GEORGIA STATE DIVISION OF CONSERVATION DEPARTMENT OF MINES, MINING AND GEOLOGY GARLAND PEYTON, Director THE GEOLOGICAL SURVEY Information Circular 18 SOURCE AND QUALITY OF GROUND WATER IN SOUTHWESTERN GEORGIA by Robert L. Wait ATLANTA 1960 GEORGIA STATE DIVISION OF CONSERVATION DEPARTMENT OF MINES, MINING AND GEOLOGY GARLAND PEYTON, Director THE GEOLOGICAL SURVEY Information Circular 18 SOURCE AND QUALITY OF GROUND WATER IN SOUTHWESTERN GEORGIA by Robert L. Wait ATLANTA 1960 Prepared in cooperation with the United States Department of the Interior, Geological Survey, Water Resources Division, Ground Water Branch CONTENTS Introduction --------------------------------------------------Location of area -----------------------------------------Previous investigations ----------------------------------Supervision and acknowledgments --------------------------- Geology and geochemical properties of aquifers ----------------Upper Cretaceous rocl<.s ------------------------------------ Clayton formation ----------------------------------------vlilcox group ---------------------------------------------Claiborne group ------------------------------------------Ocala limestone ------------------------------------------Oligocene series -----------------------------------------Miocene series -------------------------------------------Principal artesian aquifer -------------------------------River-terrace deposits -----------------------------------Pu~page --------------------------------------------------Guality of water -----------------------------------------Suitability of ground water for irrigation ---------------- Method of sampling ---------------------------------------Constituents ---------------------------------------------Conclusions ----------------------------------------------Selected references -------------------------------------------- Appendix ------------------------------------------------------Records of chemical analyses and well-constructi(Xl infonnation -----------------------------------------Index ---------------------------------------------------------- Page 1 2 4 5 6 6 11 12 12 13 14 15 15 16 16 20 23 28 32 39 40 42 43 73 ILLUSTRATIONS Figure l. Map showing location of area and physiographic provinces ------------------------- 3 2. Nap showing locations of wells sampled and aquifers which they tap ------------------------- 17 3. \.Jell locations, showing the amounts of certain chemical constituents in ground water ----------- 22 4. Suitability of selected ground waters for irrigation in southwestern Georgia -------------- 25 TABLES Table 1. Generalized table of deposits in southwestern Georgia ----------------------------------------- 7 2. Nunicipal pumpage in southwestern Georgia ------------ 19 ]. Sodium-adsorption-ratio and specific conductance cf ground ;.raters in southwestern Georgia -------- 26 4. Classification of irrigation waters ------------------ 29 Source and quality of ground water in southwestern Georgia By Robert L. Wait INTRODUCTION A quality-of-water sampling program was begun in 1957 in Georgia by the U. S. Geological Survey in cooperation with the Georgia Department of Mines, Mining and Geology. The purpose of this program is to determjne the quality of water in various aquifers and the changes in quality of ground water that occur with time. The sampling program will be continued in the future. However, the analyses made during the first year of the program are valuable to those who are concerned with the planning of city, industrial, and irrigation supplies who may require water of a certajn quality. It is intended to present this portion of the first year's work as an aid to those people who heve need for such dat.a. The analytical program carried out in southwestern Georgia included municipal supplies in 28 cities located in 25 counties, and one sample from an industrial well. A municipal supply in each of the counties in the area was sampled. The wells from which water samples were obtained were usually those for which drill cuttings are available. The drill cuttings are filed in the sample library of the Georgia Geological Survey. By sa:mp1:lng wells for which a record of the geologic formations penetrated is available, the quality of the water frcm the well can be related to the rock type and to the geologic formation. 1 Constructional data for each well were obtained so far as records and memories permitted. The depth of a well alone is not indicative of the zone or zones frcm which water is obtained. It is also necessary to know the location of open hole or screened zones and other constructional features. The constructi.on data are listed with the chemical analyses. Data are presented to show the amount of water pumped by each municipal supply. In cities where the water was not metered, an estimate of water consumption was made, based on the population served by the supply and a conservative per capita consumption of 100 gallons per day. l.lcation of area The area discussed in this report is in the Coastal Plain of Georgia and includes 25 counties coverine an area of approximately 9,800 square miles (fie. 1). The topographic divisions of the Coastal Plain in the area include parts of the Fall Line Hills and the Tifton Upland, and the fuugherty Plain. 