum in samples from eight stations, with levels ranging up to 10 ppb. No MCLs apply to molybdenum. Proportionately more of the molybdenum detections occurred in basic waters than in acid waters. Uranium accompanied molybdenum in samples from six stations, four of them in basic waters. Molybdenum detections occasionally coincide with zinc detections but do not coincide with iron, manganese, copper, or vanadium detections. None of the dually sampled wells gave samples with detectable molybdenum.
Uranium, found in samples from 35 stations, may be merely uncommon rather than rare. Concentrations ranged up to 43 ppb (station Fay-2), in excess of the Primary MCL of 30 ppb. This exceedance caused Fay-2, a ,municipal supply well, to undergo resampling, which again found excessive uranium. Uranium is more likely to occur in samples that contain chloride, nitrate, or sulfate. Uranium detections were more frequent in basic sample waters. Of the multiply sampled wells, Hll-2 and Ful-2 showed no detectable uranium. For Grn2, the wellhead sample contained uranium, but the distal sample did not. For Fay2, both samples contained excessive uranium at nearly equal concentrations.
Vanadium was detected in six samples from six stations, with a high concentration of 18 ppb. No MCLs apply to vanadium. Two detections of the metal

occurred for stations with basic waters; the remaining four for stations with acidic waters. The two basic samples also contained detectable titanium. A possible association between vanadium and phosphorus was mentioned in section 4.3.5.
4.4.6 Aluminum and Titanium
Aluminum was detected in samples from 17 stations, five of them public supplies, with levels ranging up to 2,700 ppb. Most of the aluminum detections occurred in acidic waters, although the two highest levels came from stations yielding basic waters. Waters with detectable aluminum, as a rule, tended to have lower concentrations of calcium, magnesium, and sodium. Aluminum detections seemed to be proportionally more common in waters with detectable chloride. No obvious association between aluminum and sulfate is apparent. All aluminum detections occurred in waters with detectable nitratelnitrite. Iron or manganese detections accompanied all aluminum detections. In half the cases in which field notes comment on sediment in the sample water, detectable aluminum was present in the water. For aluminum, a Secondary MCL range of 50 ppb to 200 ppb applies, due to the varying success which treatment operations have with controlling aluminum levels. All reportable aluminum for this study was above the 50 ppb level.
Titanium was detected using the ICP method in samples from five stations. The levels ranged up to 270 ppb. No MCLs exist for titanium. In all cases in which detectable titanium was present in the sample water, detectable aluminum was also present.
4.4.7 Volatile Organic Compounds
Analyses for VOCs were for the most part, performed at stations in counties with population growth rates greater than 8% during the period 20002004 (Table A-I). Exceptions were made for low-growth urban counties (e.g., Fulton) and low-growth rural- industrial counties (e.g., Troup and Upson). These two classes of counties could be considered to have increased chances for VOCcontaminated ground water due long-standing industrial and commercial activities.
The EPD laboratory analyzed 88 samples from 86 stations for VOCs. Thirteen samples from 12 stations tested positive for one or more of these compounds. Chloroform was the most widely occurring, being found in waters
from wells Dws-I , Dws-2, Dws-3, Mad-2, Pau-I, Wal-I , and Wsh-I . Methyl-tert-
butyl ether (MTBE) was next, being found in samples from three wells: Fay-2
(both first and follow-up samples), Gwn-I , and Mur-I. Tetrachloroethylene
(PCE) was found in a sample from well Ful-2, and, trichloroethylene (TCE) was found in samples from wells Gwn-I and New-I. None of the occurrences exceeded Primary MCLs (Table A-3 in Appendix). The follow-up sample taken at well Ful-2 did not contain detectable PCE.

4.5 Gamma Radiation
One hundred and eight pairs of gamma-ray measurements are available for 105 stations. The background measurement differed from the above-water measurement at just three stations. At spring Tia-I the position of the overflow pipe prevented filling the five-gallon bucket in a reasonable length of time, so a gamma-ray measurement was taken directly above the overflow pool. The count above the pool was higher than the background most likely because of a heavy mineral lag deposit at the bottom of the overflow pool. At well Pic-2, the location of the well at the side of a crushed stone driveway on a steep hillside , prevented obtaining a suitable background measurement. At well Jak-2, the over-water gamma-ray count exceeded the background gamma-ray count, even though the bucket was moved and paired readings were taken at several points near the well.
The uranium concentration in the sample water from well Jak-I was a moderate 15 ppb, suggesting other radioactive materials may have been present in the water. The owner was advised to consider testing the water for radon and radium.
For the three dually sampled wells with gamma-ray data available, background and over-water measurements were higher at the wellhead than at the distal spigot at well Grn-2. For wells Hll-2 and Ful-2, background and overwater counts measured during the first sampling differed from those taken during the second sampling.

