ANALYSES OF COAL FROM NORTHWEST GEORGIA by S.L.Coleman,T.J.Crawford, and J.H.Medlin prepared in cooperation with the U .S.Geological Survey Georgia Geologic Survey Environmental Protection Division Department of Natural Resources 7 6 CINIRFOCURMLAARTION ANALYSES OF COAL FROM NORTHWEST GEORGIA by S. Lynn Coleman, Thomas J. Crawford, and Jack H. Medlin U.S. Geological Survey The Georgia Geological Survey Department of Natural Resources prepared in cooperation with the U.S. Geological Survey CONTENTS Page Introduction ................................... 1 Coal Sampling Procedures ............................. 2 Precision and Accuracy of Analytical Methods...................... 4 Explanation of Statistical Terms Used in Summary Tables......... 10 Organization of Appendix A........................................ 11 Organization of Appendix B........................................ 12 Acknowledgements .............................................. 14 References .................................................... 15 Appendix A. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 Appendix B. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65 TABLES TABLE 1. Concentration ranges and precision for elements deter- mined by computerized emission spectroscopy by the u.s. Geological Survey 5 2. Detection limits and precision for elements and oxides using X-ray fluorescence analysis, by the U.S. Geological Survey . ............................. . 7 3. Atomic absorption spectroscopy detection limits for elements determined by the U.S. Geological Survey. 8 4. Instrumental neutron activation analysis (INAA) detection limits for elements determined by the U.S. Geological Survey..................................... 9 Page 5. Correlation between field number, USGS laboratory number, and coal bed name for samples from Sand and Lookout Mountains, Georgia and Alabama................ 6~ 6a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama............................ 67 6b. Summary statistical table of analytical data for 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama................................... 69 6c. Major- and minor-oxides and trace-element concentrations in laboratory ash of 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama....... 71 6d. Contents of 22 trace-elements in 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama........................................... 83 6e. Major- minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama....... 89 6f. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, and ash-fusion temperature determinations for 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama . 103 7a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for eight bituminous coal samples from coal bed No. 10, Sand and Lookout Mountains, Georgia and Alabama 111 ii Page 7b. Summary statistical table of analytical data for eight bituminous coal samples from coal bed No. 10, Sand and Lookout Mountains, Georgia and Alabama .... 112 7c. Major- and minor-oxides and trace element concentrations in the laboratory ash of eight bituminous coal samples from coal bed No. 10, Sand and Lookout Mountains, Georgia and Alabama........... . . ... .. . . . .. . ........... 114 7d. Contents of 22 trace-elements in eight bituminous coal samples from coal bed No. 10, Sand and Lookout Mountains, Georgia and Alabama................................... 120 7e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of eight bituminous coal samples from coal bed No. 10, Sand and Lookout Mountains, Georgia and Alabama............................................... 123 7f. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, an ash-fusion temperature determinations for eight bituminous coal samples from coal bed No. 10, Sand and Lookout Mountains, Georgia and Alabama................................ . .. 129 Sa. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for three bituminous coal samples from coal bed No. 9A, Sand and Lookout Mountains, Georgia and Alabama 131 8b. Summary statistical table of analytical data for three bituminous coal samples from coal bed No. 9A, Sand and Lookout Mountains, Georgia and Alabama 132 iii Page 8c. Major- and minor-oxides and trace-element concentra- tions in the laboratory ash of three bituminous coal samples from coal bed No. 9A, Sand and Lookout Mountains, Georgia and Alabama ... 134 8d. Contents of 22 trace-elements in three bituminous coal samples from coal bed No. 9A, Sand and Lookout Mountains, Georgia and Alabama . 139 8e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from coal bed No. 9A, Sand and Lookout Mountains, Georgia and Alabama. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142 8f. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, and ash-fusion temperature determinations for three bituminous coal samples from coal bed No. 9A, Sand and Lookout Mountains, Georgia and Alabama ................................ 148 9a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for four bituminous coal samples from coal bed No. 9, Sand and Lookout Mountains, Georgia and Alabama 150 9b. Summary statistical table of analytical data for four bituminous coal samples from coal bed No. 9, Sand and Lookout Mountains, Georgia and Alabama 151 9c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of four bituminous coal samples from coal bed No. 9, Sand and Lookout Mountains, Georgia and Alabama .................................... 153 iv Page 9d. Contents of 22 trace-elements in four bituminous coal samples form coal bed No. 9, Sand and Lookout Mountains, Georgia and Alabama .................................... 159 9e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of four bituminous coal samples from coal bed No. 9, Sand and Lookout Mountains, Georgia and Alabama ........................................... 162 9f. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, and ash-fusion temperature determinations for four bituminous coal samples from coal bed No. 9, Sand and Lookout Mountains, Georgia and Alabama .................................... 168 lOa. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for three bituminous coal samples from coal bed No. 8, Sand and lookout Mountains, Georgia and Alabama 170 lOb. Summary statistical table of analytical data for three bituminous coal samples from coal bed No. 8, Sand and Lookout Mountains, Georgia and Alabama .. 171 lOc. Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituminous coal samples from coal bed No. 8, Sand and Lookout Mountains, Georgia and Alabama .................................... 173 lOd. Contents of 22 trace-elements in three bituminous coal samples from coal bed No. 8, Sand and Lookout Mountains, Georgia and Alabama .................................... 179 v Page lOe. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from coal bed No. 8, Sand and Lookout Mountains, Georgia and Alabama . 182 lOf. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, and ash-fusion temperture determinations for three bituminous coal samples from coal bed No. 8, Sand and Lookout Mountains, Georgia and Alabama .................................... 188 lla. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for one bituminous coal sample from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama .. 190 llb. Major- and minor-oxides and trace-element concentrations in the laboratory ash of one bituminous coal sample from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama ............................ 191 llc. Contents of 22 trace-elements in one bituminous coal sample from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama ................................... 196 lld. Major-, minor-, trace-element concentrations, on whole-coal basis, of one bituminous coal sample from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama ............................................ 199 vi Page lle. Proximate and ultimate analyses, heat content, forms- of-sulfur, free-swelling index, and ash-fusion temperature determinations for one bituminous coal sample from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204 12a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for seven bituminous coal samples from coal bed No. SA, Sand and Lookout Mountains, Georgia and Alabama 206 12b. Summary statistical table of analytical data for seven bituminous coal samples from coal bed No. SA, Sand and Lookout Mountains, Georgia and Alabama 207 12c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of seven bituminous coal samples from coal bed No. SA, Sand and Lookout Mountains, Georgia and Alabama .................................... 209 12d. Contents of 22 trace-elements in seven bituminous coal samples from coal bed No. SA, Sand and Lookout Mountains, Georgia and Alabama . 215 12e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of seven bituminous coal samples from coal bed No. SA, Sand and Lookout Mountains, Georgia and Alabama . ................................... 218 12f. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, and ash-fusion temperature determinations for seven bituminous coal samples from coal bed No. SA, Sand and Lookout Mountains, Georgia and Alabama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 224 vii Page 13a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for two bituminous coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama . 226 13b. Summary statistical table of analytical data for two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama 227 13c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 229 13d. Contents of 22 trace-elements in two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama 235 13e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 238 13f. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, and ash-fusion temperature determinations for two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 244 14a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama ... 246 viii Page 14b. Summary statistical table of analytical data for 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama 247 14c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 249 14d. Contents of 22 trace-elements in 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 255 14e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia 258 14f. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, and ash-fusion temperature determinations for 11 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama .............................. 264 !Sa. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for three bituminous coal samples form coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama . 266 lSb. Summary statistical table of analytical data for three bituminous coal samples from coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama . 267 ix Page lSc. Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituminous coal samples from coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama.................................... 269 lSd. Contents of 22 trace-elements in three bituminous coal samples from coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama . ................................... 275 lSe. Major-, minor-, and trace-element concentrations on whole-coal basis, of three bituminous coal samples from coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama .................................... 278 lSf. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, and ash-fusion temperature determinations for three bituminous coal samples from coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama . ................................... 284 16a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama . 286 16b. Summary statistical table of analytical data for two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama 287 16c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama .................................... 289 X Page 16d. Contents of 22 trace-elements in two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama .................................. 294 16e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama ........................................... 297 16f. Proximate and ultimate analyses, heat content, formsof-sulfur, free-swelling index, and ash-fusion temperature determinations for two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 303 17a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for one bituminous coal sample from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama 305 17b. Major- and minor-oxides and trace-element concentrations in the laboratory ash of one bituminous coal sample from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama .................................... 306 17c. Contents of 22 trace-elements in one bituminous coal sample from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama . ................................... 311 17d. Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama . ........................................... 314 xi Page 17e. Proximate and ultimate analyses, heat content, forms- of-sulfur, free-swelling index, and ash-fusion temperature determinations for one bituminous coal sample from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 320 APPENDICES Appendix A Field sample number, map location, and stratigraphic section descriptions of coal samples from Sand and Lookout Mountains, Georgia and Alabama. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17 Appendix B Tables of Chem.ical Data............................................ 65 xii INTRODUCTION Many coal samples have been collected from northwest Georgia coal fields over the last 100 years. Chemical analyses of these have been reported in numerous publications including McCallie (1904), Gildersleeve (1946), Butts and Gildersleeve (1948), Johnson (1946), and Nelson (1945). With the exception of Johnson and Nelson, many difficulties are encountered when compilation and comparison of these analyses are attempted. These difficulties fall into several categories, namely: The location of many of these samples with regard to latitude and longitude, elevation, and stratigraphic position is virtually impossible. The type of sample collected is difficult to discern. For example, whether the sample was a full or partial channel, run-of-mine, grab or other; or whether rock partings were included or excluded from the sample. e The analytical standards followed, if any, during the chemical analysis is difficult to determine. e The use of many different names for the same coal bed or the use of one name for several different coal beds is a further difficulty. The analysis of the coal samples by many different laboratories cast doubt on their credibility. To overcome many of these difficulties, a systematic coal sampling and analysis program was initiated in the northwest Georgia coal fields in 1977. The objective of this program, which was integrated with a systematic geologic mapping program of the coal fields, was to collect, 1 where possible, well documented, unweathered coal samples from the northwest Georgia coal fields and to analyze them. The product of the collection, analytical and statistical efforts is the comprehensive analytical data for 47 coal samples presented in this report and discussed by Coleman and others (1985). In the present report more than 100 geologic, geographic, and analytical properties are presented in tables for each of these 47 samples. This includes more than 80 major-, minor-, and trace-element determinations, physical properties, calorific values, and forms-of-sulfur. For a general location of these samples in relation to each other, Figure 1 in Coleman and others (1985) should be consulted. The sample locations for each of the coal samples are also found on 7.5 minute scale geologic maps in Geologic Atlas 2 (Crawford, 1985). COAL SAMPLING PROCEDURES Coal samples generally were collected according to methods outlined by Swanson and Huffman (1976). For completeness, a description of the method used follows. Full channel samples are collected by first selecting a place along the mine high wall or mine face where the coal bed in the exposed area. Approximately 6 to 12 inches of the sampling site is cut back to 3 inches with a pick to obtain fresh coal. The surface 1s then cleaned with a whisk broom to remove rock chips, coal chips, and clay s1ze particles. A channel approximately 4 inches wide and 3 inches deep is collected on a tarpaulin, 6 to 8-feet square, covered by a thick plastic sheet. This procedure will yield approximately 5 pounds of coal for each 1 foot of coal bed thickness. All partings greater than 3/8-inches thick are normally excluded. 2 .28 J "'"":: 6676 ;1ti37G268 &070 13 liB 27 4 16.81 I ~4 0 48 0 4eilf. .28 u 80 71 B EXPLANATION 1. 1GA 2. 2GA 3 3GA 4. 4GA 5. 5GA 6. 6GA 7. 7GA B. BGA 9. 9GA 10. 10GA 11. 11GA 12. 12GA 13 , 13GA 14. 14GA 15. 15GA 16. 1BGA SAMPLES 17. 18. 19. 20 , 21 . 22. 23. 24. 25. 26 . 27 . 28. 29 . 30. 31' 32 . 17GA 18GA 19GA 20GA 21GA 22GA 23GA 24GA 25GA 26GA 27GA 28GA 29GA 30GA 31 GA 32GA 33 . 34 . 35 . 36 , 37 . 38 . 39 . 40 . 41. 42 . 43 . 44 . 45 . 46 . 47 . 33GA 34GA 35GA 36GA 37GA 3BGA 39GA 1ALA 2ALA 3ALA 4ALA 5ALA 6ALA 7ALA BALA COLLECTED BY CRAWFORD-USGS 48 . 49 . 50 . 51 . 52 . BM1-1 BM1-2 BM2-3 BM5-4 BM6-5 53. BM7-6 54. BMB-7 55. BM9-B 56. BM17-9 57. BM19-10 58 , 59 , 60 61 62 . BM19-11 BM-GP1-12 BM-GP5-13 BM-GP6-14 BM-GP6-15 CORE SAMPLE ANALYSES BUREAU OF MINES PROJECT 817 BM (Hole Numberl-(Sample Number) EX , BM6 5 0 5 10 MILES 63 . 64 . 65 . 66 . 67 . 68 . 69 . J-H209 J-H212 J-H213 J-H214 J-H216 J-B42726 J-B42730 70. 71. 7 2. 73 , 74. 7 5, 76 . J-B42731 J-B42734 J-B42735 J-B42736 J-B42737 J-B42853 J-B42854 77 . 78 . 79, 80 , 81 . J-B4304 7 J-B43048 J-B43049 J-B43050 J-B4309S ANALYSES PUBLISHED BY V.H. JOHNSON USGS, 1946 D 82 , G-B42727 83 , G-B42728 84 . G-B43897 ANALYSES PUBLISHED BY B. G, GILDERSLEEVE TVA REPORT, 1946 (FEB) PENNSYLVANIAN ROCKS Figure 1. Coal-bearing Pennsylvanian rocks underlying Sand and Lookout Mountains, Georgia, Alabama, and Tennessee. Black dots locate coal samples collected and analyzed during the U.S. Bureau of Mines Project 817 (Troxell, 1946), and during investigations by Johnson (1946), and Gildersleeve (1946). 3 Detailed descriptions of the coal and enclosing rock lithologies were made ~n the present study. In selected areas, underclay and roof-rock samples were collected. Site documentation consists of locating samples in terms of latitude and longitude, elevation, coal bed, and formation; measuring coal bed thickness; describing the coal bed, describing and estimating the thickness of the overlying and underlying lithologies; and collecting coal samples. PRECISION AND ACCURACY OF ANALYTICAL METHODS Figure 6 ~n Coleman and others (1985) is a diagram which illustrates the plan by which all coal samples are processed by the U.S. Geological Survey. Samples are analyzed by a variety of analytical methods. These include semi-quantitative emission spectroscopy, x-ray fluorescence (XRF), flame atomic absorption spectroscopy (AAS), graphite furnace atomic absorption spectroscopy, wet chemistry, and instrumental neutron activation analysis (INAA). Samples are analyzed either on a whole-coal or coal-ash basis depending on the analytical technique and volatility of the element being determined. The analytical method selected depends on the quality of the analytical determination desired for any specific element. The least precise method is semi-quantitative emission spectroscopy. This method is used for those elements for which other methods are not conveniently available and for which high precision is not critical to the evaluation of coal quality. Detection limits will vary slightly depending on emission speeds and other analytical factors; typical detection limits are given in Table 1; precision is +50 and -33 percent of the amount reported. 4 Table 1. Concentration ranges and precision for elements determined by computerized emission spectroscopy by the U.S. Geological Survey. Oxide Formulas (Majors) Concentration Range (%) Element (Trace) Si02 0.0099 - 73 Ag A1 2o3 0.088 - 60 As Fe 2o3 O.Oll - 34 Au MgO 0.0052 - 50 B CaO 0.0021 - 44 Ba Na 2o 0.0063 - 11 Be K2o 0.082 - 13 Bi Ti02 0.0053 - 25 Cd P2o5 0.16 - ll Ce MnO 0.00013 - 60 Co Cr Cu Dy Er Eu Symbols used in report Ga < less than lower limit (4) Gd > greater than upper limit (4) Ge H note 2 Hf * note 3 Ho Concentration Range (PPM) 0.10 - 10,000 150 - 10,000 10 - 1,500 4.6 - 320 2.2 - 3,200 1.0 10 32 43 1.0 - 680 - 4,600 - 10,000 - 29,000 - 10,000 1.0 - 6,800 1.5 - 3,200 22 - 1,000 10 - 1,000 2.2 - 1,000 1.5 15 1.5 IS 6.8 - 1,000 - 1,000 - 10,000 - 10,000 - 1,000 Element (Trace) In Ir La Li Lu Mn Mo Nb Nd Ni Os Pb Pd Pr Pt Re Rh Ru Sb Sc Concentration Range (PPM) 6.8 - 10,000 15 - 10,000 10 - 10,000 68 - 32,000 15 - 1,000 1.0 -460,000 1.0 - 1,000 3.2- 1,000 32 - 6,800 1.5 - 15,000 22 - 6,800 6.8 - 1,000 1.0- 3,200 68 - 4,600 4.6 - 10, 000 10 - 10,000 2.2 - 10,000 2.2 - 6,800 32 - 10,000 1.0 - 1,000 Element (Trace) Srn Sn Sr Ta Tb Th Tl Tm u v w y Yb Zn Zr Concentration Range (PPM) 10 - 1,000 1.5- 10,000 1.0- 460,000 460 - 10,000 32 - 3,200 22 - 4.6 4.6 320 - 1.0 - 10,000 10,000 1,000 10,000 1,000 10 - 1.5 - 0.15- 15 - 3.2- 10,000 10,000 1,000 10,000 32,000 Notes: I. The relative standard deviation for each reported concentration is plus 50%, and minus 33%. 2. ~denotes the occurrence of an unresolved interference. 3. "*"denotes use of a sample weight less than 15 mg. Reported results are based on the actual sample weight. 4. The above ranges apply for initial calibration conditions. In some cases interferences will narrow the range. CJl Table 2 shows those elements determined by XRF and the detection limit and precision for each. The major oxides are determined by XFR on a coal-ash basis. Chlorine and phosphrous are determined on the whole-coal. Table 3 lists detection limits and relative precision for elements that are determined by atomic absorption spectroscopy. Mercury and fluorine are determined by a combination of instrumental techniques (atomic absorption) and wet chemical techniques on the whole-coal. This procedure is followed because mercury is volatile and is lost at ashing temperatures of 525 degrees C. Table 4 lists the elements, their detection limits, and the precision of the measurements when determined by INAA. This table shows that 24 elements are routinely determined by INAA. These determinations are made on a whole-coal basis because of the volatility of such elements as antimony, selenium, and arsenic. Approximately 600 grams of each coal sample are split and analyzed following an ASTM analytical standard aptly described in U.S. Bureau of Mines Bulletin 638 (1967). These analytical determinations include the proximate and ultimate analyses; forms-of-sulfur, ash-fusibility temperatures, calorific values (Btu per pound), and the free-swelling index. These chemical and physical determinations are important both from a technological viewpoint and in characterizing coal for end use. These determinations provide data which can be used to predict coal washability, reactivity, and product yield of the coal. Characteristics such as the free-swelling index are invaluable in evaluating coals for metallurgical uses and for blending of metallurgical coals. the ash-fusion temperatures are important when the coal is used as a boiler 6 Table 2. Detection limits and precision for elements and oxides using X-ray fluorescence analysis, by the U.S. Geological Survey. Oxide/element CaO MnO Cl p Detection Limit % in ash Precision* (%) 0.1 1 0.1 1 0.01 1 0.01 1 0.01 1 0.01 1 0.01 3 0.01 3 0.1 3 Parts-per-Million in Coal 50 5 so 10 *Precision estimates include errors due to _sample preparation procedures and counting statistics, and assumes concentration levels normally present in coal and coal-ash. 7 Table 3. Atomic absorption spectroscopy detection limits and prec1s1on for elements determined by the U.S. Geological Survey. Element Li Cu Pb Zn Mn Mg Na Detection Limit Parts-Per-Million in Ash 10 10 10 10 10 100 100 Precision* (%) 5 5 10 5 5 5 5 Flameless (Graphite Furnace) Cd 0.1 10 Flameless (Cold Vapor) Hg 0.01 10 *Precision is expressed as percent relative standard deviation and assumes concentration levels normally present in coal and coal-ash. 8 Table 4. Instrumental neutron activation analysis (INAA) detection limits and precision for elements determined by the U.S. Geological Survey. Detection Limit Parts-per-million Fe 400 Na 50 As 1 Ba 200 Br 1 Co 0.5 Cr 5 Cs 0.5 Hf 0.3 Rb 5 Sb 1 Se 1 Precision 2% 2% 2% 20% 2% 2% 5% 15% 15% 30% 5% 5% Detection Limit Parts-per-million Ta 0.5 Th 0.5 Zn 10 Sc 0.03 La 1 Ce 5 Nd 50 Sm 0.1 Eu 0.1 Tb 0.5 Yb 0.5 Lu 0.5 Precision 5% 10% 10% 1% 5% 20% 6% 3% 3% 15% 5% 15% *Precision estimates are expressed in percent relative standard deviation for a single determination on a typical coal as represented by NBS reference sample 1632. 9 feedstock; they indicate the possibility of caking and fouling in the boiler. Ultimate and proximate analyses are important from both a technological and an economic viewpoint, especially the calorific value and the ash and sulfur contents. EXPLANATION OF STATISTICAL TERMS USED IN SUMMARY TABLES The geometric mean (GM) is used as the estimate of the most probable concentration (mode). The GM is calculated by taking the logarithm of each analytical value, summing the logarithms, dividing the sum by the total number of values, and obtaining the antilogarithm of the result. The measure of scatter about the mode used here is the geometric deviation (GD), which is the antilog of the standard deviation of the logarithms of the analytical values. These statistics are used because the quantities of trace elements in natural materials commonly exhibit positively skewed frequency distributions; such distributions are normalized by statistically analyzing and summarizing trace-element data on a logarithmic basis. If the frequency distributions are lognormal, the GM is the best estimate of the mode, and the estimated range of the central two-thirds of the observed distribution has a lower limit equal to GM/GD and an upper limit equal to GM x GD. The estimated range of the central 95 percent of the observed distribution has a lower limit equal to GM/(GD)2 and an upper limit equal to GM x (GD)2 (Connor and others, 1976). The geometric mean 1s generally an adequate estimate of the most common analytical value; it is, nevertheless, a biased estimate of the arithmetic mean. The estimates of the arithmetic means listed in the summary tables in Appendix Bare Sichel's ~statistic (Miesch, 1967). 10 A common problem in statistical summaries of trace-element data arises when the element content of one or more of the samples is below the limit of analytical detection. This results in a "censored" distribution. Procedures developed by Cohen (1959) were used to compute unbiased estimates of the geometric mean, geometric deviation, and arithmetic mean where the data are censored. Following is an explanation of the organization of these chemical and physical data found in the summary tables that constitute the appendices of this circular. All these analytical data are currently stored in the U.S. Geological Survey National Coal Resources Data System (NCRDS). These data may be retrieved from this data system and manipulated and displayed in a variety of formats. ORGANIZATION OF APPENDIX A Appendix A provides sample location data for all 47 coal samples collected and analyzed during this study. For example, each coal sample is located on a part of a 7.5-minute quadrangle map; below this map the sample number, map station number, quadrangle name, scale and contour interval are given. The map station number is the same as those found in Geological Atlas 2, '~eologic maps of the Pennsylvanian System of northwest Georgia" (Crawford, 1985). The map information is followed by a description of the sample location. Included in each sample location description is the sample type, coal bed name, thickness, formation, age, latitude and longitude,, county, description of type of exposure or collection site, elevation, sample collector, and date of collection. 11 A description of the geologic section at the sampling site is given under the heading "section description". This includes an estimate of rock and coal thickness, lithology, lithologic description and pertinent coal petrologic information. Information of this type should provide the user with sufficient detail to relocate the sampling sites and draw conclusions concerning the character of overburden and coal/rock associations. ORGANIZATION OF APPENDIX B Appendix B is preceded by Table 5 which provides a correlation between field numbers and laboratory numbers for each sample collected and analyzed; the coal bed name for each sample is also given. Appendix B is divided into two sections. The first section gives summary type information for all 47 coal samples collected and analyzed during this investigation. In the second section, descriptive, statistical, and analytical information are given on an individual coal bed basis. For each coal bed, there are generally six types of tables, except for those coal beds which are represented by less than two samples. In the later case, only five tables are presented for these coal beds; the summary statistical table is not included. A listing of the six types of tables and a description of their contents follows. 1. Descriptive Table--This table gives the laboratory sample number, state, county, latitude and longitude, formation, coal bed, estimated rank, sample type, and sampled thickness for each sample. 2. Summary Statistical Table--This table lists the oxides/elements, number of values, mean, standard deviation, minimum, 12 maximum, range, geometric mean, geometric deviation, sigma, and zero and qualified values. 3. Major- and minor-oxides and trace-elements in coal ash or 1n laboratory ash. Ashing temperature is 525 degrees C. 4. Content of 22 trace-elements determined on whole-coal, air-dried basis. 5. Major-, minor-, and trace-element concentrations recalculated to whole-coal basis. 6. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations. The proximate analysis includes moisture, volatile matter, fixed carbon, and ash content. The ultimate analysis includes hydrogen, carbon, nitrogen, oxygen, and sulfur concentrations. Also included is the air-dried moisture loss. The forms-of- sulfur include sulfate, organic, and pyritic. The ash-fusion temperatures are initial deformation, softening, and fluid, all in a reducing atmosphere. The ultimate and proximate analyses are presented on three bases: as-received, moisture-free, and moisture- and ash-free. The heating values and forms-of-sulfur are also given on these three bases. 13 ACKNOWLEDGEMENTS We would like to express our appreciation to the many land owners and coal company personnel on Sand and Lookout Mountains for allowing us access to their property and mines to collect the coal samples reported here. We wish to thank David A. Brackett, Chris Maples, David Knight, and J.C. Lumsden who helped collect many of the samples for analyses. Within USGS we are indebted to the following chemist for analyzing the samples: D. W. Golightly, R. Moore, L. Winters, Joseph L, Harris, W. B. Crandell, D. M. McKnown, R. B. Vaughn, S. Danahey, J. Storey, M. Coughlin, Harry J. Rose, Jr., E. Dwornik, G. Sellers, B. Scott, R. Johnson, A. Woodside, S. Fleming, J. Kane, L. Rocke, L. Mei, P. A. Baedecker, C. A. Palmer, H. T. Millard, Jr., S. Lasater, and B. Keaten. The processing of the analytical data by Linda J. Bragg, Kathleen K. Krohn, A. L. Medlin, and Pat Kerr is appreciated. We acknowledge Robin Sutton and Peggy Foose for the drafting of the figures and Melba Berry, Sara Banks, and Connie Gilbert for typing the manuscript. Finally, the thorough reviews of the manuscript by F.O. Simon and John Maberry are much appreciated. 14 REFERENCES Butts, Charles, and Gildersleeve, B. G.~ 1948, Geology and mineral resources ofthe Paleozoic area in northwest Georgia: Georgia Geol. Survey Bull. 54, 176 p. Cohen, A. C., 1959, Simplified estimators for the normal distribution when samples are singly censored or truncated: Techometrics, v. 1, no. 3, p. 217-237. Coleman, S. Lynn, Crawford, Thomas, J., and Medlin, Jack H., 1985, Quality of coal resources of northwest Georgia: Georgia Geol. Survey Bull. 102. Connor, J. J., Keith, J. R., and Anderson, B. M., 1976, Trace-metal variation in soils and sagebrush in the Powder River Basin, Wyoming and Montana: U.S. Geol. Survey, Journal of Research, v. 4, no. 1, p. 49-59. Crawford, Thomas J., 1985, Coal resources of northwest Georgia: Georgia Geol. Survey Bull. 103. Crawford, Thomas J., 1985, Geologic maps of the Pennsylvanian System of north-west Georgia: Georgia Geol. Survey Geologic Atlas 2. Gildersleeve, B. G., 1946, Minerals and structural materials of the Hales Bar and Chickamauga Reservoir areas: Tenn. Valley Authority, U.S. Dep. Commerce, Regional Products Research Division, Rept. No. 4, 54 p. Johnson, V. H., 1946, Coal deposits on Sand and Lookout Mountains, Dade and Walker Counties, Georgia: U.S. Geol. Survey, Preliminary map, scale 1:48,000. McCallie, S. W., 1904, A preliminary report on the coal deposits of Georgia: Georgia Geol. Survey Bull. 12, 121 p. 15 Miesch, A. T., 1967, Methods of computation for estimating geochemical abundance: U.S. Geol. Survey Prof. Paper 574-B, 15 p. Nelson, W. A., 1945, Analyses of Tennessee coals (including Georgia): U.S. Bureau of Mines Technical Paper 671, 243 p. Swanson, V. E. and Huffman, Claude, Jr., 1976, Guidelines for sample collecting and analytical methods used in the U.S. Geological Survey for determining chemical composition of coal: U.S. Geol. Survey Circular 735, 11 p. U.S. Bureau of Mines, 1967, Methods of analyzing and testing coal and coke: U.S. Bureau of Mines Bull. 638, 82 p., 50 figures . . 