2 N I SCALE 25 0 25 50 MILES c-=:~-===-:._:_::]1-- Figure I -Map showing location of area and physiographic provinces 3 Previous investigations The first ground~ater investigation in Georgia was that of McCallie (1898). Several chemical analyses of waters from springs and wells are listed in his report. A second report by McCallie (1908) also listed chemical analyses of ground waters. The zoost comprehensive ground-water report on the Coastal Plain is that of Stephenson and Veatch (1915). One or roore chemical analyses of water are listed for zoost of the counties of the Coastal Plain, and an entire section is devoted to a discussion of the quality of both grou:.1d and surface waters. A comprehen.sive report (Collins a:1.:l others, 1934) on the quality of water in the United States contains m1alyses of 14 mu.11icipal supplies in Georgia. Lamar (1942) dis- cussed the quality of water in Georgia and listed analyses of the supplies of most of the larger cities of the Stat.e. A zoore recent report of the same nature is Water-Supply Paper 1299 (1954), which contains analyses of the supplies for many of the larger cities in Georgia. Chemical analyses of grounci waters are found in all the Georgia Geological Survey bulleti.."l.s concerning the groW1d-l:ater resources of the State. Many of these reports rnny be consulted at libraries throughout the State. A list of selected references is at the end of this report. Supervision and acknowledgments This report was prepared by the U. S. Geological Survey in cooperation with the Georgia Department of Mines, Mining and Geology, Garland Peyton, Director. Ground-water investigations in the United States are under the general supervision of P. E. LaMoreaux, Chief, Ground \-later Branch, and in Georgia are under the direct supervision of J. T. Callahan, District Geologist. The chemical analyses were made by the Quality of Water Laboratory of the U. s. Geological Survey, Ocala, Fla., under the supervision of J. w. Guerin, District Chemist. s. M. Herrick, Staff Stratigrapher, Atlanta, Ga., furnished much of the information regarding the geologic formations penetrated by various wells. The cooperation of the superintendents of the various water systems, who assisted in obtaining water samples and who furnished pumpage and well-construction data, is gratefully acknowledged. Thanks are also due Messrs. Jolm David and Jack Carlson of the Layne-Atlantic Co., Albany, Ga., who kindly furnished well-construction data for several of the wells that were sampled. 5 GEOLOOY ANJ GEOCHEMICAL PROPERTJES OF AQUIFERS The Coastal PlaL~ of Georgia is the part of the State south of the Fall Line, a line or zone extending from Columbus through Macon, Milledgeville, and August.a. It includes nearly 35,000 squ'~-*sediments of Oligocene age are thin or absent, and that the Hawthorn formation of Miocene age rests directly on the Ocala limestone." It is now known that limestones of Miocene and Oligocene age are present in the Coastal area of Georgia where the principal artesian aquifer was defined by Warren. Accordingly, the principal artesian aquifer, redefined, is now considered to be composed of limestones of late Eocene, Oligocene,and Miocene age. 15 Wells that produce water from the principal artesian aquifer are shown on figure 2. Analyses from $ylvester, Tifton, Moultrie, Cairo, Thomasville, Quitman, and Valdosta illustrate the chemical quality of ground water from the principal artesian aquifer, as wells in these cities obtain ground water from part or all of it. River-terrace deposits Terrace deposits are present along most of the major rivers of the state, but are too far above the rivers in most places to be recharged by them. It is possible, however, that in the areas above dams, adjacent to ponded water, the sand and gravel of the terraces may yield water to wells. In the area above the Jim Woodruff dam the terraces are flooded by ponded water along both the Chattahoochee and Flint Rivers. Terraces along the Flint River are flooded to the vicinity of Bainbridge, Decatur County. No wells are known to derive water from the terrace deposits, but the possibility that they may be a source of ground water should not be overlooked. Pumpage Figure 2 shows the location of municipal supplies sampled and the aquifer from which the water was obtained. In the northwestern part of the area, ground water is usually obtained from the Upper Cretaceous rocks. Throughollt most o.f the Dougherty Plain ground water is obtained from the Ocala limestone, the Claiborne group, and the Clayton formation. In the Tifton Upland the principal artesian aquifer is the main source of ground water. 