CHAPTER 5. SUMMARY AND CONCLUSIONS
5.1 FIELD PARAMETERS
One hundred and twenty six pH measurements were made on waters from all 120 stations drawing water from the PiedmontIBlue Ridge aquifer system.. The pHs ranged from 4.58 to 8.60. The sample water was acidic at 83 stations and basic at 36 stations. For well Grn-2, the rise in the pH of sample water between the wellhead and the distant spigot showed that plumbing can affect sample water.
One hundred and twenty six conductivity measurements were made covering all 120 stations. The conductivity measurements ranged from 6 uS1cm to 563 uSlcm. Sample waters drawn from quartzites registered the two lowest conductivity measurements recorded for this study: 6uSIcm and 9uSIcm. Inspection of Table A-2 shows that sample waters with lower conductivities generally tend to have acidic pHs and lower contents of sulfate and chloride and of the major metals calcium, magnesium, and sodium.
5.2 ANIONS AND NON-METALS
Samples from all 120 stations received testing for chloride, sulfate, nitrate1 nitrite, and total phosphorus. On-site dissolved oxygen measurements are available for 82 stations. Samples from 26 stations underwent analyses for sulfide. At the request of a student at the University of CaliforniaIRiverside, sent through EPA Region 4, two samples (Lin-I and Mwr-I) were forwarded to that university for perchlorate analysis.
The chloride contents of sampled waters ranged from undetectable to 22 ppm. Detectable chloride occurred in samples from 15 stations.
Analyses detected sulfate in samples from 41 stations. Although waters with detectable sulfate constituted only about a third of the samples, these waters accounted for half or more of the detections of molybdenum, uranium, and manganese. On the other hand, the two-thirds of the samples with no detectable sulfate accounted for about 80% each of the lead and copper detections.
Nitratelnitrite was detected in samples from 88 stations and ranged up to 16 ppm as nitrogen. The sample with the 16 ppm nitratelnitrite content came from a domestic well and represented the only nitratelnitrite Primary MCL exceedance' in the project. An adjacent kennel likely contributes to the nitratelnitrite content of the well water. Another kennel and a now-unused chicken house at distances of a few hundred feet from the well may also be contributors. Three other samples, two from public wells, had nitratelnitrite above the 5 ppm level, the level above which the Drinking Water Compliance Program can require intensive monitoring. No sources of nitratelnitrite for these

wells were immediately obvious. samples from 113 stations contained nitratelnitrite as nitrogen at levels less than 3 ppm, the level above which human influence on the nitrate-nitrogen content is considered likely.
Dissolved oxygen measurements are available for 82 stations. Sample waters at 77 of the stations contained detectable dissolved oxygen, with concentrations ranging up to 9.63 ppm. Sample waters with basic pHs commonly have low dissolved oxygen contents. Dissolved oxygen measurements are subject to interference from well and plumbing configurations that admit air to the sample water.
Total phosphorus data are available from all 120 stations. Phosphorus was detected in samples from 81 stations and ranged up to to 1.3 ppm. All samples containing detectable vanadium also contained detectable phosphorus.
5.3 METALS
Metals were analyzed in samples for all 120 stations, using ICP and ICPIMS methods. The ICP method has generally lower sensitivity and is subject to interferences. The method generally works well for the more abundant metals in ground water such as calcium, magnesium, aluminum, iron, manganese, and sodium. ICPIMS analysis works well for trace metals and can be especially sensitive. This analytical method has showed barium to be a widespread trace metal and has proved uranium to occur more widely than otherwise might be believed. The method did not detect any arsenic, selenium, cadmium, antimony, thallium, silver, or cobalt.
The EPD laboratory tested samples from all 120 stations for the alkali metals sodium and potassium. The low analytical sensitivity for potassium resulted in only three detections, with a. high level of 6,400 ppb. Sodium was detected in samples from 116 stations, with a high level of 41,000 ppb in samples from two wells. Two of the stations providing waters with no detectable sodium were wells drilled into quartzite. One of the wells (Ctn-I) with the highest sodium content also showed the highest conductivity and the second-highest calcium and sulfate levels encountered in the study. As a general rule, waters with basic pHs and higher conductivities tend to have higher alkali metal contents.
Calcium was detected in samples from 115 stations, with the maximum level being 100,000 ppb in the sample from well Bwn-2, a public supply well. This well produced water with the highest sulfate level and the second highest conductivity observed during the study. Magnesium was detected in samples from 95 stations, with a high of 16,000 ppb occurring in samples from two wells. One of these two wells is used for irrigating a golf course, and the magnesium could partly come from fertilizers applied to the course. The concentrations of both metals tend to be depressed in waters with the lowest pHs (below about 6.00).

The ICPIMS method detected barium in samples from 114 stations, with a high level of 590 ppb. This concentration is well below the Primary MCL of 2,000 ppb. The analytical sensitivity afforded by ICPIMS testing for barium showed the metal to be a widespread trace element.
Copper was detected for 24 stations, lead for 25 stations, and zinc for 58 stations. Copper concentrations ranged up to 90 ppb. The maximum lead concentration found was 9.4 ppb. The highest zinc level encountered was 1,600 ppb. These levels were below applicable action levels and MCLs, both Primary and Secondary, for the three metals. Detectable copper and zinc concentrations seem slightly more likely to occur in acid waters, while detectable lead seems about equally likely to occur in acid waters as in basic waters. The three metals commonly occurred in various combinations in single samples.
lron was detected in samples from 67 stations, with Secondary MCL exceedances at 25 stations, 14 of them public supply stations. Manganese was found in samples from 63 stations, with Secondary MCL exceedances at 36 stations, 22 of them public supply stations. Nickel was detected at three stations and chromium at one. The high nickel concentration was 18 ppb.
lron levels in the samples ranged up to 5,600 ppb. lron detections and exceedances tend to be more numerous in acid waters than in basic waters. Turbid sample waters generally had iron present, commonly in excess of the Secondary MCL.
Manganese levels ranged up to 360 ppb. As with iron, acid waters were more favorable for manganese detections and manganese Secondary MCL exceedances than basic waters. Manganese occurred along with iron in samples from 47 stations.
The EPD laboratory found molybdenum in samples from eight stations, with levels ranging up to 10 ppb. Proportionately more of the molybdenum detections occurred in basic waters than in acid waters. Uranium accompanied molybdenum in samples from six stations, four of them in basic waters. Molybdenum detections occasionally coincide with zinc detections but do not coincide with iron, manganese, copper, or vanadium detections.
Uranium, found in samples from 35 stations, may be uncommon rather than rare. Concentrations ranged up to 43 ppb (well Fay-2), in excess of the Primary MCL of 30 ppb. This exceedance caused Fay-2 to undergo resampling, which again found excessive uranium. Uranium is more likely to occur in samples that contain chloride, nitrate, or sulfate. Uranium detections are more frequent in basic sample waters.
Vanadium was detected in six samples from six stations, with a high concentration of 18 ppb. The metal is more common in acidic sample waters than