16 APPENDIX A Field sample number, map location, and stratigraphic section descriptions of coal samples from Sand and Lookout Mountains, Georgia and Alabama 17 Sample No. lGA (Map Sta. 93A, Dougherty Gap Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of No. 4 coal bed (Johnson, 1946), 9 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3433'43"N, 85029'23"W, (3.07 mi or 4.95 km north of Cloudland) Chattooga Co., Ga. Fresh exposure in highwall of active strip mine (Lookout Mountain Coal Co., Chattooga No. 1 Mine). Elev. at base of bed approx 1702 ft (estimated from topo.); coll. by Thomas J. Crawford and Jack H. Medlin, Oct. 16, 1976. Section Description ----~12 ft Shale ----~15 ft Sandstone, massive ----~3 in. Shale, silty ----~2 ft Sandstone, silty ----~5 ft Siltstone, gray, slabby ----~2 ft Siltstone, gray, slabby ----~5 ft Siltstone and shale, laminated, with 3 in. beds of micaceous quartz sandstone, 18 in. from bottom _____6 ft Siltstone, medium-gray, massive, with concretions up to 3 in. in diameter _____9 in. Coal, bright attritus (80 to 90 percent), as bands 1/4 in. or less thick, alternating with dull attritus bands 1/16 in. or less in thickness; fusain bands 1/16 in. or less are common _____.2 in. Shale, dark-gray, with stigmaria fragments _____.2 in.+ Underclay, dark-gray 18 Sample No. 2GA (Map Sta. 82, Dougherty Gap Quad., 1:24,000, c.r. = 5 meters) Sample Location Channel sample of No. SA coal bed (modification of Johnson, 1946), 9 1/4 in. thick; Sewanee Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3403S'45"N, 8S029'17"W (2.09 mi or 3.36 km WSW of Dougherty Gap) Walker Co., Ga. Fresh exposure in highwall of active strip mine (Canamex Coal Corp, Mine G-9). Elev. at base of bed approx. 1867 ft (hand level-topo); coll. by Thomas J. Crawford, August 31, 1977. Section Description ----~20 ft Sandstone, fine- to medium-grained, layering 1/2 in. to 1 in. in lower 3 ft, thickens upward to 6 in. to 8 in. ----~3/4 in. Shale and siltstone, coal; coal occurs as thin discontinuous laminae _____12 ft Shale, clayey, medium-gray, silty, massive, scarce fossil plants; light and dark laminations in upper 3 ft are 1/8 in. to 1/4 in. thick _____9 1/4 in. Coal, mixture of bright attritus and dull attritus; bright, approximately 80 to 90 percent, occurs in layers generally less than 1/4 in. thick alternating with paper-thin layers of dull attritus; scattered pyrite on cleats; fusain is scarce as less than 1/16 in. bands and rare lenses up to 1/4 in. thick _____4 in.+ Shale, clayey, with stigmaria fragments 19 Sample No. 3GA (Map Sta. 104A, Dougherty Gap Quad., 1:24,000, c.r. = 5 meters) Sample Location Channel sample of No. SA coal bed (modification of Johnson, 1946), 8 1/2 in. thick; Sewanee Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3430'37"N, 8529'0l"W (0.79 mi or 1.28 km NNE of Cloudland) Chattooga Co., Ga. Fresh exposure in highwall of active strip mine (operated by William [Bill] Selman, Jr., Summerville, Ga.) Elev. at base of bed approx. 1451 ft (hand level-topo); coll. by Thomas J. Crawford, August 31, 1977. Section Description ----~18 ft Sandstone, very light-gray, medium- to coarse-grained, well sorted. Irregular bedding, 1 in. to 12 in. thick ----~8 1/2 in. Coal mixture of bright and dull attritus; approximately 80 to 90 percent bright attritus in layers generally less than 1/4 in. thick alternating with paper thin dull attritus. Fusain is scarce in the upper and middle parts of bed but constitutes approximately 50 percent of the lower 1 1/2 in. Pyrite is rare on cleat, but forms common small lenses along bedding ----~8 in. Underclay, light- to dark-gray, with stigmaria fragments 20 Sample No. 4GA (Map Sta. 93A, Dougherty Gap Quad., 1:24,000, C.I. = 5 meters) Sample Location Drill hole sample of No. 4 coal bed (Johnson, 1946), 13 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3433'42"N, 8529'24"W (3.07 mi or 4.95 km north of Cloudland) Chattooga Co., Ga. Fresh sample from drill hole cuttings (Lookout Mountain Coal Co. Chattooga No. 1 Mine). Elev. at base of bed approx. 1703 ft (surveyed); coll. by Thomas J. Crawford, September 1, 1977. Section Description ----~20 ft 4 in. Sandstone, light-brown, buff, tan and white; brown and orange in places, friable ____9 ft 2 in. Shale, light-brown to light-gray, sandy; with brown and light-brown friable sandstone layers _ _17 ft Shale, sandy, light-gray, hard to very hard; displays brown gravely spots ____.11 ft 6 in. Shale, dark-gray ____13 in. Coal _ _4ft 9 in. Shale, gray and light-gray; interlayered with hard sandy shale 21 Sample No. 5GA (Map Sta. 87D, Dougherty Gap Quad., 1:24,000, C. I. = 5 meters) Sample Location Channel sample of the No. 4 coal bed (Johnson, 1946), 14 1/2 in. thick; Whitwell Shale member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3434'25"N, 8529'07"W (2.73 mi or 4.40 km SW of Dougherty Gap) Chattooga Co., Ga. Fresh exposure in highwall of active strip mine (Lookout Mountain Coal Co., Chattooga No. 1 mine, Area K). Elev. at base of bed approx. 1800 ft (hand level-topo); coll. by Thomas J. Crawford, September 1, 1977.. Section Description ----~25 ft+ Sandstone, light-gray, fine- to medium-grained, slabby, well developed bedding, 4 in. to 12 in. thick ----~1 ft 6 in. Shale, dark-gray, abundant fossil plants; some coaly material; sandy, with irregular bedding _____11 ft Shale, gray, massive appearing, with ironstone concretions. Light and dark clay laminations in part ----~14 1/2 in. Coal, mixture of bright and dull attritus; approximately 80 to 90 percent bright bands, 1/4 in. or less thick, alternate with paper thin dull attritus bands; fusain common as approximately 1/16 in. lenses. Scarce pyrite along cleats ----~2 in.+ Underclay, light- and dark-gray, with stigmaria fragment 22 Sample No. 6GA (Map Sta. 101, Cedar Grove Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. SA coal bed (modification of Johnson, 1946), 7 1/4 in. thick; Sewanee Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 34040'56"N, 8529'10"W (0.68 mi or 1.10 km NW of Mt. Carmel Church) Dade Co., Ga. (location plots in Walker Co. on the Cedar Grove 7.5' topo. map due to error in placement of county boundary). Slightly weathered exposure in highwall of abandoned strip mine (Canamex Coal Corp., Mine G-8). Elev. at base of bed approx. 2040 ft (hand level-topo); coll. by Thomas J. Crawford, September 1, 1977. Section Description _____10ft+ Sandstone, light-gray to tan (weathered), thin- to thick-bedded ( 4 in. 'to 3 ft); conglomeratic in part ----~5 ft 6 in. Shale and silty shale, gray, light and dark layered in part 4 in. to 6 in. siltstone layer near base _ ____:3 ft Sandstone, beds 9 in. to 16 in. thick _ _12ft Shale, gray, silty, interlayered with siltstone generally 1/2 in. or less thick, shale layers 1/2 in. to 14 in. thick _____7 1/4 in. Coal, irregular; mixture of bright and dull attritus with fusain bands approximately 1/16 in. thick _____4 in.+ Underclay, gray, with .stigmaria fragments. 23 Sample No. 7GA (Map Sta. lR, New Home Quad., 1:24,000, c.r. ... 5 meters) Sample Location Composite test-pit sample of the No. 9 coal bed (Johnson, 1946), 16 in. to 40 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3457' 55"N, 8530'3 9"W ( 1.49 mi or 2.40 km NE of New Home) Dade Co., Ga. Fresh exposure (poorly exposed) in highwall of active strip mine (Galaten-Key Mining Co., Pullen No. 1 Mine). Elev. at base of bed approx. 1365 ft (hand level-topo); coll. by Thomas J. Crawford, September 2, 1977. Section Description ----~20 ft+ Sandstone, gray, weathers to buff and white, fine- to medium-grained, slightly feldspathic and micaceous _ _16 to 20 ft Shale, dark-gray, silty, laminated. Interlayered gray shale and white silty shale, 1/16 in. to 1 in. thick ----~16 to 40 in. Coal, bright and dull attritus, 80 to 90 percent bright attritus, 1n layers generally less than 1/4 in. thick; 10 to 20 percent dull attritus in layers generally less than 1/16 in. thick. Layers folded and offset; minor fusain; pyrite is scarce _____2 ft Sandstone, dark-gray, fine- to medium-grained. No underclay 24 Sample No. 8GA (Map Sta. 4, New Home Quad., 1:24,000, C.I. = 5 meters) Sample Location Composite test-pit sample of the No. 8 coal bed (Johnson, 1946), 18 in. to 20 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 340S8'04"N, 8S030'45"W; (1.50 mi or 2.41 km NE of New Home), Dade Co., Ga. Slightly weathered exposure faced-up in test pit of active mine (Galaten-Key Mining Co., Pullen No. 1 Mine). Elev. at base of bed approx. 1358 ft (hand level-topo); coll. by Thomas J. Crawford, Sept. 2, 1977. Section Descriptio~ ----~20 ft+ Sandstone, gray, medium-grained, weathers buff and white; layering 2 in. to 36 in. thick _____18 to 20 ~n. Coal, bloom exposed around contour. A test pit is being reopened. Sample taken from test pit 25 Sample No. 9 GA (Map Sta lP, New Home Quad., 1:24,000, C.I. = 5 meters) Samp le Location Channel sample of the upper 20 in. of the No. 9A coal bed (modification of Johnson, 1946), total of 54 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3456'5l"N, 8530'39"W; (1.34 mi or 2.15 km ESE of New Home), Dade Co., Ga. Slightly weathered exposure in highwall of active strip mine (Slimp Construction Co.). Elev. at base of bed approx. 1403 ft (hand level-topo); call. by Thomas J. Crawford, Sept. 2, 1977. Section Description _____4 ft Soil ----~25 ft Sandstone ----~18 in. Coal, No. 8 coal bed -----45 ft Shale ----~36 to 42 in. Coal, No. 9 coal bed --------~-5404 to 45 in. ft Shale Coal, No. 9A coal bed (Sample 9 GA represents the upper 20 in.; mostly bright attritus, with little little fusain; no pyrite _____4 in. Shale noted). 26 Sample No. lOGA (Map Sta. lP, New Home Quad., 1:24,000, CI. = 5 meters) Sample Location Channel sample of the upper 41 in. of the No. 9 coal bed (Johnson, 1946); total of 48 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 34057'0l"N, 85030'42"W; (1.19 mi or 1.92 km ESE of New Home), Dade Co., Ga. Fresh exposure in highwall of active strip mine (Slimp Construction Co.). Elev. at base of bed approx. 1452 ft (hand level-topo); coll. by Thomas J. Crawford, Sept. 2, 1977. Section Description - - - '20 ft+ ____48 in. Shale and siltstone Coal, bright attritus (80 to 90 percent), and dull attritus (10 to 20 percent), with minor fusain. Some pyrite. Strong cross-cutting cleat prevents good description of bed. The upper 12 in. contains thin, 1/16 in. to 5/16 in., discontinuous shale partings included in the sample ____:20 ft+ Shale and siltstone 27 Sample No. llGA (Map Sta. lP, New Home Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of the No. 8 coal bed (Johnson, 1946), 18 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3456'54"N, 8S030'45"W; (1.18 mi or 1.90 km ESE of New Home), Dade Co., Ga. Weathered exposure in abandoned adit, 6 ft from portal, near the highwall of active strip mine (Slimp Construction Co.). Elev. at base of bed approx. 1503 ft (hand level-topo); coll. by Thomas J. Crawford, Sept. 2, 1977. Section Description ----~56 ft+ Sandstone and conglomerate ----~18 in. Coal, bright attritus (90 percent) and dull attritus, with little fusain. Pyrite present, but very scarce _ __40 ft+ Shale and siltstone 28 Sample No. 12GA (Map Sta. 18A, New Home Quad., 1:24,000, C. I. = 5 meters) Sample Location Channel sample of the No. 9 coal bed (Johnson, 1946), 17 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3558'19"N, 8533'56"W (2.24 mi or 3.6 km NW of New Home), Dade Co., Ga. Fresh exposure in floor of recently abandoned strip mine (Charbon, Inc. Mine). Elev. at base of bed approx. 1414 ft (hand level-topo); coll. by Thomas J. Crawford, Sept. 8, 1977. Section Description ----~20 ft+ Sandstone, gray, fine- to medium-grained, weathering to buff and tan. Bedding 2 in. to 20 in. thick, well developed _ _20ft Shale, siltstone and silty shale, gray, thinly layered _____1. ft Conglomerate, with large ironstone pebbles in a matrix of coarse quartz sand and pebbles _ _ _4 f t Shale, dark-gray to black, clayey, with little silt ___17 in. Coal, bright and dull attritus; 80 to 90 percent bright attritus in layers generally less than 1/4 in. thick; 10 to 20 percent dull attritus in layers generally 1/16 in. or less thick. Minor fusain in layers up to 1/8 in. thick. Some pyrite as thin lenses and coatings along the cleat. Where the coal bed is exposed in the highwall 1500' to the north, it measures 20 in. thick. Mine inactive since May 1976. Sampled 10 feet away from the base of the highwall. Coal bed pitches and rolls, thickening and thinning over short distances _____1. 0 in + Underclay, gray with stigmaria fragments, upper 10 in. of bed sampled; bottom not exposed 29 Sample No. 13GA (Map Sta. 209, Durham Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of the lower bench of the No. 3 coal bed (Johnson, 1946), 20 in. thick; Vandever Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 340S0'43"N, 8S027'1l"W (1.46 mi or 2.35 km SW of Durham), Dade Co., Ga. Fresh exposure on highwall of active strip mine (Brown Bros. Coal Co.). Elev. at base of bed approx. 1898 ft (estimated from topo); coll. by Thomas J. Crawford, Sept . 9, 197 7 Section Description ----~20 ft+ Shale, gray, silty _____12 in. Coal, pinches out to 0 in. within 30 ft _____4 ft Shale, dark-gray with abundant fossil plants ----~20 in. Coal, approximately 70 to 80 percent bright attritus, 20 to 30 percent dull attritus. Minor fusain in discontinuous lenses less than 1/4 in. thick. Pyrite common along the cleat, and as discontinuous lenses less than 1/4 in. thick ----~3 in.+ Underclay, gray 30 Sample No. 14GA (Map Sta. 210, Durham Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 2 coal bed (Johnson, 1946); Sample No. 14GA represents upper 9 in. of the the No. 2 coal bed; Sample No. 15GA represents the lower 6 in. of the No. 2 coal bed; Vandever Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3450'33"N, 8526'48"W (1.34 mi or 2.15 km SSW of Durham), Dade Co., Ga. Fresh exposure on highwall of active strip mine (Brown Bros. Coal Co.). Elev. at base of bed approx. 1928 ft (estimated from topo); call. by Thomas J. Crawford, Sept. 9, 1977. ----~20 ft+ _____9 in. ----~1/2 to 1 in. _____6 in. _ _ _2 0 f t + Shale and silty shale, gray, finely laminated; 1/32 in. to 1/4 in. thick; shale and silty shale (pale-gray to white) contrast well after weathering Coal, greater than 90 percent bright attritus, less than 10 percent dull attritus; minor fusain. No pyrite noted (Sample No. 14 GA) Shale Coal, greater than 90 percent bright attritus, less than 10 percent dull attritus; minor fusain. No pyrite noted (Sample No. 15 GA) Shale, silty 31 Sample No. 15GA (Map Sta. 210, Durham Quad., 1:24,000, c.r. = 5 meter). Sample Location Channel sample of the No. 2 coal bed (Johnson, 1946); Sample No. 15GA represents lower 6 in. of the the No. 2 coal bed; Sample No. 14GA represents the upper 9 in. of the No. 2 coal bed; Vandever Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3450'33"N, 8526 '48"W ( 1.34 mi or 2.15 km SSW of Durham), Dade Co., Ga. Fresh exposure on highwall of active strip mine (Brown Bros. Coal Co.). Elev. at base of bed approx. 1928 ft (estimated from topo); call. by Thomas J. Crawford, Sept. 9, 1977. ----~20 ft+ _____9 in. _____1/2 to 1 in. ----~6 in. ----~20 ft+ Shale and silty shale, gray, finely laminated; 1/32 in. to 1/4 in. thick; shale and silty shale (pale-gray to white) contrast well after weathering Coal, greater than 90 percent bright attritus, less than 10 percent dull attritus; minor fusain. No pyrite noted (Sample No. 14 GA) Shale Coal, greater than 90 percent bright attritus, less than 10 percent dull attritus; minor fusain. No pyrite noted (Sample No. 15 GA) Shale, silty 32 Sample No. 16GA (Map Sta. 211, Durham Quad., 1:24,000, C.I. = 20 ft) Sample Location Channel sample of the upper bench of the No. 3 coal bed (Johnson, 1946), 22 in. thick; Vandever Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3451'59"N, 852S'll"W (1.40 mi or 2.25 km SSW of Durham) Dade Co., Ga. Fresh exposure in highwall of active strip mine (Brown Bros. Coal Co.). Elev. at base of bed approx. 1897 ft (estimated from topo); call. by Thomas J. Crawford, Sept. 9, 197 7 Section Description ----~25 ft+ Shale, gray, silty in part; sandy in upper 8 ft to 12 ft ----~22 m. Coal, bright attritus 80 to 90 percent, dull attritus 10 to 20 percent, with thin 1/16 in. to 1/32 in. thick fusain bands at 1/2 in. to 1 in. intervals, discontinuous ----~2 to 3 in. Shale, gray to black, coaly ------'2 in. _____18 m. Coal Shale, gray ------'20 in. Coal--not sampled here; apparent equivalent bed sampled a short distance to the NW (Sample No. 13GA) 33 Sample No. 17GA (Map Sta. 200, Durham Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of the upper bench of the No. 3 coal bed (Johnson, 1946), 13 1/2 in. thick; Vandever Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3451'59"N, 8525'll''W (0.93 mi or 1.50 km NE of Durham) Walker Co., Ga. Slightly weathered exposure in recent test pit on highwall of old abandoned strip mine. Elev. at base of bed approx. 1839 ft (estimated from topo); call. by Thomas J. Crawford, Sept. 9, 1977. Section Description ----~20 ft+ Shale and silty shale, well laminated, alternating clay and silt layers 1/16 in. to 1/4 in. thick. Discontinuous 3 in. to 6 in. layers of crossbedded fine sand and silt. Abundant fossil plants _ _13 1/2 in. Coal, 60 to 70 percent bright attritus, 30 to 40 percent dull attritus, minor fusain; no pyrite noted. Lower part of bed is under water in test pit, not included in measurement or sample _____18 in.+ Shale, dark-gray, clayey, parting 34 Sample No. 18GA (Map Sta. 38, Hooker Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 4 coal bed (Johnson, 1946), 13 1/4 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3453'30"N, 8524'24"W (0.19 mi or 0.30 km south of Camp Lookout), Walker Co., Ga. Fresh exposure in floor of active strip mine, Brown Bros. Coal Co., Church Property Mine. Elev. at base of bed approx. 1664 ft (hand level-topo); call. by Thomas J. Crawford, Sept. 9, 1977. Section Description ----~20 ft+ Shale and silty shale, gray to black, dense; interlayered silt and shale laminae ----~20 ft Shale, gray, with abundant fossil plants _____13 1/4 in. Coal, 70 to 80 percent bright attritus, 15 to 25 percent dull attritus, and 5 percent fusain _____4 in.+ Underclay, gray, with stigmaria fragments 35 Sample No. 19GA (Map Sta. 56, New Home Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of the No. 9A coal bed (Johnson, 1946), 18 in. to 56 in. thick (36 in. sampled); Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3454'40"N, 8531'19"W (2.48 mi or 4.0 km NNW of Trenton), Dade Co., Ga.; slightly weathered exposure at base of cliff overhang near old abandoned underground mine (New England Co. Mine, McCallie, 1904). Elev. at base of bed approx. 1380 ft (estimated from topo); coll. by Thomas J. Crawford, Aug. 15, 1978. _ __;17 ft+ ----~18 to 56 in. _____.2 ft+ Siltstone and fine-grained sandstone Coal, No. 9A bed, extremely deformed (folded, fractured, and faulted); sulfide lenses near the middle of the bed. Bed 36 in. thick where sampled Shale 36 Sample No. 20GA (Map Sta. 68, New Home Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of the No. 8 coal bed (Johnson, 1946), 30 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian, 3456'39"N, 8335'33"W (2.80 mi or 4.5 km SSE of the GA-ALA-TENN boundary intersection), Dade Co., Ga. Slightly weathered exposure at base of cliff overhang adjacent to abandoned mine portal (Castle Rock Mine, old, underground, abandoned; McCallie, 1904); elev. at base of bed approx. 1375 ft (hand level-topo); coll. by Thomas J. Crawford, Aug. 31, 1978. Section Description _____49 ft+ Conglomeratic sandstone and quartz-pebble conglomerate of Warren Point Member of Gizzard Formation ----~30 to 40 in. Coal, No. 8 bed; rom-scale fusain/vitrain banding. No shale breaks noted; no pyrite noted _ __:3 ft Underclay _____47 ft+ Shale and siltstone, interbedded 37 Sample No. 21GA (Map Sta. 9, Trenton Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 10 coal bed (Johnson, 1946), 28 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3449'20"N, 84030'22"W (3.39 mi or 5.45 km SSE of Trenton), Dade Co., Ga.; weathered exposure approx. 10ft in from portal of old, abandoned mine (Phoenix Iron and Coal Co. mine, McCallie, 1904); elev. at base of bed approx. 1815 ft (hand level-topo); coll. by Thomas J. Crawford and David A. Brackett, June 27' 1979. Section Description _____83 ft+ Sandstone and quartz-pebble conglomerate of Warren Point Member of Gizzard Formation _ _28 in. Coal, No. 10 bed, generally bright, but extremely contorted, and sheared; scattered thin sulfide "eyes" and lenses of shale "sheared into" the coal ___8 in. Underclay ----20 ft+ Siltstone, shale, and fine-grained sandstone, interbedded 38 Sample No. 22GA (Map Sta. 10, Trenton Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 9A coal bed (modification of Johnson, 1946), 32 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3447'56"N, 85031'00''W (2.73 mi or 4.4 km NNE of Rising Fawn), Dade Co., Ga.; weathered exposure at portal of old, abandoned mine (Georgia Iron and Coal Co., Hannah Bank Mine, McCallie, 1904); elev. at base of bed approx. 1862 ft (hand level-topo); coll. by Thomas J. Crawford and David A. Brackett, June 27, 197 9. Section Description _____40 ft Sandstone and quartz-pebble conglomerate _____4 in. Shale ----~32 in. Coal, No. 9A, mostly bright attritus, but extremely deformed; no regular cleat; minor sulfide noted ____6 in. Underclay _ _ 40ft Warren Point sandstone and quartz-pebble conglomerate 39 Sample No. 23GA (Map Sta. 13, Trenton Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 10 coal bed (Johnson, 1946), 21 in. thick (19 in. sampled); Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3446'31"N, 8530'41"W (1.49 mi or 2.4 km NE of Rising Fawn), Dade Co., Ga.; weathered exposure at portal of old, abandoned mine (High Point Mine, McCallie, 1904). Elev. at base of bed approx. 1877 ft (hand level-topo); coll. by Thomas J. Crawford and David A. Brackett, July 2, 1979. Secti_gn D~scrj.J!!ion _ ___40 ft+ Sandstone and quartz-pebble conglomerate of Warren Point Member of Gizzard Formation ___9 1.n. Coal, No. 10 coal bed; upper 19 in. of coal sampled, excluding the 2 in. shale break ---~2 ~n. Shale _ ___10 to 14 ~n. Coal _ _ _4 ~n. Shale ___.2 in. Coal 40 Sample No. 24GA (Map Sta. 51, Durham Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 10 coal bed (Johnson, 1946), 42 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3447'30"N, 8528'4S"W (1.24 mi or 2.0 km west of Newsome Gap), Dade Co., Ga.; weathered exposure at portal of old, abandoned mine (Georgia Iron and Coal Co., Drift No. 4, McCallie, 1904); elev. at base of bed approx. 1850 ft (hand level-topo); coll. by Thomas J. Crawford and David A. Brackett, July 3, 1979. Section Description _____40 ft+ Sandstone and quartz-pebble conglomerate of Warren Point Member of Gizzard Formation _____.27 ft Shale, siltstone, and thin-bedded sandstone, interbedded ___7 ft 6 m. Sandstone _____42 in. Coal, No. 10 bed, extremely deformed (folded, broken), with shale streaks, and a few thin sandstone beds folded in with the coal _____5 in. Shale _____6 ft Sandstone, fine-grained, thin-bedded _ _14ft Siltstone, shale, and sandstone 41 Sample No. 25GA (Map Sta. 32, Hooker Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 4 coal bed (Johnson, 1946), 23 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3452'31"N, 8525'18 W 11 (2.92 mi or 4.7 km SW of Nickajack Gap) Walker Co., Ga.; slightly weathered exposure on adit wall approx. 25 ft from portal of old, abandoned mine (No. 78 of Johnson, 1946). Elev. at base of bed approx. 1621 ft (hand level-topo); coll. by Thomas J. Crawford and David A. Brackett, Dec. 12' 197 9. __Section Descri~ion _;20 ft+ Newton Sandstone Member of Crab Orchard Mountains Formation ___67 ft Shale, siltstone, and fine-grained lenticular sandstone ___.23 in. Coal, No. 4 bed _ _2ft Underclay - - -20 ft+ Shale, siltstone, and fine-grained lenticular sandstone 42 Sample No. 26GA (Map Sta. 123, Durham Quad., 1:24,000, c.r. = 10 meters) Sample Location Channel sample of the No. 4 coal bed (Johnson, 1946), 18 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3449'59"N, 8525'46"W (1.86 mi or 3.0 km south of Durham) Walker Co., Ga.; fresh exposure on highwall of active strip mine (Brown Bros. Coal Co., Inc., Hise Mine); elev. at base of bed approx. 1863 ft (hand level- topo); coll. by Thomas J. Crawford, Dec. 17, 197 9. Section Description ----~5 ft Shale, weathered -----4 to 6 in. Coal _____10 to 19 ft Siltstone, light- and dark-gray, shaly; lenticular _____15 ft Sandstone, light-gray, fine-grained, feldspathic and micaceous; lenticular _____18 1n. Coal, bright (80 to 90 percent) and dull (10 to 20 percent) attritus in bands less than 1 mm thick. Pyrite scarce and along cleat _____6 ft+ Underclay, gray, with stigmaria fossil plants 43 Sample No. 27GA (Map Sta. 136, Durham Quad., 1:24,000, C.I. = 10 meters) Sample Loca~ion Channel sample of No.4 coal bed (Johnson, 1946), 20 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3450'49"N, 8524'42"W (1.52 mi or 2.45 km SE of Durham), Walker Co., Ga. Fresh exposure in highwall of abandoned strip mine; elev. at base 'of bed approx. 1882 ft (hand level-topo); call. by Thomas J. Crawford and Chris Maples, July 16, 1980. Section DescriJ?!ion ----~20 ft+ Shale, gray, silty in part; with sandstone lenses up to 6 ft thick ----~20 in. Coal, 75 to 80 percent vitrain, 10 to 15 percent fusain; approx. 5 percent dull attritus; mm-scale layering. Pyrite scattered as thin film on cleat and _____1/2 in. bedding and concentrated with attritus Shale -__-_-_-_71 in. in. Coal Underclay -----1 in. ----~20 in.+ Coal streaks Underclay 44 Sample No. 28 GA (Map Sta. 142A, Durham Quad., 1:24,000, c.r. = 10 meters) Sample Location Channel sample of No. 1 coal bed (Johnson, 1946), 25 in. thick; Vandever Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3451'15 11N, 8526'25 11W (0.50 mi or 0.8 km SW of Durham), Walker Co., Ga. Slightly weathered adit-wall exposure, approx. 50 ft in from portal; adit is in highwall of old abandoned Durham strip mine; elev. at base of bed approx. 1923 ft (hand level-topo); coll. by Thomas J. Crawford and Chris Maples, July 18, 1980. Section Description ----~20 ft+ Shale and siltstone, interbedded ----~25 in. Coal, No. 1 bed ----~3 ft+ Shale, coaly, with abundant pyrite 45 Sample No. 29GA (Map Sta. 152, Durham Quad., 1:24,000, c.r. = 10 meters) Sample Location Channel sample of No. 4 coal bed (Johnson, 1946), 19 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3449'53"N, 8526'32"W, (1.99 mi or 3.2 km SSW of Durham), Walker Co., Ga.; slightly weathered adit-wall exposure, approx. 50ft in from portal (old abandoned mine); elev. at base of bed approx. 1804 ft (hand level-topo); coll. by Thomas J. Crawford and Chr i s Maples, Aug. 12, 1980. =S-=ec.::c-=t-=i:.::ocn='--=D:.e.::.:s::..c:=riP t ion ___15 ft+ Shale, siltstone, and thin-bedded sandstone, interbedded - - --'19 in. _ _ __;3 ft+ Coal, No. 4 bed; mostly bright attritus Underclay 46 Sample No. 30GA (Map Sta. 50, Dougherty Gap Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of the No. SA coal bed (modification of Johnson, 1946), 13 in. thick; Sewanee Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3433'57"N, 8526'26"W (at the head of Neal Gulf, on Allgood Branch), Chattooga Co., Ga.; slightly weathered sample from pillar of old abandoned underground mine, approx. 60 ft from portal; elev. at base of bed approx. 1586 ft (hand level-topo); coll. by Thomas J. Crawford and Chris Maples, Aug. 13, 1980. Section Description ----~53 ft+ Quartz-pebble conglomerate and sandstone of Sewanee Member _____.13 in. Coal, No. SA bed; mostly bright attritus ---~24 in.+ Underclay 47 Sample No. 31GA (Map Sta. 13, Dougherty Gap Quad. 1:24,000, C.I. = 5 meters) Sample Location Channel sample of the No. 10 (11?) coal bed (Johnson, 1946), 21 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 34 36' 05"N, 85 25' 17"W (0.72 mi or 1.16 km NW of Harrisburg Gap), Walker Co., Ga. Slightly weathered adit-wall exposure approx. 10 ft in from portal of prospect adit. Elev. at base of bed approx 1490 ft (hand 1evel-topo); coll. by Dave Brackett, Thomas J. Crawford, and Chris Maples, August 14, 1980. Section Description _____ 6 ft+ Sandstone, fine- to medium-grained, lenticular, massive ____.16 m. Siderite-pebble conglomerate _ _10ft Shale, gray, silty ___ _.21 in. Coal, No. 10 (11?) bed; sheared and shaly 1n lower 4 in. of bed ---2 ft+ Siltstone and shale, interbedded 48 Sample No. 32GA (Map Sta. 74, Cedar Grove Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 10 coal bed; Johnson (1946) correlated this bed with the No. 8 in his report. This sample represents the upper 31 in. of a 45 in. coal bed. The lower 14 in. contains shale partings and was not included in this sample; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3444'28"N, 8529'12"W (1 . 27 mi or 2.05 km due north of Tatum Gulf) Dade Co., Ga. Slightly weathered exposure at the portal of old underground mine (abandoned). Elev. at base of bed approx. 1724 ft (hand level-topo); coll. by Thomas J. Crawford and David Knight, June 25, 1981. Section Description 20 ft+ 29 ft 19 ft 45 l.n . 10 in.+ Sandstone and quartz-pebble conglomerate of the Warren Point Member of the Gizzard Formation Siltstone, interbedded with shale and thin-bedded sandstone Sandstone, lenticular, interbedded with shale and siltstone Coal, No. 10 bed; lower 14 in. contains shaly partings and was not included in this sample. Sample No. 32GA represents only the upper 31 in. Underclay 49 Sample No. 33GA (Map Sta. 74, Cedar Grove Quad., 1:24,000, c.r. = 10 meters) Sample .Location Channel sample of the No. 10 coal bed; Johnson (1946) correlated this bed with the No. 8 in his 1946 report; 45 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3444'28"N, 8529'12"W (1.27 mi or 2.05 km due north of Tatum Gulf), Dade Co., Ga. Slightly weathered exposure at the portal of old underground mine (abandoned); elev. at base of bed approx. 1724 ft (hand level-topo); collected by Thomas J. Crawford and David Knight, June 25, 1 981 Section Description 20 ft+ 29 ft 19 ft 45 in. 10 in.+ Sandstone and quartz-pebble conglomerate of the Warren Point Member of the Gizzard Formation Sandstone, interbedded with shale and thin-bedded sandstone Sandstone, lenticular, interbedded with shale and siltstone Coal, No. 10 bed; lower 14 in. contains shaly partings Underclay 50 Sample No. 34GA (Map Sta. 100, Dougherty Gap Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of the No. 4 coal bed (Johnson, 1946), 13 1/2 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 34032'40"N, 8529'42"W (2.02 mi or 3.25 km due north of Cloudland), Chattooga Co., Ga. Fresh exposure in highwall of abandoned strip mine. Elev. at base of bed approx. 1641 ft (hand level-topo). This coal bed has a total thickness of 28 1/2 in. including a 6 in. shale break. This sample represents only the 13 1/2 in. of coal above the shale break. Coll. by Thomas J. Crawford and David Knight, Sept. 8, 1981. Section Description _ _12ft _ _18ft 3 ft _ _13 1/2 in. 6 in. 9 1n. 2 in.+ Shale, buff weathering; fossil plant debris Sandstone, fine- to medium-grained, thin bedded; some siltstone and shale interbedded Siltstone, fine-grained sandstone, thin bedded; and shale, interlayered Coal, bright, with finely spaced cleat; coal bed is too disturbed for accurate description. Minor pyrite along cleat Shale, gray, coaly Coal, shaly, with pyrite along cleat Underclay, gray, with stigmaria fragments 51 Sample No. 35GA (Map Sta. 100, Dougherty Gap Quad., 1:24,000, C. I. = 5 meters) Sample Locatio~ Channel sample of the No. 4 coal bed (Johnson, 1946), 9 in. thick; w~itwell Shale Member of the Crab Orchard Mountains Formation , Lower Pennsylvanian; 3432'40"N, 8529'42"W (2.02 mi or 3.25 km due north of Cloudland), Chattooga Co., Ga. Fresh exposure in highwall of abandoned strip mine; elev. at base of bed approx. 1640 ft (hand level-topo); this coal bed has a total thickness of 28 1/2 in., including a 6 in. shale break. This sample represents only the 9 in. of coal below the shale break. Coll. by Thomas J. Crawford and David Knight, Sept. 8, 1981. Section .Descrip!ion _ __1. 2 ft _ _18ft --- 3 ft ___.13 1/2 1.n. 6 1.n. ___ 9 1.n. 2 in.+ Shale, buff weathering; fossil plant debris Sandstone, fine- to medium-grained, thin-bedded; some siltstone and shale interbedded Siltstone, fine-grained sandstone, thin-bedded; and shale, interlayered Coal, bright, with finely spaced cleat; coal bed is too disturbed for accurate description. Minor pyrite along cleat Shale, gray, coaly Coal, shaly, with pyrite along cleat Underclay, gray with stigma~ia fragments 52 Sample No. 36GA (Map Sta. 97A, Dougherty Gap Quad., 1:24,000, C. I. = 5 meters) Sample Location Channel sample of No. 4 coal bed (Johnson, 1946), 13 in. thick (2 1/2 in. of shale followed by 2 in. of coal in the lower part of the bed were included in the sample); Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3433'30"N, 8528'12"W (1.27 mi or 2.05 km due West of GA HWY 239 at Neal Gap), Chattooga Co., Ga. Fresh exposure in highwall of abandoned strip mine. Elev. at base of bed approx. 1703 ft (hand level-topo); coll. by Thomas J. Crawford and J. C. Lumsden, July 6, 1982. Section Description _ __;23 ft+ _ _.13ft __ 2 1/2 m. ___ 2 1n. ___ 6 in.+ Siltstone, shale and sandstone, all thin-bedded and interbedded, laser-bedded in part, lenticular. Sandstone beds generally less than 1 in. to 8 in. thick Coal, pyrite noted along cleat Shale Coal Underclay Sample 36GA is from the 13 1n. coal bed; sample 37GA is a composite of the 13 in. coal bed plus the 2 in. coal bed and the 2 1/2 in. thick shale bed 53 Sample No. 37GA (Map Sta. 97A Dougherty Gap Quad., 1:24,000, C.I. = 5 meters) Sample Locations Channel sample of the No. 4 coal bed (Johnson, 1946), 17 1/2 in. thick (includes 2 1/2 in. of shale); Whitwell Shale Member of the Crab Mountains Formation, Lower Pennsylvanian; 34 33' 30"N; 85 28' 12"W (1.27 mi or 2.05 km due West of GA HWY 239 at Neal Gap) Chattooga Co., Ga. Fresh exposure in highwall of abandoned strip mine; elev. at base of bed approx. 