16 _,--------, / ' r: / ,-----.J ~...._\ D 0 0 L Y ! rmer~cus .'1 ev,enno rillS U t>IOinS T E R ~- __ --------1 {, I "- {_"-----"---, eorgetow~ : --1 ___ _r~ .. esl1e \ C R-;or~el; : -~-s;;!t1v;il(;- 1 Bronwooi. --'\ }_..__ ~-~ \ -~-.r--,J .ruthbert l! E~~~ fj <' "': ____ _j \ ' RA ND0 L PH ~ l ( L E / L._, ___ \, \ , 1 Leesburg \ /'>-'v'-",'__ ____L __ . __/ , J \ T U"N E R . !1' shburn j L . ._ 1 Fort Go,nes < oCIT ! 0 Gt-=.~.-g- eto'i,_wc~,.._-----"--- __, : Plains ~ _ . ll c s __ 1 5.5 N ___, t720.2 I ~ - -114 137 Smi t h 0 v Leshe ilie--- \ ' ~ .Cordele 160 R I p ,.ru.. L_! OUITMAN 1 12 .- -~-~-,--15S cuthbert ~Bronwood \ o.o jl4~ 0 ,...!Z. ERR ELL J 81 13 oawson f L E E )._..,_ . "\,. ',.\.J :----1 . --~ _~\ \ 1 'RANDOLPH\116 0 11. 249 :' / 1_!i Leesburg \ , 1 T U ~RANshbEurnR \ ' L--r---~- -,----~4___ 9J~ ~ I~ 20' \ ,.!...!.!.. .ll. 9; , l .,___ \ <'251 F o r t"'1Ga~ mes~ <~ . Edoson 161 ~- ------,-)CAL H 0 U N ' Albanyo..-" \ ( ') D Merck and 0 UGH E RCoT. 2~~38-'c' W0 RT H 1 8 i43 iSQSylvester -~ ' -- --"t ~ T I F T '--, , - r .li.. 'L. ___ T - - ,rJ.______ ~ 1M-{ .~ Q;!,Tifton' 134 J ..ll.. Blakely 214 E A R L Y I , j' rf BAKNeEwtoRn~ _,_,.~- l 1 I I T6l r'' .~------..r-L' --,-" - ' ....1 - - l 1 : ---~~- ~ I I ...!..Q_ Colquitt I 125 0 "3'ioi4 .) Ml TCHELL ; "'TT'r' ..Q.,!, .ll.Q. Camilla ,/V 140 'j C0 L0 ..f.Q}. O I, '\ 1 UIT T \ . . (C 0 0 K '... , 1 <( L- _ _ I L M 1 ___ L _ L ER ;r_..,r-- _j - ( i -,-----~--~ 448 Moultne 761 ( i9818 Adel ( f..-_~9 .'\ i l \ ___ ...:. ___l Donals~nville [ ~-----l-----' I I "'---- SEl~'4i~'ZoN6OLE1(,1~ M0...EBCainAbrTidgUe R I . r f 124 r- . ---------- J. -=:__-k..._ ___ i - ' G R A ov 255 ' 355 Cairo 1 "60'5 I T HoMA s 182 'zoo Thomasville ~ ! ~ -~_ L o wN o E s~ B R 0 0 K 7-:~, _ J f , 1.2 ill.. a .t . ...!_Valdosta 105 I I ! 154 Ul ma"\. _______ j _________ j_ _ _ _ - __ _IJ F L A N t SCALE 10 0 10 201.11LES Parts per million 1.5 Sulfate J!.Q_Hordness as CoC03 103 Dissolved solids Figure 3 -Well locations, showing the amounts of certain chemical constituents 1n ground water. 22 Suitability of ground water for irrigation The suitability of water for irrigation is determined by the amount and kind of mineral matter dissolved in the water and by the sodium-adsorption-ratio (SAR). (See table 3.) The mineral matter in the water is indicated roughly by the electrical conductivity of the water. In general the conductivity of water increases with increased amounts of dissolved material. The amount of increase depends upon the kind and amount of material that is added to the solution. Not all substances increase the conductivity by the same amount for an equal amount of the substance added. The conductivity can be used in a general.way to indicate the amount of material dissolved in the water but cannot be used to determine any individual constituent present. The conductivity of water varies according to the temperature, and for this reason all conductivity measurem&~ts are referred to a standard temperature of 2SOc. The sodium-absorption-ratio (SAR) is (a ratio) related to the amount of sodium adsorbed by soil to which the water is added and is determined according to the following formula: SAR: Na + Mg Ca 2 where the concentration of the constituents is given in equivalents per million. 23 Of the 30 water samples analyzed, only 3 appear to be unsuitable for irrigation. These are the waters from wells at Cairo, Moultrie, and Georgetown. The waters from Cairo and Moultrie have a low sodium hazard but a high salinity hazard (fig. 4). The water from the Georgetown well has a meditlm salinity hazard and a very high sodium hazard. The water sample from the Fort Gaines well has a medium salinity hazard and a medium sodium hazard. This type of water can be used in coarse-textured, moderately well leached soils. Table 3 lists the SAR and specific conductance for each of the water samples. These data may be used to determine the suitability of each water sample for irrigation. Figure 4 shows the suitability of 9 water samples. The remaining values of SAR and specific conductance were not plotted on this diagram, as the,y are very closely grouped in the range "low" to "medium" salinity hazard, and 11low11 sodium hazard. The values that are plotted give the extreme range of ground waters sampled during the investigation. 24 100 30 28 26 I (.!) f'(') I (/) 24 22 0 0:: (\J 0 0 (/) 20 0 1- 0 0 (/) 10 8 3; 0 _J (/) 4 2 3 4 5 6 7 8 1000 Georgetown 0 Fort Gomes 4 5000 10 V1enno Sm1thville ~-L--'~--~o~o ______ --'L--+~--~~~-L-L~~~-------L~---L--~~0 IOC 250 750 2250 CONDUCTIVITY (micromhoslcm at 25c) Cl LOW C2 MEDIUM C3 HIGH C4 VERY HIGH SALINITY HAZARD Figure 4- Suitability of selected ground waters for irrigation 1n southwestern Georgia 25 Table 3.