in basic ones. The two basic samples examined for this study also contained detectable titanium. A possible association exists between vanadium and phosphorus.
Aluminum was detected in samples from 17 stations, five of them public supply stations, with levels ranging up to 2,700 ppb. Most of the aluminum detections occurred in acidic waters, although the two highest levels came from stations yielding basic waters. Waters with detectable aluminum, as a rule, tended to have lower concentrations of calcium, magnesium, and sodium. Aluminum detections seemed to be proportionally more common in waters with detectable chloride. No obvious association between aluminum and sulfate is apparent. In this study, aluminum seems strongly associated with nitratelnitrite, iron, and manganese. Turbid sample waters can contain considerable aluminum.
Titanium was detected in samples from five stations. The levels ranged up to 270 ppb. Sample waters containing detectable titanium also contained detectable aluminum.
The EPD laboratory analyzed 88 samples from 86 stations for VOCs. Thirteen samples from 12 stations tested positive for one or more of these compounds. Chloroform was the most widely occurring, being found in waters from seven stations. MTBE was next, being found in four samples from three stations. Tetrachloroethylene was found in a sample from one station, and, trichloroethylene was found in samples from two stations. None of the
occurrences exceeded Primary MCLs .
5.4 PAIRED SAMPLES
Paired samples were taken at four wells, Fay-2, Ful-2, Hll-2, and Grn-2. The first three underwent follow-up sampling in response to a Primary MCL exceedance or a VOC detection. At the last well, one sample was taken at the wellhead and another at a spigot about 600 feet away from the wellhead. The results for these wells illustrate the effects that plumbing and the passage of time can have on various parameters and solute concentrations. For well Grn-2, the pH increased between the wellhead and the distant spigot; the conductivity stayed the same. For wells Fay-2, Ful-2, and Hll-2, the pH and the conductivity declined for the second sampling. For well Grn-2, the zinc level rose during passage to the distant spigot. For the other three stations, levels of various solutes varied over time. The levels of the metals iron, manganese, aluminum, copper and zinc seemed to undergo the most severe changes. For all four stations, the levels of nitratelnitrite and of phosphorus seemed to undergo a minimum amount of change.

5.5 OCCURRENCES OF NUTRIENTS AND VOCS ACCORDING TO COUNTY CLASS
One of the objectives the project sought to examine was the existence of obvious differences in nutrient (nitratelnitrite and total phosphorus) and VOC contents of ground waters according to county types. Seventy-four of the 120 stations were located in "high-growth" counties. Of the 46 "low-growth counties", 27 are classified as "low-growth ruralJ', 15 are classified as "low-growth ruralindustrial1',and four are classified as "low-growth urban".
5.5.1 VOCs
The detected VOCs consist of chloroform, MTBE, PCE; and TCE. Samples from 12 stations contained detectable VOCs. Nine of these 12 stations are situated in high-growth counties, one is in a low-growth urban county, and two are located in low-growth rural counties. Low-growth urban and ruralindustrial counties might be thought to have increased chances of VOC contamination because of long standing heightened industrial and commercial activities.
No VOCs were found in samples from any of the low-growth ruralindustrial counties. All of the samples containing TCE and MTBE and five of the seven samples containing chloroform originated in high-growth " counties. The sample containing PCE came from a low-growth urban county. The lack of VOC detections in samples from low-growth rural-industrial counties may indicate a need for an increase in the sampling station density.
5.5.2 Nutrients
Nutrient testing examined the sample waters for nitratelnitrite and total phosphorus. Detectable nitratelnitrite occurred in samples from 88 stations (about 73% of all stations). By county class, nitratelnitrite was found in samples from:
18 of 27 "low-growth rural" stations (about 66%); 11 of 15 "low-growth rural-industrial" stations (about 73%); 56 of 74 "high-growth" stations (about 76%); four of four "low-growth urban" stations (100%).
The sample with the highest nitratelnitrite concentration came from a domestic well in a "low-growth rural-industrial" county. The high proportion of "low-growth urban" stations contributing samples with detectable nitritelnitrite owes to the relatively small size of the sample set.
Phosphorus was detected in samples from 79 stations:

1) 23 of 27 "low-growth rural" stations (about 85%); 2) 8 of 15 "low-growth rural-industrial" stations (about 53%); 3) 46 of 74 "high-growth" stations (about 62%); 4) 3 of 4 "low-growth urban" stations (75%).
Again, the size of the sample set may affect some of the above-mentioned findings.
Phosphorus levels seem to be overall higher in ground-waters from lowgrowth rural counties. VOCs and nitratelnitrite, on the other hand, seem to be somewhat inclined to concentrate in ground water in high-growth counties.
5.6 OVERALL QUALITY OF GROUND WATER IN THE PIEDMONTIBLUE RIDGE REGION
From the standpoint of human health, the chemical quality of ground water in the PiedmontIBlue Ridge region is generally good. Only two of the 120 stations visited for the study yielded water with Primary MCL exceedances. One, a domestic well located near animal enclosures, produced water with excessive nitratelnitrite. The other, a municipal public water source, produced water with naturally excessive uranium. Copper, chromium, nickel and lead are subject to health-related limits, but the study found no exceedances for any of these metals. Chromium and nickel are naturally occurring, while copper and lead are mostly derived from plumbing.
Iron, manganese and aluminum are present naturally and occur widely in ground waters from the PiedmontlBlue Ridge region. These metals exceeded Secondary MCLs in samples from 46 of the 120 stations and are a major cause of poor chemical and physical quality for ground water in the region. These three metals are often associated with turbid ground waters. Secondary MCLs apply to the metals copper and zinc and to the anions chloride and sulfate. The study found none of these in excess of its Secondary MCL. 'Copper and zinc, though possibly naturally occurring in cases, seem mostly derived from plumbing. Chloride and sulfate are naturally occurring.