1703 ft (hand level-topo); coll. by Thomas J. Crawford and J.C. Lumsden, July 6, 1982. Section De scription ----~23 ft+ Siltstone, shale and sandstone, all thin-bedded and interbedded, flaser-bedded in part lenticular sandstones beds generally less than 1 in. to 8 in. thick _____1. 3 in. Coal, pyrite noted along cleat __ 2 1/2 in. Shale _____ 2 in. Coal _____ 6 in.+ Underclay Sample 36GA is from the 13 in. coal bed; sample 37GA is a composite of the 13 in. coal bed plus the 2 in. coal bed and the 2 1/2 in. shale bed 54 Sample No. 38GA (Map Sta. 125 Dougherty Gap Quad., 1:24,000, c.r. = 5 meters) Sample Location Channel sample of the No. SA coal bed (Modification of Johnson, 1946), 14 in. thick; Sewanee Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 34 34' 37"N, 850 28' 03"W (1.65 mi or 2.65 km NW of GA HWY 239 at Neal Gap), Chattooga Co., Ga. Slightly weathered exposure on cut bank of sediment control pond. Elev. at base of bed approx. 1694 ft (hand level-topo); coll. by Thomas J. Crawford and J.C. Lumsden, July 13, 1982. Section Description ----~10 ft+ Sandstone, fine- to medium-grained, thin-bedded _____12 to 18 in. Shale, weathers to light-gray and salmon pink. Abundant fossil plants _____.14 in. Coal, bright (60 percent) and dull (40 percent) attritus in mm scale layers; closely spaced cleat ----- 4 ft+ _ _10ft+ Underclay, dark-gray, with stigmaria fragments Sandstone, coarse-grained, slightly feldspathic; planar and undulatory crossbedding 55 Sample No. 39GA (Map Sta. 92B, New Home Quad., 1:24,000, c.r. = 5 meters) Sample Location Channel sample of the No. 10 coal bed (Johnson, 1946), 32 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 3457'14"N, 8530'10"W (0.87 mi or 1.40 km North of Hale Gap), Dade Co., Ga. Slightly weathered exposure in channel of intermittent stream adjacent to, and on south side of abandoned adit. Elev. at base of bed approx. 1350 ft (hand level-topo); coll. by Thomas J. Crawford and J.C. Lumsden, Sept. 3, 1982. Section Description ___10 ft+ Siltstone, gray, thin-bedded ___.32 in. Coal, No. 10 bed 56 Sample No. lALA (Map Sta. 85, Valley Head Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 5 coal bed (Johnson, 1946), 10 1/4 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 34 32' 06"N, 85 32' 42"W (1.52 mi or 2.45 km WNW of Four Roads), DeKalb Co., Ala. Fresh exposure in highwall of active strip mine (Fort Norman Exploration, Inc., Oliver No. 2 Mine). Elev. at base of bed approx. 1550 ft (hand level-topo); coll. by Thomas J. Crawford, Sept. 13, 1977. Section Description ----~15 ft+ Siltstone and fine-grained sandstone, gray, shaly, weathers to tan and brown; beds are 1 in. to 4 in. thick ----~18 ft Sandstone, gray, medium-to coarse-grained, crossbedded, with thin dark-gray, shaly partings at 3 in. to 20 in. intervals ----~3 to 5 ft Sandstone, same as above, but 10 to 30 percent shale layers between silt and fine-grained sandstone layers ----~3 in. to 5 ft Shale, dark-gray, coaly, with abundant plant fossils _____10 1/4 in. Coal, bright (80 to 90 percent) and dull (10 to 20 percent) attritus; fusain occurs in lenses to 1/2 in. thick but lenses are discontinuous and scattered. Pyrite occurs as thin (less than 1/4 in.) discontinuous lenses parallel to bedding. Coal bed rolls and pitches, thins and thickens (5 in. to 12 in.), with average thickness of about 9 in. in the pit _____10 in.+ Shale, gray, with plant fossils 57 Sample No. 2ALA (Map Sta. 87, Valley Head Quad., 1:24,000, c.r. = 10 meters) Sample L_9cation Channel sample of the No. SA coal bed (modification of Johnson, 1946), 22 in. thick; Sewanee Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 3432'30"N, 8532'47"W (1.71 mi or 2.75 km NW of Four Roads), DeKa1b Co., Ala. Slightly weathered exposure in test pit at old adit portal. Elev. at base of bed approx. 1473 ft (hand level-topo); coli. by Thomas J. Crawford, Sept. 13, 1977. Section Description ___10 ft+ Conglomerate, quartz pebbles in quartz sand 7 ft Shale, siltstone, and silty shale, gray, interlayered, with plant fossils 8 ft Shale, black, silty; with plant fossils _ _22 ~n. Coal, bright attritus (60 to 70 percent) and dull attritus (30 to 40 percent) in alternating bands generally 1/16 in. to 1/32 in. thick; minor fusain; a discontinuous shale break approx. 6 in. from the top of the coal bed is 0 in. to 6 in. thick; included in sample 2 in.+ Shale, black, coaly 58 Sample No. 3ALA (Map Sta. 83, Valley Head Quad., 1:24,000, C.I. = 10 meters) Sample Location Channel sample of the No. 5 coal bed (Johnson, 1946), 9 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 34 32' 37"N, 85 32' 12"W (1.42 mi or 2.28 km NW of Four Roads), DeKalb Co., Ala. Fresh exposure in highwall of active strip mine (Southeastern Metallurgical Coal, Inc.). Elev. at base of bed approx. 1550 ft (hand level-topo); coll. by Thomas J. Crawford, Sept. 13, 1977. Section Description ----~5 ft+ Sandstone, gray, weathers to buff, cream and tan colors; bed 3 in. to 14 in. thick ----~25 ft Siltstone and shale , light-to dark-gray, interlayered. ln middle part of unit are 3 to 6 beds of fine-to medium-grained sandstone; this horizon persists, but individual beds pinch out _____12 to 15 ft Sandstone, pale-gray to cream, medium-to coarse-grained, crossbedded in part; 2 in. to 20 in. beds _ _ ,2 to 5 ft Shale, dark-gray, plant fossils; coaly in part ____9 in. Coal, bright (80 to 90 percent) and dull (10 to 20 percent) attritus, with fusain in lenses up to 1/2 in. thick, fusain lenses discontinuous; scarce pyrite along cleat _____4 in.+ Shale, gray, with fossil plant fragments 59 Sample No. 4ALA (Map Sta. 5, Jamestown Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of the No.4(?) coal bed (Johnson, 1946), 9 in. thick; Whitwell Shale Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 34 29' 40"N, 85 32' 52"W (1.74 mi or 2.80 km West of Mt. Calvary Church), Cherokee Co., Ala. Fresh sample from stockpile of active strip mine (Fort Norman Exploration, Inc.). Elev. at base of bed approx. 1580 ft (estimated from topo); coll. by Thomas J. Crawford, Sept. 14, 1977. Section Description _____10 ft+ Sandstone, gray, medium-to coarse-grained; weathers tan to buff ----~8 to 10 ft Shale, gray, silty; shale with thin (1/16 in. to 1 in.) layers and lenses of silt. Much of the silt is finely cross-bedded. Weathering gives striking gray and white bands. Plant fossils common _____8 to 10 in. Coal, bright (60 to 70 percent) and dull (30 to 40 percent) attritus; bands of bright, 1/4 in. to 1 in. thick, alternate with bands of mixed 1/4 in. to 1/2 in. bright and dull layers; fusain bands up to 1/4 in. thick are common. Scarce pyrite occurs as small lenses along bedding and along cleat 60 Sample No. SALA (Map Sta. 6, Jamestown Quad., 1:24,000, C.I. = 5 meter) Sample Location Channel sample of the No. SA (?) coal bed (modification of Johnson, 1946), 22 in. thick; Sewanee Member of the Crab Orchard Mountains Formation, Lower Pennsylvanian; 34 28' 49"N, 8532' 07"W (1.38 mi or 2.23 km SW of Mt. Calvary Church), Cherokee Co. Ala. Fresh sample from the highwall of recently abandoned strip mine (Slimp Construction Co.). Elev. at base of bed approx. 1510 ft (estimated from topo) ; coll. by Thomas J. Crawford, Sept . 14, 1977. Section Description ----~25 ft+ Quartz sandstone, medium- to coarse-grained, conglomeratic in part with quartz pebbles _____.2 to 8 ft Conglomerate, quartz pebble and siderite ironstone dominant. Ironstone cobbles are 6 in. across by 1 in. thick. Common siltstone and shale fragments up to 8 in. across. Common coal zones intricately associated as "slices", "lenses", and "beds". Appears to be a fault zone ----'2 in. Coal, shaly, bone, very dense with thin, less than 1/16 in. thick layers of bright attritus ----~20 to 24 in. Coal, bright attritus (80 to 90 percent) in layers 1/4 in. to 3/4 in. thick. Dull attritus (10 to 20 percent) as thin, less than 1/32 in. thick. Fusain layers 1/8 in. thick, occur at 1/4 in. to 2 in. intervals. Scarce pyrite occurs as small lenses parallel to bedding _____.2 in. Shale, dark gray, coaly _ _4ft+ Shale, silty shale and siltstone, gray 61 Sample No. 6ALA (Map Sta. 96, New Home Quad., 1:24,000, C.I. = 5 meters) Sample Location Channel sample of No. 9 coal bed (Johnson, 1946), 24 in. thick; Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian; 340 53' 26"N, 85 36' 2l"W (3.22 mi or 5.18 km. West of Stephensville, Ga.; Sec. 5, T25, RlOE) Jackson Co., Ala. Fresh exposure in highwall of active strip mine; Sand Mountain Minerals Pacific Power & Light Co., Reece Ballard Mine; elev. at base of bed approx. 1375 ft (hand level-topo); coll. by Thomas J. Crawford and Chris Maples, June 19, 1980. Section Description _____43 ft Sandstone, gray, medium-to coarse-grained, feldspathic; conglomeratic in part; layers of quartz pebble conglomerate near base ___10 in. Coal, contorted, not sampled -----'20 ft Shale and siltstone, gray and white, interlayered; beds generally less than 1 in. thick ; siltstone stringers are discontinous _ __c24 in. Coal, sampled -----'51 ~n. Sandstone, gray, fine-to medium-grained; slabby; bedding ranges from 1 in. to 10 in. in thickness with thin laminae of very micaceous siltstone. Also, thin slabs of white and dark-gray, banded shaley siltstone _____.3 3 1n. Coal, not sampled 62 Sample No. 7ALA (Map Sta. 9 Sulphur Springs Quad., 1:24,000, c.r. = 10 meters) Sample Location Channel sample of the No. 10 coal bed, (Johnson, 1946), 44 in. thick (sample includes two shale breaks totaling 4 to 6 inches thick; excludes 2 inches of bone beneath the coal); Raccoon Mountain Member of the Gizzard Formation, Lower Pennsylvanian, 34 38' 45"N, 85 33' 28'~ (0.50 mi or 0.80 km SE of Battelle BM Z54 909; Sec. 35, T4S, RlOE); fresh exposure in highwall of active strip-auger mine, Burton Coal Co., Inc., Mentone Mine No. 1. Elev. at base of bed approx. 1763 ft (hand level-topo); coll. by Thomas J. Crawford and David Knight, Sept 16, 1981 Section Description Sandstone and conglomerate of the Sewanee Member of Crab Orchard Mountains Formation _ _15ft Signal Point Shale Member of the Grizzard Formation _ _95ft Sandstone, massive, and conglomeratic in lower part of the Warren Point Member of the Gizzard Formation _ _18ft Shale, gray silty __ 7ft Coal, sampled ---3 ft -~21ft __ 3ft Shale Coal, sampled Shale _ _12ft Coal, sampted; pyrite occurs along cleat, along bedding, and as lenses and balls in the coal as well as the shale layer interbedded with the coal ---'2 ft Bone coal ----'2 in.+ Underclay 63 Sample No. 8ALA (Map Sta. 1, Jamestown Quad., 1:24,000, C.I. = 20 ft) Sample Location Channel sample of the No. 6 coal bed (Johnson, 1946), 24 in. thick; Signal Point Shale Member of the Gizzard Formation, Lower Pennsylvanian; 34 28' 04"N, 85 32' 52"W (2.05 mi or 3.30 km. NW of Chesterfield, Ala.; Sec. 35, T6S, RlOE), Cherokee Co., Ala. Fresh exposure at portal of active underground mine: Cash Mines, Inc., Cash Mine No. 1. Elev. at base of bed approx. 1385 ft (hand level-topo); coll. by Thomas J. Crawford, Jack H. Medlin, and S. Lynn Coleman, Oct. 30, 1981. Section Description --- 2 ft+ --- 8 in. Sandstone, thin-bedded Coal ---~36 in .+ Underclay ---~82 ft Sandstone, gray, medium-grained, thin- to medium-bedded; crossbedded; crossbedding sets are approximately 6 ft.to 8 ft in thickness. Bottom one-half of unit is a quartz and siderite pebble conglomerate containing shale fragments; layers are 0 in. to 24 in. thick ---~24 in. Coal, mostly bright attritus; dull attritus occurs in layers less than 1/2 in. thick, mostly toward the bottom. There is a 1/2 in. to 1 in. bone coal layer at base of the coal bed. This not included in sample ---~12 in.+ Shale, gray, with slickensides and containing coal lenses 1/2 in. to 1 in. in thickness 64 APPENDIX B Tables of Chemical Data 65 Table 17. Correlation between field number, USGS laboratory number, and coal bed name for samples from Sand and Lookout Mountains. Field Number 1GA 2GA 3GA 4GA SGA 6GA 7GA 8GA 9GA 10GA llGA 12GA 13GA 14GA 1SGA 16GA 17GA 18GA 19GA 20GA 21GA 22GA 23GA 24GA 2SGA 26GA 27GA 28GA 29GA 30GA 31GA 32GA 33GA 34GA 3SGA 36GA 37GA 38GA 39GA !ALA 2ALA 3ALA 4ALA SALA 6ALA 7ALA 8ALA USGS Laboratory Number W199974 W19997S W199989 W199990 W199991 W199976 W199977 W199978 W19997 9 W199980 W199981 W199982 W199983 W199984 W19998S Wl99986 Wl99987 Wl99988 W2096 77 W209678 W209679 W209680 W209681 W209682 W209683 W209684 W212S63 W212S64 W212S6S W212S66 W212S67 W21S4S4 W21S4SS W21S4S6 W21S4S7 W218689 W218690 W218691 W218692 Wl99992 Wl99993 Wl99994 Wl9999S W199996 W212568 W2154S2 W21S4S3 Coal Bed Name No. 4 No. SA No. SA No. 4 No. 4 No. SA No. 9 No. 8 No. 9A No. 9 No. 8 No. 9 No. 3 No. 2 No. 2 No. 3 No. 3 No. 4 No. 9A No. 8 No. 10 No. 9A No. 10 No. 10 No. 4 No. 4 No. 4 No. 1 No. 4 No. SA No. 10 No. 10 No. 10 No. 4 No. 4 No. 4 No. 4 No. SA No. 10 No. s No. SA No. s No. 4 No. SA No. 9 No. 10 No. 6 66 Table 6a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama. sample state county latitud longitud formation coal bed rank no . wl99992 alabama de kalb 343204n 85324lw crab orchard mts no 5 bit w199993 alabama de kalb 343234n 853249w crab orchard mts no 5a bit wl99994 alabama de kalb 343238n 853203w crab orchard mts no 5 bit w199995 alabama cherokee 342940n 853237w crab orchard mts no 4 bit w199996 alabama cherokee 342848n 853208w crab orchard mts no Sa bit sample type channel channel channel channel channel sampled thickness (inches) 10.0 22.0 9.0 9.0 22.0 w199974 georgia w199975 georgia w199976 georgia w199977 georg i a w199978 georgia chattooga walker dade dade dade 343343n 343546n 344054n 345756n 345804n 852921w crab orchard mts no 4 852917w crab orchard mts no 5a 852911w crab orchard mts no 5a 853108w gizzard no 9 853116w gizzard no 8 bit channel 9.0 bit channel 9.0 bit channel 7.0 bit composite 24 . 0 bit composite 20 . 0 wl99979 georgia wl99980 georgia w199981 georgia w199982 georgia wl99983 georgia dade dade dade dade dade 345653n 345702n 345655n 345818n 345043n 853037w gizzard no 9a 853044w gizzard no 9 853047w gizzard no 8 853356w gizzard no 9 852712w crab orchard mts no 3 bit channel 20 . 0 bi t channel 41.0 bit bit channel channel 18 . 0 17 .o bit channel 20 . 0 w199984 georg i a w199985 georgia w199986 georg i a wl99987 georg i a w199988 georgia dade dade dade walker walker 345033n 345033n 34503ln 345158n 345330n 852645w crab orchard mts no 2 852645w crab orchard mts no 2 852648w cr ab orchard mts no 3 852508w crab orchard mts no 3 852422w crab orchard mts no 4 bit channel 9.0 bit channel 6.0 bit channel 22 . 0 bit channel 13 . 5 bit channel 14 . 0 wl99989 georgia w199990 georgia w199991 georg i a w209677 georgia w209678 georgia chattooga chattooga chattooga dade dade 343137n 343343n 343425n 345440n 345639n 852932w crab orchard mts no 5a 852921w crab orchard mts no 4 852905w crab orchard mts no 4 853122w gizzard no 9a 853533w gizzard no 8 bit channel 9.0 bit dri 11 core 13 . 0 bit channel 14.0 bit channel 36 . 0 bit channel 30 . 0 w209679 georgia w209680 georg i a w209681 georgia w209682 georgia w209683 georgia dade dade dade dade walker 344920n 344756n 344631n 344730n 345231n 853022w gizzard no 10 853101w gizzard no 9a 853041w gizzard no 10 852845w gizzard no 10 852518w crab orchard mts no 4 bit channel 28.0 bit channel 32 . 0 bit channel 19.0 bit channel 42.0 bit channel 23.0 w209684 georgia w212568 alabama w212563 georgia w212564 georgia w212565 georgia walker jackson walker walker walker 344959n 345326n 345049n 345115n 344953n 852546w crab orchard mts no 4 853621w gizzard no 9 852442w crab orchard mts no 4 852625w crab orchard mts no 1 852632w crab orchard mts no 4 bit channel 18.0 bit channel 24 . 0 bit channel 20.0 bit channel 25 . 0 bit channel 19.0 al -.1 Table 6a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for 47 bituminous coal samples from Sand and lookout Mountains, Georgia and Alabama--continued. sample state county latitud longitucl formation coal bed rank sample no. type w212566 georgia w212567 georgia w215452 alabama w215453 alabama w215454 georgia chattooga walker de kalb cherokee dade 343357n 343605n 343845n 342804n 344428n 852626w crab orchard mts no 5a 852517w gizzard no 10 853328w gizzard no 10 853252w gizzard no 6 852912w gizzard no 10 bit channel bit channel bit channel bit channel bit channel sampled thickness (inches) 13.0 21.0 44.0 24.0 31.0 w215455 georgia w215456 georgia w215457 georgia w218689 georgia w218690 georgia dade chattooga chattooga chattooga chattooga 344428n 343240n 343240n 343330n 343330n 852912w gizzard no 10 852942w crab orchard mts no 4 852942w crab orchard mts no 4 852812w crab orchard mts no 4 852812w crab orchard mts no 4 bit channel 45.0 bit channel 14 . 0 bit channel 9.0 bit channel 13.0 bit channel 17 . 5 w218691 georgia w218692 georgia chattooga dade 343437n 852803w crab orchard mts no 5a 345714n 853010w gizzard no 10 bit channel 14.0 bit channel 32.0 0} 00 Table 6b. SIPII3ry statistical table of analytinl data for 47 bitlninous coal Sal!1lles from Sand and Lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion t8111leratures in degrees F. data values item used m--e-an- -s-td--d-e-v- -xm-in -xm--a-x -ra-n-g--e -g-eo--m--e-an- geo dev sigma usgs ash 47 11.03 8.78 1.900 35.70 33.80 7.84 2.38 8.88 statistics for following data items on ash basis sio2 47 a12o3 47 cao 47 mgo 47 na2o 47 k2o 47 fe2o3 47 mno 45 tio2 47 p2o5 42 sol 42 40.97 25.16 2.34 . 1.02 0.28 2.02 19.61 0.07 1.04 0.38 3.52 12.75 6.70 1.94 0.44 0.17 0.96 16.32 0.15 0.31 0.51 2.98 11.900 7.300 0.170 0.365 0.073 0.210 2.240 0.003 0.300 0.020 0.500 56.92 34.92 7.84 1.99 0.97 4.33 70.06 o. 72 1.67 2.75 10.00 45.02 27.62 7.67 1.63 0.90 4.12 67.82 0.72 1.37 2.73 9.50 38.37 23 . 93 1.61 0.92 0 . 24 1.77 13.93 0 . 02 0.99 0.21 2. 41 1.48 1.42 2.52 1.59 1. 73 1.77 2.36 3.50 1.44 2.91 2.43 12.89 6. 77 1.96 0.45 0.17 0.97 16.50 0.16 0.31 0.52 3.02 zero 0 0 0 0 0 0 0 0 2 0 0 0 qual 0 0 0 0 0 0 0 0 0 0 5 5 statistics for following data Hems on "whole-coal" basis ag 44 0.07 0.09 0.010 as 47 48.28 123.80 1.100 there were less than two positive-valued items for au b 46 14.20 15.41 0.616 ba 47 67.75 52.06 4.221 be 47 1.68 0.81 0.504 there were less than two positive-valued items for bi br 47 4.83 3.18 0.751 cd 44 0.07 0.10 0.005 ce 47 22.12 16.60 4.000 cl 43 871.63 411.66 230.000 co 47 9.24 4.95 1. 700 cr 47 16.72 13.34 3.000 cs 43 1.29 1.19 0.100 cu 47 17.66 19.00 5.890 dy 16 1.84 1.79 0.484 er 15 1.13 1.47 0.330 eu 47 0.43 0.30 0.090 f 35 63.94 41.89 20.000 ga 47 4.32 3.23 0.627 gd 27 2.01 1.85 0.418 ge 43 2.21 2.29 0.216 hf 46 0.69 0.63 0.100 hg 46 0.23 0.19 0.010 ho 7 0.28 0.07 0.178 there were less than two positive-valued items for in there were less than two positive-valued items for ir la 47 12.78 10.25 2.000 1i 47 30.98 39.12 1.239 lu 46 0.14 0.07 0.040 mn 47 29.22 80.20 2.160 mo 45 2.81 3.97 0.129 nb 47 2.25 2.34 0 . 163 nd 44 12.13 9.64 1.496 0.49 815.00 69.93 245.00 4.52 13.44 0.51 69.00 1830.00 20.50 '52.70 6.40 134.75 7.28 6.44 1.61 190.00 14.28 9.52 10.00 3.40 0.85 0.40 38.00 135.66 0.40 515.20 25.74 10.35 46.41 0.48 813.90 69.31 240.78 4.01 12.69 0.50 6'5.00 1600.00 18.80 49.70 6.30 128.86 6.80 6.11 1.'52 170.00 13.65 9.10 9.78 3.30 0.84 0.22 36.00 134.42 0.36 513.04 25.61 10.19 44.91 0.05 13.20 8.01 49.96 1.49 3.71 0.0'5 16.82 764.34 7.70 12 . 33 0.78 14.12 1.32 0.77 0.35 '52.85 3.23 1.'50 1.34 0.47 0.14 0.27 9.25 13.85 0. 12 11.15 1. 79 1.35 9.06 2.21 4.59 3.07 2.28 1.63 2.19 2.48 2.13 1. 72 1.92 2.20 3.09 1.77 2.16 2.08 1.91 1.84 2.19 2.09 2.83 2.'52 3.11 1.28 2.29 3.80 1.6'5 2.87 2.43 2.86 2.19 0.09 125.14 15.58 52.62 0.82 3.22 0.10 16.78 416.53 5.00 13.49 1.20 19.21 1.84 1.53 0.30 42.50 3.26 1.89 2.32 0.63 0.19 0.07 10.36 39.'54 0.07 81.06 4.02 2.37 9.75 0 3 0 0 0 1 0 0 0 0 0 0 0 3 0 0 0 4 0 0 0 0 0 4 0 0 0 31 0 32 0 0 0 12 0 0 0 20 0 4 0 1 0 1 0 40 0 0 0 0 0 1 0 0 0 2 0 0 0 3 0') ~ Table 6b. Summary statistical table of analytical data for 47 bituminous coal samples from Sand and lookout Mountains, Georgia and Alabama Zero and qualified values excluded; ash-fusion temperatures in degrees F--continued ni 47 20.10 27.06 4.160 193.20 189.04 14.65 2.02 27.35 0 there were less than two positive-valued items for os pb 46 11.80 19.90 0.880 127.50 126.62 6.43 2.73 20.12 0 there were less than two positive-valued items for pd pr 10 7.49 5.92 1.748 20.16 18.41 5.63 2.11 6 . 24 0 there were less than two positive-valued items for pt rb 12 22 . 83 15.56 10.000 68.00 58.00 19.29 1. 73 16.25 0 there were less than two positive-valued items for re there were less than two positive-valued items for rh there were less than two positive-valued items for ru sb 40 1.09 1.30 0.200 8.10 7.90 0.78 2.11 1.32 0 sc 47 3.76 2.94 0.850 16.05 15.20 2.93 2.01 2.98 0 se 47 2.81 1.95 0.700 8.71 8.01 2.32 1.83 1.97 0 sm 47 1.94 1.41 0.400 7.70 7.30 1.55 1.94 1.42 0 sn 15 0.76 0.62 0.046 2.22 2.17 0.50 2.79 0.64 0 sr 46 199.66 131.59 56.760 563.50 506.74 164.34 1.85 133.05 0 ta 32 0.05 0.07 0.002 0.29 0.29 0.02 3.71 0.07 0 tb 44 0.34 0.24 0.110 1.37 1.26 0.28 1. 75 0.25 0 there were less than two positive-valued items for te th 47 2.52 2.32 0.300 10.80 10.50 1.68 2.52 2.34 0 tl 4 1.46 0.83 0.699 2.83 2.13 1.26 1. 70 0.96 0 there were less than two positive-valued items for tm u 42 1.01 1.07 0.020 4.40 4.38 0.58 3.11 1.09 0 v 47 22.46 18.99 2.112 74.97 72.86 15.21 2.57 19.20 0 w 23 0.16 0.14 0.011 0.61 0.60 0.09 3.33 0.14 0 y 47 7.88 4.15 2.420 20.34 17.91 6.85 1. 72 4. 19 0 yb 47 0 . 95 0.53 0.300 2.50 2.20 0.82 zn 47 18.66 30.83 3.250 211.60 208.35 11.69 zr 47 23.62 23.28 2.640 114.24 111.60 15.04 1. 70 2.32 2.65 0.54 0 31.16 0 23.53 0 statistics for following data items on "as received" basts data values item used m--ea-n -std-d-ev -xmi-n -xm-ax -ran-ge -g-eo--m--e-an- geo dev sigma zero btu 45 ashdef 41 ashsof 39 ashfld 37 freswel 42 moistur 45 volmat 45 ftxedc 45 bmash 45 hydrogn 45 carbon 45 ni trogn 45 oxygen 44 sulfur 45 sulfate 43 sulfpyr 45 sulforg 45 adloss 45 13364.40 2427.56 2496.92 2560.00 6.62 2.03 21.62 65.98 10.37 4.40 76.41 1.37 6.31 1.27 0.07 0.65 0.55 1.01 1597.22 247.70 223.59 193.59 2.44 1.43 2.46 8.24 8.19 0.33 8.82 0.25 3.22 1.16 0.11 1.05 0.23 0.85 9404.000 1940.000 2000.000 2170.000 1.000 1.100 17.990 45.300 1.650 3.400 54.500 0.700 3.050 0.490 0.010 0.010 0.250 0.320 15193.00 2800.00 2800.00 2800.00 9.00 7.90 28.00 77.30 34.20 5.10 87.20 1. 70 19.00 5.30 0.42 4.02 1.39 4.60 5789.00 860.00 800.00 630.00 8.00 6.80 10.01 32.00 32.55 1. 70 32.70 1.00 15.95 4.81 0.41 4.01 1.14 4.28 13261.92 2414.76 2486.68 2552.50 5.84 1.77 21.49 65.42 7.53 4.39 75.87 1.34 5.81 0.98 0.03 0.25 0.51 0.82 1.13 1615.26 2 1.11 250.78 0 1.10 226.51 0 1.08 196.26 0 1.82 2.47 4 1.58 1.44 1 1.12 2.49 1 1.14 8.33 1 2.30 8.29 1 1.08 0.33 1 1.13 8.92 1 1.22 0.25 1 1.45 3.26 1 1.90 1.17 1 3.96 0.11 3 3.94 1.06 1 1.44 0.23 1 1.79 0.86 0 0 1 37 35 7 0 0 0 32 1 15 3 0 43 5 0 24 0 0 0 0 qual 0 6 8 10 1 1 1 1 1 1 1 1 2 1 1 1 1 2 -l 0 Table 6c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. l means less than the value shown; H, interference for an element which cannot be resolved by any routine method; G, greater than; 8, not determined: S, after element title indicates - - -- determinations are to be taken as plus 50% and minus 35%. Sample number is laboratory number). ------ - Sample Ash Si02 Al203 CaD MgD Na2D k2D Fe203 TiD2 P205 Sample number ----- - (percent) (percent) (percent) (percent) (percent) (p-e-rcent) (percent) (percent) (percent) (percent) m.lllber wl9CJ992 2.1 34 32 wl99993 10.4 47 35 w199994 3.6 34 29 w199995 10.2 53 27 w1999CJ6 4.9 53 24 6.2 1.4 0.43 2.3 11 1.2 0.24 w199992 1.3 .68 .31 2.4 6.3 1.2 .19 w199993 4.0 1.1 .27 1.9 23 .97 .44 w199994 1.2 .91 .22 2.7 10 1.2 .32 w199995 1.8 .98 .23 3.3 11 1.1 .06 w19C)996 w199C)74 2.4 25 w1C)9975 w199976 '6.2' 27 41 w199977 11.1 53 w199978 6.6 14 25 5.2 1.8 .19 1.5 29 11 2.2 .78 .27 1.3 44 29 2.1 1.1 .18 3.1 15 26 1.1 .71 .11 2.0 10 7.3 2.2 .53 .07 .56 70 .65 .08 w1C)9974 .76 .27 w1C)C)975 .93 .06 wl99976 1.2 .79 w199977 .30 .05 w199978 w199979 9.2 13 w199980 11.6 52 w19CJ981 8.2 12 w199982 2.4 32 w199983 3.5 42 11 32 8.7 24 34 3.1 2.0 .61 .78 2.9 .36 6.3 2.0 2.5 .93 .01 .60 53 .13 2.4 2.2 .16 .21 67 .15 1.3 18 .28 2.0 7.2 .33 1.4 .53 .75 .97 2.0 .81 .85 .13 .54 w199979 w199980 w199981 w19CJ982 w199983 w199984 12.4 28 19 w199985 24.5 39 29 w199986 2.2 32 26 w199987 8.1 52 31 w199988 2.1 25 27 1.5 .68 .66 .76 4.5 1.3 1.0 1.0 5.8 1.1 .27 1.2 43 .19 2.0 22 .66 1.6 18 .51 3.3 2.8 .50 .84 24 .82 1.0 .94 1.2 .72 .48 w199984 .84 w199985 .09 w199986 .09 w199987 .57 w199988 w199989 10.1 49 27 w199990 8.5 49 16 w199991 2.2 24 14 w209677 26.7 55 32 w209678 17.8 53 31 .93 1.0 .24 3.5 10 1.3 .08 w199989 1.6 1.5 .15 2.9 21 .80 .09 w1999CJO 5.2 2.0 .11 1.1 37 .55 .14 w199991 .50 .36 .19 1.3 3.1 1.4 .14 w209677 .62 .95 .18 2.9 7.1 1.3 .24 w209678 w209679 11.4 42 27 w209680 33 . 3 53 33 w209681 13.0 50 27 w209682 35.7 56 26 w209683 2.2 40 28 .88 .46 .18 1.3 23 1.4 .21 .88 .15 4.3 4.0 1.1 1.2 .50 .18 1.2 16 1.4 .17 .37 .13 1.6 4.8 1.5 3.1 .83 .39 2.7 15 1.2 .41 w209679 .04 w209680 .18 w209681 .15 w209682 .45l w209683 w209684 2.4 38 25 w212568 8.6 57 26 w212563 2.5 47 27 w212564 10.2 49 29 w212565 1.9 23 26 3.9 1.5 .52 1.1 3.3 1.5 2.6 1.4 6.2 1.4 .97 1.4 21 .15 2.9 5.1 .53 1.8 9.2 .49 2.2 3.9 .43 1.2 24 1.1 .38 w209684 1.3 .12l w212568 1.2 .40l w212563 1.2 2.8 w212564 .87 .53L w212565 w212566 6.2 39 25 w212567 22.7 51 26 w215452 18.9 49 28 w215453 3.4 23 13 w215454 13.5' 52 ]] 2.2 1.2 .28 2.3 22 1.1 .16 w212566 .49 .75 .26 1.4 15 1.2 .08 w212567 .94 .40 .30 .98 17 1.3 .16 w21545'2 4. 1 . 63 .35 1.3 45 .67 .65 w215453 1.4 .56 .22 1.2 6.2 1.6 .40 w215454 .-...J... Table 6c. Sample number wl9'J'J'J2 w1'J'J9'J3 wl99994 w199995 w199996 w19'J974 w199975 w199976 w199977 w199978 wl99979 wl99980 w199981 wl99982 wl99983 w19998ft w199985 w199986 w199987 w199988 w199989 w199990 w199991 w209677 w209678 w209679 w209680 w209681 w209682 w20'J683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 Major- and minor-oxides and trace-element concentrations in the laboratory ash of 47 bituminous coal samples from Sand- and lookout Mountains, Geor-g-ia-a-n-d Alabama--continu--ed. --- SOl Ag-S (-per-ce-n-t) (ppm) B-S (ppm) Ba-S (ppm) Be-S (ppm) Bi-S (ppm) Br (p-p-m) Cd (ppm) Ce -(ppm) Co (ppm) 10 0.4'J 110 710 46 15l 4,200 2.2 .83 170 1,400 18 15l 550 5.9 1.1 79 680 39 15l 2,500 1.5 .51 65 630 19 15l 620 2.6 .65 110 460 38 15l 1,200 1.5 640 410 1.3 220 70 1.5 720 340 1.2 180 140 .45 180 63 8.0 .7'J 44 1,200 21 15l 2,'JOO 2.9 .66 71 400 15 15l 760 2.8 .69 100 520 28 15l 1,100 .76 .53 100 530 14 15l 510 3.5 .60 25 610 21 15l 950 .68 210 460 .90 130 60 .87 170 140 .29 220 150 .87 91 200 7.5 .21 61 1,500 16 15l 320 1.2 .10l 97 B'JO 15 15l 450 4.7 .65 51 870 22 15l 540 8.3 .49 150 1,200 34 15l 2,700 2.8 .76 110 1,100 44 15l 1,000 5.5 110 220 1.0 190 140 .35 260 85 .45 290 630 . 79 540 250 2.0 1.2 H 960 10 15l 190 .71 2.0 80 1,000 11 15l 7ft 7.2 1.8 190 2,100 24 15l 1,600 .97 .58 160 930 15 15l 430 8.7 1.6 86 1,100 32 15l 2,200 .69 140 21 1.8 280 67 2.4 180 130 .66 250 62 .68 520 540 1.1 2.9 9.3 .70 .85 .53 100 .33 57 .89 28 .30 170 .26 180 510 460 1,000 520 530 27 10 31 9.0 12 15l 760 15l 1,000 15l 4,700 10l 6ft lOl 260 .47 160 50 .62 120 200 . 72 180 660 .16 160 12 .11 150 47 1.1 .70 1.3 .50 3.6 .53 110 .10l 210 2.9 120 .42 150 .92 120 560 580 530 400 1,100 12 4.7 13 8.9 38 lOl 260 lOl 120 10l ft70 10l 69 lOl 1,900 .lOl 230 .16 160 .lOl 210 .10l 180 1.0 410 22 16 13 6.2 ft90 8 1,9 120 1,200 46 10l 1,800 1.2 .lOl 130 430 35 10l 510 4.2 1.1 130 1,400 46 10l 1,700 2.7 .13 350 1,500 11 10l 150 8.3 1.3 97 1,700 34 lOl 2,100 2.0 460 420 .85 160 130 .76 400 390 .24 240 25 9.0 320 520 2.7 .50 170 600 1.3 .33 110 390 1.2 .44 110 570 6.1 1.2 110 630 1.6 .47 180 630 29 16 1,100 12 lOl 140 9.5 lOl 200 4ft lOl 1,700 10 lOl 380 2.0 180 190 .10 250 19 .50 260 51 .60 120 100 .20 290 30 Sample number w1'J'J'J'J2 w199993 w1999'J4 w199995 w199996 w199974 w19'J975 wl99976 w199977 wl99'J78 w199979 w199'J80 w199981 w199982 w199983 w19998ft w199985 w1'J9'J86 w199'J87 w1'J9'J88 w199989 w199990 w199991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 -.:] tv Table 6c. Sample nunber Major- and minor-oxides and trace-element concentrations in the laboratory ash of 47 bituminous coal samples - - - - - from Sand and Lookout Mountains, Georgia and Alabama--continued. Cr cs Cu Dy-S Er-S Eu Ga-S (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) - Gd-S (ppm) - Ge-S (ppm) _______ __ Hf (ppm) , . Sample number wl99992 250 w199993 180 w199994 230 w199995 150 w199996 150 w199974 160 w199975 93 w199976 180 w199977 200 w199978 50 w199979 78 w199980 180 w199981 82 w199982 170 w199983 200 w199984 130 w199985 190 w199986 220 w199987 180 w199988 240 w199989 150 w199990 100 w199991 litO w209677 160 w209678 150 w209679 180 w209680 160 w209681 120 w209682 140 w209683 250 w209681t 270 w212568 160 w212563 21t0 w212564 150 w212565 210 w212566 150 w212567 120 w215452 litO w2151t53 190 w215451t 150 9.5 650 13 160 11 540 16 260 8.2 230 4.2 380 6.6 280 13 300 9.9 100 30L 200 3.3 170 14 130 24L 88 4.2 380 5.7 430 7.3 340 9.0 550 4.5 500 23 190 33L 360 20 220 5.9 130 36L 420 8.6 61 15 59 10 71t 19 110 10 79 7.6 26 14 370 13 620 21 140 8.0 420 15 70 5.3 480 13 330 7.9 litO 7.4 litO 2.9 300 7.4 110 .u 30 12 57 22L lOL 4.9 39 36 21 14 58 22L 10L 3.1 44 22L lOL 4.9 36 24 10L 24 lOL 22L 12 22L lOL 22L lOL 5.8 47 2.0 51 3.5 52 3.7 41 2.0 33 22L 10L 22L 13 22L lOL 32 17 38 19 2.3 21 3.4 41 5.0 28 5.8 47 9.1 55 22L lOL 2.9 41 22L lOL 6.6 35 37 22 6.4 50 22L 12 5.2 62 45 22 12 64 22L lOL 22L 10L 22 lOL 22L lOL 22L lOL 2.9 65 2.5 18 4.1 58 2.6 32 2.2 38 22L 10L 46L 10L 22L 10L 22L 10L 46L 15 4.1 38 2.9 37 3.9 32 2.8 40 9.5 55 22L 46L 11 53 22L lOL 3.6 37 48 34 10 48 22L 10L lt.O 32 31 10L 8.4 33 22L 10L 22L 10L 22L 10L 22L 10L 22L lOL 3.2 50 lt.1 34 lt.8 31 3.8 48 4.7 35 50 16 36 17 13 26 26 20 20 6.8L 6.8L 20 25 34 30 21 19 37 21 lt7 12 14 19 15L 46L 46L 46L 46L 46L 15L 46L 15L 29 15L 22 15L 15L 15L 15L 15L 30 1.5L 46 28 19 11 26 59 33 79 2.7 4.9 53 69 91 7.4 1.5L 40 35 lit 28 3.6 69 5.5 5.6 54 1.5L 11 28 27 66 72 86 3.0 33 12 8.8 1.6 10 1.6 9.5 w199992 6.7 w199993 5.6 w199994 6.9 wl99995 8.2 w199996 4.2 w199974 4.0 w199975 4.8 w199976 7.2 w199977 1.5 w199978 3.3 w199979 8.6 w199980 3.7 w199981 4.2 w199982 5.7 wl99983 5.6 w19':1984 5.3 w199985 9.1 w199986 6.2 w199987 4.8 w199988 7.9 w199989 8.2 w199990 4.5 w199991 6.0 w209677 5.1 w209678 8.6 w209679 4.5 w209680 6.2 w209681 9.5 w209682 9.1 w209683 8.3 w209684 7.0 w212568 8.0 w212563 7.8 w212564 5.3 w212565 6.5 w212566 5.7 w212567 6.3 w215452 5.9 w215453 8.1 w215451t -.J "" Table 6c. Sample nunber w199992 w199993 w199994 w199995 w199<)96 w199974 w199975 w1. Table 6d. Content of 22 trace-elements in 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama--continued. ------------ - - - --------------- Sample Th u Yb number (ppm) (ppm) (ppm) wl99992 wl'J9993 w199994 wl'JCJ995 w199996 w199974 wl'J9975 w199976 w199977 w199978 wl99979 w199980 wl'J9981 w199982 w199983 w199984 w199985 w199986 w199987 wl99988 w199989 wl'J9990 w199991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 0.9 3.5 1.7 2.3 1.0 .4 1.4 1.4 2.7 .5 .7 3.6 1.1 .4 .9 2.0 11 .4 2.0 .6 2.5 1.1 .3 5.3 3.2 4.6 7.2 2.0 8.0 .7 1.0 2.6 .8 2.9 .5 1.4 4.9 4.7 .5 3.9 0.19L 0.6 .39 .9 .02 .9 .30 1.0 .19 .6 .16 .4 .70 .6 1.2 .7 .43 .9 .16 .3 .16 .4 .60 1.0 .29 .7 .17 .5 .19 .6 .55 .8 3.5 2.5 .18 .5 .56 1.0 .17 .6 .83 .8 .17 .6 .17 .3 1.9 1.7 .99 1.1 3.8 1.5 3.4 2.0 1.4 1.1 4.4 2.2 .33L .5 .29 .5 .73 .8 .40 .6 1.3 .9 .25L .4 1.3 .6 1.7 1.7 1.6 1.6 .16L .5 1.0 1.2 00 01 Table 6d. --- Sample nunber Content of 22 trace-elements in 47 bituminous coal samples from Sand and lookout Mountains, - Georgia and Alabama--continued. --- ------------ -- As Ce Cl Co Cr cs Eu F Hf Hg Sample (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) nurber w215455 7.4 53 470 7.8 46 2.6 0 . 91 70 w215456 17.7 10 1,400 7.8 7.4 .2 .24 30 w215457 16.1 28 800 15 28 2.2 .68 70 w218689 45.0 12 B 16 10 .6 . 30 20 w218690 20.0 35 B 16 35 3.0 . 70 80 w218691 24.0 25 w218692 246 13 B 3.0 22 B 14 16 3.0 .so 60 1.2 . 30 100 2.1 0.16 w21!5455 .6l .19 w21!5456 .6 .22 w215457 .3 .36 w218689 1.3 .19 w218690 .7 .33 w218691 .6 . 36 w218692 00 0) Table 6d. Content of 22 trace-elements in 47 bituninous coal san.,les from Sand and Lookout Mountains, Georgia and Alabama--continued. sa...,le number La (ppm) Lu (ppm) Na (ppm) p (ppm) Rb (ppm) Sb (ppm) Sc (ppm) - Se (ppm) Sm (ppm) w21S4SS 36 w215456 5 w21S457 15 w218689 6 w218690 19 0.3 510 220 60L 1.1 8.3 8.7 4.1 .2L 77 87 SOL .90 1.6 2.0 1.0 .2 320 110 70L 1.0 5.3 2.6 2.9 .1 260 4 15 .40 2.3 4.3 1.0 .2 590 61 33 .40 6.7 2.0 2.6 w218691 15 w218692 6 .2 260 .1 380 57 21 35L 13 1.7 5.8 2.2 1.9 1.6 3.4 2.8 1.0 Tb -(ppm) 0.7 .2 .4 .2 .4 .4 .2 sa...,le number w215455 w215456 w215457 w218689 w218690 w218691 w218692 00 -l Table 6d. Content of 22 trace-elements in 47 bituminous coal samples from Sand and lookout Mountains, --------G-eo-r-gi-a and Alabama--continued. Sample Th u Yb number (ppm) (ppm) (ppm) w215455 8.0 w215456 .5 w2154!H 2.9 w218689 1.3 w218690 4.7 w218691 3.1 w218692 1.5 2.4 1.9 .23l .7 .64 1.4 .31 .6 1.6 1.5 2.0 1.7 .35 .8 00 00 Table 6e. Major-, minor - , and trace-element concen.trations, on whole- coal basis, o.f 47 bit~inous coal . samples from Sand and Lookout Mountains, Georgia and Alabama. . (Values 1n percent or parts-per-million. 22 elements are from direct determinations on who).e-coal; all other elemen_ts cal cul a ted . H, . interfer e nce for an eleme nt which cannot be resolved by any routine method; ll, not determined; G, greater - than; Samp 1e number is 1abora tory number ) 0 Sample Si Al Ca Hg Na K Fe Ti Ag-S As Sample n~ber (percent) (percent) (percent) (percent) (percent) (percent) (percent ) (percent) (ppm) (ppm) number w19999'2 w199'993 w199994 w199995 w199996 w199974 w199975 w199976 w199977 w199978 w199979 w199980. w19.998J. w199982 w199983 w199984 w199985 w199986 wl99987 w199988 w199989 w199990 w199991 w209677' w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 0.33 2.3 .56 2.5 1.2 .28 1.3 1.2 2.7 .44 .56 2.8 .46 .36 .69 1.6 4.4 .33 2.0 .25 2.3 2.0 . 