--Sodium-adsorption-ratio and specific conductance of ground waters in southwestern Georgia City Adel Albany Americus Ashburn Bainbridge Blakely Bronwood Cairo Camilla Colquitt Cordele Cuthbert Dawson Donaldsonville Edison Fort Gaines Georgetown Leesburg Leslie Moultrie Sodium-adsorption-ratio (SAR) .1 2.0 .1 .1 .1 .9 .4 1.1 .1 .1 .1 .1 3 .1 .5 8.7 27 .1 .o .8 Specific conductance (micromhos at 25C) 399-:~- 362* 240 164 201 222 249 219 261 254 249 250 251 403~:- 497-:i240 21)~ 966-:f- 26 Table 3---continued City Merck and Company Newton Plains Quitman Smithville Sylvester Thomasville Tifton Valdosta Vienna Sodium-adsorption-ratio (SAR) .1 3 .1 .1 .4 .1 .2 .1 .o .l Specific conductance (micromhos at 25C) 239 218 150 268 294 418-~ 146 149 254-Y<- * These values plotted in figure 4. Table 4 lists a classification of irrigation waters according to the U. s. Salinity Laboratory staff (1959). This classification can be used to determine the suitability for irrigation of the ground waters listed in the appendix and in tablF 3, The water obtained from the Miocene, Oligocene, and Eocene limestones and sands and from limestone of the Clayton formation appears to be the best suited for irrigation. The water from the Upper Cretaceous series is high in sodium but may be used with caution in some areas. In the vicinity of the \'Jithlacoochee anticline the ground waters appear to be too saline for irrigation. However, it is possible that suitable water can be obtained at a shallower depth. Method of sampling The samples taken during this investigation were collected in pyrex glass bottles. It has been found that if water samples are collected in ordinar~y glass jugs, the reaction of ~~e water with the glass tends to increase the amount of silica present in the sample (Collins and Riffenb~g, 1923). A separate 6-ounce s~mple was collected for the determination of iron. This sample bottle was filled completely and capped tightly to prevent oxidation of the iron in the water. The sample was filtered into the bottle through a fiber-glass fiter to remove all solid particles. The iron reported by the analyst represents that which was in solution in the water at the time of collection. 28 Table 4.--Classification of irrigation waters* Conductivity Low-salinity water, (C-1) can be used for irrigation with most crops on most soils with little likelihood that soil salinity will develop. Some leaching is required, but this occurs under normal irrigation practices except in soils of extremely low permeability. Medium-salinity water, (C-2) can be used if a moderate amount of leaching occurs. Plants with moderate salt tolerance can be grown in most cases without special practices for salinity control. High-salinity water, (C-3) cannot be used on soils with restricted drainage. Even with adequate drainage, special management for salinity control may be required and plants with good salt tolerance should be selected. Very high salinity water, (C-4) is not suitable for irrigation under ordinary conditions, but may be used occasionally under very special circumstances. The soils must be permeable, drainage must be adequate, irrigation water must be applied in excess to provide considerable leaching, and very salt-tolerant crops should be selected. 29 Table 1;..--continued Sodium Low-sod~~~ water, (S-1) can be used for irrigation on almost all soils with little danger of the development of harrr~ul levels of exchangeable sodium. However, sodimn-sensitJ.ve crops such as stone-fruit trees and avocados may accumulate injurious concentrations of sodium. Medium-sod~~ water, (S-2) present an appreciable sodium hazard in fine-textured soils having high cation-exchange-capacity, especially under low-leaching conditions, unless gypsum is present in the soil. This water may be used on coarse-textured or organic soils with good perrneabi1 i ty. High-sodium water, (S-3) may produce harmful levels of exchangeable sodium in most soils and will require special soil management--good drainage, high leach:i.ng, and organic matter additions. Gypsiferous soils may not develop harmful levels of exchangeable sodium, except that amendments may not be feasible with waters of very high salinity. Very high sodium water, (S-4) is generally unsatisfactory for irrigation purposes except at low and perhaps medium salinity, where the solution of c~lcium from the soil or use of gypsum or other amendments may make the use of these waters feasible. -:~United States Department of Agriculture, 1954, Agriculture Handbook No. 60 30 The water samples are thought to be representative of the waters usually yielded by the wells from which the.y are drawn. It has been shown, however, (Sayre and