CHAPTER 6. LIST OF REFERENCES
Berry, M., 2005, Domestic Pesticide Sampling Testing Project 2000-2004: Georgia Geologic Survey Project Report 55, 154 p.
Cressler, C.W., Thurmond, C.J., and Hester, W.G., 1983: Ground Water in the Greater Atlanta Region, Georgia. GGS Information Circular 63, 144 p., 1 PI.
Daniel Ill, C.C., and Harned, D., 1997: Ground-Water Recharge to and Storage* in the Regolith-Crystalline Rock Aquifer System, Guilford County, North Carolina: USGS Water Resources Investigations Report 97-4140, 65 p. EPD, 1991, A Ground-Water Management Plan for Georgia: Georgia Geologic Survey Circular 11 (1991 edition).
EPD, 1998, A Ground-Water Management Plan for Georgia: Georgia Geologic Survey Circular 11 (1998 edition).
Glen, J.C., 2001, Pesticide Monitoring Network 1989-2000: Georgia Geologic Survey Project Report 43, 58 p.
Heath, R.C., 1980, Basic Elements of Ground-Water Hydrology with Reference to Conditions in North Carolina: USGS Open File Report 80-44, 87 p.
Hewett, D. F., and Crickmay, G. W., 1937, The Warm Springs of Georgia, Their Geologic Relations and Origin, a Summary Report: USGS Water Supply Paper 818, 40 p., 8 pl.
Madison, R.C., and Brunette, J.O. Brunett, 1985, Overview of the Occurrence of Nitrate in Ground Water of the United States in National Water Summary 1984, Hydrologic Events, Selected Water-Quality Trends, and Ground-Water Resources: USGS Water Supply Paper 2275, p.93-105.
Overacre, L., 2004, Domestic Well Water Testing Project 2003: Georgia Geologic Survey Project Report 53, 65 p.
Shellenberger, D.L., Barget, R.G., Lineback, J.A., and Shapiro, E.A., 1996, Nitrate in Georgia's Ground Water: Georgia Geologic Survey Project Report 25, 12 p., 1 pl.
Stuart, M.A., Rich, F.J., and Bishop, G.A., 1995, Survey of Nitrate Contamination in Shallow Domestic Drinking Water Wells in the Inner Coastal Plain of Georgia: Ground Water, Vol. 33, No. 2, p. 284-290.

US Census Bureau, 1997, in www.fedstats.gov./qf/states/l3000/html, 6 Feb 2007.
US Census Bureau, 2000 Decennial Census Tables, <http://factfinder.census. gov>, Dec. 2006, Jan. 2007.
Williams, L. J. , Albertson P. N., Tucker, D. D., and Painter, J. A., 2004, Methods and Hydrogeologic Data from Test Drilling and Geophysical Logging Surveys in the Lawrenceville, Georgia, Area: USGS Open File Report 2004-1366,41 p.

APPENDIX Laboratory and Well Data

LABORATORY AND WELL DATA

Table A-I shows by county the estimated percent population change between July I,2000 and July I , 2004 and the estimated population density in people per square mile on July 1, 2004. Also shown is the county growth class: high-growth (high), low-growth rural (lowlrural), low-growth urban (lowlurban), low-growth rural-industrial (lowlrural-industrial).

Table A-2 lists the values for both laboratory parameters and field parameters for each well or spring. For this table, the following abbreviations are used:

assn
b g chk sta C I Co. cond.
CPS
Cr. diss 0 2
-
GFC maint. temp
mgr MTBE N A ND NOx PCE POA
PPm PPm N PP~ SO4 TCE uSlcm VOC WMA Wtr. Auth.

=association =background =WMA hunting check station =chloride =county =conductivity =counts per second (Geiger counter) =creek =dissolved oxygen =Georgia Forestry Commission =maintenance =temperature (degrees Celsius) =manager =methyl-tert-butyl ether = not available or not analyzed = not detected =nitratelnitrite =tetrachloroethylene (perchloroethylene) =property owners' association = milligrams per liter (parts per million) = milligrams per liter as nitrogen = micrograms per liter (parts per billion) =sulfate =trichloroethylene = microsiemenslcentimeter =volatile organic compound =Wildlife Management Area =water authority

Table A-3 gives the reporting limits for the various analytes. The list of abbreviations used in Table A-2 also applies to Table A-3.

TABLE A-1 GEORGIA PIEDMONTIBLUE RIDGE COUNTIES, POPULATION GROWTH AND DENSITIES.

TABLE A-I GEORGIA PIEDMONTIBLUE RIDGE COUNTIES, POPULATION GROWTH AND DENSITIES, CONTINUED.

Table A-2. Ground-Water Quality Analyses for the PiedmontlBlue Ridge Unconfined Aquifer System. Part A: Station Identification and Location, Date of Sampling, Field Parameters, VOCs, Anions, and Non-Metals.