25 6.9 4.4 3.4 8.3 3.0 9.4 .41 .43 2.3 .55 2.4 .21 1.1 5.4 4.3 .36 3.3 0.'35 1.9 .'55 1.5 .62 .32 .91 .96 L5 .'25 :53 2.0 .38 .30 .62 1.2 3 . 7 .30 1.3 .31 1.5 .72 .16 4.5 2.9 2.5 5.8 1.8 5.0 .32 . 32 1.2 .35 1.6 . 26 .83 3.2 2.8 .23 2.3 0.093 .098 .10 .085 .063 .089 .16 .095 .084 .10 .21 .051 .17 .11 .062 .13 .12 .071 . 058 .087 .067 .094 .082 . 095 .079 .11 .050 .11 .043 .048 .066 .032 .059 .19 .083 .098 .079 .13 .099 .13 0.017 .043 .024 .056 .029 .026 .046 .042 .048 .021 .11 . 054 .018 .029 .020 .051 .11 .017 .051 .014 .064 .077 .026 .059 .10 .049 .18 . 039 .078 . 011 .021 .059 .022 .087 .016 .043 .10 .045 .013 .046 0.007 .024 .007 .016 . 008 .003 .020 .008 .009 .004 .005 .011 .010 .003 .007 .025 .034 .011 . 031 . 008 .018 .009 .002 .037 .023 .023 .037 .017 .034 .006 . 017 . 009 .010 .037 .006 .013 .043 .042 .009 .022 0.040: .21 .055 .23 .13 ' . 030 .11 .16 .18 . 03.1 .046 . 23 . 014 .026 .El57 .13 .40 .03.0 .23 .015 .30 .21' .019 .30 .42 .19 L2 . .13 .49 .049 , 029 . 21 .038 .19 .018 .12 .26 .15 . 037 .13 0.16 .46 57 .73 .37 .48 3.0 .67 .79 3.2 3.4 .18 3.9 :.31 .18 3.7 3.7 .28 .16 .35 .73 1.3 .57 .58 .88 2.8 .94 1.4 1.2 .24 .35 .31 .16 .27 .32 .95 2.4 2.2 1.1 .58 0.015 .077 .021 .. 073 .032 .. 009 . ;045 .035 .082 . 012 , . 018 .098 .026 .011 . . 020 .ou ,. 15 .012 .060 .009 .077 .041 .007 .22 .14 .15 .22 .11 .31 .015 .016 .068 .017 .076 .010 .042 .16 .15 .014 . 13 0.010 .086 .040 .052 . 032 .01,9 .065 .043 .059 .040 .019 .012L .053 .012 .op .15 .49 .040 .047 .034 . 054 .028 .020 . 080 . 046 .092 .033L .38 .15 .020 .046 .oon . 028 .013 .025 .031 .075 .083 . 041 .063 2.0 3.0 9.0 25 7.6 2.4 110 24 21 86 5.4 1:3 110 2.4 2.9 220 820 13 8.1 3.8 16 11 3.8 7.1 22 66 26 53 42 2.8 2.0 2.6 1.8 2.2 1.1 28 84 26 19 3. 1 w199992 w199993 w199994 w1999'5 w1999~6 w199974 w199975 w199976 wU9977 w199978 wl99979 wl99980 w199981 w199982 w199983 w199984 w199985 w199986 wl99987 w199988 w199989 w199990 w199991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 \Y) CD Table 6e . Sai!IJile nU'IIber w199992 w199993 w199994 w199995 w199996 w199974 w199975 w199976 w199977 w199978 w199979 w199980 w19'1!81 w199982 w199983 w199984 w199985 w199986 w199987 w199988 w199989 w199990 wl99991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w21.l!565 w212566 w212567 w215452 w215453 w215454 Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from - - Sand and lookout Mountains, Georgia and Alabama--continued. --- ------ 8-S Ba-S Be-S Bi-S Br Cd Ce Cl Co Cr (ppm) ( ppm) (ppm ) (ppm) - (ppm) -- ( ppm) -( p pm) ( ppm) (ppm--) -- (ppm ) 2.3 15 1 O.Jl 88 0.03 14 1,300 8.7 5.3 18 150 2 1.6l 58 .14 23 340 7.3 19 2.8 24 1 .5l 90 .05 26 1,200 12 8.1 6.6 64 2 1.5l 64 .12 18 760 15 15 5.4 23 2 .7L 58 .02 9.0 980 3. 1 7.2 1.1 29 1 .4L. 69 7.0 40 1 1. 5L 76 6. 2 32 2 .9l 70 11 59 2 1.7l 56 1.7 40 1 l.OL 62 .02 5.0 960 .09 13 1,400 .05 11 830 . 03 24 820 .06 6.0 1,500 11 6.0 8.9 16 14 3.8 9.3 11 22 3.3 5.6 140 1 1.4L 30 11 100 2 1. 7l 53 4.2 71 2 1.2l 44 3.6 29 1 .4l 64 3.9 39 2 .5l 35 .51 10 410 .12 22 340 .03 21 1,000 .01 7.0 1,600 .03 19 590 21 16 7.0 15 8.8 7.2 21 6.7 4.0 7.1 H 12{) 1 1.9l 24 20 250 3 3.7l 18 4.2 46 1 .3l 36 13 75 1 1.2l 34 1.8 23 1 .3l 47 .09 17 3'JO .44 69 230 .05 4.0 610 .05 20 560 .01 11 1,000 2.6 17 2.8 5.0 11 16 47 4.9 14 5. 1 10 52 3 1.5l 76 4.8 39 1 l.Jl 85 .6 22 1 .Jl 100 45 140 2 2.7l 17 32 94 2 1.8l 46 . 05 16 1,200 .05 10 1,200 . 02 4.0 1,600 . 04 42 250 .02 27 860 5.1 17 15 3.3 8.3 16 8.5 3.0 42 26 19 97 2 1.7l 45 70 190 2 3.3l 39 16 69 2 1.3l 62 54 140 3 3.6l 25 2.6 24 1 .2l 42 . 02l 40 910 ..0o5n 52 27 470 1, 200 .04l 64 330 .02 9.0 990 3.8 5.4 1.7 2.2 11 31 53 15 50 5.6 2.9 29 1 .2l 44 11 37 3 .9l 44 3.3 35 1 .Jl 44 36 150 1 l.Ol 15 1.8 32 1 .2l 40 . 05 it 1 ,1>00 . 07 ,14 660 . 02 10 1,100 .02 24 410 . 17 6.0 860 10 11 9.8 2.6 9.9 6.5 13 6.0 15 4.0 11 37 2 1.0 67 25 89 3 2.3l 31 32 110 2 l.C}l 37 3.7 21 1 .3l 59 24 85 1 1.4l 52 .12 11 1,800 .02 57 450 .09 49 370 .02 4.0 1,300 .03 39 900 12 4.3 9.7 3.-4 4.1 9.2 27 27 6.3 21 Sa"l'le nU'IIber w199992 w199993 w199994 w199995 w199996 w199974 w199975 w199 1H6 wl99977 w199978 w199979 wl99980 w199981 w199982 w199983 wl99984 w199985 w199986 w199987 w199988 w199989 w199990 w199991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215ft53 w215454 ~ 0 ... Table 6e. Sample number Major-, minor-, and trace-eiement concentrations, on whole-coal basis, of 47 bituminous coal san~les from - - Sand and lookout'Hountains, Georgia and Alabama--continued . - .. ------ Cs Cu Dy-S Er-S Eu F Ga-S Gd-S Ge-S Hf , .. Sample (ppm) (ppm-) (ppm) (ppm) (ppm) (ppm) (ppm) (pp-m) (ppm--) - --(-ppm) . number w199992 0.2 14 w199993 1.3 17 wl99994 .4 19 w199995 1.6 27 w199996 .4 11 0.9 2.3l 1.3 2.2L 1.1l 0.6 l.Ol .8 l.Ol .5l 0.26 20l .51 21 .52 20l .32 20l .24 20l 1.2 1.1 0.63 0.2 w199992 4.1 1.7 .16l .7 wl99993 2.1 1.3 1.7 .2 w199994 4.5 1.7 2.9 .7 w199995 1.8 .64 .93 .4 wl99996 w199974 w199975 w199976 wl99977 w199978 .1 .7 .8 1.1 2.0l 9.1 28 19 11 13 .6 2.4 1. 4l 2.4l 1.5l .2l l.Ol .7 1.1l .7l .14 20L .20 34 .22 26 .41 60 .13 20l 1.1 .62 .41 .1 wl99974 5.0 2.6 2.6 .4 w199975 3.2 1.2 3.7 .3 w199976 4.6 2.2 3.7 .8 w199977 2.2 .45l 5.2 .1 w199978 w199979 wl99980 w199981 w199982 w199983 .3 1.6 2.0l .1 .2 16 15 7.2 9.1 15 2.0l 2.6l 1.8l .8 1.3 .9l 1.5 .8l .4 .7 .21 20l .40 38 .41 20l .14 20l .32 32 1.9 .63l .25 .3 w199979 4.8 2.3 .57 1.0 w199980 2.3 2.1 4.3 .3 w199981 1.1 .82 1.7 . 1 w199982 1.9 1.1 3.2 .2 w199983 w199984 w199985 w199986 w199987 w199988 .9 2.2 .1 1.9 .7l 42 130 11 15 7.6 2.7l 1.2l .36 28 5..a4l 2.5l .5 1..6n 20l 20l 1.8l 1.0 .42 36 .9 .5 .25 28 5.1 ' 8.6 1.1 5.0 1.3 2.6 4.7 .81 1.7 .99 .92 1 w199984 .37l 1.3 wl99985 .88 .2 w199986 2.8 .5 w199987 .29 .1 w199988 w199989 w199990 w199991 w209677 w209678 2.0 .5 .8l 2.3 2.6 22 11 9.2 16 11 2.2l 1.9l .5 5.9L 3.9L l.Ol .9l .2l 2.7L 1.8L .29 ' 20l .21 22 .09 23 .70 100 .40 90 6.6 1.2 . 2.8 .8 w199989 1.5 1.2 .31 .1 wl99990 1.3 .42 1.'5 .1 w199991 8.5 4.0l 1.5 1.6 w209677 6.8 8.2l 1.0 .9 w209678 w209679 1.8 w209680 6.4 w209681 1.3 w209682 2.7 w209683 .3 13 37 10 9.3 8.1 3.8L 15l 2.9l 7.9L l.Ol 1.7l 3.3L 1.3l 3.6L .3 .71 70 .97 190 .51 30 1.0 120 .21 70 6.6 12 4.2 14 1.2 8.0l 9.4 1.5 w209679 15L .50L 1.5 w209680 6.0l 1.4 .8 w209681 16l 10 3.4 w209682 .33l .59 .2 w209683 w209684 .3 w212568 1.8 w212563 .2 w212564 1.5 w212565 .1 w212566 .8 w212567 1.8 w215452 1.4 w215453 .1 w215454 1.0 15 12 11 7.1 9.1 20 32 26 10 15 .5L 1.9l 1.2 2.2l .6 1.4L 5.0l 4.2l .7L 3.0L 1.1L . 9L .9 l. OL .2L .6L 2. 3l 1.9L .JL 1.4L .27 50 .31 80 .26 40 .41 160 .16 50 .20 40 .93 50 .91 100 .13 60 .63 160 1.3 1.1L 1.6 .2 w209684 3.2 1.3L 6.2 .6 w212568 1.2 . 73 2.2 .2 w212563 3.3 1.5L . 31 .8 w212564 .6 .42 .63 ! w212565 3.1 .93l .74 .4 w212566 7.7 3.4L 2.0 1.3 w212567 5.9 2.8l .30 1.2 w215452 1.6 .51L .34 .2 w215453 4.7 2.0l .22 1.1 w215454 t.C 1-' Table 6e . Sample nunt>er Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama--continued. --- - Hg Ho-S La Li Lu Hn Mo - S Nb-S Nd-S Ni-S (ppm) ( ppm ) (ppm) ( ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) w199992 w199993 w199994 w199995 w199996 wl99974 w199975 w19'1976 w199977 w199978 w199979 w199980 wl99981 w199982 w199983 w199984 w199985 wl99986 w199987 w199988 w199989 w199990 w1'J9991 w209677 w209678 w209679 w209680 w209681 ~209682 w209683 w209684 w212568 w212563 w212561t w212565 w212566 w212567 w215452 w215453 w215454 0.010 .020 .10 .21 .040 0.25 7 .71l 15 .40 14 .69L 11 .33L 5 .24 .16L 3 .27 .67L 8 . 55 .93l 6 .85 .75L 14 . 65 .45L 3 .55 .010L .41 .010 .19 .63l 7 .79L 14 .56l 11 .22 4 .33 10 .46 .84l 10 .32 3.7L 38 .040 .24 2 .093 .55L 11! .020 .32 5 .11 .030 .014 .28 .21 .69L 10 .5BL 5 .15l 2 1.8l 29 1.2l 15 .14 1.2L 22 .13 2.3L 33 .56 2.0l 18 .28 2.4L 33 .052 .18 4 .46 .36L 5 .065 .58L 7 .042 .38l 4 .16 .69L 11. .042 .lll 3 .19 .93L 7 .27 1.5L 33 .19 1.3L 33 . 25 .23L 2 .22 .92l 26 1.2 26 7.9 27 6.9 4.8 16 24 40 4.7 4.6 23 6.2 4.6 11 30 130 3.3 17 1.6 29 8.1 2.6 110 59 49 110 44 140 4.2 4.3 15 5.3 28 1.6 11 120 -68 1.5 51 0.1 6.3 .2 21 .1 6.5 .2 12 .1 9.3 .1 23 .1 16 .1 15 .2 11 .1 11 .1 520 .2 21 .l 14 .1 6.0 .1 3.9 .1 17 .4 15 .1 2.9 .2 7.0 .1 3.4 .2 11 .1 200 .0 35 .2 8.0 .2 11 .2 7.1 .3 15 .2 5.9 .3 8.9 .1 2.9 .1 2.2 .1 6.4 .1 3.3 .1 8.2 .1 10 .1 20 .2 11 .2 13 .1 170 .1 4.2 1.1 2.3 1.4 4.2 3.1 . 89 26 2.0 1.7 .45L 1.1 . 35 1.3 .70 1.3 7.2 9.3 3.1 2.2 1.7 2.4 1.7 .97 1.6 .59 3.5 1.5 5.2 4.6 1.2 L.4 .13 1.6 1.5 1.4 7.4 1.8 1.0 3.3 .78 0.78 1.2 .47 2.7 .64 .26 2.2 1.2 3.9 .86 .81 3.7 1.1 . 55 . 70 1.~ 1.9 . 24 1.4 .25 .78 1.0 .16 7.7 -6.8 4.5 4.3 3.8 10 .22 .41 1.5 .75 3.7 .49 1.7 4.8 2.1 .44 2.0 6.1 12 7.9 13 5.9 2.1 12 5.3 14 3 . 0L 4.2L 16 7. 2 3.1 8.8 11 32 3.1 13 4.8 8.2 7.5 1.5 29 20 24 33 17 46 3.5 6.5 5.6 6.0 11 2.9 4.8 22 16 1.1L H 11 28 14 23 5.9 8. 4 22 20 28 22 190 36 6.9 16 20 9.7 32 4.6 7.4 11 20 14 14 13 20 5.2 29 4.2 12 7.3 9.6 15 12 4.11 21 16 17 13 7.5 4.6 Sample number w199992 w199993 w199994 w199995 w199996 wl99974 wl99975 w199976 w199977 w199978 w199979 w199980 wl9998l w199982 w199983 w199984 w199985 wl99986 w199987 w199988 w199989 w199'J'JO w199991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 co 1:-.j Table 6e. Sample number Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from - Sand and lookout Mountains, Georgia and Alabama--continu--ed. ---- p Pb Pr - S Rb Sb Sc Se Sm Sn-S Sr-S (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) -(p-pm) w199992 22 w199993 87 w199994 70 w199995 140 w199996 13 1.8 2.9 60L 7.7 7.ll 60l 5.0 4.7 70l 8.3 6.9l 70l 4.2 3.3l 50l 0.20 1.6 0.7 1.3 0.03l 84 .80 4.1 1.7 2.5 .21 120 .40 3.0 1.6 2.5 .05l 150 1.4 3.6 1.3 1.6 .15l 210 .50 1.4 1.7 1.1 .07l 59 w199974 9 w199975 120 w199976 17 w199977 380 w199978 13 3.1 3.7 8.1 11 34 2.6 70L 6.7l CJOL 4.3 BOL 7.5l 90l 4.5l 80l .20 1.0 1.4 .60 .04l 150 4.0 2.9 2.5 1.1 H 150 .90 2.3 1.3 1.1 .OCJL 93 1.0 3.5 3.4 2.0 .17l 440 1.0 1.5 3.7 .60 H 260 w199979 800 w199980 410 w199981 310 w199982 13 w199983 83 .92L 6.3L 70l 7.4 7.9l BOL 15 5.6l 80l 2.9 3.6l 60l 3.9 5.3l 60l .40 1.3 2.9 1.0 H H .30 3 .9 3.0 1.9 .93 460 .80 1.4 3.3 2.0 H 490 .50 1.4 1.6 .70 .04l 130 .60 2.4 1.1 1.6 .05l 120 w199984 260 wl99985 900 w199986 9 w199987 31 w199988 52 4.3 47 .88 5.8 1.1 8.4l 37l 3.3l 5.5l 3.2L SOL 200l SOL 70l SOL 1.7 3.3 3.8 1.6 .19L 220 8.1 16 8.7 7.7 .37l 560 1.2 1.5 1.3 .70 .03l 200 1.3 3.7 1.3 1.9 .41 150 .30 1.4 1.0 1.2 .03l 120 w199989 35 w199990 35 w199991 13 w209677 160 w209678 190 6.7 130 2.4 CJ.1 10 6.9l 70l 13l 70l 3.3l 60l 18l 16 12l 27 1.2 4.5 1.6 1.4 .22 82 .40L 1.4 2.4 1.1 .17l 170 .40 1.0 1.8 .40 . 04l 130 .40 7.2 4.7 3.6 2.2 290 .50 4.6 2.2 2.0 .87 270 w209679 w209680 w209681 w209682 w209683 310 57 100 240 44l 19 15 26 43 1.7 26L 12 23l 68 20l 10 24l 31 l.Sl 20l 1.5 6.1 8.2 3.3 .26l 310 1.6 8.9 2.7 4.4 1.5 190 .70 3.8 4.4 2.4 .20l 200 1.8 11 5.9 4.7 1.2 330 .80 1.6 1.1 .80 .05 92 w209684 w212568 w212563 w212564 w212565 39 44l 44l 1,200 44l 3.8 3.6l 20l 3.4 7.1 18 2.8 1.7l 30l 9.4 6.9l 40l 3.4 1.7 20l .60 1.6 1.8 2.0l 3.2 1.4 2.0L 1.8 1.2 l.Ol 3.5 .9 l.Ol .85 1.4 1.0 1.3 .90 1.8 .60 .18 140 .20 57 .04l 88 .35 510 .03l 57 w212566 44 w212567 79 w215452 130 w215453 96 w215454 240 2. 5 11 2.5 1.4 5.7 5.3 10 17 40l 13l 55l 2.3l 40l 9.2l 60l l.Ol 2.4 1.8 .90 .O'Jl 99 l.OL 6.7 4.3 4.0 .so 6.0 5.1 3.9 . 34l 100 .28l 400 .50 1.3 2.4 .50 H 82 .60 4.7 5.0 2.8 .93 350 Sample number w199992 w199993 w199994 w199995 w199996 w199974 w199975 w199976 w199977 w199978 w199979 w199980 w199981 w199982 w199983 w199984 wl99985 w199986 w199987 w199988 w199989 w199990 w199991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 co c,., Table 6e. Sample number w199992 wl99993 w199994 wl99995 w199996 w199974 w199975 w199976 w199977 wl99978 w199979 w199980 w199981 w199982 w199983 w199984 w199985 w199986 wl99987 wl99988 w199989 w199990 w199991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from - Sand and Lookout Mountains, Georgia and Alabama--continued. Ta-S Tb Th Tl-S u v-s (ppm) (ppm) (ppm) -(ppm) (ppm) (ppm) H-S (ppm) Y-S (ppm) Vb (ppm) Zn (ppm) O.OOL .02 .OIL .02 .00 0.22 .30 .33 .31 .18 0.90 3.5 1.7 2.3 1.0 0.07l .33L .12L .33l .16L 0.19L .39 .02 .30 .19 8.0 29 15 24 12 8 5.9 0.6 5.5 8 7.5 .9 25 8 5.8 .9 12 B 10 1.0 55 B 4.7 .6 8.8 .OOL .01 .01 .02 .Oll .50l .20 .18 .28 .14 .40 1.4 1.4 2.7 .50 .07l .32L l .4 .70 .2ll .16 .70 1.2 .43 .16 3.4 21 21 22 2.8 8 2.9 8 12 8 7. 4 8 12 8 4.8 .4 5.3 .6 59 .7 14 .9 9.0 .3 14 .02l . 03 .02L .OOL .Oll .60L .22 .25 .11 .27 .70 3.6 1.1 .40 .90 .29l .16 10 .37l .60 28 .26l .29 4.9 .07l .17 3.4 .11l .19 12 8 5.0 8 12 B 5.7 B 4.3 8 6.3 .4 210 1.0 19 .7 6.6 .5 8.2 .6 16 .01 .06 .OOL .01 .OOL .26 l.O .12 .28 .19 2.0 11 .40 2.0 .60 .37l .55 20 .74l 3.5 64 .07l .18 9.5 .89 .56 26 .06L .17 5.3 8 8.1 B 20 8 4.4 8 11 8 4 .8 .8 27 2.5 29 .5 5.5 1.0 6.2 .6 4.2 .02 .01 .OOL .13 .06 .22 .12 .50l .49 . 30 2.5 1.1 .30 5.3 3.2 2.8 .27l .07l 1.2l .82l .83 .17 .17 1.9 .99 19 9.4 2.1 69 34 B 4.9 8 6. 4 8 2.4 .32 13 .18 12 .8 23 .6 9.4 .3 6.6 1.7 11 1.1 11 .07 .30 4.6 .SOL 3.8 35 .22 .67 7.2 1.5l 3.4 73 .04 .32 2.0 .60L 1.4 21 .29 .46 8.0 1.6l 4.4 75 .00 .18 .70 .10l .33l 4.0 .17 11 .30 12 .14 13 .61 19 .01 2.4 1.5 11 2.0 29 1.1 5.9 2.2 9.3 .5 3.5 .OOL .20 1.0 .02 .30 2.6 .00 . 54 .80 .03 . 25 2.9 .OOL .35 .50 . lll .40l . 12l .47l . 09l .29 .73 .40 1.3 .25l 6.5 15 10 23 4.4 .01 4.3 .10 4.0 .01 7.3 . 06 8.3 .01 3.6 .5 4. 3 .8 18 .6 3.3 .9 5.3 .4 23 .01 .16 .10 1.4 .06 .72 .Oll .13 .05 .47 1.4 4.9 4.7 .50 3.9 .29l l.Ol .87L .16l .62l 1.3 1.7 1.6 .16l 1.0 20 45 32 4.1 28 .04 6.8 .23 12 .11 9.6 .07L 2.7 .16 5.3 .6 30 1.7 9.1 1.6 16 .5 3.3 1.2 3.8 Sample number w199992 w199993 wl99994 wl99995 wl99996 w199974 w199975 wl99976 w199977 w199978 w199979 w199980 w199981 w199982 w199983 w199984 w199985 W199986 w199987 w199988 w199989 wl99990 w199991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 ~ ,p.. Table 6e. Sample number Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from Sand and lookout Mountains, Georgia and-A--la-b-a-m--a----c-o-n-ti-n-u-e-d-.-------- Zr-S (ppm) wl'J9992 w199993 w199994 w199995 wl'J9996 wl'J9974 w199975 w199976 w199977 w199978 w199979 w199980 w199981 w199982 w199983 w199984 w199985 w199986 w199987 w199988 w199989 w199990 w199991 w209677 w209678 w209679 w209680 w209681 w209682 w209683 w209684 w212568 w212563 w212564 w212565 w212566 w212567 w215452 w215453 w215454 10 11 5.4 31 8.8 2.6 33 11 48 6.5 9.0 43 9.8 7.4 6.7 20 32 5.1 24 3.8 9.9 23 4.4 59 71 50 43 42 110 2.6 5.0 11 8.5 43 7.8 17 36 30 5.4 20 c.o 01 Table 6e. Sample n!Bber Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from Sand and lookout Mountains, Georgia and Alabama--continued. -- ------- ------ - - ---- Si Al Ca Mg Na K Fe Ti Ag-S As Sample (percent) (percent) (percent) (percent) (percent) (percent) (perc-e-nt) (percent) (ppm) (ppm) number w215455 w215456 w215457 w218689 w218690 7.1 .35 3.7 1.2 7.4 4.9 .31 2.2 .72 3.8 0.11 .17 .097 .10 .090 0.096 .024 .085 .057 .27 0.051 .008 .032 . 026 .059 0.34 .040 .43 .16 .94 0.99 .61 .71 1.1 1.5 0.28 .013 .084 .037 .19 0.13 .030 .088 .038 .048 7.4 18 16 45 20 w215455 w215456 w215457 w218689 w218690 w218691 3.0 2.1 w218692 2.8 1.3 .062 . 084 .026 .37 .85 .14 .070 .038 .28 5.0 .090 .080 24 .073 .097 250 w218691 w218692 co 0') Table 6e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from - - - - - - - -Sa-nd and lookout Mountains, Georgia and Alabama--continued. ----------------- Sample 8-S Ba-S Be-S Bi-S Br Cd Ce Cl Co Cr number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) Sample number w215455 45 110 2 w215456 1.7 40 1 w215457 17 99 1 w218689 4.3 4.2 1 w218690 28 45 2 w218691 13 10 5 w218692 10 14 3 2.8l 37 .3l 77 1.5l 62 .6l 61 2 . 8l 48 1.3l 61 1.6l 30 0..0oo4 53 10 470 1,400 . 09 28 800 .03 12 B .11 35 B .09 25 B . 07 13 B 7.8 7.8 15 16 16 3.0 14 46 7.4 28 10 35 22 16 w215455 w215456 w215457 w218689 w218690 w218691 w218692 <:0 -:] Table 6e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from ---- ---- Sand and Lookout Mountains, Georgia and Alabama--continued. ----- Sample Cs Cu Dy-S Er-S Eu F Ga-S Gd-S Ge-S Hf n-u-mb-er- - - -(p-pm-)- -- --(ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) w215455 2.6 w215456 .2 w215457 2.2 w218689 .6 w218690 3.0 25 5.9 11 6.2 11 6.2l .8 3 . 2l 2.3 7.3 2.8l .4 1.5l .6 6.4 0.91 70 .24 30 .68 70 ,30 20 .70 80 9.6 4.2l 1.0 2.1 1.2 .47l 1.6 .6l 4.5 2.2l 2.9 .6 2.6 2.6 .32 .3 10 9.5 1.3l 1.3 w218691 3.0 19 3.4 1.8 .50 60 w218692 1.2 7.2 4.6 .8l .30 100 7.1 3.6 2.8 .7 8.9 4.6 6.7 .6 Sample number w215455 w215456 w215457 w218689 w218690 w218691 w218692 ~ 00 Table 6e. Sample runber Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from Sand and- Lookout Moun--tains, Georgia and Al-abama--continued. -------- - - - - - - Hg Ho-S La Li Lu Mn Ho-S Nb-S Nd-S Ni-S (ppm) (ppm) -- -(p-pm-) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) w215455 0.16 w215456 .19 w215457 .22 w218689 .36 w218690 .19 1.9L 36 .21L 5 .99L 15 .43L 6 1.9L 19 120 3.1 32 3.2 18 0.3 6.5 .2L 5.6 .2 9.7 .1 5.1 .2 23 1.0 8.8 10 20 1.0 .40 3.1 9.9 1.2 2.0 12 20 .82 . 88 4.8 19 .28L 5.3 28 45 w218691 .33 .88L 15 w218692 .36 1.1L 6 13 4.4 .2 3.4 2.3 1.9 15 21 .1 23 5.6 2.6 5. 7 31 Sample niJI'Iber w215455 w215456 w215457 w218689 w218690 w218691 w218692 ~ ~ Table 6e. Sample n~er Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples From - - Sand and lookout Mountains, Georgia and Alabama--continued. - p Pb Pr-S Rb Sb Sc Se Sm Sn-S Sr-S (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) -- (ppm) w215455 220 w215456 87 w215457 110 w218689 4 w218690 61 14 3.4 11 4.2 8.4 19l 60l 2.1L 50l 9.9l 70l 4.3l 15 20 33 1.1 8.3 8.7 4.1 1.7 280 .90 1.6 2.0 1.0 .05l 160 1.0 5.3 2.6 2.9 .54 130 .40 2.3 4.3 1.0 .29l 110 .40 6.7 2.0 2.6 1.3l 160 w218691 57 w218692 35l 9.2 9.3 21 11 lll 13 1.7 5.8 2.2 1.9 1.6 3.4 2.8 1.0 . 59l 63 .75l 140 ------ Sample numbe-r - w215455 w215456 w215457 w218689 w218690 w218691 w218692 I-' 0 0 Table 6e. Sample number Major-, minor-, and trace-element concentrations, on whole-coal basis, of ~7 bituminous coal samples from - - - S-and Ta-S and lookout Tb Mountai-ns, Th Georgia and Tl-S Alabama--continued. u v-s H-S v-s Yb Zn (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) - (ppm) --- (ppm) (ppm) (ppm) w215455 w215456 w215~57 w218689 w218690 0.20 .Oll .01 .01 .11 0.71 .24 -~3 .17 .36 8.0 .50 2.9 1.3 4.7 1.3l .14l .67l .63l 2.8l 2.4 .23l .64 .31 1.6 51 3. 7 26 6.9 45 0.28 .02 .13 .0~ .31 9.9 3.0 8.0 3.1 13 1.9 11 .7 8.7 1.4 16 .6 5.0 1.5 26 w218691 .03 w218692 .02 .36 3.1 . 18 1.5 1.3l 1.6l 2.0 34 .35 18 .15 12 .26 6.6 1.7 19 .8 14 Sample number w215~55 w215~56 w215457 w218689 w218690 w218691 w218692 1-' 0 1-' Table 6e . Sample number Major-, minor-, and trace-element concentrations, on whole-coal basis, of 47 bituminous coal samples from Sand and lookout Mou-n-t-a-in-s-, -G--eo-r-gia and Alabama--c-o-n-ti-n-u-e-d-. Zr-S (ppm) w215455 w215456 w215457 w218689 w218690 w218691 w218692 85 3.1 19 4.3 34 17 16 ~ 0 !:>:) Table 6f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabama. (All analyses except Kcal/kg, Btu, free-swelling index, and ash-fusion temperatures in percent. For each sample number, the analyses are reported three ways: first, as-received, second, moisture-free, and third, moistur- and ash-free. All analyses by Coal Analysis Section, Department of Energy, Pittsburgh, Pa.; B, not determined; 1540 for ash-fusion temperatures means greater - t h a n- -1-540 C). -- ----- Proximate Analysis Ultimate Analysis Heat of Combustion Sample number Volatile Fixed Moisture matter carbon Ash Hydrogen Carbon Nitrogen Oxygen Sulfur Kcal/kg Btu/lb- w199992 w199993 w199994 w199995 w199996 w199974 w199975 w199976 w199977 w199978 w199979 1.2 19.5 77.3 2.0 19.7 78.2 20.1 79.9 2.0 - 7.9 21.8 63.6 6.7 23.7 69.1 7.3 25.5 74.5 - 1.3 20.2 74.9 3.8 20.5 75.9 21.3 78.9 -3.9 1.7 19.3 69.8 9.2 19.6 71.0 21.7 78.3 9-.4 1.5 21.8 71.4 5.3 22.1 72.5 23.4 76.6 -5.4 1.3 19.2 77.2 2.3 19.5 19.9 78 . 2 80.1 -2-.3- 1.1 21.8 70.2 6.9 22.0 71.0 23.7 76.3 7-.0 1.3 21.6 71.4 5.7 21.9 72.3 5.8 23.2 76.8 - 1.5 23.9 63.9 10.7 24.3 27.2 64.9 72.8 1-0-.9- 1.4 27.0 65.8 5.8 27.4 66.7 29.1 70.9 -5.9 6.7 25.3 60.1 7.9 27.1 64.4 29.6 70.4 -8-.5- 4.6 86.5 4.5 87.6 4.6 89.4 4,1 68.5 3.5 74.4 3.8 80.2 4.4 85.6 4.3 86.7 4.5 90.2 4.5 78.6 4.4 80.0 4.8 88.2 4.5 81.9 4.4 83.1 4.6 87.9 4.2 87.2 4.1 88.3 4.2 90.5 4.0 80.2 3.9 81.1 4.2 87.2 4.6 82.6 4.5 83.7 4.8 88.8 4.6 76.7 4.5 77.9 5.0 87.4 4.6 79.4 4.5 80.5 4.8 85.6 4.3 69.7 3.8 74.7 4.2 81.6 1.5 4.8 1.5 3.8 1.5 3.9 1.2 19.0 1.3 13.0 1.4 14.0 1.6 4.0 1.6 2.9 1.7 3.0 1.5 5.3 1.5 3.9 1.7 4.3 1.4 6.1 1.4 4.8 1.5 5.1 1.6 3.9 1.6 2.8 1.7 2.8 1.5 5.0 1.5 4.1 1.6 4.4 1.5 4.3 1.5 3.2 1.6 3.4 1.4 5.7 1.4 4.4 1.6 5.0 1.5 5.6 1.5 4.4 1.6 4.7 1.3 16.3 1.4 11.1 1.5 12.1 0.6 8,420 15,160 .6 8,520 15,340 .6 8,700 15,660 .5 6,220 11,200 .5 6,750 12,160 .6 7,280 13,110 .9 8,250 14,850 .9 8,360 15,050 .9 8,690 15,650 .'9 7,630 13,730 .9 7,760 13,960 1.0 8,560 15,410 .a 8,070 14,530 .8 8,200 14,750 .9 8,660 15,590 .7 8,390 15,090 .7 1,500 15,290 .7 8,700 15,660 2.5 7,930 14,270 2.5 8,020 14,430 2.7 8,620 15,510 1.2 8,040 14,470 1.2 8,150 14,660 1.3 8,650 15,560 .9 7,480 13,470 .9 7,600 13,680 1.0 8,520 15,3<40 3.1 7,930 14,270 3.1 1,040 14,470 3.3 8,540 15,380 .5 6,470 11,650 .5 6,940 12,490 .6 7,580 13,640 ....... 0 C;:l Table 6f. Sample nunber Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for 47 bituminous coal samples from Sand and Lookout Mountains, Georgia and Alabam--a---co-nt-inu-ed-. ------- - Forms of sulfur Ash fusion temperature, C Air-dried loss Sulfate Pyritic Organic - Free swelling index Initial deformation Softening Fluid wl'J9992 w199993 w199994 wl99995 w199996 w199974 w199975 w199976 w199977 w199978 w199979 0.6 0.01 0.20 0.41 .01 .20 .41 .01 .21 .42 4.6 .01 .07 .38 .01 .08 .41 .01 .08 .44 .5 .01 .36 .49 .01 .36 .50 .01 .38 .52 .1 .01 .17 .72 .01 .11 .13 .01 .19 .81 .7 .01 .20 .57 .01 .20 .58 .01 .21 .61 .6 .01 .26 .48 .01 .26 .49 .01 .27 .50 .4 .01 2.14 .33 .01 2.16 .33 .01 2.33 .36 .6 .01 .68 .52 .01 .69 .53 .01 .73 .56 .7 .01 .67 .25 .01 .68 .25 .01 .76 .28 .6 .01 2.79 .32 .01 2.83 .32 .01 3.01 .34 3.4 .01 .21 .30 .01 .23 .32 .01 .25 .35 4.5 .o 8.5 8.0 8.5 8.0 8.0 9.0 9.0 9.0 . .0 1,345 1,540 1,270 1,455 1,360 1,245 1,140 1,320 1,495 1,150 1,155 1,395 1,540 1,320 1,515 1,405 1,310 1,205 1,365 1,540 1,210 1,205 1,440 1,540 1,370 1,540 1,465 1,390 1,250 1,410 1,540 1,265 1,265 1-' 0 ~ Table 6f. ---- Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for 47 bituminous coal samples from Sand and lookout Mountains, Georgia and Alabama--continue-d.- - --- - ----- Proximate Analysis Ultimate Analysis Heat of Combustion Sa~le number Volatile Fixed Moisture matter carbon Ash Hydrogen Carbon - - - - Nitrogen- - -O-xy-ge-n- - -S-u-lfur Kcal/kg Btullb w1 Table 7c. Major- and minor-oxides and trace-element concentrations in the labor a tory ash of eight bituminous coal samples from coal bed No. 10, Sand and lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. l means less than the value shown; H, interference for an element which cannot be resolved by any routine method; G, greater than; 8, not de termi ned; S, after element title indicates determinations are to be taken as plus 50% and minus 35%. Samp 1e number i s 1abor a tory number ) . Sample number Ash Sl02 Al203 CaD HgO Na20 K20 Fe203 Ti02 P205 Sample (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) number w209679 17.4 42 27 w209681 13.0 50 27 w209682 35.7 56 26 w212567 22.7 51 26 w215452 18.9 49 28 w215454 13.5 52 33 w215455 28.3 54 33 w218692 16.4 36 15 0.88 1.2 .17 .49 0.46 .50 .37 .75 0.18 .18 .13 .26 J 11..23 1 11..64 23 16 4.8 15 .94 .40 .30 .9 . 17 1.4 .56 .22 1.21 6.2 .55 .56 .24 1.4 i 5.0 1.2 .71 .31 2.1 I 43 1.4 0.41 w209679 1.4 .18 w209681 1.5 .15 w209682 1.2 .08 w212567 1.3 .16 w215452 1.6 .40 w215454 1.7 .18 w215455 7t+ .05l w218692 I ...... ...... ~ Table 7c. --- Sample nunber Major- and minor-oxides and trace-element concentrations in the laboratory ash of eight bituminous coal samples from coal bed-No. 10, Sand and Lookout Hountat-ns-,--Georgia and Alabama--continued. S03 Ag-S 8-S Ba-S Be-S Br Cd Ce Co Cr Sample (percent) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (p-p-m) (ppm) number w209679 1.1 0.53 110 560 w209681 1.3 2.9 120 530 w209682 .50 .42 150 400 w212567 1.3 .33 110 390 w215452 1.2 .44 170 570 12 260 13 470 8.9 69 12 140 9.5 200 0.10L 230 .10L 210 .lOL 180 .10 250 .50 260 22 180 13 120 6.2 140 19 120 51 140 w209679 w209681 w209682 w212567 w215452 w215454 1.6 .47 180 630 w215455 .80 .47 160 400 w218692 8 .!59 64 88 10 380 8.5 130 19 180 .20 290 .13 190 .40 79 30 150 w215454 28 160 w215455 85 98 w218692 ~ ~ 01 {, Table 7c. Sample nunber Major- and minor-oxides and trace-element concentrations in the laboratory ash of eight bituminous coal samples - from coal bed No. 10, Sand and Lookout Mountains, Georgia and'Alabama--con tinued . -- Cs Cu Dy-S Eu Ga-S Gd- S Ge-S Hf La Li Sample (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) -m-n-b-e-r-- - w209679 10 74 22L 4.1 38 46L 54 8.6 130 280 w209679 w209681 10 79 22L 3.9 32 46L 11 6.2 140 340 w209681 w209682 7.6 26 22L 2.8 40 46L 28 9.5 92 380 w209682 w212567 7.9 140 22L 4.1 34 15L 8.8 5.7 150 540 w212567 w215452 7.4 140 22L 4.8 31 15L 1.6 6.3 170 360 w215452 w2151t54 7.1t 110 22L lt.7 35 15L 1.6 8.1 190 380 w215454 w2151t55 9.2 88 22L 3.2 34 15L 3.6 7.4 130 440 w215455 w218692 7.3 44 28 1.8 54 28 41 3.7 37 27 w218692 ~ ~ 0) Table 7c. --- Sample number Major- and minor-oxides and trace-element concentrations in the laboratory ash of eight bituminous coal samples from coa-l -b-ed No. 10, Sand an--d Lookout Mountains, Georgia and A-l-ab-a-m-a---c-o-nt-in-ue-d-. ------ Lu Mn Ho-S Nb-S Nd-S Ni-S Pb Pr-S Rb Sc Sample (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (p-pm) (ppm) (ppm) (ppm) number w209679 1.0 41 w209681 1.2 45 w209682 .8 25 w212567 1.1 75 w215452 1.2 70 20 26 140 40 29 130 13 29 130 8.1 21 96 5.4 11 85 30 110 150L 69 35 w209679 32 200 150L 77 29 w209681 34 120 68L 87 31 w209682 77 47 74 180L 30 w212567 70 13 68L 290L 32 w215452 w215454 1.0 31 5.8 15 80 34 42 68L 440L 35 w215454 w215455 .9 23 3.7 31 37 70 51 68L 210L 29 w215455 w218692 .6 140 34 16 35 190 70 68L 79 21 w218692 f--1. f--1. -J Table 7c. Sample number Major- and minor-oxides and trace-element concentrations in the laboratory ash of eight bituminous coal samples from coal Sm bed No. Sn-S 10, Sand and lookout Sr-S Ta Mountain-s-, Tb Georgia Th an-d -Al-a-ba-m-a---c-o-nt u inued. v-s --- -- -H-S Y-S Sample (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w209679 w209681 w209682 w212567 w215452 w215454 w215455 w218692 19 18 13 18 21 21 14 6.1 1.5l 1.5l 3.3 1.5l 1.5l 6.9 5.9 4.6l 1,800 1,500 920 450 2,100 2 , 600 1,000 880 0.40 1.7 26 . 33 2.5 15 .82 1.3 22 . .44 6.0 22 .34 3.8 25 22 200 11 160 12 210 7.4 200 8.4 170 .37 3.5 29 .70 2.5 28 . 15 1.1 9. 1 7.5 210 8.3 180 2.1 110 1.0 64 1.1 100 1.7 53 1.0 51 .6 51 1.2 39 1.0 35 1.6 40 w209679 w209681 w209682 w212567 w215452 w215454 w215455 w218692 f-1 f-1 00 Table 7c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of eight bituminous coal samples from coal bed No. 10, Sand and lookout Mountains, Georgia and Alabama--continued. S8J!1>Ie nlnber Yb (ppm) Zn (ppm) Zr-S (ppm) w209679 8.6 62 290 w209681 8.5 45 320 w209682 6.2 26 320 w212567 7.5 40 160 w215452 8.5 84 160 w215454 8.9 28 150 w215455 6.7 I 39 300 w218692 4.9 88 100 ~ ~ co Table 7d. Content of 22 trace-elements in eight bituminous coal samples from coal bed No. 10, Sand and lookout Mountains, Georgia and Alabama. -- - - -- - -- -- (Analysis performed on whole-coal. Values in parts-per-million(ppm). l, less than the value shown; B, not determined). Sample As Ce Cl Co Cr Cs Eu F Hf Hg Sample number (p-pm-) - - -(p-pm-) - - -(ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w209679 w209681 w209682 w212567 w215452 w215454 w215455 w218692 66.0 52.8 41.5 83.7 25.6 3.1 7.4 246 40 910 27 1,200 64 330 57 450 49 370 39 900 53 470 13 B 3.8 31 1.7 15 2.2 50 4.3 27 9.7 27 4.1 21 7.8 46 14 16 1.8 0. 71 70 1.3 .51 30 2.7 1.0 120 1.8 .93 50 1.4 . 91 100 I 1.0 . 63 160 2.6 . 91 70 1.2 100 . 3, 1.5 0.14 w209679 .8 .56 w209681 3.4 .28 w209682 1.3 .27 w212567 1.2 .19 w215452 1.1 .22 w215454 2.1 .16 w215455 .6 . 36 w218692 ~ t-:) 0 Table 7d. - Sample nllllber Content of 22 trace-elements in eight bituminous coal samples from coal bed No. 10, Sand and lookout Hountains, - -- Georgia and Alabama--continued. -- --- - -- La lu Na p Rb Sb Sc Se Sm Tb Sample (ppm) - (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) nllllber w209679 22 w209681 18 w209682 33 w212567 33 w215452 33 0.2 230 310 12 1.5 6.1 8.2 3.3 0.3 w209679 .2 170 100 10 .70 3.8 4.4 2.4 .3 w209681 .3 340 240 31 1.8 11 5.9 4.7 .5 w209682 .2 430 79 40l l.Ol 6.7 4.3 4.0 1 w212567 .2 420 130 55l .50 6.0 5.1 3.9 .7 w215452 w215454 26 w215455 36 w218692 6 .1 220 240 60l .3 510 220 60l .1 380 35l 13 .60 4.7 5.0 2.8 1.1 8.3 8.7 4.1 1.6 3.4 2.8 1.0 .5 w215454 .7 w215455 .2 w218692 I-' ~ I-' Table 7d. Sample number Content of 22 trace-elements in eight bituminous coal samples from coal bed jNo. 10, Sand and Lookout Mountains, Georgia and Alabama--continued. ' Th (ppm) u (ppm) Yb (ppm) w209679 4.6 w209681 2.0 w209682 8.0 w212567 4.9 w215452 4.7 w215454 3.9 w215455 8.0 w218692 1.5 3.8 1.5 1.4 1.1 4.4 2.2 1.7 1.7 1.6 1.6 1.0 1.2 2.4 1.9 .35 .8 ~ ~ ~ Table 7e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of eight bituminous coal samples from coal bed No. 10, Sand and lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinations on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine method; 8, not determined; G, greater than. Sample number is laboratory number-)-. - Sample Si Al Ca Mg Na K Fe Ti Ag-S As Sample number - - - (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (ppm) (ppm) number w209679 3.4 2.5 0.11 0.049 0.023 0.19 2.8 0.15 0.092 66 w209679 w209681 3.0 1.8 .11 .039 .017 .13 1.4 .11 .38 53 w209681 w209682 9.4 5.0 .043 .078 .034 .49 1.2 .31 .15 42 w209682 w212567 5.4 3.2 .079 .10 .043 .26 2.4 .16 .075 84 w212567 w215452 4.3 2.8 .13 .045 .042 .15 2.2 .15 .083 26 w215452 w215454 3.3 2.3 w215455 7.1 4.9 w218692 2.8 1.3 .13 .046 .022 .13 .58 .13 .063 3.1 w215454 .11 .096 .051 .34 .99 .28 .13 7.4 w215455 .14 .070 .038 .28 5.0 .073 .097 250 w218692 ~ 1:\:) CA:l Table 7e. Sarf4>le number Major-, minor-, and trace-element concentrations, on whole-coal basis, of e i ght bituminous coal samples from - coal bed No. -10, Sand and Lookout Mountains, Georgia and Alabama--continued . -- 8-S Ba-S Be- S Br Cd Ce Cl Co Cr Cs (ppm) (ppm) - (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) Sarf4>le number w209679 19 97 w209681 16 69 w209682 54 140 w212567 25 89 w215452 32 110 2 45 2 62 3 25 3 31 2 37 0.02l 40 .Oll 27 .04L 64 .02 57 .09 49 910 1,200 330 450 370 3.8 31 1.7 15 2.2 50 4.3 27 9.7 27 1.8 w209679 1.3 w209681 2.7 w209682 1.8 w212567 1.4 w215452 w215454 24 85 w215455 45 110 w218692 10 14 1 52 2 37 3 30 .03 39 .04 53 .07 13 900 470 8 4.1 21 7.8 46 14 16 1.0 w215454 2.6 w215455 1.2 w218692 1-' 1:..:1 *"' Table 7e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of eight bituninous coal samples from coal bed No. 10, Sand and Lookout Mountains, Georgia and Alabama--continued. Sample nunber Cu (ppm) Dy-S (ppm) Eu (ppm) F (ppm) Ga-S (ppm) Gd-S (ppm) Ge-S (p-pm) Hf (ppm) Hg (ppm) La (ppm) Sample nunber w209679 w209681 w209682 w212567 w215452 13 10 9.3 32 26 3.8L 2.9L 7.9L 5.0L 4.2L 0.71 70 .51 30 1.0 120 .93 50 .91 100 6.6 8.0L 9.4 1.5 4.2 6.0L 1.4 .8 14 16L 10 3.4 7.7 3.4L 2.0 1.3 5.9 2.8L .30 1.2 0.14 22 .56 18 .28 33 .27 33 .19 33 w209679 w209681 w209682 w212567 w215452 w215454 w215455 w218692 15 25 7.2 3.0L 6.2L 4.6 .63 160 .91 70 .30 100 4.7 2.0L .22 1.1 9.6 4.2L 1.0 2.1 8.9 4.6 6.7 .6 .22 26 .16 36 .36 6 w215454 w215455 w218692 ....... 1:>:1 01 Table 7e. ----- Sample nt.tnber Major-, minor-, and trace-element concentrations, on whole-coal basis, of ei ght bituminous coal samples from coal bed No. 10, Sand and Lookout Mountains, Georgia and Alabama--conti nued. Li (ppm) Lu (ppm ) Hn (ppm) Mo-S (ppm) Nb-S (ppm) Nd- S (ppm) Ni - S (ppm) p (ppm) Pb (ppm) Pr-S (ppm) Sample nt.tnber w209679 w209681 w209682 w212567 w215452 w215454 w215455 w218692 49 44 140 120 68 51 120 4.4 0.2 7.1 .2 5.9 .3 8.9 .2 17 .2 13 .1 4.2 .3 6.5 .1 23 3.5 4.5 5.2 3.8 4.6 10 1.8 4.8 1.0 2.1 .78 2.0 1.0 8.8 5.6 2.6 24 17 46 22 16 11 10 5.7 5.2 310 4.2 100 12 240 17 79 13 130 4.6 240 20 220 31 35L 19 26 43 11 2.5 5.7 14 11 26L 20L 24L 17 13l 9.2L 19l 11l w209679 w209681 w209682 w212567 w215452 w215454 w215455 w218692 ...... t..:l 0':1 Table 7e. --- Sample I"'UUiler Major-, minor-, and trace-element concentrations, on whole-coal basis, of eight bituminous coal samples from ----- coal bed No. 1-0-,--Sand and lookout Mountains, Georgia and Alabama--continued. - Rb Sb Sc Se Sm Sn-S Sr-S Ta-S Tb Th (ppm) -- (ppm) (ppm) - (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) - Sample I'IU!iler w209679 12 w209681 10 w209682 31 w212567 40l w215452 55l 1.5 6.1 8.2 3.3 0.26l 310 .70 3.8 4.4 2.4 .20l 200 1.8 11 5.9 4.7 1.2 330 l.Ol 6.7 4.3 4.0 .34l 100 .50 6.0 5.1 3.9 .28l 400 0.07 .04 .29 .10 .06 0.30 .32 .46 1.4 .72 4.6 w209679 2.0 w209681 8.0 w209682 4.9 w212567 4.7 w215452 w215454 60l w215455 60l w218692 13 .60 4.7 5.0 2.8 .93 350 1.1 8.3 8.7 4.1 1.7 280 1.6 3.4 2.8 1.0 .75l 140 .05 .47 3.9 w215454 .20 .71 8.0 w215455 .02 .18 1.5 w218692 1-' 1.\:) -l Table 7e. Si\mple number Major-, minor-, and trace-element concentrations, on whole-coal basis, of ei ght bituminous coal samples from --- --coal bed No. 10, Sand and lookout Mountains, Georgia and Alabama--conti nued . u v-s H-S Y-S Yb Zn Zr-S Sample - (ppm) (ppm) (ppm) (ppm) -(ppm) (ppm) (ppm) number w209679 3.8 35 w209681 1.~ 21 w209682 ~-4 75 w212567 1.7 45 w215452 1.6 32 0.17 .lit .61 .23 .11 11 13 19 12 9.6 1.5 11 50 1.1 5.9 ~2 2.2 9.3 110 1.7 9.1 36 1.6 16 30 w209679 w209681 w209682 w212567 w215452 w215454 1.0 28 w215455 2.4 51 w218692 .35 18 .16 5.3 .28 9.9 .26 6.6 1.2 3.8 20 1.9 11 85 .8 14 16 w215454 w215455 w218692 --- - - - ..... !:>:) 00 Table 7f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for eight bituminous coal samples from coal bed No. 10, Sand and lookout Mountains, Georgia and Alabama. (All analyses except Kcal / kg, Btu, free-swelling index, and ash-fusion temperatures in percent. For each sample number, the analyses are reported three ways : first, as-received, second, moisture-free, and third, moisture- and ash-free. All analyses by Coal Analysis Section, Department of Energy, Pittsburgh, Pa.; 8, not determined; 1540 for ash-fusion te-m-peratures means greater than 1540 C). - -------- Proximate Analysis Ultimate Analysis Heat of Combustion Sample nunber Moisture Volatile matter Fixed carbon Ash Hydrogen Carbon - Nitrogen Oxygen - - Sulfur Kcal/kg Btullb w209679 w209681 w209682 w212567 w215452 w215454 w21545S w218692 1.9 25.7 56.1 16.3 4.4 70.0 1.0 7.2 1.1 6,810 12,250 26 . 2 31.4 57.2 68.6 1-6.6 4.3 71:4 5.1 85.6 1.0 1.2 5.6 6.7 1.1 6,940 12,490 1.3 8,320 14,980 2.0 22.3 63.4 12.3 4.3 74.2 1.1 7.4 22 . 8 64.7 12.6 4.2 75.7 1.1 5.7 26.0 74.0 --- 4.8 86.6 1.3 6.6 .7 7,160 12,890 .7 7, 310 13,160 .8 8,360 15,040 1.5 18 . 0 46.3 34.2 3.4 54.5 .7 S.9 1.3 S,220 9,400 18.3 47.0 34.7 3.3 55.3 .7 4.6 1.3 S,300 9,550 28.0 72.0 --- 5.0 84.8 1.1 7.1 2.0 8,130 14,630 3.3 19.3 57 . 1 20.3 4.0 6S . 5 .9 7.5 1.7 6,300 11.330 20.0 59.0 21.0 3.8 67.7 1. 0 4.8 1.8 6,510 11,720 25.3 74.7 - 4.8 8S . 7 1.2 6.0 2.3 8,240 14 , 830 2.5 21.3 60 . 8 15.4 4.1 71.4 1.2 5.9 2.0 6,970 12,550 21.9 26.0 62.3 74 . 0 1-5 .-8 4.0 73 . 2 4.7 86 . 9 1.2 1.4 3.8 4.6 2.0 7,150 12 , 870 2.4 8,490 15,280 1.4 20.1 66.1 12.3 4.3 76.3 1.2 s.o .9 7,370 13,270 20.4 67.1 12.5 4.2 77.4 1.2 3.8 1.0 7,480 13 , 460 23.4 76.6 --- 4.8 88 . 4 1.4 4.3 1.1 8,550 15,380 2.0 18 . 2 52.5 27.3 3.8 60.7 .9 6.3 1.0 5,870 10,560 18 . S 25.7 53.6 74.3 2-7.9 3.6 62.0 5.0 85.9 .9 1. 3 4.6 6.3 1.1 S,CJ90 10,780 1.5 8,300 14,940 1.3 26.2 58.3 14.2 4.5 71.1 1. 2 3.7 5.3 7,140 12,860 26.5 31.0 59.1 69.0 1-4-.-4 4.4 72.0 5.2 84.1 1. 2 1.4 2.6 3.1 5.4 7,240 13,030 6.3 8,450 15,210 ..... !:') ~ Table 7f. Saq~le number Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swe lling index, and ash-fusion temperature determinations for eight bituminous coal samples from coal bed No. 10, Sand and Lookout Mountains, Georgia and Alabama--continued - - - - --- Forms of sulfur Ash fus i on temperature, C Air- dried loss Sulfate Pyritic Free Organic swelling index Initial deformation Softening -- -- Fluid w209679 w209681 w209682 w212567 w215452 w21S4S4 w21S4SS w218692 0.9 0.01 0.19 0.90 7.0 .01 .19 .92 .01 .23 1.10 1.0 .01 .OS .61 3.5 .01 .os .62 .01 .06 .71 .7 .15 . 22 .89 1.0 .15 . 22 .90 .23 . 34 1.38 2.3 .42 .80 .51 3.5 .43 .83 .53 .ss 1.05 .67 1.~ .19 1.17 .63 7.0 .19 1.20 .65 .23 1.42 .77 .6 .09 .16 .69 6.5 .09 . 16 .70 . 10 . 19 .80 1.1 . 25 .25 .55 3.0 .26 . 26 .56 .35 .35 .78 .4 . 41 3.50 1.39 8.5 .42 3. 55 1.41 .49 4 . 14 1.64 1,280 1,365 1,540 1,400 1,425 1,470 1,520 1,060 1,325 1,425 1,540 1,440 1,470 1,515 1,540 1,095 1,395 1,470 1,540 1,465 1,495 1,540 1,540 1,190 1-' C/.:1 0 Table Sa. saq>le no. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for three bituminous coal samples from coal bed No. 9A, Sand and lookout Mountains, Georgia and Alabama. state county latitud longitud formation coal bed rank w199979 georgia dade 345653n 853037w gizzard no 9a bit w209677 georgia dade 345440n 853122w gizzard no 9a bft w209680 georgia dade 344756n 853101w gizzard no 9a bit sample type chamel charvlel chamel sampled thickness (inches) 20.0 36.0 32.0 1-' Co:> 1-' Table 8b. Summary statistical table of analytical data for three bituminous coal sa~les from coal bed No. 9A, Sand and lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash~fusion temperatures in degrees F. data values item used mean ---- std dev ------- xmin ---- -xm--a-x range ----- geo mean -' - - - geo dev sigma zero qual usgsash 3 23.07 10.17 9.200 statistics for following data items on ash basis 33.30 24.10 20.15 1. 75 12.45 0 0 sio2 3 al2o3 3 cao 3 mgo 3 na2o 3 k2o 3 fe2o3 3 mno 3 tio2 3 p2o5 3 so3 3 40.39 25.24 1.28 1.08 0.14 2.09 20.19 0.24 0.94 0.73 2.97 19.36 10.16 1.31 0.68 0.05 1.61 23.52 0.34 0.45 0.90 3.21 13.030 10.880 0.210 0.365 0.073 0 . 600 3.100 0.004 0.330 0.040 0. 700 55.04 32.79 3.13 1.99 0.19 4.33 53.44 0.72 1.39 2.00 7.52 42.01 21.91 2.92 1.63 0.12 3.73 50.34 0.72 1.06 1.96 6.82 33.65 122.53 0.69 0.86 0.13 1.51 8.73 0.03 0.79 0.22 1.54 1.96 1.67 3.08 2.00 1.50 2.25 3.62 9.61 1.87 5.11 3.06 23.72 12.44 1.61 0.83 0.06 1.98 28.80 0.41 0.55 1.10 3.94 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 statistics for following data items on "whole-coal" basis ag 2 0.05 0.03 0 . 019 as 3 12.77 9.24 5 . 400 there were less than two positive-valued items for au b 3 40.31 26.50 5.612 ba 3 156.66 25.80 138.000 be 3 1.81 0.42 1.472 there were less than two positive-valued items for bi br 3 6.73 4.43 2.745 cd 3 0.20 0.22 0.043 ce 3 34.67 17.91 10.000 cl 3 376.67 92.86 250.000 co 3 9.73 7.66 3.300 cr 3 33.83 19.37 7.200 cs 3 3.00 2.54 0.300 cu 3 22.85 9.75 15.640 there were less than two positive-valued items for dy there were less than two positive-valued items for er eu 3 0.63 0.31 0.210 f 2 145.00 45.00 100.000 ga 3 7.60 4.29 1.932 there were less than two positive-valued items for gd ge 2 0.86 0.61 0.248 hf 3 1.13 0.59 0.300 hg 3 0.32 0.17 0.130 there were less than two posit ve-valued terns for ho there were less than two posit ve-valued terns for in there were less than two posit ve-valued terns for ir la 3 23.00 11.43 7.000 li 3 76.65 50.95 4.600 lu 3 0.20 0.07 0.100 mn 3 179.51 237.39 8.010 mo 3 1.40 0.21 1.104 nb 3 4.29 2.83 0.810 nd 2 31.34 1.97 29.370 0.08 25.80 69.93 193.14 2.40 12.92 0.51 52.00 470.00 20.50 52.70 6.40 36.63 0.97 190.00 12.32 1.47 1.60 0.55 33.00 113.22 0.27 515.20 1.60 7.74 33.30 0.06 20.40 64.32 55.14 0.93 10.18 0.46 42.00 220.00 17.20 45.50 6.10 20.99 0.76 90.00 10.39 1.22 1.30 0.42 26.00 108.62 0.17 507.19 0.50 6.93 3.93 0.04 9.96 126.12 154.68 1. 77 5.44 i 0.10 127.95 363.87 1 1.15 25.08 I 1.64 121.05 0.52 137 .84 5.88 0.60 0.90 0.27 18.85 38.80 0.19 39.84 1.38 3.01 31.27 2.04 1.98 3.01 1.17 1.24 1.91 3.06 2.08 1.31 2.16 2.43 3.57 1.48 1.93 1.38 2.23 2.43 2.17 1.80 2.02 4.52 1.56 6.23 1.18 2.60 1.06 0.04 11.32 32.46 31.60 0.51 5.43 0.26 21.94 113.72 9.38 23.72 3.11 11.94 0.39 63.64 5.26 0.86 0 . 72 0.21 14.00 62.40 0.09 290.74 0.26 3.47 2.78 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 ...... C.IJ _1:-j Table 8b. Summary statistical table of analytical data for three bituminous coal samples from coal bed No. 9A, Sand and lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion temperatures in degrees F--continued. ni 3 78.35 81.50 12.549 193.20 180.65 41.42 3.14 99.81 0 0 there were less than two positive-valued items for os pb 2 12.03 2.95 9.078 14.99 5.91 11.66 1.28 4.18 0 1 there were less than two positive-valued items for pd there were less than two positive-valued items for pr there were less than two positive-valued items for pt rb 2 42.00 26.00 16.000 68.00 52.00 32.98 2.06 36.77 0 1 there were less than two positive-valued items for re there were less than two positive-valued items for rh there were less than two positive-valued items for ru sb 3 0.80 0.57 0.400 1.60 1.20 0.63 1.92 0.69 0 0 sc 3 5.82 3.27 1.300 8.94 7.64 4.38 2.37 4.01 0 0 se 3 3.44 0.90 2.730 4.70 1.97 3.33 1.28 1.10 0 0 sm 3 3.00 1.45 1.000 4.40 3.40 2.51 1.93 1. 78 0 0 sn 2 1.84 0.38 1.465 2.22 0.75 1.80 1.23 0.53 0 1 sr 2 240.09 53.61 186.480 293.70 107.22 234.03 1.25 75.82 0 1 ta 2 0.18 0.05 0.131 0.22 0.09 0.17 1.31 0.07 0 1 tb 2 0.58 0.09 0.490 0.67 0.18 0.57 1.17 0.13 0 1 there were less than two positive-valued items for te th 3 4.40 2.73 0.700 7.20 6.50 2.99 2.81 3.34 0 0 there were less than two positive-valued items for tl there were less than two positive-valued items for tm u 3 1.81 1.32 0.160 3.38 3.22 1.01 3.75 1.61 0 0 v 3 50.93 28.90 10.120 73.26 63.14 37.20 2.51 35.40 0 0 w 2 0.31 0.01 0.300 0.32 0.02 0.31 1.03 0.01 0 1 y 3 10. 10 3. 67 4.968 13.35 8.38 9.26 1.56 4. 50 0 0 yb 3 1.37 0.69 0.400 2.00 1.60 1.11 2.06 0.85 0 0 zn 3 83.84 90.64 10.947 211.60 200.65 40.64 3.43 111.01 0 0 zr 3 37.02 20.78 9.016 58.74 49.72 28.41 2.27 25.45 0 0 statistics for following data items on "as received" basis data values mean std dev xmin item used xmax range geo mean geo dev sigma zero qual btu ashdef ashsof ashfld freswel moistur volmat fixedc bmash hydrogn carbon nitrogn oxygen sulfur sulfate sulfpyr sulforg adloss 3 10775.67 704.04 9926.000 11650.00 3 2570.00 325.27 2110.000 2800.00 3 2600.00 282.84 2200.000 2800.00 3 2636.67 230.99 2310.000 2800.00 2 5.50 0.50 5.000 6.00 3 3.40 2.33 1. 700 6.70 3 22.73 1.83 21.200 25.30 3 52.20 6.08 45.300 60.10 3 21.67 9.99 7.900 31.30 3 4.03 0.21 3.800 4.30 3 62.37 5.57 56.200 69.70 3 1.07 0.17 0.900 1.30 3 10.17 4.34 6.900 16.30 3 0.73 0.17 0.500 0.90 has insufficent variance to calculate statistics 3 0.14 0.05 0.080 0.21 3 0.59 0.21 0.300 0.79 3 1.77 1.16 0.900 3.40 1724.00 690.00 600.00 490.00 1.00 5.00 4.10 lit. 80 23.40 0.50 13.50 0.40 9.40 0.40 0.13 0.49 2.50 10752.67 2548.00 2583.72 2626.09 5.48 2.74 22.66 51.85 18.55 4.03 62.12 1.05 9.36 0.71 0.13 0.55 1.45 1.07 1.14 1.12 1.09 1.10 1.88 1.08 1.12 1.84 1.05 1.09 1.17 1.48 1.29 1.49 1.53 1.83 862.26 398.37 346.41 282.90 0.71 2.86 2.24 7 . 45 12.24 0.25 6.83 0.21 5.32 0.21 0.07 0.26 1.42 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ,...... c:.J c:.J Table 8c. Major- and minor-oMides and trace-element concentrations in the laboratory ash of three bituminous coal samples from coal bed No. 9A, Sand and lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. L means less than the value shown; H, interference for an element which cannot be resolved by any routine method; G, greater than; 8, not determined; S, after element title indicates determinations are to be taken as plus 50% and minus 35%. Sample number is laboratory number ) . Sample number Ash Si02 A1203 CaD MgO Na20 K20 Fe203 Ti02 P205 Sample (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) nu-m-be-r - - w199979 9.2 13 11 w209677 26.7 55 32 w209680 33.3 53 33 3.1 2.0 0.07 0.60 53 .50 . 36 .19 1.3 3.1 .21 .88 .15 4.3 4.0 0.33 2.0 w199979 1.4 .14 w209677 1.1 .04 w209680 Table Sc . Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituminous coal samples --- from coal bed No. 9A, Sand-a-nd-Lookout Mounta-ins, Georgia and Alabama--continued. Sample S03 Ag-S 8-S Ba-S Be-S Br Cd Ce Co Cr Sample -nu-mb-er- - -(-p-e-rcen-t) - (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199979 w209677 w209680 7.5 .70 .70 0.21 61 . 30 170 .10L 210 1,500 520 580 16 320 9.0 64 4.7 120 5.5 110 220 78 wl99979 .16 160 12 160 w209677 .16 160 16 160 w209680 ~ CA:I 01 Table 8c . Major- and minor-oxides and trace-element concentrations in the la bora tory ash of three bituminous coal samples - - --- from coal bed No. 9A, Sand and lookout Mountains, Georgia and Alaballla~on t inued . --- Sample Cs Cu Eu Ga-S Ge-S Hf la li lu Mn Sample -num-b-er - - (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199979 3.3 170 w209677 8.6 61 w209680 19 110 2.3 21 2.6 32 2.9 37 2.7 3.3 76 50 5.5 6.0 110 420 1.5l 4.5 99 340 1.1 5,600 .9 30 .8 46 w199979 w209677 w209680 "c".";", 0) Table 8c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituminous coal s~les from coal bed No. 9A, Sand and lookout Mountains, Georgia and Alabama--continued. SaJI1)1e nunber Mo-S (ppm) Nb-S (ppm) Nd-S (ppm) Ni-S (ppm) Pb (pplll) Rb (pp-m) Sc (ppm) Sm (pplll) Sn-S (ppm) Sr-S (ppm) SaJ11>le nuri>er w199979 12 w209677 6.0 '29 46l 2,100 110 47 lOl 760l 14 34 60 27 11 13 w209680 4.5 13 100 88 45 200 27 13 H H 8.3 1,100 4.4 560 w199979 w209677 w209680 1-" ~ -J -f Table Be. Sample number Hajor- and minor-oxides and trace-element concentrations in the labor at orx ash of three bituminous coal samples __________________ - - from coal bed No. 9A, Sand and Lookout Mountains, Georgia and Alabama--conti nued. Ta Tb Th u v-s H-S Y-S Yb (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) -------- Zn Zr-S Sample (ppm) (ppm,) number w199979 w209677 w209680 0.20L .49 .67 6.5L 1.8 2.0 7.6 20 22 1.7 110 7.0 260 10 220 8 54 1.2 50 .9 36 4.3 2,300 98 w199979 6.4 41 220 w209677 6.0 87 130 w209680 ..... CJ,:) 00 Table 8d. Content of 22 trace-elements in three bituminous coal samples from coal bed No. 9A, Sand and Lookout Mountains, Georgia and Alabama. (Analysis performed on whole-coal. Valu-es in parts-per-mtllion(ppm). L, less than the value shown-; --B-, not determined). Sample As Ce Cl Co Cr Cs Eu F Hf Hg Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199979 5.4 10 410 w209677 7.1 42 250 w209680 25.8 52 470 21 7.2 0.3 0.21 20l 3.3 42 2.3 .70 100 5.4 53 6.4 . 97 190 0.3 0.55 w199979 1.6 .28 w209677 1.5 .13 w209680 ""c"""o" Table 8d. Content of 22 trace-elements in three bituminous coal samples from coal bed No. 9A, Sand and lookout Mountains, Georgia and Alabama--continued. Sample number La (ppm) lu (ppm) Na (ppm) p Rb (ppm) - (ppm) Sb (ppm) Sc (ppm) Se (ppm) Sm (ppm) Tb (ppm) Sample number w199979 7 w209677 29 w209680 33 0.1 50 800 70l 0.40 1.3 2.9 1.0 0.6l w199979 .2 370 160 16 .40 7.2 4.7 3.6 .5 w209677 .3 370 57 611 1.6 8.9 2.7 4.4 .7 w209680 1-' ~ 0 Table Sd. Content of 22 trace~elements in three bituminous coal samples from coal bed No. 9A, Sand and lookout Mountains, Georgia and Alabama--continued. Sample n~r Th (ppm) u Yb (ppm) ---(pp-m) w199979 0.7 w209677 5.3 w2096SO 7.2 0.16 0.4 1.9 1.7 3.4 2.0 ....... ~ ....... Table Be. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from coal bed No. 9A, Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinations on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine me thod; B, not determined; G, greater than. Sample number is laboratory nu-m-be-r-).-------------------------------------------------------------- Sample Si Al Ca Hg Na k Fe Ti Ag-S As Sample nunber (-pe-rc-en-t)- -(p-er-c--en-t-)---(-p-er-cent) (perce-nt) (percent) (perce-nt) (percent) (percent) (ppm) (ppm) number w199979 W209677 w209680 0 . !56 6.9 8.3 0.!53 4.!5 !5.8 0.21 .09!5 0.11 .059 0.01)!; .037 0.046 .30 3..s4a .050 .18 .037 1.2 .94 0.018 .22 .22 0.019 .080 .033L !5.4 7.1 26 w199979 w209677 w209680 .....,.... t-:) Table Be. ------ Sample FlUltJer Major-, minor-, and trace-el~t concentrations, on whole-coal basis, of three bituminous coal samples from - coal bed No. 9A, Sand and Looko-u-t--Mountains, Georgia-a-nd Alabama--continued. - 8-S Ba-S Be-S Br Cd Ce Cl Co Cr Cs (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) ----- Sample I"UUt!er w199979 5.6 140 w209677 45 140 w209680 70 190 1 30 2 11 2 39 0.51 10 410 .04 42 250 .05 52 470 21 7.2 3.3 42 5.4 53 0.3 w199979 2.3 w209677 6.4 w209680 ...... .;:.. Co -{ Table 8e. Sjo'- ond mi""-''''"' '"' t'ooo-ol...,t "'"'""''''''"' lo tho loborotoj, h of ''"' bituol"'"' oool ,..,,., --- from coal bed No-. 9-, -Sa-nd-an-d lookout Mountains, Georgia and Alabama--c ntinued. -- ---- La li lu Hn Ho-S Nb-S Nd-S Ni-S Pb Pr-S Sample (ppm) (ppm) (ppm-) -- (ppm) (ppm) - (ppm) (p-pm) (ppm) (ppm) (ppm) number w199977 130 360 w199980 120 200 w199982 170 190 w212568 81 170 1.5 100 1.5 180 2.5 250 1.3 74 15 35 130 250 100 68l w199977 3.0 32 140 310 64 68L w199980 29 23 130 670 120 150L w199982 1.5 17 65 170 40 83 w212568 ..... 01 0') Table 9c. Sample number Major- and minor-oxides and trace-element concentrations in the laboratory ash of four bituminous coal samples - from coal bed No. 9, Sand and lookout Mountains, Georgia and Alabama--continued. -- - - - - - - Rb Sc Sm Sn-S Sr-S Ta Tb Th Tl-S u Sample (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199977 810l 31 18 w199980 690l 33 16 wl99982 2,500l 58 29 w212568 210 37 15 l.Sl 4,000 8.0 4,000 1.5l 5,400 2.3 660 0.17 2.5 24 .25 1.9 31 .20l 4.6 17 .19 3.5 30 6.3 3.9 w199977 3.2l 5.2 w199980 3.0L 7.1 w199982 4.6L 8.5 w212568 ....... CJ1 -J \; Table 9c. -- Sa""le number Major- and minor-oxides and trace-element concentrations in the laboratorr ash of four bituminous coal samples -from coal bed No. 9, Sand and lookout Mountains, Georgia and Alabama--cont inued. v-s H-S Y-S Yb Zn Zr-S Sample (p-pm-)- - (ppm) (ppm) (ppm) (ppm) (ppm) number w199977 200 w199980 240 w199982 140 w212568 170 8 110 8 100 8 180 1.2 47 8.1 81 430 w199977 8.6 160 370 w199980 21 340 310 w199982 9.3 210 130 w212568 ~ 01 00 Table 9d. Content of 22 trace-elements in four bituminous coal samples from coal bed No. 9, Sand and Lookout Mountains, Georgia and Alabama. (Analysis performed on whole-coal. Values in parts-per-million(ppm-). L, less than the value show--n; B, not determined). Sample As Ce Cl Co Cr Cs Eu F Hf Hg Sample number (p-pm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199977 21.3 24 820 16 22 1.1 0.41 60 0.8 0.85 w199977 w199980 1.3 22 340 16 21 1.6 .40 38 1.0 .010L w199980 w199982 2.4 7.0 1,600 15 4.0 .1 .14 20L .1 .010 w199982 w212568 2.6 14 660 11 13 1.8 .31 80 .6 .065 w212568 1-' 01 c.o Table 9d. S:> Table 9e. Sample -n~r Major-, minor~, and trace-element concentrations, on whole-coal basis, of four bituminous coal samples from coal bed- No. 9, Sand and lookout Mountains, Georgia and Alabama--c-ontinued. 8-S Ba-S Be-S Br Cd Ce Cl Co Cr Cs (ppm) (ppm) (ppm-) ----(ppm) (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) w199977 11 59 w199980 11 100 w199982 3.6 29 w212568 11 37 2 56 2 53 1 64 3 44 0.03 24 820 16 22 1.1 .12 22 340 16 21 1.6 .01 7.0 1,600 15 4.0 .1 .07 14 660 11 13 1.8 Sample ~r w199977 w199980 w199982 w212568 1-' 0') c,., Table 9e . Sample n~Dber Major-, minor-, and trace-element concentrations, on whole-coal basis, of f our bituminous coal samples from coal bed No. 9, Sand and lookout Mountains, Georgia and Alabama--continued . Cu (ppm) Dy-S (ppm) Er-S (ppm) Eu (ppm) F (ppm) Ga-S (ppm) Gel-S (ppm) Ge-S (ppm) Hf (ppm) Hg (ppm) Sample nurber w199977 11 w199980 15 w199982 9.1 w212568 12 2.4L 1.1l 0.41 60 2.6L 1.5 .40 38 .8 .4 .14 20L 1.9L .9l . 31 80 4.6 2.2 3.7 0.8 0.85 w199977 4.8 2. 3 .57 1.0 .OlOL w199980 1.1 . 82 1.7 .1 . 010 w199982 3.2 1.3l 6.2 .6 .065 w212!i68 ...... 0') *"" Table 9e. --- Sample number Major-, minor-, and trace-element concentrations, on whole-coal basis, of four bituminous coal samples from coal bed No. 9, Sand and-lookout Mountains, Georgia and Alabama--continued. Ho-S La li lu Mn Mo-S Nb-S Nd-S Ni-S p (ppm) (ppm) (pp-m) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) w1<)<)977 w199980 wl99982 w212568 0.75l 14 . 79l 14 .22 4 .58l 7 40 0.2 11 1.7 3.9 14 28 380 23 .2 21 . 35 3.7 16 36 410 4.6 .1 6.0 .70 .55 3.1 16 13 15 .1 6.4 .13 1.5 5.6 15 44l Sample nurber w199977 wl<)<)980 w1<)<)982 w212568 ~ m C1l -, - - Table 9e. Sample n!Pber Major-, minor-, and trace-element concentrations, on whole-coal basis, oflfour bituminous coal samples from ------ coal bed No. 9, Sand and lookout Mountains, Georgia and Alaba-m-a---co-nt-in-u Pb Pr-S Rb Sb Sc Se Sm Sn-S Sr-S Ta-S (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) w199977 w199980 w199982 w212568 11 7.4 2.9 3.4 7.5l 90l 7.'Jl SOL 3.6l 60l 7.1 18 1.0 3.5 3.4 2.0 0.17l 440 .30 3.9 3.0 l.'J .93 460 .50 1.4 1.6 .70 .04l 130 2.0l 3.2 1.4 1.3 .20 57 0.02 .03 .OOl .02 Sample n!P-be-r - - w199977 w199980 w199982 w212568 ~ 0) 0) Table 9e. Sample nuroer Major-, minor-, and trace-element concentrations, on whole-coal basis, of four bituminous coal samples from - - - - - - - coal Tb bed No . 9, Th Sand and lookout Tl-S Mountains, u Georgia v-s and Alabama--con-tinued. H-S Y-S Yb - Zn Zr-S (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) w199977 0.28 2.7 0.70 0.43 22 w199980 .22 3.6 .37l . 60 28 w199982 .11 .40 .07l .17 3.4 w212S68 .30 2.6 .40l .73 IS B 12 B 12 B 4.3 .10 4.0 0.9 9.0 48 1...as0 19 8.2 18 43 7. 4 11 Sample l"-ll.l-lbl-r- - w19CJ977 wl'JCJ980 w199982 w212S68 ...... (J} -.:] Table 9f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for four bituminous coal samples from coal bed No. 9, SaOd and lookout Mountains, Georgia and Alabama. (All analyses except Kcal/kg, Btu, free-swelling index, and ash-fusion temperatures In percent. For each sample number, the analyses are reported three ways; first, as-received, second, moisture-free, and third, moisture- and ash-free. All analyses by Coal Analysis Section, Department of Energy, Pittsburgh, Pa.; 8, not determined; 1540 for ash-fusion temperatures means greater than 1540--C-).-------------------------- Proximate Analysis Ultimate Analysis Heat of Combustion Sample number Volatile Fixed Moisture matter carbon Ash Hydrogen Carbon Nitrogen Oxygen Sulfur Kcal/kg Btu/lb w199977 w199980 w199982 w212568 1.5 23.9 63 . 9 10.7 24.3 64.9 10.9 27.2 72.8 6.2 22.8 59.3 11.7 24.3 63.2 12.5 27.8 72.2 1.5 28.0 68.0 2.5 28.4 69.0 2.5 29.2 70.8 1.9 23.4 66.2 8.6 23.8 67 . 4 8.7 26.1 73.9 4.6 76.7 4.5 77.9 5.0 87.4 4.1 65.9 3.6 70.3 4.2 80.3 5.1 84.5 5.0 85.8 5.1 88.0 4.7 79.1 4.6 80.6 5.0 88.3 1' .4 5.7 1.4 4.4 1.6 5.0 1.3 16.6 i.4 11.8 i.6 13. 5 1.6 5.8 1.6 4.5 1.7 4.7 1.4 5.5 1.4 3.9 1.6 4.3 0.9 7,480 13,470 .9 7,600 13,680 1.0 8,520 15,340 .5 6,190 11,150 .5 6,600 11,880 .6 7,540 13,580 .5 8,310 14,970 .5 8,440 15,190 .5 8,660 15,590 .1 7,680 13,820 .1 7,820 14,080 .8 8,570 15,430 to-" 0') 00 Table 9f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for four bituminous coal samples from coal bed No. 9, Sand and Lookout Mountains, - Georgia and Alabama--continued. - Forms of sulfur Ash fusion temperature, C Sample number Air-dried loss Sulfate Pyritic Free Organic swelling index Initial deformation Softening - Fluid wl99977 wl99980 w199982 w212568 0.7 0.01 0.67 0.25 9.0 .01 .68 .25 .01 .76 .28 3.3 .01 .04 .45 .0 .01 .04 .48 .01 .05 .55 .6 .01 .05 .45 9.0 .01 .05 .46 .01 .05 .47 .3 .06 .15 .50 7.5 .06 .15 .51 .07 .17 .56 1,495 1,540 1,255 1,460 1,540 1,540 1,300 1,510 1,540 1,540 1,355 1,530 I-' 0) c.P Table lOa. Descriptive information for sample numbers, geographic location, and forlation and coal bed correlations for three bituminous coal samples from coal bed No. 8, Sand and lookout Mountains, Georgia and Alabama. sample state county latitud longitud formation coal bed rank no. w199978 georgia dade 345804n 853116w gizzard no 8 bit wl99981 georgia dade 345655n 853047w gizzard no 8 bit w209678 georgia dade 345639n 853533w gizzard no 8 bit sample type composite channel channel sampled thickness (inches) 20.0 18.0 30.0 t-' -l 0 Table lOb. Summary statistical table of analytical data for three bituminous coal samples from coal bed No. 8, Sand and Lookout Mountains, Georgia and ~labama. Zero and qualified values excluded; ash-fusion temperatures in degrees F. data values item used mean ---- -st-d--d-e-v -xm-in -xm-ax - - range -geo-me-an geo dev Si!JII'l zero qual usgsash 3 10.87 4.95 6.600 statistics for following data items on ash basis 17.80 11.20 9.88 1.53 6.06 0 0 sio2 3 a12o3 3 cao 3 mgo 3 na2o 3 k2o 3 fe2o3 3 rnno 3 tio2 3 p2o5 3 so3 3 26.35 15.52 1.90 0.61 O.l't 1.21 48.17 0.02 0.72 0.38 3.02 18.76 10.65 0.94 0.24 0.05 1.18 29.07 0.00 0.44 0.34 1.62 11.900 7.300 0..20 0.365 0.073 0.210 7.090 0.010 0.300 0.040 0.850 52.84 30.56 2.85 0.95 0.18 2.86 70.06 0.02 1.32 0.85 4. 74 40.94 23.26 2.23 0.58 0.10 2 . 65 62.97 0.01 1.02 0.81 3.89 20.80 12.47 1.58 0.57 0.13 0.70 32.22 0.02 0.59 0.20 2.41 1.94 1.89 1.95 1.48 1.49 2.94 2.92 1.39 1.84 3.50 2.11 22.97 13.04 1.15 0.30 0.06 1.44 35.60 0.01 0.54 0.42 1.98 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 statistics for following data items on "whole-coal" basis ag 3 0.05 0.01 0.040 as 3 73.60 37.70 22.400 there were less than two positive-valued items for au b 3 12.62 13.77 1.650 ba 3 68.65 22.16 40.260 be 3 1. 78 0.31 1.386 there were less than two positive-valued items for bi br 3 5.32 2.07 3.608 cd 3 0.04 0.02 0.020 ce 3 18.00 8.83 6.000 cl 3 1126.67 271.95 860.000 co 3 9.60 2.81 7.000 cr 3 11.97 9.95 3.300 there were less than two positive-valued items for cs cu 3 10.31 2.45 7.216 there were less than two positive-valued items for dy there were less than two positive-valued items for er eu 3 0.31 0.13 0.130 there were less than two positive-valued items for f ga 3 3.75 2.13 2.178 there were less than two positive-valued items for gd ge 3 3.52 1.82 0.997 hf 3 0.43 0.34 0.100 hg 3 0.42 0.18 0.210 there were less than two positive-valued items for ho there were less than two positive-valued items for in there were less than two positive-valued items for ir la 3 9.67 4.99 3.000 1i 3 23.19 25.14 4.686 lu 3 0.11 0.04 0.080 rnn 3 11.67 1.61 10.502 mo 2 0.95 0.36 0.587 nb 3 2.92 2.72 0.858 nd 2 13.40 6 . 18 7.216 0.05 112.10 32.04 94.34 2.14 8.24 0.06 27 . 00 1500.00 13.50 25.90 13.20 0.41 6.76 5.21 0.90 0.65 15.00 58.74 0.16 13.94 1.31 6.76 19.58 0.01 89.70 30.39 54.08 0.75 4.63 0.04 21.00 640.00 6.50 22.60 5.98 0.28 4.59 4.22 0.80 0.44 12.00 54 . 05 0.08 3 . 44 0 . 72 5.91 12 . 36 0.05 60.06 6.05 64.71 1. 75 4.97 0.03 15.04 1095.80 9.22 8.30 10.00 0.28 3.23 2.83 0.30 0.38 7.91 11.92 0.10 11.56 0.88 1.88 11.89 1.13 2.03 3.45 1.43 1.19 1.44 1.56 1.93 1.26 1.32 2.35 1.28 1.71 1.69 2.10 2.45 1.59 2.01 3.11 1.35 1.14 1.49 2.49 1.65 0.01 46.18 16.86 27.14 0.38 2.54 0.02 10.82 333.07 3.44 12.19 3.00 0.16 2.61 2.23 0.42 0.22 6.11 30.79 0.04 1.97 0.51 3.33 8.74 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 1 ,.... -,...l. \ j I Table lOb. Summary statistical table of analytical data for three bituminous coal sJmples from coal bed No. 8, Sand and lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ashlfusion temperatures in degrees F--continued. ni 3 16.30 6.76 6.888 22.44 15.55 14.46 1.69 8.28 0 0 there were less than two positive-valued items for os pb 3 19.68 10.53 9.968 34.32 24.35 17.16 1.68 12.90 0 0 there were less than two positive-valued items for pd there were less than two positive-valued items for pr there were less than two positive-valued items for pt there were less than two positive-valued items for rb there were less than two positive-val~ed items for re there were less than two positive-valued items for rh there were less than two positive-valued items for ru sb 3 0.77 0.21 0.500 1.00 0.50 o. 74 1.33 0.25 0 0 sc 3 2.49 1.48 1.390 4.58 3.19 2.12 1.72 1.81 0 0 se 3 3.07 0.67 2.160 sm 3 1.53 0.66 0.600 there were less than two positive-valued items for sn 3.74 2.00 1.58 1.40 J 2.99 1.34 1.26 1. 76 0.82 0.81 0 0 0 0 sr 3 338.80 108.40 257.400 492.00 234.60 23.37 1.35 132.76 0 0 there were less than two positive-valued items for ta tb 3 0.23 0.07 0.140 0.30 0.16 0.22 1.38 0.08 0 0 there were less than two positive-valued items for te th 3 1.60 1.16 0.500 3.20 2.70 1. 21 2.14 1.42 0 0 there were less than two positive-valued items for tl there were less than two positive-valued items for tm u v 3 0.48 0.36 0.160 0.99 0.83 3 13.86 14.14 2.838 33.82 30.98 0.36 7.79 2.14 2.89 0.45 17.32 0 0 0 0 there were less than two positive-valued items for w y 3 7.53 3.25 4.818 12.10 7.29 6.91 1.49 3.99 0 0 yb 3 0.70 0.33 0.300 1.10 0.80 0.61 1.71 0.40 0 0 zn 3 10.31 2.98 6.560 13.86 7.30 9.85 1.36 3.65 0 0 zr 3 29.17 29.75 6.468 71.20 64.73 16.55 2.85 36.44 0 0 statistics for following data items on "as received" basis data values item used m-e-a-n -std-d-ev -xm-in -xm-ax btu ashdef ashsof ashfld freswel moistur volmat fixedc bmash hydrogn carbon ni trogn oxygen sulfur sulfate sulfpyr sul forg ad loss 3 13449.00 902.77 12192.000 14271.00 3 2383.33 300.92 2100.000 2800.00 3 2446.67 254.60 2210.000 2800.00 3 2520.00 206.07 2310.000 2800.00 3 6.67 3.30 2.000 9.00 3 1.63 0.33 1.400 2.10 3 26.43 0.87 25.200 27.10 3 62.00 4.10 56.300 65.80 3 9.93 4.63 5.800 16.40 3 4.60 0.16 4.400 4.80 3 71t.47 4.04 69.500 79.40 3 1.43 0.05 1.400 1.50 3 6.80 0.88 5.600 7.70 3 2.73 1.69 0.500 4.60 has insufficent variance to calculate statistics 3 2.31 1.63 0.110 4.02 3 0.45 0.12 0.320 0.61 3 0.80 0.22 0.600 1.10 -ran-ge 2079.00 700.00 590.00 490.00 7.00 0.70 1.90 9.50 10.60 0.40 9.90 0.10 2.10 4.10 3.91 0.29 0.50 I ~eo mean 13J:~~::-- 2365.12 2~33.90 2511.76 5.45 1.60 26.42 61.86 8.97 4.60 74.36 1.43 6.74 1.92 1.07 0.43 0.77 geo dev 1.07 1.13 1.11 1.08 2.03 1.21 1.03 1.07 1.55 1.04 1.06 1.03 1.14 2.63 5.04 1.30 1.29 sigma 1105.66 368.56 311.82 252.39 4.04 0.40 1.07 5.03 5.67 0.20 4.95 0.06 1.08 2.07 2.00 0.15 0.26 zero qual 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ....... -J 1.\:) Table 10c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituminous coal samples from coal bed No. 8, Sand and lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. l means less than the value shown; H, interference for an element which cannot be resolved by any routine method; G, greater than; B, not determined; S, after element title Indicates - determinations are to be take-n as plus 50% an-d minus 35%. Sample number is laboratory number). Sample Ash Si02 Al203 CaD MgO Na20 K20 Fe203 Ti02 P205 Sample number (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (perc-en-t)- -(-percent) n~r wl99978 6.6 14 w199981 8.2 12 w209678 17.8 53 7.3 2.2 0.53 0.07 0.56 70 0.30 0.05 w199978 8.7 2.9 .36 .16 .21 67 .53 .85 w199981 31 .62 .95 .18 2.9 7.1 1.3 .24 w209678 !-' -J ~ tra~e-element laboratory~ Table lOc. Major- and minor-oxides and concentrations tn the ash of three bituminous coal samples - - - ---- from coal bed No. 8, Sand-a-nd-L-o-ok-ou-t Mountains, Georgia and Alabama--continued Sample S03 Ag-S 8-S Ba-S Be-S Br Cd Ce Co Cr Sar11>le -nu-m-be-r -- (percent) (ppm) (ppm) (ppm) (ppm) ----(p-p-m--)- - -(-pp-m )----(-pp-m)-- (ppm) (ppm) number wl99978 3.5 0.60 25 610 w199981 4.7 .65 51 870 w209678 .85 .26 180 530 21 950 22 540 12 260 0 . 87 91 200 50 w199978 .35 260 85 82 w199981 . 11 150 47 150 w209678 ...... -...,J. Table 10c. Major- and minor-oxides and trace-elenent concentrations in the laboratory ash of three bituminous coal samples from coal bed No. 8, Sand and lookout Mountains, Georgia and-Alabama--continued Sample Cs Cu Eu Ga-S Gd-S Ge-S Hf La li lu Sample nuliler (pp-m) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (pprl) (ppm) (ppm) number w199978 30l 200 w199981 24l 88 w209678 15 59 2.0 33 5.0 28 2.2 38 6.8l 79 1.5 45 71 25 53 3.7 130 75 46l 5.6 5.1 84 330 1.2 wl99978 1.1 w199981 .9 w209678 ~ -l 01 '"'"'"' l' Table 10c. - MfroomJoc-ooanl dbmedlnNoo.-o8,ldSanodnadndLoo-kooult'"M""o-'u'n"ta"in's", 'G'"e'o'r"g-i'a' '"andthAolabama--co tinuhedof thoo bltuolno"' .,., ''"''"' Sa.Jl1lle Hn Ho-S Nb-S Nd-S Ni-S Pb Rb Sc Sm Sn-S Sa.Jl1lle number (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) n~Jliler wl99978 160 w199981 170 w209678 59 6.8L 13 46L 340 520 1,200L 23 16 14 88 84 180 980L 17 3.3 38 110 110 56 150 26 9. 1 24 11 H w199978 H wl99981 4.9 w209678 f-' -.:] ~ ... .. Table 10c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituninous coal Sllq)les from coal bed No. 8, Sand and lookout Mountains, Georgia and Alabama--continued Sample nunber Sr-S (ppm) Ta (ppm) Tb (ppm) Th (ppm) u (ppm) v-s (ppm) H-S (ppm) v-s (ppm) Vb (ppm) Zn (ppm) Sllq)le I'Uiiler w199978 3,900 w199981 6,000 w209678 1,500 0.20l 2.1 7.6 .20l 3.0 13 .33 1.7 18 2.4 43 3.5 60 5.6 190 8 73 8 69 1.0 68 4.5 210 8.5 80 6.2 59 w199978 w199981 w209678 .... ..;J ..;J Table lOc. Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituminous coal samples from coal bed No. 8, Sand and Lookout -- Hountal-n-s-, --G-e-o-rg-i-a-a-n-d--A-l-ab-a-m-a-----co-n-t-in-u-e-d----------------------------------- Sample Zr-S number (ppm) wl99978 98 wl99981 120 w209678 400 t-' -l 00 Table 10d. Content of 22 trace-elements in three bituminous coal samples from coal bed No. a, Sand and Lookout Mountains, Georgia and Alabama. - - - - ----- (Analysis performed on whole-coal. Values in parts-per-million(ppm). L, less than the value shown; 8, no-t determined). Sample number As (ppm) Ce (ppm) Cl (ppm) Co (ppm) Cr (ppm) Cs (ppm) Eu (ppm) F (ppm) Hf (ppm) Hg (ppm) ~~ wl99978 w199981 w209678 86.3 112 22.4 6.0 1,500 21 1,000 27 860 14 3.3 7.0 6.7 8.3 26 2.0L 0.13 20L 2.0L .41 20L 2.6 .40 90 0.1 0.65 w199978 .3 .41 w199981 .9 .21 w209678 ...... -.J ~ ---, Table 10d. Content of 22 trace-elements in three bituminous coal samples from coal bed No. 8, Sand and Lookout Mountains, - Georgia an-d Alabama--continued Sample La Lu Na p Rb Sb Sc Se Sm Tb Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) numer w199978 3 w1999S1 11 w20967S 15 0.1 36 13 .1 9S 310 .2 230 190 SOL SOL 27 1..s0o .so 1.5 1.4 4.6 3.7 3.3 2.2 0.60 2.0 2.0 0.1 w19997S .3 w1999S1 .3 w20967S .... 00 0 Table lOd. Content of 22 trace-elements in three bituminous coal samples from coal bed No. 8, Sand and Lookout Mountains, Georgia and Alabama--continued Sample n~r Th (ppm) u (ppm) Yb (ppm) wl99978 0.5 wl99981 1.1 w209678 3.2 0.16 0.3 .29 .7 .99 1.1 ..... 0...0.. Table lOe. Hajor-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from coal bed No. 8, Sand and lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinations on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine mathod; 8, not determined; G, greater than. Sample number fs laboratory number). - Sample Sf Al Ca Hg Na K Fe Ti Ag-S As Sample number - (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (ppm) (ppm) IIU!tler w199978 w199981 w209678 0.44 .46 4.4 0.25 .38 2.9 0.10 0.021 0.004 0.031 3.2 .17 .018 .010 .014 3.9 .079 .10 .023 .42 . 88 0.012 .026 .14 0.040 86 .053 110 .046 22 w199978 w199981 w209678 I-' 00 1:-:> Table 10e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from coal bed -N-o. B, Sand and L-ookout Mountains, Georgia and Alabama----c-o-ntinued Sample B-S Ba-S Be-S Br Cd Ce Cl Co Cr Cs Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) (ppm) number w199978 1.7 40 w199981 4.2 71 w20967B 32 94 1 62 2 44 2 46 0.06 6.0 1,SOO .03 21 1,000 .02 27 860 14 3.3 7.0 6.7 8.3 26 2.0L w199978 2.0L w199981 2.6 w209678 1-' c0o0 Table lOe. Major-, minor-, and trace-element concentrations, on whole-coal basi s, of three bituminous coal samples from coal bed No. 8, Sand and Lookout Mountains, Georgia and Alabama--continued Sample number Cu {ppm) Eu {ppm) F {ppm) Ga-S (ppm) Gd-S {ppm) Ge-S (ppm) Hf (ppm) Hg {ppm) La (ppm) L1 (ppm) Sample f'llmt)er w1CJCJ978 13 w1CJCJ981 7.2 w209678 11 0.13 20L .41 20L .40 90 2.2 0.45L 5.2 0.1 0.65 3 2.3 2.1 4.3 .3 .41 11 6.8 8.2L 1.0 .9 .21 15 4. 7 w1CJCJCJ78 6.2 wl'JCJ'JBl 59 w209678 ~ 00 ,j::.. Table 10e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from coal bed No. 8, Sand and lookout Mountai-ns, Georgia and Alabama-continued Sa~le lu Mn Mo-S Nb-S Nd-S Ni-S p Pb Rb Sb Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (p-pm) (ppm) (ppm) (ppm) -(ppm) numer w199978 0.1 11 w199981 .1 14 w209678 .2 11 o.