Bwn-I Baldwin

MeriwetherIGolden Pond # I (public)

Bwn-2 Baldwin

Erin Shores # I (public)

Bnk-I Banks

Homer Big Well (#101) (public)

Bnk-2

lrvin farm well

Banks

(wash)

B~w-I

Statham Main Spring

Barrow

(public)

Brw-2 Barrow

Auburn Mobile Home Park well (public)

Glade Marina # I (public)

Bib-I Bibb

Oak Haven Golf Club south green well (irrigation)

Bts-I Butts

Indian Spring (historic)

Bts-2 Butts

Welch house well (domestic)

Crl-I Carroll

Tanner State Park well (public)

Crl-2 Carroll

Mclntosh Reserve well (public)

Table A-2. Ground-Water Quality Analyses for the PiedmontlBlue Ridge Unconfined Aquifer System, Continued. Part A: Station Identification and Location, Date of Sampling, Field Parameters, VOCs, Anions, and Non-Metals.

Chk-1 Cherokee
Chk-2 Cherokee
Ctn-I Clayton
Ctn-2 Clayton
Clb-1 Columbia
Clb-2 Columbia
Cow-I Coweta
Cow-2 Coweta
Crw-1 Crawford
DWS-1 Dawson
DWS-2 Dawson
DWS-3 Dawson

Lake Arrowhead # I 6 (public)

34'1 9'49.2" 84'35'52.3''

Ball Ground # I (public)

34'20'09.4" 84'22'28.2"

Clayton County Wtr. Auth. 33'28'34.6"

Pates Cr. Well (public)

84'1 7'39.9

Camp Calvin Lower . Well (public)

33O23'05.9" 84'21'58.0''

Mistletoe State Park mgr's 33'38'32.0''

house well (domestic)

82'22'59.6"

Columbia 2 house well (domestic)

33'28'44.6" 82'1 5'55.1"

Jackson house well (domestic)

33'27'36.3'' 84'52'06.2''

Turin # I (public)

33'1 9'27.0" 84'38'00.6''

Musella # I (public)

32047'45.8" 84'01 '33.2"

GFC Dawson Unit staff house well (domestic)

34'22'49.5'' 84O03'35.3"

Amicalola Falls State Park # I 34'33'34.1"

(public)

84O14'54.5"

Dawson Forest WMA chk sta well (domestic)

34'25'30.2" 84'1 2'27.1"

Table A-2. Ground-Water Quality Analyses for the PiedmontlBlue Ridge Unconfined Aquifer System. Part B: Metals.

Latitude Longitude

Date Sampled

Temp y radiation cps

bg. [ water

VOCs PP~

C1 SO4 NOx S P PPm PPm PPm N PPm PPm

Dgl-I Douglas
Dgl-2 Douglas
Ebt-I Elbert
Ebt-2 Elbert
Fan-I Fannin
Fay-I Fayette
Fay-2 Fayette
Fay-2 Fayette
FSY-1 Forsyth
Frk-I Franklin
Frk-2 Franklin
Ful-I Fulton

Spencer house well (domestic)

33'47'05.9'' 84'43'24.4''

Staton house well (domestic)

33'39'48.1" 84'45'08.7''

GFC Elbert-Madison Co. Unit 34'05'23.1''

(domestic)

82'55'1 9.2"

Wiles house well (domestic)

34'1 3'30.2" 82'49'58.0''

Toccoa River Restaurant well (public)

34'47'00.0'' 84'1 5'51.9"

Wendell Coffee Golf Center 33'30'52.3''

well (public)

84'34'1 4.6"

Brooks # I (public)

33'1 7'26.0" 84'27'36.0"

Brooks # l Repeat (public)

33'17'26.0" 84'27'36.0''

Colonial Club Estates # I (public)

34'15'45.2" 84'02'40.7''

O'Connor house well (domestic)

34'23'14.2'' 83'1 9'03.2"

GFC Franklin-Hart Co. Unit 34'23'52.8''

well (domestic)

83'06'1 6.6"

Costello house well (domestic)

34'1 0'57.7" 84'16'19.7"

ND ND ND NA ND ND RID NA ND ND 0.92 ND ND 11 ND ND ND 12 ND NA ND ND 1.90 NA ND 14 0.11 NA ND 15 0.12 NA ND 16 0.09 NA ND ND ND ND ND 11 ND ND ND ND 0.70 NA

FuI-2 Fulton
Ful-2 Fulton
Ful-3 Fulton
Gmr-1 Gilmer
Gmr-2 Gilmer
Grn-1 Greene
Grn-2A Greene
Grn-2B Greene

Chestnut Hill Academy well 33'33'42.2"

(public)

84'27'52.4''

Chestnut Hill Academy well 33'33'42.2''

(public) Repeat

84'27'52.4"

Rahbar house well (domestic)

34'03'44.1" 84'22'37.4"

Rich Mountain WMA check 34'46'52.0'' station spring (domestic) 84'19'40.3''

WRD Coosawatee rnaint. station well (domestic)

34'416'01 .2" 84'31'21.8''

GFC Greene Co. Unit well 33'34'50.7''

(domestic)

83'04'1 3.1"

Oconee WMA chk sta well 33'23'22.5" (domestic) dress rack bibb 83'07'15.2"

Oconee WMA chk sta well 33'23'25.0" (domestic) wellhead bibb 83'07'05.2''

I pH cond. diss Temp y radiation cps

uSlcrn O Z P P ~'C

bg. water

VOCs PP~

CI 504 NOx S P
PPm PPm PPm N PPm PPm

Grn-3 Greene

Redlands WMA check station 33O40'49.5"

well (domestic)

83'1 6'21.5"

Gwn-I Gwinnett

Rhodes Jordan Park #2 (public)

33'57'34.6" 83O58'44.1"

Gwn-2 Gwinnett

Suwanee # I (public)

Hbr-I

Mt. Airy City Hall Well

Habersham (public)

34'03'14.7'' 84'04'21.3''
34'30'57.9'' 83'30'07.6''

Table A-2. Ground-Water Quality Analyses for the PiedmontlBlue Ridge Unconfined Aquifer System. Part B: Metals.