~5L 0.86 3.0l 22 13 3~ SOL 1.0 w199978 1.3 1.1 7.2 6.9 310 15 SOL .80 w199981 .59 6.8 20 20 190 10 27 .50 w209678 ....... 00 C11 ~- ,f,,. Table lOe. cMoaajlo,b-e, d"'N"oo. r8-,, 'S"an'd,,a.n,d._Lo.o,.k,o.u"t 'M'"ou"n't"ai'n''s", 'G''"eo'rgioana.nd..A1.l-aoboaoml a'-"co''n'tinuoefd bttuot"'"' eoal ,..,,., '''" Sa""le nlnber Sc (ppm) Se (ppm) Sm (ppm) Sn-S (ppm) Sr-S (ppm) Ta-S (ppm) Tb (ppm) Th (ppm) u (ppm) v-s (ppm) S~le number wl99'178 1.5 3.7 0.60 H 260 w199981 1.4 3.3 2.0 H 490 w209678 4.6 2. 2 2.0 .87 270 O.Oll 0.14 .02L .25 .06 .30 0.50 1.1 3.2 0 . 16 2.8 w199978 . 29 4.9 w199981 . 99 34 w209678 ..... 00 er is laboratory l'lU!i>er). Sample number Ash SID2 Al2D3 CaD HgD Na2D K2D Fe2D3 TID2 P205 Sample (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) number w215453 3.4 23 13 4.1 0.63 0.35 1.3 45 0.67 0. 65 w215453 ..... .t.O... Table llb. Major- and minor-oxides and trace-element concentrations in the 'laboratory ash of one bituminous coal sample from coal bed-No. 6, Sand and lookout Mountains, Georgia and Alabama--continu-ed Sample SD3 Ag--S 8-S Ba-S Be-S Br Cd Ce Co Cr Sample number - (percent) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (pp-m- ) (ppm) (ppm) number w215453 6.1 1.2 110 630 44 1,700 0.60 120 100 190 w215453 1--' (J:) ~ Table llb. Major- and minor-oxides and trace-element concentrations in the laboratory ash of one bituminous coal sample --------from coal bed No. 6, Sand and lookout Mountains, Georgia and Alabama--continued San.,le Cs Cu Eu Ga-S Ge-S Hf La li Lu Mn Sample n~r ( ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) ~r w215453 2.9 300 3.8 48 10 5.9 59 45 2.4 4,900 w215453 ..... co ~ ---.- Table Ub. Major- and minor-oxides and trace-element concentrations i.n the laboratory ash of one bit~tnous coal SaJI1)le from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama--continued SaJI1)le Mo-S n~r (ppm) ----- Nb-S (ppm) Ni-S (ppm) Pb (ppm) Sc (ppm) Sm (ppm) Sr-S (ppm) Tb (ppm) Th (ppm) v-s (ppm) Sall1)le ~r w215453 96 13 220 41 39 15 2,400 3.8 15 120 w215453 ..... c.o ,j:o. Table llb. Major- and minor-oxides and trace-element concentrations in the laboratory ash of one bituminous coal saq>le from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama--continued Saq>le Y-S Yb Zn mnber (ppm) (ppm) (ppm) --------~------~----- Zr-S (ppm) w215453 79 15 'a 160 ,_. co C11 Table 11c. Content of 22 trace-elements in one bituminous coal sample from coal bedJNo. 6, Sand and Lookout Mountains, Georgia and Alabama. (Analysis performed on whole-coal. Values in parts-per-million(ppm). L, less than he value shown; B, not determined). Sample number As (ppm) Ce - (ppm) Cl (ppm) Co (ppm) Cr (ppm) Cs (ppm) Eu (ppm) - F (ppm) Hf (ppm) Hg (ppm) San.,le number w21S453 19.4 4.0 1,300 3.4 6.3 0.1 0.13 60 0.2 0.25 w2154S3 .... co 0) Table llc. Content of 22 trace-elements , fn one bftunlnous coal sa~le from coal bed No. 6, Sand and Lookout Mountains, Georgfa and Alabama--continued SaJ!1)le llU!tJer La (ppm) Lu (ppm) Na (ppm) p (ppm) Sb (ppm) Sc (ppm) Se (ppm) Sm (ppm) Tb (ppm) Th (ppm) Saq>le numer w215453 2 0.1 88 96 0.50 1.3 2.4 0.50 0.1 0.5 w21545'3 ..... co ....:J Table llc. Content of 22 trace-elements in one bituminous coal sample from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama---con-tin-ue-d - --- Sample Yb nurber (ppm) w215453 0.5 ...... ~ 00 Table lld. Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinations on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine method; B, not determined; G, greater than. Sample number is laboratory number). Sample number Si Al Ca Hg Na K Fe Tt Ag-S As ~le --------------------------- (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (ppm) (ppm) nllllber w215453 0.36 0.23 0.099 0.013 0.009 0.037 1.1 0.014 0.041 19 w215453 ...... ~ ~ v -- , -- ~ Table lld. Major-, minor-, and trace-element concentrations, on whole-coal basts, of one bituminous coal sa~le from -coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama-continued Sall1lle 8-S Ba-S Be-S Br Cd Ce Cl Co Cr Cs number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) lppm) (ppm) ( ppm) Sall1lle number w2154S3 3.7 21 1 59 0.02 4.0 1,300 3.4 6.3 0.1 w21S4S3 !!.:> 0 0 Table lld. Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from coal bed No. 6, Sand and lookout Mountains, --G-eo-rgia and Alabama--continued -- Sample Cu Eu F Ga-S Ge-S Hf Hg La u lu nurber (ppm) (ppm) (ppm) (pp!'ll) (ppm) (ppm) ( ppm) (ppm) (ppm) (ppm) w215453 10 0.13 60 1.6 0.34 0.2 0.25 2 1.5 0.1 Sample number w215453 !:.,:) .0.... Table lld. Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama--continued Sa""le nlnber Hn (ppm) Ho-S (ppm) Nb-S (ppm) Ni-S (ppm) p (ppm) Pb (ppm") Sb (ppm) Sc (ppm) Se (ppm) Sm (ppm) Sample nlnber w215453 170 3.3 0.44 7.5 96 1.4 0.50 1.3 2.4 0.50 w215453 !:-,:) 0 !:-,:) Table ltd. Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from coal bed No. 6, Sand and lookout Mountains, Georgia and Alabama--continued Sample number Sr-S (pp!ll) Tb (ppm) Th (ppm) v-s (ppm) Y-S (ppn) Yb (ppm) Zn (ppm) Zr-S (ppm) Saq~le nurber w2154!i3 82 0.13 0.50 4.1 2.7 0.5 3.3 5.4 w215453 t-.:1 0 c:,., Table 11e. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swel li ng, and ash-fusion temperature determinations for one bituminous coal sample from coal bed No. 6, Sand and lookout Mountains, Georgia and Alabama--continued (All analyses except Kcal/kg, Btu, free- swelling, and ash-fusion temperatures in percent. For each sample number, the analyses are reported three ways: first, as-received, second, moisture-free, and th ird, moisture- and ash-free. All analyses by Coal Analysis Section, Department of Energy, Pittsburgh, Pa.; 8, not determi ned; 1540 for ash-fusion temperatures means greater than 1540 C). Proximate Analysis Ultimate Analysis Heat of Combustion Sample number Volatile Fixed Moisture matter carbon Ash Hydrogen Carbon Nitraien Oxygen Sulfur Kcal/kg Btu/lb w215453 I 2.7 21.1 72.5 3.7 4.5 83.5 1. ~ 5.4 1.3 8,080 14,540 21.6 74.5 22.5 77.5 -3.8 4.3 85.8 4.5 89.2 1. ~ 1. 7 3.1 3.2 1.3 8,300 14,940 1.3 8,630 15,530 0'-"' ,j::.. Table lle. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling, and ash-fusion temperature determinations for one bituminous coal sample from coal bed No. 6, Sand and Lookout Mountains, Georgia and Alabama--continued Forms of sulfur Ash 'usion temperature, C Sample nunber Air-dried loss Sulfate Pyritic Free Organic swelling index Initial deformation Softening Fluid w215453 1.7 0.09 0.76 0.40 8.0 .09 .78 . 41 .10 .81 .43 1,105 1,150 1,190 ~ 0 01 Table 12a. Descriptive information for sample numbers, geographic location, and forLtfon and coal bed correlations for seven bituminous coal samples from coal bed No. 5A, Sa~ and lookout Mountains, Georgia and Alabama. sa~le state county latitud longitud formation coal bed rank no. w199993 alabama de kalb 343234n 853249w crab orchard mts no 5a bit w199996 alabama cherokee 342848n 853208w crab orchard mts no 5a bit w199975 georgia walker 343546n 852917w crab orchard mts no 5a bit w199976 georgia dade 344054n 852911w crab orchard mts no 5a bft w199989 georgia chattooga 343137n 852932w crab orchard rnts no 5a bit sample type channel channel channel channel channel w212566 georgia w218691 georgia chattooga chattooga 343357n 852626w crab orchard mts no 5a 343437n 852803w crab orchard mts no 5a bit channel bit channel sa~ led thickness (Inches) 22.0 22 . 0 9.0 7.0 9.0 13.0 14.0 1.\:) 0 0') Table 12b. Summary statistical table of analytical data for seven bituminous coal samples from coal bed No. 5A, Sand and lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion temperatures in degrees F. data values item used -me-an -std-d-ev -xm-in -xm-a-x -ra-n-g--e -ge-o--m-e-a-n geo dev sigma zero qual usgsash 7 8.66 2. 70 4.900 12.90 8.00 8.22 1.39 2.91 0 0 statistics for following data items on ash basis sio2 7 a12o3 7 cao 7 mgo 7 na2o 7 k2o 7 fe2o3 7 mno 7 tio2 7 p2o5 7 sol 6 43.74 26.94 1.61 0.98 0.25 2.76 16.85 0.02 1.08 0.13 2.40 8.18 5.16 0.59 0.17 0.04 o. 74 11.89 0.01 0.17 0.07 0.63 27.450 17.360 0.670 0.680 0.175 1.300 6.270 0.003 0.760 0.070 1.070 53.11 34.92 2.21 1.16 0.31 3.53 43.60 0.04 1.28 0.27 2.94 25.66 17.56 1.54 0.48 0.13 2.23 37.33 0.04 0.52 0.20 1.87 42.85 26.40 1.48 0.96 0.25 2.63 13.86 0.02 1.07 0.12 2.28 1.23 1.23 1.55 1.21 1.19 1.39 1.81 2.27 1.18 1.64 1.42 8.84 5.57 0.64 0.18 0.04 0.80 12.84 0.01 0.18 0.08 0.69 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 statistics for following data items on "whole-coal" basis ag 7 0.06 0.02 0.031 as 7 30.71 34.40 3.000 there were less than two positive-valued items for au b 7 9.96 3.99 5.390 ba 7 48.41 41.49 10.191 be 7 2.29 0.98 1.485 there were less than two positive-valued Items for bi br 7 5.76 1.88 2.823 cd 7 0.08 0.04 0.022 ce 7 15.36 5.86 9.000 cl 6 1096.67 465.07 340.000 co 7 6.41 2.88 3.000 cr 7 13.32 5.19 7.200 cs 7 1.28 0.85 0.400 cu 7 19.47 4.67 11.270 dy 2 2.87 0.49 2.376 er 2 1.28 0.53 0.744 eu 7 0.31 0.13 0.200 f 5 36.20 13.57 21.000 ga 7 4.41 1. 79 1.764 gd 6 1.82 0.99 0.637 ge 6 2.26 1.06 0.744 hf 7 0.53 0.18 0.300 hg 7 0.22 0 . 17 0.020 there were less than two positive-valued items for ho there were less than two positive-valued items for in there were less than two positive-valued items for ir la 7 9.43 3.81 5.000 1i 7 17.94 7.93 6.860 lu 7 0.13 0.04 0.070 mn 7 13.68 5.80 3.354 mo 7 6.49 8. 05 2.046 nb 7 1.38 0 . 54 0.637 nd 7 9.15 3. 84 4.836 0.09 112.40 17.68 145.60 4.52 7.87 0.14 25.00 1830.00 11.60 22.00 3.00 27.72 3.35 1.81 0.51 60.00 7.10 3.61 3.66 0.80 0.55 15.00 29.29 0.21 20.80 25.74 2.18 15.48 0.06 109.40 12.29 135.41 3.03 5.05 0.11 16.00 1490.00 8.60 14.80 2.60 16.45 0.98 1.06 0.31 39.00 5.33 2.98 2.91 0.50 0.53 10.00 22.43 0.14 17.45 23 . 69 1.54 10.64 0.05 18.22 9.22 36.22 2.13 5.42 0.07 14.33 973.32 5.76 12.36 1.04 18.87 2.82 1.16 0.29 33.87 4.01 1.57 1.93 0.50 0.14 8.70 16.03 0.12 11.95 3.98 1.26 8.36 1.47 2.85 1.48 2.11 1.42 1.44 1.80 1.44 1. 70 1.60 1.47 1.90 1.29 1.19 1.56 1.46 1.44 1.57 1. 75 1.84 1.42 3.02 1.49 1.64 1.39 1.80 2.37 1.53 1.54 0.02 37.16 4.31 44.81 1.06 2.03 0.04 6.33 509.46 3.11 5.60 0.92 5.04 0.69 0.75 0.14 15.17 1.94 1.09 1.16 0.20 0.19 4.12 8.56 0.05 6.26 8.70 0.58 4.15 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 5 0 5 0 0 0 2 0 0 0 1 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 t-:1 0 -J I . Table 12b. Summary statistical table of analytical data for seven bituminous coal s~les from coal bed No. SA , Sand and lookout Mountains, Georgia and Alabama. Zero and qualified va l ues excluded; ash- f sion temperatures in degrees F--continued . ni 7 19.02 6.29 5.880 28.08 22.20 17.46 1.60 6.79 0 0 there were less than two positive-valued items for os I pb 7 6.00 2.33 2.542 9.16 6.62 5.48 1.56 2. 52 0 0 there were less than two positive-valued items for pd I pr 3 6.28 2.17 4.278 9.29 5.01 5.94 1.39 2. 65 0 4 there were less than two positive-valued items for pt I rb 2 15.50 5.50 10.000 21.00 11.00 14.49 1.45 7. 78 0 5 there were less than two positive-valued items for re there were less than two positive-valued items for rh there were less than two positive-valued items for ru sb 6 1.51 1.15 0 . 500 sc 7 3.34 1.40 1.430 se 7 1.83 0.37 1.250 sm 7 1.42 0.54 0.900 3.95 5.80 2.46 2.50 3.45 4.37 1.21 1.60 1. 19 3.04 1. 79 1. 34 1.92 1.56 1.22 1.40 1.26 1. 52 0.40 0.58 0 1 0 0 0 0 0 0 sn 2 0.22 0.01 0.208 0.22 0.01 0.21 1.03 0.01 0 5 sr 7 95.62 29.91 58.800 148.50 89.70 91. 08 1.37 32.31 0 0 ta tb 7 7 0.01 0.23 0.01 0.003 0.07 0.160 0.03 0.36 0.03 0.20 0.01 0.22 2.11 1.32 0.01 0 0 0. 07 0 0 there were less than two positive-valued items for te th 7 2.04 0 . 91 1.000 3.50 2.50 1. 84 1.56 0.99 0 0 tl 2 2.13 0.70 1.426 2.83 1.40 2.01 1.41 0.99 0 5 there were less than two positive-valued items for tm u 7 0.95 0.58 0.190 2.03 1.84 0.76 2.10 0.63 0 0 v 7 22.19 6.58 11.760 33.54 21.78 21.19 1.36 7 . 11 0 0 w 2 0.10 0.06 0.043 0.15 0.11 0.08 1.89 0.08 0 5 y 7 7.92 2.78 4.704 12.13 7.42 7. 45 1.41 3. 00 0 0 yb 7 0.84 0.37 0.600 1.70 1.10 0 . 79 1.42 0.40 0 0 zn 7 25.68 15.28 8.820 59.40 50.58 2i.93 1.75 16 . 51 0 0 zr 7 15.45 7.66 8.820 32.67 23.85 14.01 1.52 8. 28 0 0 statistics for following data items on "as received" basis data values item used btu 7 ashdef 6 ashsof 5 ashfld 4 freswel 6 moistur 7 volmat 7 fixedc 7 bmash 7 hydrogn 7 carbon 7 nitrogn 7 oxygen 7 sulfur 7 sulfate 7 sulfpyr 7 sulforg 7 ad loss 7 -me-an 13577.14 2255.00 2442.00 2455.00 6.50 2.54 21.80 68.17 7.50 4.35 78.07 1.41 7.57 1.11 0.03 0.59 0.48 1.26 -st-d -de-v 1154.91 568 . 29 211.41 168.89 3.11 2.25 0.11 3.39 2.43 0.23 4. 90 0.12 4.77 0.61 0.03 0.67 0.11 1.40 -xm-in 11197 .ooo 1080.000 2200.000 2280.000 1.000 1.100 21.600 62.780 5 . 300 4 . 000 68.!;QO 1.200 4.300 0.500 0.010 0.070 0.330 0.400 -xma-x 14530.00 2790.00 2750.00 2670.00 9.00 7.90 22.00 71.40 12.65 4.60 82.60 1.50 19.00 2.50 0.11 2.14 0.60 4.60 - - range 3333.00 1710.00 550.00 390.00 8.00 6.80 0.40 8.62 7.35 0.60 14.10 0.30 14.70 2.00 0.10 2.07 0.27 4.20 -g-e-o m-ean 13524.34 215~.93 2432.86 2449.21 ~-18 1.97 21.80 68.08 l 1. 374 7~.91 .40 6.64 0.99 0.02 Q.32 Q.47 0.85 geo dev s i !JII3 zero qual 1.09 1.38 1.09 1.07 2.24 1.89 1.01 1.05 1.33 1.06 1.07 1.09 1.59 1.60 2.30 3.11 1.26 2.16 1247.44 622 .54 236.37 195.02 3.41 2.43 0 . 12 3.66 2.62 0.25 5.29 0 . 13 5. 15 0. 66 0.04 0 . 72 0.11 1.51 0 0 0 1 0 2 0 3 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 tv 0 00 Table 12c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of seven bituminous coal samples from coal bed No. 5A, Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. L means less than the value shown; ~. interference for an element which cannot be resolved by any routine method; G, greater than; B, not determined; S, after element title indicates - determinations are to be taken as plus 50% and minus 35%. SaMple number is laboratory number). Sample Ash Si02 A1203 CaD MgD Ha2D K20 Fe203 Ti02 P205 Sample number - (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) number w199993 10.4 47 35 w199996 4.9 53 24 w199975 9.9 27 17 w199976 6.2 41 29 w199989 10.1 49 27 1.3 0.68 0.31 2.4 6.3 1.8 . 98 .23 3.3 11 2.2 . 78 .27 1.3 44 2.1 1.1 .18 3.1 15 .93 1.0 .24 3.5 10 1.2 0.19 w199993 1.1 .06 w199996 .76 .27 w199975 .93 .06 w199976 1.3 .08 w199989 w212566 6.2 39 25 w218691 12.9 50 31 2.2 1.2 .67 1.1 .28 2.3 22 1.1 .27 3.4 9.5 1.2 .16 w212566 .10 w218691 t\:) 0 ~ Table 12c. Major- and minor-oxides and trace-element concentrations fn the laboratory ash of seven bituminous coal samples - - from coal bed No. SA, Sand and Lookout Mountains, Georgia and Alabama--conti nued Sample S03 Ag-S 8-S Ba-S Be-S Bi-S Br Cd Ce Co Sample number (percent) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) nUii>er w199993 2.2 0.83 170 1,400 18 1SL 550 w199996 2.6 .65 110 460 38 1SL 1,200 w199975 2.9 .66 71 400 15 1SL 760 wl99976 2.8 .69 100 520 28 151: 1,100 wl99989 1.1 .53 100 510 27 1SL 760 w212566 2.7 .so 170 600 29 16 1,100 w218691 8 .62 99 79 35 10L 470 1.3 220 70 w199993 .45 180 63 w199996 . 90 130 60 w199975 . 87 170 140 w199976 .47 160 50 w199989 2.0 180 190 w212566 . 68 190 23 w218691 1.\:) 1-' 0 Table 12c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of seven bituminous coal samples - - - - from coal bed No. 5A, Sand and Lookout Mountains, Georgia and Alabama-~ontinued Sa""le Cr Cs Cu Oy-S Er-S Eu Ga-S Gd-S Ge-S Hf Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199993 180 w199996 150 w199975 93 w199976 180 w199989 150 w212566 150 w218691 170 13 160 8.2 230 6.6 280 13 300 20 220 13 330 23 150 22L 10L 22L 10L 24 10L 22L 12 22L 10L 22l lOL 26 14 4.9 39 4.9 36 2.0 51 3.5 52 2.9 65 3.2 50 3.9 55 16 1.5L 6.7 w199993 13 19 8.2 w199996 26 26 4.0 w199975 20 59 4.8 w199976 12 28 7.9 wl99989 15l 12 28 22 6.5 w212566 5.4 w218691 .~ ......... Table 12c . Major- and minor-oxides and trace-element concentrations in the laboratory ash of seven bituminous coal samples - from coal bed No. SA, Sand and lookout Mountains, Georgia and Alabama-cont i nued Sample la li lu Hn Ho-S Nb-S Md-S Hi-S Pb Pr-S Sample number (ppm) (ppm) (ppm) (ppm-) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) - -nu-mber w199993 140 2SO w199996 100 140 w19997S 81 160 w199976 97 390 w199989 99 290 1.4 200 22 2.0 190 64 1.2 160 260 1.6 240 33 1.S 110 24 12 120 270 74 13 120 120 86 22 120 220 37 19 86 330 130 8 81 200 66 68l w199993 68l w199996 68l w19997S 69 w199976 68l w199989 w212S66 110 170 w218691 120 100 1.1 330 120 27 78 260 41 as w212S66 1.6 26 18 1S 120 160 71 72 w218691 IS:) 1-' IS:) Table 12c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of seven bituminous coal samples from co-al bed No. !5A, Sand and Lookout Mountains, Georgia and Alabama--continued Sample Rb Sc Sm Sn-S Sr-S Ta Tb Th Tl-S u Sample number (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) (ppm) (ppm) (p-pm) (ppm) number w1'.1'.1'.1'.13 !580L 3'.1 24 w1'.1'.1'.196 1,000L 2'.1 22 w19997!5 '.110L 29 11 w199'.176 1,300L 38 17 w1'.1'.1989 690L 4!5 14 2.0 1,200 1.!5L 1,200 H 1,!500 1.!5L 1,!500 2.2 810 0.1'.1 2.9 34 .06 3.7 20 .08 2.0 14 .10 2.'.1 23 .1!5 2.2 2!5 3.2L 3.8 wl'.l'.l'.l'.l3 3.2L 3. '.1 w1'.1'.1'.1'.16 3.2L 7.1 w1'.1'.1'.17!5 23 20 w19'.1976 28 8.2 w199989 w212!566 160 38 15 w218691 160 4!5 1!5 1.5L 1,600 4.6L 490 .14 2.6 23 .26 2.8 24 4.6L 21 10l 16 w212566 w218691 1:,:) 1-' ~ ,, Table 12c. Major- and minor-oxides and trace-element concentrations in the laborat ory ash of seven bituminous coal samples Sample - from v-s coal bed No. H-S SA, Sand Y-S and Look-ou-t -Mountains, Yb Zn Georgia and--Alabama-conti nued Zr-S Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199993 280 w199996 240 w199975 210 w199976 340 w199989 190 w212566 320 w218691 260 B 72 B 96 B 120 B 120 B 49 .7 110 1.2 94 8.7 240 110 w199993 12 180 180 w199996 6.1 600 330 w1999 75 11 220 180 Wl99976 7.9 230 98 wl99989 9.7 490 280 w212566 13 150 130 w218691 .!:.....:.>. ,j:>.. Table 12d. Content of 22 trace-elements in seven bttuninous coal san.,les from coal bed No. SA, Sand and Lookout Mountains, Georgia and Alabama. (Analysis performed on whole-coal. Values-in parts-per-million(ppm). L, less than the value shown; B, not determined). San.,le As Ce Cl Co Cr Cs Eu F Hf Hg San.,le n~Bber (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) ( ppm ) (ppm) number wl99993 wl99996 w19997S wl99976 w199989 3.0 7.6 112 23.5 16.4 23 9.0 13 11 16 340 980 1,400 830 1,200 7.3 19 1.3 0.51 21 3.1 7.2 .4 .24 20L 6.0 9.3 .7 .20 34 8.9 11 .8 .22 26 5.1 16 2.0 .29 20L w212S66 28.1 11 1,800 12 9.2 .8 w218691 24.0 25 8 3.0 22 3.0 ..s2o0 40 60 0.7 0.020 w199993 .4 .040 w199996 .4 .3 .8 ...2sus7 w19997S w199976 w199989 .4 .19 w212S66 .7 .33 w2111691 .~ ..... 01 Table 12d. Content of 22 trace-elements in seven bituminous coal samples from coal bed No. 5A, Sand and lookout Mountains, Georgia and Alabama--continued Sample number La (ppm) lu (ppm) Na (ppm) p (ppm) Rb (ppm) Sb (ppm) Sc -(ppm) Se (ppm) Sm (ppm) Tb (ppm) Sa1111le nmber w199993 15 wl99996 5 w199975 8 wl99976 6 w199989 10 0.2 240 87 60l 0.80 4.1 1.7 2.5 0.3 wl99993 .1 83 13 50l .50 1.4 1.7 1.1 .2 w199996 .1 200 120 90l 4.0 2.9 2.5 1.1 .2 w199975 .1 80 17 SOL .90 2.3 1.3 1.1 .2 w199976 .2 180 35 70l 1.2 4.5 1.6 1.4 .2 w199989 w212566 7 w218691 15 .1 130 44 10 .2 260 57 21 l.Ol 2.4 1.8 .90 .2 w212566 1.7 5.8 2.2 1.9 .4 w218691 .t.-..:.l. ~ Table 12d. Content of 22 trace-elements in seven bituninous coal Sllq)les from coal bed No. 5A, Sand and lookout Mcultains, S~le - - - - Georgia and Alabama--continued Th u Yb nurber (ppm) (ppm) (ppm) wl'J9993 3.5 w199996 1.0 wl'J9975 1.4 w199976 1.4 w199989 2.5 w212566 1.4 w218691 3.1 0.39 0.9 .19 .6 .70 .6 1.2 .1 .83 .8 1.3 .6 2.0 1.7 ~ ...... -.1 Table 12e. Major-, minor-, and trace-element concentrations, on whole-coal basis , of seven bituminous coal samples from coal bed No. 5A, Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinati ons on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine method ; 8, not determined; G, greater than. Sample number is laboratory number). Sample number Sl AI Ca Hg Na K Fe Ti Ag-S (percent) (percent) (percent) (percent) (percent) (percent) (per cent ) (percent) (ppm) As - (ppm) Sample nunber w199993 2.3 w199996 1.2 w199975 1.3 w199976 1.2 w199989 2.3 1.9 0 . 098 0.043 0.024 0.21 0.46 0.017 0.086 3.0 w199993 .62 .063 .029 .008 .13 .37 .032 .032 7.6 w199996 .91 .96 .16 .095 .046 .042 ..o0o2s0 .11 .16 3.0 .67 .045 .065 110 .035 .043 24 wl99975 w199976 1.5 .067 .064 .018 .30 73 .017 .054 16 w199989 w212566 1.1 .83 .098 .043 .013 .12 .95 .042 .031 28 w212566 w218691 3.0 2.1 .062 .084 .026 .37 .85 .090 .080 24 w218691 .t.-.:.1.. 00 Table 12e. Major-, minor-, and trace-element concentrations, on whole-t:oal basis, of seven bit~~ninous coal s~les from - - - - coal bed No. 5A, Sand and lookout Mountains, Georgia and Alabama--continued S~le B-S Ba-S Be-S Bi-S Br Cd Ce Cl Co Cr S~le numer (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) llU!tler w199993 18 150 2 1.6l 58 0.14 23 340 7.3 19 w199993 w199996 5.4 23 2 .7l 58 .02 9.0 980 3.1 7.2 w199996 w199975 7.0 40 1 1.5l 76 .09 13 1,400 6.0 9.3 w199975 w199976 6.2 32 2 .9l 70 .05 11 830 8.9 11 w199976 w199989 10 52 3 1.5l 76 .05 16 1,200 5.1 16 w199989 w212566 11 37 2 1.0 67 w21B691 13 10 5 1.3l 61 .12 11 1,800 .09 25 B 12 9.2 w212566 3.0 22 w218691 t..:l ~ ~ Table 12e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of seven bituminous coal samples from - coal bed No. 5A, Sand and Lookout Mountains, Georgia and Alabama--continued Sample Cs Cu Dy-S Er-S Eu F Ga-S Gd-S Ge-S Hf Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199993 1.3 17 w199996 .4 11 wl99975 .7 28 w199976 .8 19 w199989 2.0 22 w212566 .8 20 w218691 3.0 19 2.3L l.OL 0.51 21 1.1L .5L .24 20L 2.4 l.OL .20 34 1.4L .7 .22 26 2.2L l.OL .29 20L 1.4L .6L 3.4 1.8 .20 40 .50 60 4.1 1.7 0.16L 0.7 w199993 1.8 .64 .93 .4 w199996 5.0 2.6 2.6 .4 w199975 3.2 1.2 3.7 .3 w199976 6.6 1.2 2.8 .8 w199989 3.1 .93L . 74 .4 w212566 7.1 3.6 2.8 .7 w218691 1:\:) 1:\:) 0 Table 12e. Major-, minor-, and trace-ele.nent concentrations, on whole-coal basis, of seven bituninous coal s~les from - coal bed No. 5A, Sand and Lookout Mountains, Georgia and Alabama~ontfnued SaJ1'4>le Hg La l1 lu Hn Ho-S Nb-S Nd-S Ni-S p S~le m.nber (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) nlJ\j)er w199993 w199996 w199975 w199976 w199989 w212566 w218691 0.020 15 .040 5 .27 8 .55 6 .11 10 .19 7 .33 15 26 0.2 21 2.3 1.2 12 28 87 w199993 6.9 .1 9.3 3.1 .64 5.9 5.9 13 w199996 16 .1 16 26 2.2 12 22 120 w199975 24 .1 15 2.0 1.2 5.3 20 17 w199976 29 .2 11 2.4 .78 8.2 20 35 w199989 11 .1 20 7.4 1.7 4.8 16 44 w212566 13 .2 3.4 2.3 1.9 15 21 57 w2111691 ~ ~ ....... Table 12e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of seven bituminous coal samples from - coal bed No. 5A, Sand and lookout Mountains, Georgia and Alabama--continued -- Sample Pb Pr- S Rb Sb Sc Se Sm Sn-S Sr-S Ta-S Sample mnber (ppm) (ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) nlnber w199993 7.7 w199996 4.2 w199975 3.7 w199976 8.1 w199989 6.7 w212566 2.5 w218691 9.2 7.1l 60l 3.3l SOL 6.7l 90l 4.3 SOL 6.9l 70l 5.3 10 9.3 21 0.80 4. 1 1.7 2.5 0.21 120 . 50 1.4 1.7 1.1 .07l 59 4.0 2.9 2.5 1.1 H 150 .90 2.3 1.3 1.1 .09l 93 1.2 4.5 1.6 1.4 .22 82 1. 0l 2.4 1.8 .90 . 09l 99 1.7 5.8 2.2 1.9 . 59l 63 0.02 .oo w199993 w199996 .01 w199975 .01 w199976 .02 w199989 .01 w212566 .03 w218691 1.\:) 1.\:) 1.\:) Table 12e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of seven bituminous coal samples from Sample coal Tb bed No. 5A, Th Sand and lookout Mountains, Tl-S u vG-seor-gi-a-anHd -SA lab ama-continue Y-S d Yb Zn Zr-S Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199993 0.30 3.5 w199996 .18 1.0 w199975 .20 1.4 w199976 .18 1.4 w199989 .22 2.5 w212566 .16 1.4 w218691 .36 3.1 0.33l 0.39 29 .16l .19 12 .32l .70 21 1.4 1.2 21 2.8 .83 19 .29l 1.3 20 1.3l 2.0 34 B 7.5 B 4.7 B 12 B 7.4 B 4.9 .04 6.8 .15 12 0.9 25 11 w199993 .6 8.8 8.8 w199996 .6 59 33 w199975 .7 14 11 w199976 .8 23 9.9 w199989 .6 30 1.7 19 17 w212566 17 w218691 1:>:) 1:>:) CA:I Table 12f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for seven b ituminous coal samples from coal bed No. SA, Sand and lookout Mountains, Georgia and Al abama-continued (All analyses except Kcal /kg, Btu, free-swelling index , and ash-fusion temperatures in percent. For each sample number, the analyses are reported three ways first, as-received, second, moisture-free, and third, moisture- and ash-free. All analyses by Coal Ana.lysis Sect ion, Department of Energy, Pittsburgh, Pa.; 8, not determined; 1540 for ash-fusion temperatures means greater than 1540 C). - Proximate Analysis Ultimate Ana lysis Heat of Combustion Sample number Volatile Fixed Moisture matter carbon Ash Hydrogen Carbon Nit~ogen Oxygen Sulfur Kcal/kg 8tu/1b w199993 w199996 wl99975 w199976 w199989 w212566 w218691 7.9 21.8 63.6 6.7 23.7 69.1 25.5 74.5 -7.3 1.5 21.8 71.4 5.3 22.1 72.5 23.4 76.6 5-.4 1.1 21.8 70.2 6.9 22.0 71.0 7.0 23.7 76.3 - 1.3 21.6 71.4 5.7 21.9 72.3 23.2 76.8 -5.8 1.3 22.0 67.4 9.3 22.3 68.3 24.6 75.4 -9.4 1.8 21.9 70.4 5.9 22.3 71.7 23.7 76.3 -6.1 2.8 21.7 62.8 12.6 22.4 25.7 64.6 74.3 1-3.-0 4.1 68.5 3.5 74.4 3.8 80.2 4.5 81.9 4.4 83.1 4.6 87.9 4.0 80.2 3.9 81.1 4.2 87.2 4.6 82.6 4.5 83.7 4.8 88.8 4.5 78.6 4.4 79.6 4.9 87.9 4.6 81.6 4.4 83.1 4.7 88.4 4.2 73.2 4.0 75.3 4.5 86.5 I i.2 19.0 1.3 13.0 1.4 14.0 1' .4 6.1 1.4 4.8 1.5 5.1 1.5 5.0 1.5 4.1 1.6 4.4 I 1.5 4.3 1.5 3.2 1.6 3.4 1.5 5.2 1.5 4.1 1!.7 4.5 1.5 5.7 1!.5 4.2 1.6 4.4 J;.3 7.7 l! .3 5.3 l'.5 6.1 0.5 6,220 11,200 .5 6,750 12,160 .6 7,280 13,110 .8 8,070 14,530 .8 8,200 14,750 .9 8,660 15,590 2.5 7,930 14,270 2.5 8,020 14,430 2.7 8,620 15,510 1.2 8,040 14,470 1.2 8,150 14,660 1.3 8,650 15,560 1.0 7,700 13,850 1.0 7,800 14,040 1.1 8,610 15,500 .7 7,870 14,170 .7 8,020 14,430 .8 8,530 15,360 1.1 6,970 12,550 1.1 7,170 12,910 1.3 8,250 14,850 !:>:) !:>:) ~ Table 12f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for seven bituminous coal samples from coal bed No. 5A, Sand and lookout Mountains, Georgia and Alabama---co-n-ti-nu-e-d- - Forms of sulfur Ash fusion temperature, C Sample number Air-dried loss Sulfate Pyritic Free Organic swelling index Initial deformation Softening - Fluid w199993 w199996 w199975 w199976 w199989 w212566 w218691 4.6 0.01 0.07 0.38 0.0 .01 .08 .41 .01 .08 .44 .7 .01 .20 .57 8.5 .01 .20 .58 .01 .21 .61 .4 .01 2.14 .33 8.0 .01 2.16 .33 .01 2.33 .36 .6 .01 .68 .52 9.0 .01 .69 .53 .01 .73 .56 .5 .01 .57 .39 9.9 .01 .58 .40 .01 .64 .44 .6 .02 .08 .60 3.S .02 .08 .61 .02 .09 .65 1.4 .u .37 .60 1.0 .11 .38 .62 .13 .44 .71 1,540 1,360 1,140 1,320 1,530 1,150 1,465 1,540 1,405 1,205 1,365 1,540 1,210 1,510 1,540 1,465 1,250 1,410 1,540 1,260 1,540 t-.:1 t-.:1 01 ~nd Table 13a. Descriptive information for sample numbers, geographic location, and fo lmation and coal bed correlations for two bituminous coal samples from coal bed No. 5, Sand lookout Mountains, Georgia and Alabama. I sample state county latitud longitud formation coal bed rank no. w199992 alabama de kalb 343204n 853241w crab orchard mts no 5 bit wl9999.r. alabama de kalb 343238n 853203w crab orchard mts no 5 bft sample type chamel chamel sampled thickness (i nches I 10.0 9.0 1:..:1 1:..:1 0) Table 13b. Summary statistical table of analytical data for two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion temperatures in degrees F. data values Item used -m-ea-n -st-d-d-e-v -xm-in -xm-ax -ra-n-g--e -geo-me-an geo dev s I!JIICl zero qual usgsash 2 2.85 0.75 2.100 3.60 1.50 2.75 1.31 1.06 0 0 statistics for following data items on ash basis slo2 2 a12o3 2 cao 2 mgo 2 na2o 2 k2o 2 fe2o3 2 mno 2 tio2 2 p2o5 2 so3 2 33.78 30.12 5.11 1.25 0.35 2.06 16.65 0.03 1.07 0.35 7.95 0.22 1.49 1.07 0.12 0.08 0.20 5.89 0.01 0.10 0.10 2.03 33.560 28.620 4.040 1.128 0.270 1.850 10.760 0.020 0.970 0.250 5.920 34.00 31.61 6.18 1.38 0 . 43 2.26 22.53 0.04 1.18 0.45 9.97 0.44 2.99 2.14 0.25 0.16 0.41 11.77 0.02 0.21 0.20 4.05 33.78 30.08 5.00 1.25 0.34 2.04 15.57 0.03 1.07 0.34 7.68 1.01 1.05 1.24 1.10 1.26 1.11 1.45 1.41 1.10 1.34 1.30 0.31 2.11 1.51 0.18 0.11 0.29 8.32 0.01 0 . 15 0.14 2.86 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 statistics for following data items on "whole-coal" basis ag 2 0.02 0.01 0.010 0.04 as 2 5.50 3.50 2.000 9.00 there were less than two positive-valued Items for au b 2 2.58 0.27 2.310 2.84 ba 2 19.69 4.78 14.910 24.48 be 2 1.18 0.22 0.966 1.40 there were less than two positive-valued Items for bl br 2 2.54 0.69 1.856 3.23 cd 2 0.04 0.01 0.032 0.05 ce 2 19.75 6.25 13.500 26.00 cl 2 1250.00 50.00 1200.000 1300.00 co 2 10.45 1. 75 8.700 12.20 cr 2 6.70 1.40 5.300 8.10 cs 2 0.30 0.10 0.200 0.40 cu 2 16.54 2.89 13.650 19.44 dy 2 1.08 0.22 0.861 1.30 er 2 0.69 0.06 0.630 0.76 eu 2 0.39 0.13 0.260 0.52 there were less than two positive-valued items for f ga 2 1.64 0.45 1.197 2.09 gd 2 1.17 0.12 1.050 1.30 ge 2 1.14 0.51 0.630 1.66 hf has insufflcent variance to calculate statistics hg 2 0.05 0.04 0.010 0.10 ho 2 0.32 0.07 0.252 0.40 there were less than two positive-valued items for in there were less than two positive-valued Items for ir la 2 10.50 3.50 7.000 14.00 li 2 4.58 3.34 1.239 7.92 lu 2 0.11 "{). 02 0.100 0.13 mn 2 6.39 0.09 6.300 6.48 mo 2 1.28 0.16 1.113 1.44 nb 2 0.62 0.15 0.468 o. 78 nd 2 7.00 0.91 6.090 7.92 0.03 7.00 0.53 9.57 0.44 1.38 0.02 12.50 100.00 3.50 2.80 0.20 5.79 0.43 0.13 0.26 0.89 0.25 1.03 0.09 0.14 7.00 6.68 0.03 0.18 .0.33 0.31 1.83 0.02 4.24 2.56 19.10 1.16 2.45 0.04 18.73 1249.00 10.30 6.55 0.28 16.29 1.06 0.69 0.37 1.58 1.17 1.02 0.03 0.32 9.90 3.13 0.11 6.39 1.27 0.60 6.94 1.96 2.12 1.11 1.28 1.21 1.32 1.31 1.39 1.04 1.18 1.24 1.41 1.19 1.23 1.10 1.41 1.32 1.11 1.62 3.16 1.25 1.41 2.53 1.14 1.01 1.14 1.29 1.14 0.02 4.95 0.38 6.77 0.31 0.97 0.02 8.84 70.71 2.47 1.98 0.14 4.09 0.31 0.09 0.18 0.63 0.17 0.73 0.06 0.10 4.95 4.72 0.02 0.13 0.23 0.22 1.29 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 11..:> 11..:> -.J s~les Table 13b. Summary statistical table of analytical data for two bituminous coal from coal bed No. 5, Sand and :ookout Mountains, Georgia and Alabama. Zero and qualified valued excluded; asH-fusion temperatures in degrees F--continued. ni 2 12.30 1.38 10.920 13.68 2.76 12.22 1.12 1.95 0 0 there were less than two positive-valued items for os pb 2 3.43 1.61 1.827 5.04 3.21 3.03 1.66 2.27 0 0 there were less than two positive-valued items for pd pr 2 3.81 0.87 2.940 4.68 1.74 3.11 1.26 1.23 0 0 there were less than two positive-valued items for pt there were less than two positive-valued items for rb there were less than two positive-valued items for re there were less than two positive-valued items for rh there were less than two positive-valued items for ru sb 2 0.30 0.10 0.200 0.40 0.20 0 . 28 1.41 0 . 14 0 0 sc 2 2.29 0.68 1.610 2.96 1.35 2.18 1.36 0.95 0 0 se 2 1.11 0.47 0.100 1.64 0 . 94 1.07 1.53 0.66 0 0 sm 2 1.90 0.60 1.300 2.50 1.20 1.80 1.39 0.85 0 0 there were less than two positive-valued items for sn sr 2 119.40 35.40 84.000 154.80 70.80 114.03 1.36 50.06 0 0 there were less than two positive-valued items for ta tb 2 0.27 0.05 0.220 0.33 0.11 0.27 1.22 0.08 0 0 there were less than two positive-valued items for te th 2 1.30 0.40 0.900 1. 70 0.80 1.24 1.37 0.57 0 0 there were less than two positive-valued items for tl there were less than two positive-valued items for tm there were less than two positive-valued items for u v 2 11.37 3.39 7.980 14.76 6.78 10.85 1.36 4.79 0 0 there were less than two positive-valued items for w y 2 5.82 0.06 5.760 5.88 0.12 5.82 1.01 0.08 0 0 yb 2 0.73 0.18 0.550 0.90 0. 35 0.70 1.28 0.25 0 0 zn 2 8.85 3.39 5.460 12.24 6.78 8.17 1.50 4.79 0 0 zr 2 7.84 2.44 5.400 10.29 4.89 7.45 1.38 3.46 0 0 statistics for following data items on "as received" basis data values item used m--e-an- std dev ------- xmin ---- -xma-x range -- 1!:~-~~ -g-eo--d--ev- -si-g-m-a- z--e-ro- q--u-a-l btu ashdef ashsof ashfld freswel moistur volmat fixedc bmash hydrogn carbon ni trogn oxygen sulfur sulfate sulfpyr sulforg ad loss 2 15005.50 153.50 14852.000 15159.00 2 2385.00 65.00 2320.000 2450.00 2 2475.00 65.00 2410.000 2540.00 2 2060.00 560.00 1500.000 2620.00 2 6.50 2.00 4.500 8.50 2 1.25 0.05 1.200 1.30 2 19.85 0.35 19.500 20.20 2 76.10 1.20 74.900 77.30 2 2.90 0.90 2.000 3.80 2 4.50 0.10 4.400 4.60 2 86.05 0.45 85.600 86.50 2 1.55 0.05 1.500 1.60 2 4.40 0.40 4.000 4.80 2 0.75 0.15 0.600 0.90 has lnsufficent variance to calculate statistics 2 0.28 0.08 0.200 0.36 2 0.45 0.04 0.410 0.49 2 0.55 0.05 0.500 0.60 307.00 130.00 130.00 1120.00 4.00 0.10 0.70 2.40 1.80 0.20 0.90 0.10 0.80 0.30 0.16 0.08 0.10 1~004. 72 2384.11 2474.15 :1!982.42 I 61..1285 I 19.85 I 76.09 2.76 4.50 86.05 1.55 4.38 0.73 0.27 0.45 0.55 1.01 217.08 0 0 1.03 91.92 0 0 1.03 91.92 0 0 1.32 791.96 0 0 1.37 2.83 0 0 1.04 0.07 0 0 1.02 0.49 0 0 1.02 1. 70 0 0 1.38 1.27 0 0 1.02 0.14 0 0 1.01 0.64 0 0 1.03 0.07 0 0 1.10 0.57 0 0 1.22 0.21 0 0 1.34 0.11 0 0 1.09 0.06 0 0 1.10 0.07 0 0 ~ ~ 00 Table llc. Hajor- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. L means less than the value shown; H, interference for an element which cannot be resolved by any routine method; G, greater than; B, not determined; S, after element title indicates determinations are to be taken as plus 50% and minus 3~!.. Sample number is laboratory number). Sample number Ash SiD2 A12D3 CaD HgD Na20 k20 Fe203 Ti02 P2D5 Sample (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) number w199992 2.1 34 32 w199994 3.6 34 29 6.2 1.4 0.43 2.3 11 4.0 1.1 .27 1.9 23 1.2 0 . 24 wl99992 .97 .44 wl99994 ~ ~ co Table 13c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples from coal bed No. 5, Sand and Loo-kout Mountains, Georgia and Alabama--continued Sample 503 Ag-S B-S Ba-S Be-S Br Cd Ce Co Cr Sa!l1)le number (percent) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm-)- ---(p-pm-)----(p-pm-)----(p-p-m-) -----num-b-er-- - w199992 10 0.49 110 710 w199994 5.9 l.l 79 680 46 4,200 39 2,500 1.5 640 410 250 w199992 1.5 720 340 230 w199994 1:..:1 ~ 0 Table 13c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples from coal bed No. 5, Sand--and Lookout Mountains, Georg-ia-a-n-d A- labama--continued Sample Cs Cu Dy-S Er-S Eu Ga-S Gd-S Ge-S Hf Ho-S Sample number (ppm) (p-pm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (p-pm) (ppm) number w199992 9.5 650 41 30 12 51 50 30 wl99994 11 540 36 21 14 58 36 46 9.5 12 5.6 11 wl99992 wl99994 1.\:) .c.;...:.., Table 13c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples from coal bed No. S, Sand and-L-o-okout Mountains, Geo-rgia and Alabama--continue-d Sample La Li Lu Hn Ho-S Nb-S Nd-S Ni-S Pb Pr-S Sample number (ppm) (ppm) (ppm) (ppm) (ppm) -----(p-pm-)-- (ppm) (ppm) (ppm) (ppm) n~r w19n92 330 S9 w199994 390 220 4.8 300 S3 37 290 S20 87 140 wl99992 3.6 180 40 13 220 380 140 130 w199994 ~ < t.:) Table 13c. Major- and mtnor-oxides and trace-element concentrations fn the laboratory ash of two bftunfnous coal S3JI1'1es from coal bed No. 5, Sand and lookout Mountains, Georgia and Alabama-continued S3J11'le nullber Sc (ppm) Sm (ppm) Sr-S (ppm) Tb (ppm) Th (ppm) u (ppm) v-s (ppm) Y-S (ppm ) Yb (ppm) Zn (ppn) S3111'le nullber w199992 n w199994 82 62 4,000 69 4,300 10 43 9.2 47 9.0l 380 280 .56 410 160 26 260 w199992 25 340 w199994 t..:l Cl:l Cl:l Table 13c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples - - - - -- - - - from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama--continued Sample Zr-S n~er (ppm) ----------- w199992 490 wl99994 150 !:..:> "~ " Table !3d. Content of 22 trace-elements in two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama. -(A-na-ly-sis performed on whole-coal. Values in parts-per-mlllion(ppm). L, less th-a-n--th-e value shown; B, -not determined). Sample As Ce Cl Co Cr Cs Eu Hf Hg La Sample llU!Der (ppm) (ppm) (ppm) (ppm) (ppm-) (ppm) (ppm) (ppm) (ppm) (ppm) number w19'J'J92 2.0 wl'J'J'J94 9.0 14 1,300 26 1,200 8.7 5.3 0.2 0.26 0.2 0.010 7 w199992 12 11.1 .4 .52 .2 .10 14 w199994 t-:1 OJ 01 f Table 13d. Content of 22 trace-elements in two bituminous coal samples from coal bed No. 5, Sand and lookout Mountains, Georgia and Alabama--continued Saq:>le lu nunber - (ppm) Na (ppm) p (ppm) Sb (ppm) Sc (ppm) Se Sm (ppm) (ppm) - Tb (ppm) Th (ppm) u (ppm) Saq:>le -nu-m-ber- w199992 0.1 67 22 w199994 .1 72 70 0.20 1.6 0.7 1.3 0.2 0.9 0.19l w199992 .40 3.0 1.6 2.5 .3 1.7 .02 w199994 ~ ~ 0) Table 13d. Content of 22 trace-elements in two bituminous coal samples from coal bed No. 5, Sand and lookout Hountalns, Georgia and Alabama--continued Sample number Yb (ppm) wl99992 0.6 wl99994 .9 ~ C/.:1 -l Table 13e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinations on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine method; B, not determined; G, greater than. Sample number is laboratory number). Sample Si Al Ca Mg Na K Fe Ti Ag-S - - - ---- n\eber (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (ppm) As Sample (ppm) - --num-b-er - - wl99992 0.33 0.35 0.093 0.017 0.007 0.040 0.16 0.015 0.010 2.0 w199992 w19999ft .56 .55 .10 .024 .007 .055 .57 .021 .040 9.0 w199994 1....:> ~ 00 Table lle. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, Georgia and Alabama-continued Sample n!Dber 8-S (ppm) Ba-S (ppm) Be-S (ppm) Br (ppm) Cd (ppm) Ce (ppm) Cl (ppm) Co (ppm) Cr (ppm) Cs (ppm) Sample number w199992 2.3 15 w199994 2.8 24 1 88 1 90 0 . 03 14 1,300 .05 26 1,200 8.7 5.3 0.2 wl99992 12 8.1 .4 w199994 I.\:) CiJ ~ Table 13e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from -- - coal bed No.5, Sand and .Lookout Mountains, Georgia and Alabama--continued -- Sample Cu Dy-S Er- S Eu Ga-S Gd-S Ge-S Hf Hg Ho-S number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) w199992 14 w199994 19 0.9 0.6 0.26 1.2 1.1 0.63 0.2 0.010 0.25 1.3 .8 .52 2.1 1.3 1.7 .2 .10 . 40 Sample num-be-r -- wl99992 w19999lo 1:..:1 0""' Table 13e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from coal bed No . .5, Sand and Lookout Mountains, Georgia-and Alabama--continu-e-d-- Sample La Li Lu Hn Ho-S Nb-S Nd-S Ni-S p Pb number (ppm) (ppm) (ppm) (ppm) (ppm) --(pp-m-) -- (ppm) (ppm) (ppm) (ppm) w199992 7 1.2 0.1 6.3 1.1 0.78 6.1 11 22 1.8 w199994 14 7.9 .1 6.5 1.4 .47 7.9 14 70 5.0 Saq,le number 11199992 wl99994 to.:) 1""-'"" v Table 13e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from Sample coal bed No. 5, Sand and lookout Mountains, Georgia and Alabama--continued Pr-S Sb Sc Se Sm Sr-S Tb Th - u v-s number (ppm) (ppm) (ppm) (ppm) (p-p-m-) (ppm) (ppm) (ppm) (ppm) (ppm) wl99992 2.9 0.20 1.6 0.7 1.3 84 wl99994 4.7 .40 3.0 1.6 2.5 150 0.22 0.90 0.19l 8.0 .33 1.7 .02 15 Sample runber w199992 wl99994 1.\:) ~ 1.\:) Table 13e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from coal bed No. 5, Sand and lookout Mountains, Georgia and Alabama--continued Sample nunber Y-S (ppm) Yb (ppm) Zn (ppm) Zr-S (ppm) w199992 5.9 w199994 5.8 0.6 5.5 10 .9 12 5.4 l\:) oj:>.. c.J Table 13f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for two bituminous coal samples from coal bed No. ~. Sand and lookout Mountains, Georgia and Alabama--continued (All analyses except Kcal/kg, Btu, free-swelling index, and ash-fusion temperatures in percent. For each sample number, th~ analyses are reported three ways; first, as- received, second, moisture-free, and third, moisture- and ash-free. All analyses by Coal Analysis Section, Department of Energy, Pittsburgh, Pa.; B, not determined; 1~40 for ash-fusion temperatures means greater than 1~40 C). - - - - - - - - - - Proximlte Analysis Ultimate Analysis Heat of Combustion Sample number Volatile Fixed Moisture matter carbon Ash Hydrogen Carbon Nitrogen Oxygen Sulfur Kcal/kg Btu/lb w199992 w199994 1.2 19.~ 17.3 2.0 4.6 86.~ 1.~ 4.8 0.6 8,420 1~,160 19.7 78.2 20.1 79.9 -2.-0 4.~ 87.6 4.6 89.4 1.5 1.~ 3.8 3.9 .6 8,~20 1~,340 .6 8,700 1~,660 1.3 20.2 74.9 3.8 4.4 8~.6 1.6 4.0 20.~ 21.3 7~.9 78.9 -3.9 4.3 86.7 4.~ 90.2 1.6 1.7 2.9 3.0 .9 11,2~0 14,8~0 .9 8,360 15,0~0 .9 8,690 1~,6~0 I.'-' ~ ~ Table 13f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for two bituminous coal samples from coal bed No. 5, Sand and Lookout Mountains, ---------G-eo-rgia and Alabama--continued----------------- Forms of sulfur Ash fusion temperature, C Sample n~r Air- dried loss Sulfate Pyritic Free Organic swe11 ing index Initial deformation Softening Fluid w199992 w199994 0.6 0.01 0.20 0.41 4.5 .01 .20 .41 .01 .21 .42 .5 .01 . 36 .49 8.5 .01 .36 .50 .01 .38 .52 1,345 1,270 1,395 1,320 1,440 1,370 1:..:1 0""1" Table 14a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama. sample state county latitud longitud formation coal bed rank no. 1 I w199995 alabama cherokee 342940n 853237w crab orchard mts no 4 bit w199971t georg i a chattooga 343343n 852921w crab orchard mts no 4 bit w199988 georgi a walker 345330n 852422w crab orchard mts no 4 bit w199990 georgia chattooga 343343n 852921w crab orchard mts no 4 bit w199991 georgia chattooga 343425n 852905w crab orchard mts no 4 bit ' w209683 georgia walker 345231n 852518w crab orchard ts no 4 bit w209684 georgia walker 344959n 852546w crab orchard mts no 4 bit w212563 georgia walker 345049n 852442w crab orchard mts no 4 bit w212565 georgia walker 344953n 852632w crab orchard mts no 4 bit w215456 georgia chattooga 343240n 852942w crab orchard mts no 4 bit w215457 georg a chattooga 343240n 852942w crab orchard mts n~ 4 b t w218689 georg a chattooga 343330n 852812w crab orchard mts no 4 b t w218690 georg a chattooga 343330n 852812w crab orchard mts no 4 b t sample sampled type thickness (inches) channel 9.0 channel 9.0 channel 14.0 dri 11 core 13.0 channel 14.0 channel channel channel channel channel 23.0 18.0 20.0 19.0 14.0 channel 9.0 channel 13.0 channel 17.5 t...:> ~ 0) Table 14b. Summary statistical table of analytical data for 13 bituminous coal samples from coal bed Ho. 4, Sand and loo~out Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion temperatures in degrees F. data values item used mean std dev xmin ---- -xm--ax- range ----- -g-eo--m--e-an- geo dev sigma zero qual usgs ash 13 6.64 7.25 1.900 28.00 26.10 4.34 2.35 7.54 0 0 statistics for following data items on ash basis sio2 13 al2o3 13 cao 13 mgo 13 na2o 13 k2o 13 fe2o3 13 mno 13 tio2 13 p2o5 10 sol 10 38.70 23.85 3.61 1.37 0.38 2.17 19.83 0.10 0.92 0.25 5.78 12.38 4.57 2.21 0.33 0.22 0.99 8.96 0.13 0.21 0.21 3.21 23.330 14.010 0.450 0.829 0.108 0.840 7.010 0.010 0.550 0.020 1.420 56.70 28.92 7.84 1.99 0.97 4.02 36.87 0.43 1.20 0.65 10.00 33.37 14.91 7.39 1.16 0.86 3.18 29.86 0.42 0.65 0.63 8.58 36.62 23.33 2.76 1.33 0.32 1.94 17.48 0.04 0.90 0.16 4.67 1.40 1.25 2.28 1.29 1.78 1.62 1. 70 3. 70 1.28 2.86 2.04 12.88 4.76 2.30 0.35 0.23 1.03 9.33 0.14 0.22 0.22 3.38 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 3 0 3 statistics for following data items on "whole-coal" basis ag 13 0.04 0.02 0.019 as 13 11.73 12.45 1.100 there were less than two positive-valued items for au b 13 5.92 7.61 0.616 ba 13 37.34 22.24 4.221 be 13 1.10 0.54 0.504 there were less than two positive-valued items for bi br 13 3.93 3.80 0.751 cd 13 0.06 0.05 0.005 ce 13 13.00 8.68 4.000 cl 11 1068.18 243.30 760.000 co 13 12.57 2.87 7.800 cr 13 10.64 9.51 3.000 cs 11 0.83 0.94 0.100 cu 13 10.80 5.08 5.890 dy 8 1. 76 2.15 0.484 er 6 1.50 2.21 0.330 eu 13 0.29 0.18 0.090 f 11 43.91 20.65 20.000 ga 13 2.52 2.56 0.627 gd 9 2.03 2.73 0.418 ge 12 1.26 0.94 0.294 hf 12 0.38 0.36 0.100 hg 13 0.16 0.14 0.014 ho 2 0.25 0.07 0.178 there were less than two positive-valued items for in there were less than two positive-valued items for ir la 13 6.65 4.95 2.000 li 13 8.88 9.65 1.596 lu 12 I 0.10 0.05 0.040 mn 13 26.15 52.23 2.160 mo 12 1.50 0.86 0.819 nb 13 1.14 1.40 0.163 nd 13 7.37 6.86 1.496 0.09 45.00 28.00 98.60 2.49 13.44 0.17 35.00 1600.00 16.90 35.00 3.00 26.52 7.28 6.44 0.70 80.00 10.36 9.52 2.90 1.30 0.46 0.31 19.00 31.90 0.23 204.00 4.18 5.32 28.00 0.07 43.90 27.38 94.38 1.99 12.69 0.17 31.00 840.00 9.10 32.00 2.90 20.63 6.80 6.11 0.61 60.00 9.73 9.10 2.61 1.20 0.45 0.14 17.00 30.30 0.19 201.84 3.36 5.16 26.50 0.03 6.34 3.33 30.73 1.00 2.50 0.04 10.81 1042.60 12.23 7.92 0.44 9.98 1.11 0.75 0.25 39.17 1.81 1.17 0.90 0.26 0.09 0.24 5.33 5.47 0.09 9.92 1.36 0.65 5.34 1.54 3.18 2.76 2.02 1.55 2.57 2.75 1.81 1.24 1.27 2.05 3.09 1.45 2.33 2.74 1. 72 1.62 2.08 2.57 2.36 2.39 3.09 1.33 1.89 2.56 1.64 3.38 1.51 2.75 2.17 0.02 12.96 7.93 23.15 0.56 3.95 0.05 9.04 255.18 2.99 9.90 0.99 5.28 2.30 2.43 0.19 21.65 2.67 2.90 0.98 0.37 0.14 0.10 5.15 10.05 0.06 54.37 0.90 1.46 7.15 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 2 0 0 0 0 0 2 0 0 0 5 0 7 0 0 0 2 0 0 0 4 0 1 0 1 0 0 0 11 0 0 0 0 0 1 0 0 0 1 0 0 0 0 t-:l ,j::>. -.1 Table 14b. Summary statistical table of analytical data for 13 bituminous coal samples from coal bed No. 4, Sand and lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion temperatures In degrees F--contlnued. ni 13 16.55 9.57 7.260 44.80 37.54 14.56 1.62 9.96 0 0 there were less than two positive-valued items for os pb 13 13.94 32.91 1.134 127.50 126.37 4.80 3.09 34.25 0 0 there were less than two positive-valued items for pd pr 3 8.18 8.48 1. 748 20.16 18.41 4.53 2.91 10. 38 0 10 there were less than two positive-valued items for pt rb 2 24.00 9.00 15.000 33.00 18.00 22.25 1.48 12.73 0 11 there were less than two positive-valued items for re there were less than two positive-valued items for rh there were less than two positive-valued items for ru sb 10 0.64 0.36 0.200 1.40 1.20 0.55 1. 78 0.38 0 3 sc 13 2.31 1.72 0.850 6.70 5.85 1.87 1.84 1. 79 0 0 se 13 1.87 0.85 0.970 4.30 3.33 1. 72 1.48 0.88 0 0 sm 13 1.21 0.72 0.400 2.90 2.50 1.04 1.71 0.75 0 0 sn 3 0.25 0.21 0.046 0 . 54 0.49 0.16 2 . 73 0.25 0 10 sr 13 133.18 39.67 57.000 214.20 157.20 126.62 1.39 41.29 0 0. ta 7 0.02 0.04 0.002 0.11 0.11 0.01 3.88 0.04 0 6 tb 11 0.28 0.12 0.120 0.54 0.42 0.26 1.55 0.13 0 2 there were less than two positive-valued items for te th 13 1.32 1.22 0.300 4.70 4.40 0.94 2.18 1.27 0 0 there were less than two positive-valued items for tl there were less than two positive-valued items for tm u 10 0.42 0.40 0.160 1.55 1.39 0.31 1.99 0.42 0 3 v 13 11.61 12.11 2.112 44.80 42.69 7.61 2.39 12.60 0 0 w 8 0.07 0.10 0.011 0.31 0.30 0.03 3.30 0.10 0 5 y 13 5.46 3.11 2.420 12.60 10.18 4. 70 1.71 3.24 0 0 yb 13 0.70 0.36 0.300 1.50 1.20 0.62 1.59 0.38 0 0 zn 13 13.13 14.12 3.250 55.08 51.83 8.68 2.34 14.69 0 0 zr 13 11.40 10.72 2.640 33.60 30.96 7.47 2.46 11.15 0 0 statistics for following data items on "as received" basis data values item used - -mean -std-d-ev -xmi-n -xm-ax -ran-ge -g-eo--m--e-an- geo dev signa zero qual btu 11 ashdef 11 ashsof 11 ashfld 10 freswel 11 moistur 11 volmat 11 fixedc 11 bmash 11 hydrogn 11 carbon 11 ni trogn 11 oxygen 10 sulfur 11 sulfate 9 sulfpyr 11 sulforg 11 ad loss 11 14372.27 2359.09 2473.64 2542.00 6.82 1.66 20.03 72.07 6.24 4.51 82.50 1.55 4.92 0.70 0.07 0.18 0.45 0.84 1159.59 148.23 150.23 132.88 2.09 0.67 1.28 5.66 6.51 0.27 6.42 0.15 1.24 0.19 0.09 0.13 0.11 0.39 11343.000 2070.000 2190.000 2280.000 1.000 1.100 17.990 56.640 1.650 3.860 65.540 1.230 3.050 0.490 0.010 0.010 0.290 0.380 15193.00 2650.00 2760.00 2770.00 9.00 3.49 22.90 77.20 23.95 4.80 87.20 1.70 7.45 1.07 0.24 0.41 0.72 1. 72 3850.00 580.00 570.00 490.00 8.00 2.39 4.91 20.56 22.30 0.94 21.66 0.47 4.40 0.58 0.23 0.40 0.43 1.34 14320.67 2354.44 2469.07 2538.49 6.11 1.57 19.99 71.82 4.17 4.50 82.22 1.54 4.76 0.67 0.03 0.12 0.44 0.77 1.09 1.06 1.06 1.05 1.81 1.38 1.07 1.09 2.30 1.06 1.09 1.11 1.29 1.32 4.05 3.09 1.28 1.50 1216.19 155.46 157 . 56 140, 06 2.19 0 . 70 1.35 5.94 6.83 0.28 6.74 0.16 1.30 0.20 0.10 0.14 0.12 0.41 2 0 0 2 0 2 0 3 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 2 1 1 3 1 1 1 1 1 0 2 1:..:1 ~ (YJ Table 14c. Major- and minor-oxides and trace-olement concentrations in the laboratory ash of 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. L means less than the value shown; H, interference for an element which cannot be resolved by any routine method; G, greater than; B, not determined; S, after element title indicates determinations are to be taken as plus 50% and minus 35%. Sample number is laboratory number). - -- - Sample Ash Si02 A1203 CaD MgD Na2D K2D Fe203 Ti02 P2D5 Sample number (percent) (percent) (percent! (percent) (percent J (percent) (percent) (percent) (percent) (p-er-c-en-t)---n-umb-er --- w199995 10.2 53 27 w199974 2.4 25 25 w199988 2.1 25 27 w199990 8.5 49 16 w199991 2.2 24 14 1.2 0. 91 0.22 2.7 10 5.2 1.8 .19 1.5 29 5.8 1.1 .50 .84 24 1.6 1.5 .15 2.9 21 5.2 2.0 .11 1.1 37 1.2 0.32 w199995 .65 .08 wl99974 .72 .57 w199988 .80 .09 w199990 .55 .14 w199991 w209683 2.2 40 28 w209684 2.4 38 25 w212563 2.5 47 27 w212565 1.9 23 26 w215456 3.1 24 19 3.1 .83 .39 2.7 15 1.2 .45l w209683 3.9 1.5 .97 1.4 21 1.1 .38 w209684 3.3 1.5 .53 1.8 9.2 1.2 .40l w212563 6.2 1.4 .43 1.2 24 .87 .53l w212565 7.8 1.3 .34 1.6 28 .72 .65 w215456 w215457 14.5 54 29 w218689 6.3 42 22 w218690 28.0 57 26 .94 . 98 .30 3.6 7.0 .97 .17 w215457 2.3 1.5 .57 3.0 25 .98 .02 w218689 .45 1.6 .28 4.0 7.6 1.2 .05 w218690 t.,j c~.a Table 14c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of 13 bituminous coal samples - - - - -- from coal bed No. 4, Sand and lookout Mountains, Georgia and Alabama--continued Sample SD3 Ag-S 8-S Ba-S Be- S Br Cd Ce Co Cr Sample n~r - (percent) (ppm) (ppm) (ppm) (ppm) (p-pm) (ppm) - (ppm) (ppm) (ppm) number w199995 1.5 w199974 8.0 wl99988 8.7 w199990 2.9 w199991 9.3 0.51 65 630 .79 44 1,200 1.6 86 1,100 .33 57 460 . 89 28 1,000 19 620 21 2,900 32 2,200 10 1,000 31 4,700 1. 2 180 140 150 w199995 . 68 210 460 160 w199974 . 68 520 540 240 w199988 . 62 120 200 100 w199990 . 72 180 660 140 w199991 w209683 w209684 w212563 w212565 w215456 3.6 8 4.2 8.3 10 .92 120 1.9 120 1.1 130 1.3 97 .97 55 1,100 1,200 1,400 1,700 1,300 38 1,900 46 1,800 46 1, 700 34 2,100 33 2,500 1.0 410 490 250 w209683 2.0 460 420 270 w209684 .76 400 390 240 w212563 9.0 320 520 210 w212565 .15 320 250 240 w215456 w215457 1.4 w218689 8 w218690 8 .61 120 680 .60 69 67 . 17 100 160 10 420 16 970 8.9 170 .63 190 100 190 w215457 .50 190 250 160 w218689 .40 130 57 130 w218690 t-:1 01 0 Table 14c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of 13 bituminous coal samples f~om coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama--continued Sample number Cs (ppm) Cu (ppm) Dy-S (ppm) Er-S (ppm--) Eu (ppm) Ga-S (ppm) Gd-S (ppm) Ge-S ____(p,p_m__ ) Hf (ppm) Ho-S -(-pp-m) Sa""le number wl99995 16 260 22L lOL 3.1 44 17 28 6.9 6.8L wl99995 w199974 4.2 380 24 lOL 5.8 47 26 17 4.2 6.8L w199974 wl99988 33L 360 45 22 12 64 47 14 4.8 15 wl99988 w199990 5.9 130 22L lOL 2.5 18 14 3.6 . 8.2 6.8L w199990 w199991 36L 420 22 lOL 4.1 58 19 69 4.5 6.8L wl99991 w209683 14 370 w209684 13 620 w212563 8.0 420 w212565 5.3 480 w215456 6.5 190 46L 15 9.5 55 22L 46L 11 53 48 34 10 48 31 lOL 8.4 33 25 12 7.7 40 15L 27 46L 66 29 86 22 33 15L 51 9.1 8.1 w209683 8.3 15L w209684 8.0 15L w212563 5.3 6.8L w212565 19L 6.8L w215456 w215457 15 79 w218689 9.5 99 w218690 11 38 22L lOL 4.7 31 15L 20 4.1 6.8L w215457 36 9.0 4.8 41 42 5.0 4.8 6.8L w218689 26 23 2.5 37. 34 4.6l 4.6 6.8l w218690 1:,:) .0..1. Table tc. Hajor- and minor-oxides and trace-element concentrations in the laboratory ash of - from coal bed No. 4, Sand and lookout Mountains, Georgia and Alabama-- continued Sample la li Lu Hn Ho-S Nb-S Nd- S Nl-S number (ppm) (p-p-m-)- (ppm) (ppm) -- (ppm ) (ppm ) - (ppm ) (ppm) w199995 110 260 wl99974 100 200 w199988 240 76 wl99990 59 95 w199991 91 120 1.6 120 41 26 130 230 2.5 960 37 11 86 350 4.3 160 79 12 230 540 1.1 2,400 20 12 88 170 1.8 1,600 44 7 68 640 w209683 180 190 w209684 210 180 w212563 160 210 w212565 160 86 w215456 160 100 3.2 130 55 10 160 330 4.2 90 57 17 270 400 3.2 130 64 30 240 470 2.6 550 76 26 150 1,100 6.5l 180 33 13 100 320 w215457 100 220 w218689 95 51 w218690 68 65 1.6 67 1.4 81 .6 82 8.2 14 82 140 13 14 76 300 l.OL 19 100 160 bituminous coal samples Pb (ppm) -Pr-S (ppm) Sample number 81 130 54 1,500 110 75 160 110 180 110 77 66 30 68l w199995 110 w199974 150l w199988 150l w199990 150l w199991 68l w209683 150l w209684 68L w212563 92 w212565 68l w215456 68l w215457 68l w218689 72 w218690 t-:1 C1l t-:1 Table 14c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama--continued ------ Sa111>le Rb Sc Sm Sn-S Sr-S Ta Tb Th u v-s Sample nunber (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) n-u-nb-e-r - w199995 690L 35 16 wl99974 2,900l 43 25 wl99988 2,400l 65 57 wl99990 820l 16 13 w199991 2,700l 46 18 1.5l 1.5L 1.5l 2.0l 2.0l 2,100 6,400 5,600 2,000 5,900 0.15 3.0 23 .20l 21l 17 .20l 9.0 29 .11 1.4 13 .20l 23L 14 2.9 240 6.7 140 8.1 250 2.0 110 7.7 96 wl99995 wl99974 wl99988 w199990 w199991 w209683 910l 70 36 w209684 830L 67 42 w212563 1,200l 73 36 w212565 1,100L 45 32 w215456 1,600L 53 32 2.1 7.4 1.5l 1.5l 1.5l 4,200 5,900 3,500 3,000 5,300 .07 8.2 32 .20l 8.3 42 .07 22 32 .09l 18 26 .20l 7.7 16 15L 180 12 270 16 400 13L 230 7.4l 120 w209683 w209684 w212563 w212565 w215456 w215457 480L 36 w218689 240 37 w218690 120 24 20 16 9.3 3.7 880 4.6l 1,800 4.6l 580 .10 3.0 20 .11 2.7 21 .41 1.3 17 4.4 180 4.9 110 5.5 160 w215457 w218689 w218690 t-:) CJ1 c.J ' Table 14c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of 13 bituminous coal samples ---- from coal bed No. 4, Sand and lookout Mountains, Georgia and Alabama--continued Sample H-S Y-S Yb Zn Zr-S nunber (ppm) (ppm) (ppm) (ppm ) ( p pm) w199995 B 100 w199974 B 120 w199988 B 230 w19'J'J'JO B 75 wl'J'J'J91 B 110 w209683 w209684 w212563 w212565 w215456 .5 110 .5 180 .5 290 .6 190 .7 96 w215457 .9 55 w218689 .7 49 w218690 1.1 45 9.8 540 300 15 220 110 29 200 180 7.1 110 270 14 300 200 23 160 120 21 180 210 24 130 340 21 1,200 410 23 280 99 9.7 110 130 9.5 80 68 5.4 93 120 ~ 01 ~ Table 14d. Content of 22 trace-elements in 13 bittn1nous coal san.,les from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama. - - - (Analysis performed on whole-coal . Values 1n parts-per-million(ppm). L, less than the value shown; B, not determined). Sample As Ce Cl Co Cr Cs Eu F Hf Hg San.,le nlnber (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) ~-r-- w199995 25. 3 18 760 15 15 1.6 0.32 20L 0.7 0.21 w199995 wl99974 2. 4 5.0 960 11 3.8 .1 .14 20L .1 .24 w199974 w199988 3. 8 11 1,000 11 5.1 .7L .25 28 .1 .020 w199988 w199990 10 .7 10 1,200 17 8.5 .5 .21 22 .7 .030 w199990 w199991 3.8 4.0 1,600 15 3.0 .8L .09 23 .1 .014 w199991 w209683 2. 8 9.0 990 11 5.6 .3 .21 70 w209684 2. 0 11 1,000 10 6.5 .3 .27 50 w212563 1. 8 10 1,100 9.8 6.0 .2 .26 40 w212565 1. 1 6.0 860 9.9 4.0 .1 .16 50 w215456 17 .7 10 1,400 7.8 7.4 .2 .24 30 .2 .052 w209683 .2 .46 w209684 .2 .042 w212563 .1 .042 w212565 .6L .19 w215456 w215457 16.1 28 800 15 28 w218689 45.0 12 B 16 10 w218690 20.0 35 8 16 35 2.2 .68 70 .6 .30 20 3.0 .70 80 .6 .22 w215457 .3 . 36 w218689 1.3 .19 w218690 t.:> 0'1 0'1 l Table 14d. Content of 22 trace-elements in 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, -- - Georgia and Alabama--continued -- ----- Sample La lu Na p Rb Sb Sc Se Sm Tb number (ppm) (ppm) - -- -(p-pm-) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) Sample number w199995 11 w199974 3 w199988 5 w199990 5 w199991 2 w209683 4 w209684 5 w212563 4 w212565 3 w215456 5 0.2 160 140 70L .1 34 9 70L .1 78 52 50l .1 93 35 70l .o 18 13 60l .1 64 .1 170 .1 97 .1 61 .2L 77 44l 20l 39 20l 44L 30L 44l 20L 87 50L 1.4 3.6 1.3 . 20 1.0 1.4 . 30 1.4 1.0 .40l 1.4 2.4 .40 1.0 1.8 .so 1.6 1.1 . 60 1.6 1.8 2.0L 1.8 1.2 l.OL .85 1.4 .90 1.6 2.0 1.6 .60 1.2 1.1 .40 .80 1.0 .90 .60 1.0 0.3 .5L .2 .1 .5l .2 .2 .5 .4 .2 w199995 w199974 w199988 wl99990 w199991 w209683 w209684 w212563 w212565 w215456 w215457 15 w218689 6 w218690 19 .2 320 110 70l 1.0 5.3 2.6 2.9 .4 w215457 .1 260 4 15 .40 2.3 4.3 1.0 .2 w218689 .2 590 61 33 .40 6.7 2.0 2.6 .4 w218690 l:...:l 01 C) Table 14d. Content of 22 trace-elements tn 13 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama-----c-o-n-ti-n-u-ed- Sample Th u Yb nl.mlber (ppm) (ppm) (ppm) w199995 2.3 w1'J'J'J74 .4 w199988 .6 wl 99990 1.1 w1999'Jl .3 w209683 .7 w209684 1.0 w212563 .8 w212565 .5 w215456 .5 w215457 2.9 w218689 1.3 w218690 4.7 0.30 1.0 .16 .4 .17 .6 .17 .6 .17 .3 .33L .5 .29 .5 .40 .6 .25L .4 .23L .7 . 64 1.4 .31 .6 1.6 1.5 1:..:> C11 -:) Table 14e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of ~3 bituminous coal samples from coal bed No. 4, Sand and lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinations on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine method; B, not determined; G, greater than. Sample n~er is laboratory n~er). - ----- Sample Si AI Ca Hg Na K Fe Ti Ag-S As Sample nunber (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (ppm) (ppm) nunber wl99995 w199974 w199988 w199990 wl99991 w209683 w209684 w212563 w212565 w215456 w215457 w218689 w218690 2.5 .28 .25 2.0 .25 .41 .43 .55 .21 .35 3.7 1.2 7.4 1.5 .32 . 31 .72 .16 .32 .32 .35 .26 .31 2.2 .72 3.8 0.085 .089 .087 .094 .082 .048 .066 .059 . 083 .17 .097 .10 .090 0.056 .026 .014 .077 .026 .011 .021 .022 .016 .024 .085 .057 .27 0.016 .003 .008 .009 .002 .006 .017 .010 .006 .008 .032 .026 .059 0.23 .030 .015 .21 .019 .049 .029 .038 .018 .040 .43 .16 . 94 0.73 .48 .35 1.3 .57 .24 .35 .16 .32 .61 .71 1.1 1.5 0.073 .009 .009 .041 .007 .015 .016 .017 .010 .013 .084 .037 .19 0.052 .019 .034 .028 .020 .020 .046 .028 .025 .030 .088 .038 .048 25 2.4 3.8 11 3.8 2.8 2.0 1.8 1.1 18 16 45 20 w199995 w199974 w199988 w199990 w199991 w209683 w209684 w212563 w212565 w215456 w215457 w218689 w218690 t-:> 01 00 Table 14e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of 1'3 bituminous coal samples from coal bed No. 4--, Sand and lookout Mountains, Georgia and Alabama--co-n-t-in-ued ------- Sample 8-S Ba-S Be-S Br Cd Ce Cl Co Cr Cs number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) w199995 6.6 64 w199974 1.1 29 w199988 1.8 23 w199990 4.8 39 w199991 .6 22 2 64 1 69 1 47 1 85 1 100 w209683 2.6 24 w209684 2.9 29 w212563 3.3 35 w212565 1.8 32 w215456 1.7 40 1 42 1 44 1 44 1 40 1 77 w215457 11 99 1 62 w218689 4.3 4.2 1 61 w218690 28 45 2 48 0.12 .02 .01 .05 .02 .02 .05 .02 .17 .00 .09 .03 .11 18 5.0 11 10 4.0 9.0 11 10 6.0 10 28 12 35 760 960 1,000 1,200 1,600 990 1,000 1,100 860 1,400 800 B B 15 15 11 3.8 11 5.1 11 8.5 15 3.0 11 5.6 10 6.5 9.8 6.0 9.9 4.0 7.8 7.4 15 28 16 10 16 35 1.6 .1 .1l .5 . Bl .3 .3 .2 .1 .2 2.2 .6 3.0 Sample num-be-r-- - w199995 w199974 w199988 w199990 w199991 w209683 w209684 w212563 w212565 w215456 w215457 w218689 w218690 t-.:l 01 ~ Table 14e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of 13 bituminous coal samples from -- coal bed No. 4, Sand and lookout Mountains, Georgia and Alabama--continued - - Sample Cu Dy-S Er-S Eu F Ga-S Gd-S Ge-S Hf Hg number (ppm) (ppm) (ppm ) (ppm) (ppm) (ppm) - (ppm) (ppm) - (ppm) (ppm) w199995 27 w199974 9.1 w199988 7.6 w199990 11 w199991 9.2 2.2l l.Ol 0.32 20l .6 .2l .14 20l .9 .5 .25 28 1.9l .9l .21 22 .5 .2l .09 23 4.5 1.7 2.9 0.7 0.21 1.1 .62 .41 .1 .24 1.3 .99 .29 .1 .020 1.5 1.2 .31 .7 .030 1.3 .42 1.5 .1 .014 w209683 w209684 w212563 w212565 w215456 8.1 15 11 9.1 5.9 l.Ol .3 .5l l.ll 1.2 .9 .6 .2l .8 .4 .21 70 .27 50 .26 40 .16 50 .24 30 1.2 .33l .59 .2 .052 1.3 1.1l 1.6 .2 .46 1.2 .73 2.2 .2 .042 .6 .42 .63 .1 .042 1.2 .47l 1.6 .6l .19 w215457 11 3.2l 1.5l .68 70 4.5 2.2l 2.9 .6 .22 w218689 6.2 2.3 .6 .30 20 2.6 2.6 . 32 .3 .36 w218690 11 7.3 6.4 .70 80 10 9.5 1.3l 1.3 .19 Saf1l)le number wl99995 wl99974 wl99988 w199990 w199991 w209683 w209684 w212563 w212565 w215456 w215457 w218689 w218690 ~ 0) 0 Table 14e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of 13 bituminous coal samples from -coal bed No . 4, Sand and lookout Mountains, Geor-g-ia and Alabama--continued ----- Sample Ho-S La li lu Hn Mo-S Nb-S Nd-S Ni-S p number (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) w199995 w199974 w199988 w1CJCJ'I90 w1CJCJCJCJ1 0.69l 11 .16l 3 .32 5 .58l 5 .15l 2 27 0.2 12 4.2 2.7 13 23 140 4.8 .1 23 .89 . 26 2.1 8.4 9 1.6 .1 3.4 1.7 .25 4.8 11 52 8.1 .1 200 1.7 1. 0 7.5 14 35 2.6 .0 35 .97 . 16 1.5 14 13 w209683 w209684 w212563 w212565 w215456 .18 4 .36l 5 .38l 4 .13l 3 .21L 5 4.2 .1 2.9 1.2 .22 3.5 7. 3 44l 4.3 .1 2.2 1.4 . 41 6.5 9.6 39 5.3 .1 3.3 1.6 .75 6.0 12 44l 1.6 .1 10 1.4 . 49 2.9 21 44l 3.1 .2L 5.6 1.0 .40 3.1 9.9 87 w215457 w218689 w218690 .CJCJL 15 .43L 6 1.9L 19 32 3.2 18 .2 '1.7 1.2 2.0 12 20 110 .1 5.1 .82 .88 4.8 19 4 .2 23 .28L 5.3 28 45 61 Sample number w199995 w199974 wl9'1988 w1CJ'ICJCJO w1CJCJ991 w209683 w209684 w212563 w212565 w215456 w215457 w218689 w218690 ~ .0...).. Table 14e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of 13 bituminous coal samples from - coal bed No . 4, Sand and Lookout Mountains, Georgia and Alabama--continued Sample Pb Pr-S Rb Sb Sc Se Sm Sn-S Sr-S Ta-S number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (p-p-m-) - w199995 w199974 w199988 w199990 w199991 8.3 3.1 1.1 130 2.4 6.9L 70L 2.6 70L 3.2L 50L 13L 70L 3.3L 60L 1.4 3.6 1.3 1.6 0.15L 210 .20 1.0 1.4 .60 .04L 150 .30 1.4 1.0 1.2 .03L 120 .40L 1.4 2.4 1.1 .17L 170 .40 1.0 1.8 .40 .04L 130 0.02 .OOL .OOL .01 .OOL w209683 1.7 1.5L 20L .80 1.6 1.1 .80 .05 92 .00 w209684 3.8 3.6L 20L .60 1.6 1.8 1.0 . 18 140 .OOL w212563 2.8 1.7L 30L 2.0L 1.8 1.2 .90 . 04L 88 .00 w212565 3.4 1.7 20L l.OL .85 1.4 .60 . 03L 57 .OOL w215456 3.4 2.1l 50l .90 1.6 2.0 1.0 .05L 160 .01l w215457 11 9.9L 70l 1.0 5.3 2.6 2.9 .54 130 .01 w218689 4.2 4.3l 15 .40 2.3 4.3 1.0 .29L 110 .01 w218690 8.4 20 33 .40 6.7 2.0 2.6 1.3L 160 .11 Sample number w199995 w199974 wl99988 wl99990 wl9999l w209683 w209684 w212563 w212565 w215456 w215457 w218689 w218690 l:'.:l (j) l:'.:l Table 14e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of 13 bituminous coal samples from Sample - coal Tb bed No. 4, Th Sand and u Loo-k-o-u-t-Mv-osuntains, Georgi-a H-S andvA-sl a b a m a---- c-Yo-bn-t i-n-u e-d- - Zn Zr-S Sample -num-b-er - - - -(p-pm-) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number wl99995 w199974 w199988 w199990 wl99991 0.31 .SOL .19 .12 .50l 2.3 .40 .60 1.1 .30 0.30 .16 .17 .17 .17 24 3.4 5.3 9.4 2.1 B 10 1.0 55 31 w199995 B 2.9 .4 5.3 2.6 w199974 B 4.8 .6 4.2 3.8 w199988 B 6.4 .6 9.4 23 wl99990 B 2.4 .3 6.6 4.4 w199991 w209683 .18 .70 w209684 .20 1.0 w212563 . 54 .80 w212565 .35 .50 w215/o56 .24 .50 .33L 4.0 .29 6.5 .40 10 .25L 4.4 .23L 3.7 .01 2.4 .01 4.3 .01 7.3 . 01 3.6 .02 3.0 .5 3.5 .5 4.3 .6 3.3 .4 23 .7 8.7 2.6 w209683 5.0 w209684 8.5 w212563 7.8 w212565 3.1 w215456 w215457 .43 2.9 w218689 .17 1.3 w218690 .36 4.7 .64 .31 1.6 26 6.9 45 .13 8.0 .04 3.1 .31 13 1.4 16 19 w215457 .6 5.0 4.3 w218689 1.5 26 34 w218690 t-:) 0) "' Table 14f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for 11 bituminous coal samples from coal bed No. 4, Sand and Lookout Mountains, Georgia and Alabama--continued (All analyses except Kcal/kg, Btu, free-swelling Index, and ash-fusion temperatures in percent. For each sample number, the analyses are reported three ways: first, as-received, second, moisture-free, and third, moisture- and ash-free. All analyses by Coal Analysis Section, Department of Energy, Pittsburgh, Pa.; B, not determined; 1540 for ash-fusion temperatures means greater than 1540 C-).--- --- - Proximate Analysis Ultimate Analysis Heat of Combustion Sample number Volatile Fixed Moisture matter carbon Ash Hydrogen Carbon Nitrogen Oxygen - Sulfur Kcallkg Btu/lb w199995 w199974 w199988 w199991 w209683 w209684 w212563 w212565 w215456 w215457 w218690 1.7 19.3 69.8 9.2 4.5 78.6 1.5 5.3 0.9 7,630 13,730 19.6 21.7 71.0 78.3 -9.4 4.4 80.0 4.8 88.2 1.5 1.7 3.9 4.3 .9 7,760 13,960 1.0 8,560 15,410 1.3 19.2 77.2 2.3 4.2 87.2 1.6 3.9 19.5 78.2 19.9 80.1 -2.3 4.1 88.3 4.2 90.5 1.6 1.7 2.8 2.8 .7 8,390 15,090 .7 8,500 15,290 .7 8,700 15,660 1.5 20.9 75.5 2.1 4.7 85.4 1.6 5.7 21.2 76.6 21.7 78.3 2-.1 4.6 86.7 4.7 88.6 1.6 1.7 4.4 4.5 .5 8,320 14,980 .5 8,450 15,210 .5 8,630 15,540 1.2 20.3 72.1 6.4 4.6 86.3 1.6 20.5 22.0 73.0 78.0 -6.5 4.5 87.3 4.8 93.4 1.6 1.7 .0 ..oo .7 8,410 15,130 .1 8,510 15,320 .8 9,100 16,380 1.4 22.9 73.5 2.2 4.7 85.1 1.6 5.8 23.2 74.5 23.8 76.2 -2.2 4.6 86.3 4.7 88.3 1.6 1.7 4.6 4.7 .5 8,350 15,020 .5 8,470 15,240 .5 8,660 15,590 1.2 20.7 75.6 2.5 4.8 86.3 1.7 4.3 21.0 21.5 76.5 78.5 2-.-5 4.7 87.3 4.8 89.6 1.7 1.8 3.3 3.4 .5 8,440 15,190 .5 8,540 15,380 .5 8,760 15,780 1.1 20.3 75.7 2.9 4.7 86.6 1.7 3.5 20.6 21.2 76.5 78.8 -2.9 4.6 87.6 4.8 90.2 1.7 1.8 2.6 2.7 .6 8,350 15,030 .6 8,440 15,200 .6 8,700 15,650 3.5 19.9 74.9 1.6 4.6 84.2 1.7 7.4 20.7 21.0 77.6 79.0 -1.-7 4.3 87.2 4.4 88.7 1.7 1.8 4.5 4.6 .5 8,050 14,490 .5 8,340 15,010 .5 8,480 15,270 1.6 20.5 74.9 3.0 4.7 86.6 1.6 3.0 1.1 8,350 15,040 20.8 21.5 76.1 78.5 -3.1 4.6 88.0 4.7 90.8 1.6 1.6 1.6 1.7 1.1 8,490 15,280 1.1 8,760 15,760 2.4 18.3 66.8 12.4 4.3 75.6 1.3 5.6 .9 7,250 13,050 18.8 21.5 68.5 78.5 1-2.8 4.1 77.4 4.7 88.8 1.3 1.5 3.5 4.0 .9 7,430 13,370 1.0 8,510 15,330 1.4 18.0 56.6 24.0 3.9 65.5 1.2 4.6 .9 6,300 11,340 18.2 24.1 57.5 75.9 2-4.-3 3.8 66.5 5.0 87.8 1.2 1.6 3.3 4.4 .9 6,390 11,510 1.2 8,440 15,200 !.-.:> 0) """ Table 14f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for 11 bituminous coal samples from coal bed No. 4, Sand and lookout Mountains, Georgia and Alabama--continued Forms of sulfur Ash fusion temperature, C Sample number ---- Air-dried loss Sulfate Pyritic Free Organic swelling index Initial deformation Softening Fluid w199995 w199974 w199988 w199991 w209683 w209684 w212563 w212565 w21.456 w215457 w218.690 0.7 0.01 0.17 0.72 8.0 .01 . 17 .73 .01 .19 .81 .6 .01 .26 .48 8.0 .01 . 26 .49 .01 .27 .50 .8 .01 .20 .31 7.0 .01 .20 .31 .01 .21 .32 .6 .01 .37 .29 8.0 .01 .37 .29 .01 .40 .31 .8 .01 .04 .45 -s.o .01 .04 .46 .01 .04 .47 .7 .01 .05 .40 9.0 .01 .05 .40 .01 .05 .42 .4 ..o0o0 .04 .04 .53 ?.5 .54 .00 .04 .55 1.7 .00 .01 .48 1-;0 ..o0o0 .01 .01 .50 .51 .8 .14 .41 .52 8.0 .14 .42 .53 .15 .43 .55 1.5 .21 .19 .47 6.5 .22 .19 ;-48 .25 .22 .55 .6 .24 .28 .35 7.0 .24 . 28 .36 .32 . 38 .47 1,455 1,245 1,265 1,130 1,295 1,265 1,340 1,3111 1,220 1,400 1,300 1,515 1,310 1,315 1,200 1,375 1,310 1,400 1~360 1,275 1,455 1,405 1,540 1,390 1,365 1,250 1,445 1,380 1,420 1,380 1,315 1,475 1,520 ~ 0) 01 Table 15a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for three bituminous coal samples from coal bed Ho. 3, Sand and Lookout Mountains, Georgia and Alabama. ' . sample sta_te county latitud longitud formation coal bed rank no. w199983 georg a dade 345043n 852712w crab orchard mts no 3 b t w199986 georg a dade 345031n 852648w crab orchard mts no 3 b t w199987 georg a walker 345158n 852508w crab orchard mts no 3 b t 'it" sample type channel channel channel sampled thickness (inches) 20.0 22.0 13.5 1:...:> 0') 0') Table 15b. Summary statistical table of analytical data for three bituminous coal samples from coal bed No. 3, Sand and lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion temperatures in degrees F. data values item used m--e-a-n -s-td---d-e-v -x-m-i-n -xm-ax . -ra-n-g--e -g-eo--m--e-a-n geo dev sigma zero qual usgsash 3 4.60 2.53 2.200 8.10 5.90 3.97 1.71 3.10 0 0 statistics for following data items on ash basis sio2 3 a12o3 3 cao 3 mgo 3 na2o 3 k2o 3 fe2o3 3 mno 3 tio2 3 p2o5 3 sol 3 42.30 30.ll 2.68 1.09 0.49 2.31 9.47 0.01 1.05 0.24 3.65 8.06 3.38 1.44 0.16 0.16 0.75 6.56 0.00 0.13 0.21 2.60 32.430 25.510 1.010 0.929 0.283 1.610 2.810 0.010 0.940 0.090 0.970 52.18 33.53 4.53 1.31 0.66 3.34 18.40 0.02 1.23 0.54 7.17 19.75 8.02 3.52 0.38 0.38 1. 73 15.59 0.01 0.29 0.45 6.20 41.52 29.91 2.25 1.08 0.46 2.20 7.19 0.01 1.04 0.17 2.69 1.21 9.88 0 0 1.12 4.14 0 0 1.85 1.77 0 0 1.15 0.20 0 0 1.43 0.19 0 0 1.36 0.91 0 0 2.15 8.04 0 0 1.39 0.01 0 0 1.13 0.16 0 0 2.27 "0.26 0 0 2.26 3.19 0 0 statistics for following data Items on "whole-coal" basis ag 3 0.04 0.01 0.027 as 3 7.87 3.96 2.900 there were less than two positive-valued items for au b 3 7.00 4.22 3.850 ba 3 53.34 15.86 38.500 be 3 1.09 0.42 0.528 there were less than two positive-valued items for bi br 3 1.61 0.86 0.792 cd 3 0.04 0.01 0.028 ce 3 14.33 7.32 4.000 cl 3 586.67 20.55 560.000 co 3 5.53 2.48 2.800 cr 3 8.73 3.97 4.900 cs 3 0.73 0 . 83 0.100 cu 3 13.81 1.99 11.000 dy 2 1.07 0.26 0.814 er 3 0.71 0.20 0.484 eu 3 0.29 0.12 0.140 f 2 34.00 2.00 32.000 ga 3 2.68 1.69 1.100 gd 3 1.19 0.38 0.814 ge 3 2.30 1.01 0.880 hf 3 0.30 0.14 0.200 hg 3 0.11 0.06 0.040 ho 2 0.28 0.04 0.242 there were less than two positive-valued items for in there were less than two positive-valued items for ir la 3 7.33 3.77 2.000 11 3 10.39 5.61 3.300 lu 3 0.10 0.04 0.070 mn 3 4.59 1. 