Latitude Longitude

Date Sampled

VOCs

Hbr-2

Hollifield Spring

Habersham (public)

HII-I

GFC Hall-Banks Unit well

Hall

(domestic)

Hll-2 Hall

Mount Shores Condo Assn well (public)

Hll-2 Hall

Mount Shores Condo Assn well (public) Repeat

Hrs-I

Hucheson house well

Harris

(domestic)

Harris

Lee house well (domestic)

Hok-I Hancock

Kennedy house well (domestic)

Hok-2 Hancock

Mayfield Utilities #2 (public)

Hrt-I Hart

Wiles II house well (domestic)

Hrt-2 Hart
Hrd-I Heard
Hry-I Henry

Bruce lake house well (domestic)
Allen house well (domestic)
Stockbridge #TI (public)

A-I 3

Table A-2. Ground-Water Quality Analyses for the PiedmontIBlue Ridge Unconfined Aquifer System, Continued. Part A: Station Identification and Location, Date of Sampling, Field Parameters, VOCs, Anions, and Non-Metals.

Hry-2 Henry
Jak-I Jackson
Jak-2 Jackson
JSP-I Jasper
Jsp-2 Jasper
Jns-I Jones
Jns-2 Jones
Lin-I Lincoln
Lin-I Lincoln
Lin-2 Lincoln
Lpk-I Lumpkin
Lpk-2 Lumpkin

Fortson 4-H Center oftice well (public)

33'22'35.7'' 84'21'21.1''

Burnett house well
(domestic) .

34'13'19.7" 83'42'09.0

Nicholson Water Authority # I 34'06'46.5"

(public)

83'25'45.0''

Turtle Cove POA Bobolink 33'22'00.2''

Well (#108) (public)

83'50'22.8''

Shady Dale Park Well (#101) 33'23' 54.0"

(public)

83'35'32.7"

GFC Jasper-Jones Unit well 33'07'1 1.On

(domestic)

83'37'34.0''

Gray - Roberts Well
(public)

33'00'50.5" 83'31'18.1"

Mercier house well (domestic)

33'48'1 3.0" 82'34'27.6"

Mercier house well

33'48'1 3.0"

(domestic) Partial Repeat 82'34'27.6''

Elijah Clarke State Park # I 33'51'26.5"

(public)

82'24'46.7"

Butler house well (domestic)

34'34'57.1 " 84'01'52.9''

Long Branch School Well (public)

34'31'21.9'' 83'55'1 2.9"

Table A-2. Ground-Water Quality Analyses for the PiedmontlBlue Ridge Unconfined Aquifer System. Part B: Metals.

Latitude Longitude

Date

pH cond. diss Temp y radiation cps

Sampled

uS/cm O Z P P ~oc bg. [ water

VOCs PP~

CI SO4 NOx S P PPm PPm PPm N PPm PPm

Mcd-I McDuffie

GFC McDuffielWarren Unit 33'26'42.5''

well (domestic)

82'32'31.2''

Mcd-2 McDuffie

Big Hart Creek Camp Well 33'36'58.9''

(public)

82'30'1 6.6"

Mad-I Madison

Watson Mill Bridge State Park 34'02'18.3'' Horse Trail Well (livestock) 83'03'47.9''

Mad-2 Madison

Zeb's Place well (public)

34'1 1'57.9" 83'1 1'52.1"

Mwr-I

GFC Meriwether County Unit 33'01'49.5''

Meriwether well (domestic)

84'45'24.0''

FDR Wilderness Camp # I Meriwether (public)

32'51'55.9'' 84'43'40.8"

Mro-I Monroe

Benson farm well (livestock)

33'00'27.5 83'53'1 3.9"

Mro-2 Monroe

High Falls State Park (#I) day use well (public)

33'1 0'46.2" 84'01'04.6''

Mrg-I Morgan

Price Mill Rd. house well (domestic)

33'45'15.6'' 83'29'36.2''

Mrg-2 Morgan

Rutledge house well (domestic)

33'36'48.5'' 83'34'36.9''

Mrg-3 Morgan

Country Boys RV Park well 3332'07.5"

(public)

83'27'1 5.4"

Mur-I Murray

Fort Mountain State Park # I 34'45'34.0"

(public)

84'42'00.9''

Table A-2. Ground-Water Quality Analyses for the PiedmontlBlue Ridge Unconfined Aquifer System. Part B: Metals.

Mur-2 Murray

Cohutta WMA Cisco check 34'56'46.6 station spring (domestic) 84'41'36.6''

New-I Newton
New-2 Newton

Dial Water System #4 (public)
Mansfield - Kellogg Street
Reserve Well (public)

33'39'42.8" 83'50'48.1"
33'30'53.3'' 83'44'1 3.7"

Oco-I Oconee

Circle C Mobile Home Park 33'55'13.6''

well (public)

83'32'06.0''

Oco-2 Oconee

Creekside Country Club well 33'51'16.5"

(public)

83'1 8'42.7"

Ogr-I

Mathews house well

Oglethorpe (domestic)

33'59'08.7'' 83'14'42.9''

Pau-I Paulding

Hiram # I (public)

33O52'30.4" 84'45'42.5

Pic-I Pickens

Yeargin house well (domestic)

34'29'1 6.5" 84'22'43.1"

Pic-2 Pickens

Yeargin rental house well (domestic)

34'27'21.8'' 84'31'42.7"

Pik-1 Pike

GFC PikelSpaldinglLamar Un 33'1 1'19.5"

well (domestic)

84'1 6'03.9"

Pik-2 Pike

Kenerly house well (domestic)

33'07'59.3" 84'1 6'57.6

Ptm-I Putnam

GFC Putnam Unit well (domestic)

33'1 6'32.3 83'21'58.1''

Table A-2. Ground-Water Quality Analyses for the PiedmontlBlue Ridge Unconfined Aquifer System. Part B: Metals.