79 2.860 mo 3 2.20 0.71 1.330 nb 3 0.77 0.47 0.242 nd 3 8.26 4.05 3.080 0.05 12.60 12.96 75.33 1.54 2.79 0.05 20.00 610.00 8.80 14.20 1.90 15.39 1.33 0.97 0.42 36.00 5.02 1.70 3.19 0.50 0.19 0.33 10.00 17.01 0.15 7.05 3.08 1.38 12.96 0.02 9.70 9.ll 36.113 1.01 2.00 0.03 16.00 50.00 6.00 9.30 1.80 4.39 0.52 0.49 0.28 4.00 3.92 0.89 2.31 0.30 0.15 0.08 8.00 13.71 0.08 4.19 1. 75 1.14 9.88 0.04 6.66 5.93 51.17 1.00 1.40 0.04 fl. 50 586.30 4.98 7.91 0.34 13.66 1.04 0.68 0.27 33.94 2.20 1.13 2.00 0.27 0.09 0.28 5.85 8.48 0.09 4.27 2.08 0.62 7.04 1.27 1.85 1.74 1.33 1.58 1.69 1.36 2.11 1.04 1.60 1.55 3.51 1.17 1.28 1.33 1.60 1.06 1.87 1.36 1. 79 1.54 1.89 1.16 2.14 2.00 1.39 1.46 1.41 2.05 1.83 0.01 4.85 5.17 19.43 0.52 1.05 0.01 8.96 25.17 3.04 4.86 1.01 2.44 0.36 0.25 0.14 2.83 2.07 0.46 1.24 0.17 0.08 0.06 4.62 6.87 0.04 2.19 0.88 0.57 4.96 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 1 0 0 0 0 0 0 0 0 0 0 0 0 0 0 !).:) 0) -J Table 15b. Summary statistical table of analytical data for three bituminous coal samples from coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion temperatures in degrees F--continued. ni 3 10.53 6.51 4.620 19.60 14.98 8.H 1.83 7.97 0 0 there were less than two positive-valued items for os pb 3 3.49 2.00 0.880 5.75 4.87 2.69 2.24 2.45 0 0 there were less than two positive-valued items for pd there were less than two positive-valued items for pr there were less than two positive-valued items for pt there were less than two positive-valued items for rb there were less tha~ two positive-valued items for re there were less than two positive-valued items for rh there were less than two positive-valued items for ru sb 3 1.03 0.31 0.600 1.30 0.70 0.98 1.42 0.38 0 0 sc 3 2.55 0.92 1.490 3.73 2.24 2.38 1.45 1.12 0 0 se 3 1.24 0.10 1.110 1.33 0.22 1.24 1.08 0.12 0 0 sm 3 1.40 0.51 0.700 1.90 1.20 1.29 1.55 0.62 0 0 there were less than two positive-valued items for sn sr 3 153.83 35.04 115.500 200.20 84.70 149.95 1.25 42.92 0 0 there were less than two positive-valued items for ta tb 3 0.22 0.07 0.120 0.28 0.16 0.21 1.48 0.09 0 0 there were less than two positive-valued items for te th 3 1.10 0.67 0.400 2.00 1.60 0.90 1.93 0.82 0 0 there were less than two positive-valued items for tl there were less than two positive-valued items for tm u 3 0.31 0.18 0.180 0.56 0.38 0.27 1.69 0.22 0 0 v 3 15.88 7.19 9.460 25.92 16.46 14.43 1.53 8.81 0 0 there were less than two positive-valued items for w y 3 7.35 2.93 4.400 11.34 6.94 6.80 1.48 3.59 0 0 yb 3 0.70 0.22 0.500 1.00 0.50 0.67 1.34 0.26 0 0 zn 3 9.14 4.68 5.500 15.75 10.25 8.11 1.60 5. 74 0 0 zr 3 12.00 8.72 5.060 24.30 19.24 9.35 1.98 10.68 0 0 statistics for following data items on "as received" basis data values item used -me-an -std-d-ev -xm-in - -xmax range -- geo mean -geo-d-ev - - -sigm-a z-er-o qual btu 3 14745.00 430.28 14154.000 15166.00 there were less than two positive-valued items for ashdef there were less than two positive-valued items for ashsof there were less than two positive-valued items for ashfld freswel 3 8.17 0.85 7.000 9.00 moistur 3 1.23 0.09 1.100 1.30 volmat 3 20.90 0.64 20.400 21.80 fixedc 3 73.63 1.93 70.900 75.10 bmash 3 4.23 2.27 2.200 7.40 hydrogn 3 4.67 0.09 4.600 4.80 carbon 3 83.90 2.90 79.800 86.10 ni trogn 3 1.57 0.09 1.500 1. 70 oxygen 3 4.93 0.79 4.100 6.00 sulfur 3 0.70 0.08 0.600 0.80 sulfate has insufficent variance to calculate statistics sulfpyr 3 0.16 0.06 0.090 0.23 sulforg 3 0.53 0.04 0.490 0.59 adloss 3 0.60 0.08 0.500 0.70 1012.00 14738.65 2.00 0.20 1.40 4.20 5.20 0.20 6.30 0.20 1.90 0.20 0.14 0.10 0.20 8.12 1.23 20.89 73.61 3.70 4.67 83.85 1.56 4.87 0.70 0.15 0.52 0.59 1.03 1.11 1.08 1.03 1.03 1.67 1.02 1.04 1.06 1.17 1.12 1.48 1.09 1.15 526.98 1.04 0.12 0.78 2.37 2.78 0.12 3.55 0.12 0.97 0.10 0.07 0.06 0.10 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ~ 0) 00 Table 15c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituminous coal samples from coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. L means less than the value shown; H, interference for an element which cannot be resolved by any routine method; G, greater than; B, not determined; S, after element title indicates - determinations are to be taken as plus 50% and minus 35%. - Sample nunber is laboeatory number). Sample Ash Si02 Al203 CaD HgD Na2D K2D Fe203 TiD2 P2D5 Sample number -- (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) number w199983 3.5 42 34 w199986 2.2 32 26 w199987 8.1 52 31 2.5 0.93 0.28 2.0 7.2 0.97 0.54 w199983 4.5 1.3 .66 1.6 18 .94 .09 w199986 1.0 1.0 .51 3.3 2.8 1.2 .09 w199987 1.\:) 0') (0 1 Table 15c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituminous coal samples --- from coal bed No. 3, Sand and loo-k-out Mountains, Georgia and Alabama--continue-d -- ---- S~le number S03 Ag-S (percent) (ppm) B-S (ppm) _______ Ba-S (ppm) Be-S (pp, m) Br (ppm) Cd (ppm) Ce (ppm) Co (ppm) Cr (ppm) Sample number w199983 2.8 w199986 7.2 w199987 .97 0.76 110 1.8 190 .58 160 1,100 2,100 930 44 1,000 24 1,600 15 430 0.79 540 250 200 w199983 2.4 180 130 220 w199986 .66 250 62 180 w199987 t-:) -J 0 Table 15c. Major- and minor-oxides and trace-element concentrations fn the laboratory ash of three bftuninous coal s~les - from coal bed No. 3, Sand- and Lookout Mou-ntains, Georgia and Alabama--continued-- -- Sample Cs Cu Dy-S Er-S Eu Ga-S Gd-S Ge-S Hf Ho-S S~le mnber (ppm) (ppm) (pp-m) (ppm) - (ppm) (ppm-) (ppm) (ppm) - (ppm) (ppm) nunber wl99983 5.7 430 wl99986 4.5 500 w199987 23 190 38 19 37 22 22L 12 9.1 55 30 91 6.4 50 37 40 5.2 62 21 35 5.7 9.3 w1999113 9.1 11 w199986 6.2 6.11L w199987 1.>:) .-.1.. Table 15c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of three bituminous coal samples from coal bed No. 3, Sand and lookout Mountains, Georgia and Alabama--continued - Sample La li lu Mn Mo-S Nb-S Nd-S Ni-S Pb Sc Sample number (ppm) (ppm-) - - (ppm) (ppm) ( ppm) (ppm) (ppm) (ppm) (ppm) -(ppm) number w199983 290 310 w199986 91 150 w199987 120 210 2.3 110 38 3.2 130 140 1.9 87 27 20 250 560 110 11 140 210 40 17 160 91 71 70 w199983 68 w199986 46 w199987 t..:l ~ t..:l Table 15c. Major- and mfnor-oKfdes and trace-element concentrations fn the laboratory ash of three bituminous coal samples Sample - from c-o-al-b-ed-N-o.-3-, -Sa-nd and lookout Hountafns, Georgia and Alabama--continued Sm Sn-S Sr-S Ta Tb Th Tl-S u v-s Y-S Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm ) (ppm ) number w199983 46 w199986 32 w199987 23 1.5l 3,300 1.5l 9,100 5.1 1,800 0.20l 1.1 26 .lOL 5.5 18 . 14 3.5 25 3.0L 5.4 350 180 w199983 3.0l 8.2 430 200 w199986 11 6. 9 320 140 wl99987 ~ -l ~ Table 15c. Major- and minor-oxides and trace-element concentrations in the laboratory P.Sh of three bituminous coal samples from coal bed No. 3, Sand and lookout Mountains, Georgia and Alabama--c-o-nt-in-u-ed--------- Sample Yb Zn Zr-S niJtlber (ppm) (ppm) (ppm) w199983 17 450 190 w199986 23 250 230 wl99987 12 76 300 1.\:) -l ~ Table 15d. Content of 22 trace-elements in three bituminous coal samples from coal bed No. 3, Sand and lookout Mountains, Georgia and Alabama. -- (Analysis performed on w-hole-coal. Values in parts-per-mtllion(ppm). l,- -le-ss--th-a-n -th-e value shown; B, not determined). Sample As Ce Cl Co Cr Cs Eu F Hf Hg Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) nu-mber w199983 2.9 w199986 12.6 w199987 8.1 19 590 4.0 610 20 560 8.8 7.1 0.2 0.32 32 2.8 4.9 .1 .14 20l 5.0 14 1.9 .42 36 0.2 0.19 w199983 .2 .040 w199986 .5 .093 w199987 to.:) ....:) Ol Table 15d. Content of 22 trace-elements in three bituminous coal samples from coal bed No. 3, Sand and Lookout Mountains, Geo-rgia and Alabama--continued Sample La Lu Na p Sb Sc Se Sm Tb Th Sample number (p-p-m) (ppm) (ppm) - (ppm) (ppm) (ppm-) -- (ppm) (ppm) -(p-pm) (ppm) number w199983 10 wl99986 2 w199987 10 0.1 73 83 .1 110 9 .2 310 31 0.60 2.4 1.1 1.6 0.3 0.9 wl99983 1.2 1.5 1.3 .70 .1 .4 wl99986 1.3 3.7 1.3 1.9 .3 2.0 w199987 1.\:1 ...;) CJ) Table 15d. Content of 22 trace-elements in three bftumfnous coal samples from coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama--continued Sample number u (ppm) Yb (ppm) w199983 0.19 0.6 w199986 .18 .5 w199987 .56 1.0 t\:) -.:] -.:] Table 15e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from coal bed No. 3, Sand and lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinations on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine method; B, not determined; G, greater than. Sample number is laboratory number). Sample number Si Al Ca Mg Na K Fe Ti Ag-S (percent) (percent) (percent) (percen-t-) (percent) (percent) (percent) (percent) --(p-p-m) As (ppm) Sample number w199983 0.69 w199986 .33 w199987 2.0 0.62 .30 1.3 0.062 0.020 0.007 0.057 0 . 111 .071 .017 .011 .030 . 28 .058 .051 .031 .23 .16 0.020 .012 .060 0.027 2.9 .040 13 .047 8.1 w199983 w199986 w199987 1::-:l -J 00 Table 15e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bit~ninous coal san.,les from coal bed No. 3, Sand and lookout Mountains, Georgi-a and Alabama-conti-n-ue-d- - S~le B-S Ba-S Be-S Br Cd Ce Cl Co Cr cs S~le n~r (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) -(-p-pm-) (ppm) ni.Jlber w199983 3.9 39 w199986 4.2 46 w199987 13 75 2 35 1 36 1 34 0.03 19 590 .05 4. 0 610 .05 20 560 8.8 7.1 2.8 4.9 5.0 14 0.2 w199983 .1 w199986 1.9 w199987 1.-.:1 .o...:J ~ Table 15e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from -- -coal bed No. 3, Sand and lookout Mountains, Georgia and Alabama--continued Sample Cu Dy-S Er-S Eu F Ga-S Gd-S Ge-S Hf Hg Sample number (ppm) (ppm) (ppm) (ppm) -- (ppm) (ppm) (ppm) (ppm) (ppm) !ppm) --n-um-b-er- wl99983 15 w199986 11 wl99987 15 1.3 0.7 .8 .5 1.8l 1.0 0 . 32 32 .14 20l .42 36 1.9 1.1 3.2 0.2 0.19 w199983 1.1 .81 .88 .2 .040 w199986 5.0 1.7 2.8 .5 .093 w199987 !:.:> 00 0 Table 1Se. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from -- coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama-continued Sa~le Ho-S La li Lu Hn Ho-S Nb-S Nd-S Ni-S p Sample ntnber (ppm) (ppm) (ppm) (pp-m) (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) number w199983 w199986 w199987 0.33 10 .24 2 .SSL 10 11 0.1 3.9 1.3 0.70 8.8 20 83 w199983 3.3 .1 2.9 3.1 .24 3.1 4.6 9 w199986 17 .2 7.0 2.~ 1.4 13 7.4 31 w199987 !:-=> .0..0. ( Table 15e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from co-a-l bed No. 3, Sand and lookout Mountains, Georgia and A-la-b-am-a----c-on-t-in-ue-d- Sample Pb Sb Sc Se Sm Sn-S Sr-S Ta-S Tb Th Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) ---n-um-b-er--- wl99983 3.9 0.60 2.4 1.1 1.6 0.05l 120 w199986 .88 1.2 1.5 1.3 .70 .03l 200 w199987 5.8 1.3 3.7 1.3 1.9 .41 150 0.01l 0.27 .COL .12 .01 .28 0.90 .40 2.0 w199983 w199986 w199987 t.:) 00 t.:) Table 15e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of three bituminous coal samples from Sample coal Tl-S bed No. u 3, Sand and look-out v-s Mountains, Y-S Georgia Yb and Alabama--continued Zn Zr-S Sample - - - - - - --- - - - - - - - - - - - - number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (pp-m-) number w199983 O.lll 0.19 12 6.3 w199986 .07L .18 9.5 4.4 w199987 .89 .56 26 11 0.6 16 6.7 w199983 .5 5.5 5.1 w199986 1.0 6.2 24 wl99987 t-,:) 00 0) l Table 15f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for three bituminous coal samples from coal bed No. 3, Sand and Lookout Mountains, Georgia and Alabama--continued (All analyses except Kcal/kg, Btu, free-swelling index, and ash-fusion temperatures in percent. For each sample number, the analyses are reported three ways: first, as-received, second, moisture-free, and third, moisture- and ash-free. All analyses by Coal Analysis Section, Department of Energy, Pittsburgh, Pa.; B, not determined; 1540 for ash-fusion temperatures means greater than 1540 C). Proximate Analysis Ultimate Analysis Heat of Combustion Sample number Moisture Volatile matter Fixed carbon - Ash Hydrogen Carbon Nitrogen Oxygen Sulfur Kcal/kg Btu/lb w199983 w199986 w199987 1.3 20.5 75.1 3.1 4.6 86.1 1.5 4.1 0.6 8,290 14,920 20 . 8 76.1 21.4 78.6 -3.1 4.5 87.2 4.7 90.1 1.5 1.6 3.0 3.1 .6 8,400 15,110 .6 8,670 15,600 1.1 21.8 74.9 2.2 4.8 85.8 1.7 4.7 22.0 75.7 22.5 77.5 -2.2 4.7 86.8 4.8 88.7 1.7 1.8 3.8 3.8 .8 8,430 15,170 .8 8,520 15,330 .8 8, 710 15,680 1.3 20.4 70.9 7.4 4.6 79.8 1.5 6.0 20.7 71.8 22.3 77.7 -7.5 4.5 80.9 4.9 87.4 1.5 1.6 4.9 5.3 .7 7,860 14,150 .7 7,970 14,340 .8 8,610 15,500 1:-:1 00 ~ Table lSf. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling Index, and ash-fusion temperature determinations for three bituminous coal samples from coal bed No. 3, Sand and lookout Mountains, Georgia and Alabama--continued Forms of sulfur Ash fusion temperature, C Sample number Air-dried loss Sulfate Pyritic Free Organic swelling index Initial deformation Softening Fluid w199983 w199986 w199987 0.6 0.01 0.09 o.so s.s .01 .09 .S1 .01 .09 .52 .5 .01 .23 .59 9.0 .01 .23 .60 .01 .24 .61 .7 .01 .17 .49 7.0 .01 .17 . 50 .01 .19 .S4 1,S40 1,240 1,540 1,S40 1,305 1,540 1,S40 1,365 1,540 1:\:) 00 01 Table 16a. Descriptive information for sample numbers, geographic location, and formation and coal bed correlations for two bituminous coal samples from coal bed No. 2, Sand and lookout Mountains, Georgia and Alabama. sample state county latitud longitud formation coal bed rank no. w19,84 georgia dade 345033n 852645w crab orchard mts no 2 bit w199985 georgia dade 345033n 852645w crab orchard mts no 2 bit sample type channel channel sampled thickness (inches) 9.0 6.0 ~:..;) 00 0) Table 16b. Summary statistical table of analytical data for two bituminous coal samples from coal bed No. 2, Sand and lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion temperatures in degrees F. data values item used m--e-an- -st-d-d-e-v -x-m-i-n -xm--ax- -ra-ng-e -ge-o-m-e-a-n geo dev signa zero qual usgsash 2 18.45 6.05 12.400 24.50 12.10 17.43 1.41 8.56 0 0 statistics for following data items on ash basis sio2 2 a12o3 2 cao 2 mgo 2 na2o 2 k2o 2 fe2o3 2 mno 2 tio2 2 p2o5 2 sol 2 33.36 23.61 1.08 0.72 0.23 1.60 32.22 0.02 0.92 0.66 1.35 5.40 5.06 0.42 0.04 0.04 0.37 10.42 0.00 0.10 0.18 0.64 27.960 18.560 0.660 0.680 0.189 1.230 21.790 0.010 0.820 0.480 0.710 38.76 28.67 1.50 0.76 0.27 1.96 42.64 0.02 1.02 0.84 1.99 10.80 10.11 0.84 0.08 0.08 0. 73 20.85 0.01 0.20 0.36 1.28 32.92 23.07 0.99 0.72 0.23 1.55 30.48 0.01 0.91 0.63 1.19 1.18 1.24 1.51 1.06 1.20 1.26 1.40 1.41 1.12 1.32 1.67 7.64 7.15 0.59 0.06 0.06 0.52 14.74 0.01 0.14 0.25 0.91 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 statistics for following data items on "whole-coal" basis ag 2 0.32 0.17 0.149 as 2 516.40 298.60 217.800 there were less than two positive-valued items for au there were less than two positive-valued items forb ba 2 182.02 62.98 119.040 be 2 1.97 0.73 1.240 there were less than two positive-valued items for bi br 2 3.69 0.77 2.923 cd 2 0.26 0.18 0.086 ce 2 43.00 26.00 17.000 cl 2 310.00 80.00 230.000 co 2 9.55 6.95 2.600 cr 2 31.35 15.45 15.900 cs 2 1.55 0.65 0.900 cu 2 88.45 46.30 42.160 there were less than two positive-valued items for dy there were less than two positive-valued items for er eu 2 0.99 0.63 0.360 there were less than two positive-valued items for f ga 2 6.83 1. 75 5.084 gd 2 3.63 1.03 2.604 there were less than two positive-valued Items for ge hf 2 1.00 0.30 0.700 hg 2 0.39 0.07 0.320 there were less than two positive-valued items for ho there were less than two positive-valued items for in there were less than two positive-valued items for ir Ia 2 24.00 14.00 10.000 li 2 82.25 52.50 29.760 lu 2 0.27 0.14 0.130 mn 2 16.40 0.96 15.435 mo 2 8.25 1.06 7.192 nb 2 1.71 0.22 1.488 nd 2 21.26 10.59 10.664 0.49 815.00 245.00 2.69 4.46 0.44 69.00 390.00 16.50 46.80 2.20 134.75 Lilt 8.57 4.65 1.30 0.46 38.00 134.75 0.40 17.36 9.31 1.94 31.85 0.34 597.20 125.96 1.45 1.54 0.36 52.00 160.00 13.90 30.90 1.30 92.59 1.25 3.49 2.05 0.60 0.14 28.00 104.99 0.27 1.92 2.12 0.45 21.19 0.27 421.32 170.78 1.83 3.61 0 . 19 34.25 299.50 6.55 27.28 1.41 75.37 0.76 6.60 3.48 0.95 0.38 19.49 63.33 0.23 16.37 8.18 1. 70 18.43 1.81 1.93 1.43 1.47 1.24 2.27 2.01 1.30 2.52 1. 72 1.56 1. 79 2.11 1.30 1.34 1.36 1.20 1.95 2.13 1.75 1.06 1.14 1.14 1. 73 0.24 422.28 89.07 1.03 1.09 0.25 36.77 113.14 9.83 21.85 0.92 65.47 0.88 2.47 1.45 0.42 0.10 19.80 74.24 0.19 1.36 1.50 0.32 14.98 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 !:.,;) 00 -.J Table 16b. Summary statistical table of analytical data for two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama. Zero and qualified values excluded; ash-fusion temperatures in degrees F--continued. ni 2 20.76 11.09 9.672 31.85 22.18 17.55 1.81 15.68 0 0 there were less than two positive-valued items for os pb 2 25.44 21.10 4.340 46.55 42.21 14.21 3.28 29.85 0 0 there were less than two positive-valued items for pd there were less than two pos it ive-valued items for pr there were less than two pos it ive-valued items for pt there were less than two pos it ive-valued items for rb there were less than two pos it ive-valued items For re there were less than two pos it ive-valued Items for rh there were less than two posi t ive-valued items for ru sb 2 4.90 3.20 1. 700 8.10 6.40 3.71 2.18 4.53 0 0 sc 2 9.66 6.39 3.270 16.05 12.78 7.24 2.22 9.04 0 0 se 2 6.26 2.43 3.830 8.69 4.86 5.77 1.51 3.44 0 0 sm 2 4.65 3.05 1.600 7.70 6.10 3.51 2.19 4.31 0 0 there were less than two positive-valued items for sn sr 2 393.35 170.15 223.200 563.50 340.30 354.65 1.59 240.63 0 0 ta 2 0.04 0.03 0.014 0.06 0.05 0.03 2 . 16 0.04 0 0 tb 2 0.65 0.39 0.260 1.04 0.78 0.52 2.00 0.55 0 0 there were less than two positive-valued items for te th 2 6.40 4.40 2.000 10.80 8.80 4.65 2.32 6.22 0 0 there were less than two positive-valued Items for tl there were less than two positive-valued items for tm u 2 2.02 1.48 0.550 3.50 2.95 1.39 2.52 2.09 0 0 v 2 41.77 21.93 19.840 63.70 43.86 35.55 1. 79 31.01 0 0 there were less than two positive-valued items for w y 2 14.20 6.14 8.060 20.34 12.28 12.80 1.59 8.68 0 0 yb 2 1.65 0.85 0.800 2.50 1. 70 1.41 1.77 1.20 0 0 zn 2 28.34 1.06 27.280 29.40 2.12 28.32 1.04 1.50 0 0 zr 2 25.84 6.00 19.840 31.85 12.01 25.14 1.27 8.49 0 0 statistics for following data items on "as received" basis data values item used -me-an -std-d-ev -xm-in -xm-ax - - range -g-eo--m--e-an- geo dev si~ zero qual btu ashdef ashsof ashfld freswel moistur volmat fixedc bmash hydrogn carbon ni trogn oxygen sulfur sulfate sulfpyr sulforg ad loss 2 12247.00 895.00 11352.000 13142.00 2 2350.00 250.00 2100.000 2600.00 2 2445.00 235.00 2210.000 2680.00 2 2525.00 225.00 2300.000 2750.00 2 6.50 1.00 5.500 7.50 has insufficent variance to calculate statistics 2 19.65 0.75 18.900 20.40 2 62.30 4.50 57.800 66.80 2 16.55 5.25 11.300 21.80 2 4.50 0.30 4.200 4.80 2 69.20 4.50 64.700 73.70 2 1.20 0.20 1.000 1.40 has insufficent variance to calculate statistics 2 4.15 0.25 3.900 4.40 2 0.19 0.02 0.170 0.20 2 3.39 0.00 3.380 3.39 2 0.60 0.26 0.340 0.86 has insufficent variance to calculate statistics 1790.00 500.00 470.00 450.00 2.00 1.50 9.00 10.50 0.60 9.00 0.40 0.50 0.03 0.01 0.52 12214.25 2336.66 2433.68 2514.96 6.42 19.64 62.14 15.70 4.49 69.05 1.18 4.14 0.18 3.38 0.54 1.08 1.11 1.10 1.09 1.17 1.04 1.08 1.39 1.07 1.07 1.18 1.06 1.08 1.00 1.59 1265.72 353.55 332.34 318.20 1.41 1.06 6.36 7.42 0.42 6.36 0.28 0. 35 0.02 0.01 0.37 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 0 ~ CXl CXl Table 16c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. L means less than the value shown; H, interference for an element which cannot be resolved by any routine method; G, greater than; B, not determined; S, after element title indicates determinations are to be -taken as plus 50% a-nd-m-in-us-3-5%-.--Sa-m-ple--nu-mb-er-i-s-la-b-or-at-ory n-um-ber-). - - - - - --------- ------- Sample Ash Si02 Al203 CaD MgD Na20 K20 Fe203 Ti02 P205 Sample number (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) number ------~------~----------- w199984 12.4 28 19 w199985 24.5 39 29 1.5 0.68 0.27 1.2 43 .66 .76 .19 2.0 22 0.82 0.48 w199984 1.0 .84 w199985 1:-:l 00 ~ Table 16c. Major- and minor-oxides and trace-elenent concentrations in the laboratory ash of two bituminous coal samples - - from coal bed No. 2, Sand and lookout Mountains, Georgia and Alabama-continued - Sa!11lle SD3 Ag-S 8-S Ba-S Be-S Br Cd Ce Co Cr Sample nr..rber (percent) (ppm-) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) -(p-pm-) nunber w199984 2.0 1.2 H 960 w199985 .11 2.0 80 1,000 10 190 11 74 0.69 140 1.8 280 21 130 w199984 67 190 w199985 ~ ~ 0 Table 16c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples from co-al bed No. 2, Sand and Lookout Mountains, Georgia and Al-abama--continued -- Sample Cs Cu Eu Ga-S Gd-S Ge-S Hf La Li Lu Sample n....tler (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) n....tler w199984 7.3 340 w199985 9.0 550 2.9 41 21 6.6 35 19 7.4 5.6 81 240 1.5L 5.3 160 550 1.0 w199984 1.6 w199985 .ct.-.:o.1. Table 16c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples from coal bed No. 2, Sand and lookout Mountains, Georgia and Alaba-m-a----continued --- Sample Mn Mo-S Nb-S Nd-S Ni-S Pb Sc Sm Sr-S Ta Sample number (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) - -(-pp-m)- - -n-um-be-r - - w199984 140 58 12 86 78 35 26 13 1,800 w199985 63 38 8 130 130 190 66 31 2,300 0.11 w199984 .26 w199985 1\:) ~ 1\:) Table 16c. Major- and minor-oxides and trace-element concentrations in the laboratory ash of two bituminous coal samples Sample from Tb coal b-e-d -No. Th 2, Sand and u lo-okout v-s Mountains, v-s Georgia and Yb Alabama-conti nued Zn Zr-S Sample number (ppm ) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) number w199984 2.1 16 4.4 160 65 6.5 220 160 w199984 w199985 4.2 4ft 14 260 83 10 120 130 w199985 1c:.o.:1 CA:I . Table 16d. Content of 22 trace-elements in two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama. (Analysis performed on whole-coal. Values in parts-per-million(ppm). L, less than the value shown; B, not determined). Sample number As (ppm) Ce (ppm) Cl (ppm) Co (ppm) Cr (ppm) Cs (ppm-) Eu (ppm) F (ppm) Hf (ppm) Hg (ppm) Sample number w199984 218 w199985 815 17 390 69 230 2.6 16 17 47 0.9 0.36 28 2.2 1.6 20L 0.7 0.46 w199984 1.3 .32 w199985 t-:1 tO ~ Table 16d. Content of 22 trace-elements fn two bitunfnous coal 5a111Jles from coal bed No. 2, Sand and Lookout Mountains, Georgfa and Alabama--continued Sample nunber La (ppm) Lu (ppm) Na (-pp-m) p (ppm) Sb - (ppm) Sc (ppm) Se (ppm) Sm (ppm) - Tb (ppm) Th (ppm) Sample nunber w199984 10 w199985 38 0.1 250 260 .4 340 900 1.7 3.3 3.8 1.6 0.3 2.0 w199984 8.1 16 8.7 7.7 1 11 w199985 1c..o.:1 01 Table 16d. Content of 22 trace-elements in two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama--continued Sample number u (ppm) Yb (ppm) w199984 0.55 0.8 w199985 3.5 2.5 ~ tO 0) Table 16e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from coal bed No. 2, Sand and lookout Mountains , Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinations on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine method; B, not determined; G, greater than. - Sample number is laboratory - -nu-m--b-er-)-. --------------------- Sample Si Al Ca Mg Na K Fe Ti Ag-S As Sample number (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (ppm) (ppm) number w199984 1.6 1.2 0.13 0.051 0.025 0.13 3.7 0.061 0.15 220 w199984 w199985 4.4 3.7 .12 .11 .034 . 40 3.7 . 15 .49 820 w199985 ~ CD -.J f Table 16e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from -- - - coal bed No . .2, Sand and Lookout Mountains, Georgia and Alabama--continued --- Sample 8-S Ba-S Be-S Br Cd Ce Cl Co Cr Cs nunber (ppm) (ppm) (ppm) (ppm) -- (ppm) (ppm) (ppm) - (ppm) (ppm) -(ppm) w199984 H 120 1 24 0.09 17 390 2.6 16 0.9 wl99985 20 250 3 18 .44 69 230 17 47 2.2 Sample n~r w199984 w199985 ~ ~ 00 Table 16e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from - coal bed No. 2, Sand and Lookout M- ountains, GeOrgia and Alabama-continued Sample Cu Eu F Ga-S Gd-S Ge-S Hf Hg La Li n!Dber (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) Sample numer wl99984 42 wl99985 130 0.36 28 1.6 20L 5.1 2.6 0.92 0.7 0.46 10 30 wl99984 8.6 4.7 .37l 1.3 .32 38 130 w199985 c~ ccc Table 16e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from - coal bed No. 2, Sand and lookout Mountains, Georgia and Alabama--continued Sample Lu Hn Ho-S Nb-S Nd-S Ni-S -p Pb Sb Sc nu-mber (ppm) - (ppm) - (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) (ppm) wl99984 0.1 17 wl99985 .4 15 7.2 1.5 11 9.3 1.9 32 9.7 260 32 900 4.3 1.7 3.3 47 8.1 16 Sample number w199984 w199985 ~ 0 0 Table 16e. Major-, minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama--continued Sample number Se (ppm) Sm (ppm) Sr-S (ppm) Ta-S (ppm) Tb (ppm) Th (ppm) u (ppm) v-s (pp-m-) v-s Yb -------- - ---~ -----Sa~le (ppm) (ppm) - -n-um-be-r - - w199984 3.8 w199985 8.7 1.6 220 7.7 560 0.01 0.26 2.0 .06 1.0 11 0.55 20 3.5 64 8.1 0.8 w199984 20 2.5 wl99985 C/.:) 0 ~ Table 16e. Major- , minor-, and trace-element concentrations, on whole-coal basis, of two bituminous coal samples from coal bed No. 2, Sand and Lookout Mountains, Georgia and Alabama--continued Sample mnber Zn (ppm) Zr-S (ppm) wl'.1'.1984 27 20 wl99985 2'.1 32 ~ 0 t.:> Table 16f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for two bituminous coal samples from coal bed No. 2, Sand and lookout Mountains, Georgia and Alabama--continued (All analyses except Kcal/kg, Btu, free-swelling index, and ash-fusion temperatures in percent. For each sample number, the analyses are reported three ways: first, as-received, second, moisture-free, and third, moisture- and ash-free. All analyses by Coal Analysis Section, Department of Energy, Pittsburgh, Pa.; 8, not determined; .1540 for ash-fusion temperatures means greater than 1540 C). ------ Proximate Analysis Ultimate Analysis . Heat of Combustion Sample number Volatile Fixed Moisture matter carbon Ash Hydrogen Carbon Nitrogen Oxygen Sulfur Kcal/kg Btu/lb w199984 w19998S l.S 20.4 20.7 23.4 66.8 67.8 76.6 1u-1..s3 4.8 73.7 4.7 74.8 S.3 84.5 1.4 1.4 1.6 4.4 3.1 3.5 4.4 7,300 13,140 s4..o5 7,410 8,370 13,340 1!i,D70 l.S 18.9 57.8 21.8 4.2 64.7 1.0 4.4 3.9 6,310 11,350 19.2 24.6 58.7 75.4 2-2.1 4.1 65 . 7 5.3 84.4 1.0 1.3 3.1 4.0 4.0 6,400 11,520 S.1 8,220 14,800 Cl' 0 Cl' Table 16f. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for two bituminous coal samples from coal bed No. 2, Sand and lookout Mountains, Georgia and Alabama--continue-d----------- Forms of sulfur Ash fusion temperature, C Sample n!Dber Air--dried loss Sulfate Pyritic Free Organic swelling index Initial deformation Softening Fluid w199984 w199985 0.6 0.17 3.39 0.86 7.5 .17 3.44 .87 .19 3.89 .99 .6 .20 3.38 .34 5.5 .20 3.43 .35 .26 4.41 .44 1,150 1,425 1,210 1,470 1,260 1,510 Col) 0 ~ Table 17a. Descriptive information for 58"1lle nunbers, geographic location, and formation and coal bed correlations for one bittninous coal Sa111Jle from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama. sa!11lle state county latitud longHud formation coal bed rank Sa111Jle S8111lled no. type thickness (inches) w212564 georgia walker 345115n 852625w crab orchard mts no 1 bit channel 25.0 ~ 0 01 Table 17b. Major- and minor-oxides and trace-element concentrations 1n the laboratory ash of one bituminous coal sample from coal bed No. 1, Sand and lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. Coal ashed at 525 C. l means less than the value shown; H, interference for an element which cannot be resolved by any routine method; G, greater than; B, not determined; S, after element title indicates - - determi~ations are to be taken as plus 50% and minus 35%. Sample number is laboratory number). Sample Ash Si02 A1203 CaD HgO Na2D K20 Fe203 1102 P205 Sample number (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) (percent) number w212564 10.2 4') 2') 2.6 1.4 0.4') 2.2 3.') 1.2 2.8 w212564 0, 0 0) Table 17b. Major- and minor-oxides and trace-element concentrations in the laboratory ash of one bituminous coal sample from coal bed No. 1, Sand- and Lookout Mo-u-n-tains, Georgia and Alabama-continued Sample SD3 Ag-S 8-S Ba-S Be-S Br Cd Ce Co Cr Sample nu-mber (percent) (ppm) (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) (ppm) number w212564 2.7 0.13 350 1,500 11 150 0.24 240 25 150 w212564 c;., 0 ....:J Table 17b. Major- and minor-oxides and trace-elenent concentrations in the laboratory ash of one bituminous coal sample from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama--continu-e-d---------- Sanple cs Cu Eu Ga-S Ge-S Hf La Li Lu Mn Sanple nunber (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) nunber w212564 15 70 4.0 32 3.0 7.8 110 270 1.0 80 w212S64 ~ 0 00 Table 17b. Major- and minor-oxides and trace-element concentrations in the laboratory ash of one bituminous coal sample from coal bed No. 1, Sand- and lookout Mountains, Georgia and Alabama--continued. Sample Mo-S Nb-S Nd--S Ni-S Pb Sc Sm Sn-S Sr-S Ta Sample number (ppm) (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) (ppm) (ppm) number w212564 15 36 110 47 92 35 18 3.4 5,000 0.25 w212564 ~ 0 cr> f Table 17b. Major- and minor-oxides and trace-element concentrations in the laboratory ash of one bituminous coal sample from coal bed No. 1, Sand and lookout Mountains, Georgia and Alabama--continued Sa~le nuriler Tb ( ppm) Th (ppm) u (ppm) v-s (ppm) H-S (ppm) Y-S (ppm) Yb (ppm) Zn (ppm) Zr-S (ppm) S~le number w212S64 2.S 28 l3 230 0.6 81 8.8 52 420 w212S64 C...A...j 0 Table 17c. Content of 22 trace-elements in one bituminous coal sample from coal bed No. 1, Sand and lookout Mountains, Georgia and Alabama. -- (Analysis performed on whole-c-oal. Values in parts-per-million(ppm). l, less than the value shown; 8, not determined). Sample As Ce Cl Co Cr Cs Eu F Hf Hg Sample number (ppm) (ppm) --(p-pm-) - - -(p-pm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) mnber w212564 2.2 24 410 2.6 1'5 1.5 0 . 41 160 0.8 0.16 w212564 c.J .............. Table 17c. Content of 22 trace-elements in one bituminous coal sample from coal bed No. 1, Sand and lookout Hountains, Georgia a-nd Alabama--continued-. - Sa~le La lu Na p Sc Se Sm Tb Th u n!JIIber (ppm) (ppm) (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) (ppm) - (ppm) Sample nunber w212564 11 0.1 370 1,200 3.5 0.9 1.8 0.3 2.9 1.3 w212564 ~ ~ t-:1 Table 17c. Content of 22 trace-elements in one bituminous coal sample from coal bed No. 1, Sand and lookout Mountains, Georgi a and A1abama--cont i nued. Sample number Yb (ppm) w212564 O.CJ c,., ....... c,., A Table 17d. Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from coal bed No. 1, Sand and lookout Mountains, Georgia and Alabama. (Values in percent or parts-per-million. 22 elements are from direct determinations on whole-coal; all other elements calculated. H, interference for an element which cannot be resolved by any routine method; B, not determined; G, greater than. Sample number is laboratory number). Sample Si AI Ca Mg Na K Fe Ti Ag-S nurber -(-per-ce-nt-) -(p-ercent) (percent) (percent) (percent) (percent) (percent) (percent) (ppm) As (ppm) Sample nurber w212!i64 2.4 1.6 0.19 0.087 0.037 0.19 0.27 0.076 0.013 2.2 w212!i64 C/.:1 1-' ~ Table 17d. Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from - coal bed No. 1, Sand and lookout Mountains, Georgia and Alabama--continued. Sample 8-S Ba-S Be-S Br Cd Ce Cl Co Cr Cs number (ppm) (ppm) (ppm) (ppm) - (ppm) (ppm) -- (ppm) (ppm) (ppm) (ppm) w212564 36 150 1 15 0.02 24 410 2.6 15 1.5 Sample number w212564 .t....:..l. 01 Table 17d . Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama--continued. - Sample Cu Eu F Ga-S Ge- S Hf Hg La Li Lu number (ppm) (ppm) (ppm-) (ppm) (ppm) (ppm) (ppm) -(ppm) (ppm) (ppm) w212564 7.1 0.41 160 3.3 0.31 0.8 0.16 11 28 0.1 sa,.,le number w212564 co I-" 0) Table 17d. Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bft~ninous coal SaJlllle from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama--continued. SaJlllle Hn -nln-b-er - (ppm) Ho-S (pp-m) Nb-S (ppm) Nd-S (ppm) Ni-S (ppm) - p (ppm) Pb (ppm) Sc (ppm) Se Sm -(p-p-m)--- (ppm) w212564 8.2 1.5 3.7 11 4.8 1,200 9.4 3.5 0.9 1.8 SaJlllle nlnber w212564 ~ ....... -J Table 17d. Hajor-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from Sample -- coal bed No. 1, Sand and lookout Mountains, Georgia and Alabama---co-n-ti-nued. H-s Sn-S Sr-S Ta-S lb Th u v-s v-s- - - -- -- - - - Vb Sample - --- number (ppm) (ppm) (ppm) (ppm) -(ppm) (ppm) (ppm-) (ppm) (ppm) (ppm) --- number w212564 0.35 510 0.03 0.25 2.9 1.3' 23 0.06 8.3 0.9 w212564 .c...:.>.. 00 Table 17d. Major-, minor-, and trace-element concentrations, on whole-coal basis, of one bituminous coal sample from coal bed No-. -1, Sand and-lookout Mountains, Georgia and Alabama--c-ontinued. Sample Zn Zr-S nl.'Tber (ppm) (ppm) w212564 5.3 43 co ~ (.0 Table 17e. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-swelling index, and ash-fusion temperature determinations for one bituminous coal sample from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama--continued. (All analyses except Kcal / kg, Btu, free-swelling index, and ash-fusion temperatures in percent. For each sample number, the analyses are reported three ways ; first, as-received, second, moisture-free, and third, moisture- and ash-free. All analyses by Coal Analysis Section, Department of Energy, Pittsburgh, Pa.; B, not determined; 1540 for ash-fusion temperatures means greater than 154-0 -C-).--------- Proximate Analysis Ultimate Analysis Heat of Combustion Sample number Volatile Fixed Moisture matter carbon Ash Hydrogen Carbon Nitrogen Oxygen Sulfur Kcal/kg Btu/lb w212564 1.5 20 . 4 68.3 9.8 4.4 78.7 1.5 4.1 1.5 7,660 13,790 20.7 23.0 69.3 77.0 10.0 -- 4.3 79.9 4.8 88.7 1.5 1.7 2.8 3.1 1.5 7,770 13,990 1.7 8,630 15,540 "'1:.:> 0 Table 17e. Proximate and ultimate analyses, heat content, forms-of-sulfur, free-Sllelling index, and ash-fusion ten.,erature determinations for one bituninous coal s~le from coal bed No. 1, Sand and Lookout Mountains, Georgia and Alabama--continued. Forms of sulfur Ash fusion temperature, C Sa~le nunber Air~ried loss Sulfate Pyritic Free Organic swelling index lnitia1 deformation Softening Fluid w212!i64 0.!5 0.17 0.06 1.2!5 9.0 .17 .06 1.27 .19 .07 1.41 1,42!5 1,480 1,!50!5 C/.:1 t.:> ~ ....... $ S7 56/ ) 00