Ptm-2 Putnam
Rbn-1 Rabun
Rbn-2 Raburn
Rok-1 Rockdale
Rok-2 Rockdale
Spd-I Spalding
Sph-I Stephens
Sph-2 Stephens
Tbt-I Tal bot
Tbt-2 Talbot
Tia-1 Taliaferro
Tay-1 Taylor

Sugar Creek Farms Property 33'27'50.9'' Owners Assn. Well (public) 83'18'10.0"

Moccasin Creek State Park 34'50'41 .OM

Entrance Well (public)

83'35'21.7"

Tallulah Falls # I (public)

34'44'08.0" 83'23'45.1"

Rockdale Medical Center irrigation well (irrigation)

33'40'47.4" 84'00'1 3.8"

Holy Spirit Monastery spring 33'35'21.2"

(public)

84'04'09.2"

Camp Cecil Jackson # I (public)

33'17'52.3'' 84'1 2'27.4"

Cheek well (domestic)

34'32'40.5'' 83'1 6'20.4"

Toccoa Falls College #2 (public)

34'35'45.9'' 83'21'29.6''

Hucheson farm well (domestic)

32'38'1 0.7" 84'37'31.4"

Big Lazer Creek WMA well 32'46'26.5''

(wash)

84'24'1 6.3"

A. H. Stephens State Park 33'33'46.8

spring (historic)

82'53'54.5"

Antioch Baptist Church well 32'41'54.1''

(wash)

84'1 5'37.1"

Table A-2. Ground-Water Quality Analyses for the PiedmontlBlue Ridge Unconfined Aquifer System. Part B: Metals.

Table A-2. Ground-Water Quality Analyses for the PiedrnontlBlue Ridge Unconfined Aquifer System, Continued. Part A: Station Identification and Location, Date of Sampling, Field Parameters, VOCs, Anions, and Non-Metals.

Twn-I Towns

Young Harris Swanson Rd. 34'55'28.0''

Well (public)

83'51'32.2''

Twn-2 Towns

Hiawassee Mountain Home 34'55'28.4'' Owners Assn. Well (public) 83'38'38.2''

Trp-I Troup

GFC TroupIHeard Unit well 33'1 1'33.1"

(wash)

85'01'27.7''

Trp-2 Troup

Brundage house well (domestic)

33'08'04.0" 85'00'44.1"

Tay-1

Antioch Baptist Church well 32'41'54.1"

Taylor

(wash)

84O15'37.1"

Uno-I

Notla Water Authority #3 34'52'47.8''

Union

(public)

83'58'54.3"

Uno-2 Union

Vogel State Park # I (public)

34'45'50.6" 83'55'42.0"

Uno-3 Union

Coopers Creek WMA check 34O46'19.9" station spring (domestic) 84'04'09.9

Ups-I Upson

GFC Upson Unit well (domestic)

32'54'40.3" 84'1 5'57.9"

Ups-2 Upson

Teal house well (domestic)

32'57'55.7" 84'22'46.5"

Wal-I Walton

GFC WaltonlMorgan Unit well 33'45'37.1"

(domestic)

83'33'06.6''

Wal-2 Walton

Strater house well (domestic)

33'53'47.1" 83'42'1 2.0"

Wrn-I Warren

Norwood # I (public)

33'27'46.5" 82'41 '54.7"

Wsh-I

Hamburg State Park well

Washington (public)

Wte-I White

Unicoi State Park #2 (public)

Wte-2 White

White Creek Christian Academy well (public)

Wik-I

Lee house well

Wilkes . (domestic)

Wik-I Wilkes

Lee house well (domestic) Partial Repeat

Temp y radiatron cps

bg. [ water

VOCs PP~

Wilkes

(public)

Table A-2. Ground-Water Quality Analyses for the PiedmontIBlue Ridge Unconfined Aquifer System. Part B: Metals.
I I I I I I I I I I I I I I I I 1 Station No. Cr Ni Cu Zn Mo Ba Pb U Al Ca Fe K Mg Mn Na Ti V ppb P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~ P P ~

TABLE A-3. CHEMICAL COMPONENTS AND REPORTING LIMITS

Component
v
Vinyl Chloride
1,lDichloroethylene Dichloromethane

Reporting Limit 0.5 ppb 0.5 ppb 0.5 ppb

Component
Dichlorodifluoromethane Chloromethane
Bromomethane

Reporting Limit 0.5 ppb 0.5 ppb 0.5 ppb

Trans-1,2Dichloroethylene Cis-1,2-
l,l,lTrichloroethane Carbon Tetrachloride Benzene

0.5 ppb 0.5 ppb 0.5 ppb 0.5 ppb 0.5 ppb

Chloroethane

0.5 ppb

Fluorotrichloro-

0.5 ppb

methane

I,I-Dichloroethane 0.5 ppb

2,2-Dichloropropane 0.5 ppb

1,2-Dichloroethane 0.5 ppb

Chloroform

0.5 ppb

- - - -

Trichloroethylene 0.5 ppb

I, I-Dichloropropene 0.5 ppb

1,2-Dichloropropane 0.5 ppb

Dibromomethane 0.5 ppb

Toluene

0.5 ppb

Bromodichloro-

0.5 ppb

methane

1,1,2-

0.5 ppb

cis-I ,3-Dichloropro- 0.5 ppb

- Trichloroethane - - pene -

Tetrachloroethylene 0.5 ppb

Tans-1,3-

0.5 ppb

Dichloropropene

Chlorobenzene

0.5 ppb

1,3-Dichloropropane 0.5 ppb

Ethylbenzene Total Xylenes

0.5 ppb 0.5 ppb

Chlorodibromomethane 1,2-Dibromoethane

0.5 ppb 0.5 ppb

Tetrachloroethane

p-Chlorobenzene 0.5 ppb

Bromoform

0.5 ppb

- - - -

o-Chlorobenzene 0.5 ppb

lsopropylbenzene 0.5 ppb

1,2,4Trichlorobenzene

0.5 ppb

I, I ,2,2-

0.5 ppb

Tetrachloroethane

TABLE A-3. CHEMICAL COMPONENTS AND REPORTING LIMITS, CONTINUED.

Trichloropropane n-Propylbenzene
o-Chlorotoluene

0.5 ppb 0.5 ppb

Total Phosphorus Silver (ICP) Aluminum (ICP) Arsenic (ICP) Barium (ICP)

0.02 ppm 10 P P ~ 60 P P ~ 80 P P ~ 10 P P ~

1,2,4Trimethylbenzene

0.5 ppb

Calcium (ICP)

2000 ppb

- -

Cobalt (ICP)

10 P P ~

Sec-Butylbenzene 0.5 ppb

Chromium (ICP)

20 P P ~

- - - -

p-lsopropyltoluene 0.5 ppb

Copper (ICP) . 20 ppb

- - - -

m-Dichlorobenzene 0.5 ppb

Iron (ICP)

20 P P ~

n-Butylbenzene

0.5 ppb

Potassium (ICP)

- -

1,2-Dibromo-3-

0.5 ppb

Magnesium-

chloropropane

Hexachlorobutadi- 0.5 ppb ene

Manganese (ICP)

Naphthalene

0.5 ppb

Sodium (ICP)

5000 ppb
10 ppb 1000 ppb

1,2,3Trichlorobenzene

0.5 ppb

Nickel (ICP)

20 P P ~

Methyl-tert-butyl

0.5 ppb

Lead (ICP)

90 P P ~

- ether (MTBE) - - -

Chloride

10 P P ~

Antimony (ICP)

120 ppb

Sulfate

10 P P ~

Selenium (ICP)

190 ppb

Nitratelnitrite Sulfide

0.02 ppm as Nitrogen 0.1 0 ppm

Titanium (ICP) Thallium (ICP)

10 P P ~ 200 ppb

TABLE A-3. CHEMICAL COMPONENTS AND REPORTING LIMITS, CONTINUED.

Component

Reporting Limit Component

Reporting Limit

Bromobenzene

0.5 ppb

Total Phosphorus 0.02 ppm

1,2,3Trichloropropane n-Propylbenzene

0.5 ppb 0.5 ppb

Silver (ICP) Aluminum (ICP)

10 P P ~ 60 P P ~

o-Chlorotoluene

0.5 ppb

Arsenic (ICP)

80 P P ~

- - - -

1,3,5Trimethylbenzene

0.5 ppb

Barium (ICP)

10 P P ~

p-Chlorotoluene

0.5 ppb

Beryllium (ICP)

10 P P ~

Tert-Butylbenzene 0.5 ppb

Calcium (ICP)

2000 ppb

- - - -

1,2,4-

0.5 ppb

Cobalt (ICP)

10 P P ~

Trimethylbenzene

Sec-Butylbenzene 0.5 ppb

p-lsopropyltoluene 0.5 ppb

m-Dichlorobenzene

n-Butylbenzene
1,2-Dibromo-3chloropropane Hexachlorobutadiene Naphthalene

0.5 ppb 0.5 ppb 0.5 ppb 0.5 ppb

Potassium (ICP) Magnesium (ICP) Manganese (ICP) Sodium (ICP)

5000 ppb 1000 ppb 10 ppb 1000 ppb

1,2,3-

0.5 ppb

- Trichlorobenzene Methyl-tert-butyl

ether (MTBE)

Chloride

10 P P ~

Sulfate

10 P P ~

Nitratelnitrite

Sulfide

0.10 ppm

Nickel (ICP)

20 P P ~

Antimony (ICP) Selenium (ICP)
' Thallium (ICP)

120 ppb
190 ppb -
10 P P ~
200 ppb

TABLE A-3. CHEMICAL COMPONENTS AND REPORTING LIMITS, CONTINUED.

Vanadium (ICP)

10 PPb

Zinc (ICP)

20 PPb

Chromium (ICPIMS) 5 ppb

Nickel (ICPIMS)

10 P P ~

Copper (ICPIMS) 5 ppb

Zinc (ICPIMS)

10 PPb

Arsenic (ICPIMS) 5 ppb

Selenium (ICPIMS) 5 ppb

Molybdenum (ICPIMS)

5 PPb

Silver (ICPIMS)

5 PPb

Cadmium (ICPIMS) 0.7 ppb

Tin (ICPIMS)

30 PPb

Antimony (ICPIMS) 5 ppb

Barium (ICPIMS) 2 PPb

Thallium (ICPIMS) 1 ppb

Lead (ICPIMS)

1 PPb

Uranium (ICPIMS) 1 ppb

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