Livingston, p. 81-83; Piper and Garrett, p. 41) that wells which produce water from several zones yield a mixture of waters that may change in chemical composition as the well is pumped. This is especially true if such a well is gravel packed. When the well is idle, water from the zone of highest head flows intc the zones of lower head. Consequently when the well is pumped after being idle for a time it produces water that is native only to the zone of highest head. After this water has been discharged from the well, the quality of water changes as each water-bearing zone begins to yield water that is native to it, and the resulting mixture from the well is a combination of the types of waters in the various water-bearing zones. The mixture produced at a particular pumping rate is proportional to the ability of each of the zones to yield water under the head conditions in the different zones at that rate. Accordingly, to be sure to obtain a representative water sample for analysis, it is necessary to lmow the normal routine of pumping, when and for how long the well was last pumped, and the constructional features of the well. 31 Constituents The concentration of the constituents in water are expressed in parts per million (ppm) and equivalents per million (epm) to show the relative and absolute concentrations of the materials present. The concentration of any constituent in grains per u. s. gallon (gpg) can be obtained by multiplying values in parts per million by 0.058. The following discussion of the constituents is adapted largely from Water-Supply Paper 658 (Collins, Lamar, and Lohr, 1934). Silica (Si02).--Silica is dissolved from practically all rocks. Its state in natural water is not definitely known, but it is assumed to be in the colloidal state, and to take no part in the equilibrium of water. Silica in water forms scale in boilers. All the samples taken for analysis were collected in pyrex bottles to avoid an increase in silica due to the action of water on ordinary glass. Iron (Fe).--Iron is dissolved from practically all rocks and is often dissolved from iron pipes, pumps, and iron storage tanks. Separate 6-ounce bottles of water were collected and analyzed for iron. These samples were filtered through a fiberglass filter at the time of collection to remove most of the iron particles suspended in the water. When iron is present both in solution and suspension and has been precipitated by oxidation it is not possible to determine how much was in solution at the time the sample was collected. The iron reported here is that which was in solution at the time of collection. 32 water that contains excessive iron stains objects with which it remains in contact, turning them red or reddish brown. Excessive iron may also interfere with the efficient operation of exchange-silicate water softeners. Iron may be removed from water by aeration of the water, followed by settling, or filtration. The pH of the water may require adjustment to reduce its corrosiveness. Calcium (Ca) and magnesium (Mg) .--Calcium and magnesium cause hardness in water. They make up most of the dissolved mineral matter in hard waters. Both calcium and magnesium are dissolved from limestone. Dolomitic limestone is a source of much of the magnesium dissolved in water in some parts of the Coastal Plain of Georgia. Gypsum (calcium sulfate) also may contribute considerable amounts of calcium to water. Some other effects of calcium and magnesium are discussed under "Hardness.,. Sodium (Na) and potassium (K).--Sodium and potassium are dissolved from most of the rocks of the earth. These two elements make up a small percentage of the dissolved constituents in water from the Tertiary formations of Georgia but are found in increasing amounts in water from the Upper Cretaceous rocks. These latter rocks contain much feldspar which is the source of some of the sodium. Sodium may also be in water as a result of contamination by sea water. Sea water that was present in rocks at the time of deposition and has not been flushed out is a source of sodium in ground water. Sodium and potassium in water have little effect on the use of the water for most domestic purposes. Water that is high in sodium is usually not suitable for irrigation. 33 Bicarbonate (Hco3) and carbonate (co3).--The bicarbonate present in natural waters is the result of the action of carbon dioxide dissolved in water upon the carbonate rocks with which it comes in contact. A small amount of carbonate reported in some waters may be the result of the action of the water sample upon the bottle (Collins and Riffenburg, 1923). However, this was avoided here by the use of pyrex glass bottles. Bicarbonate is the principal acid radical in most ground waters from the Tertiary formations of Georgia, and also in most of the Upper Cretaceous formations. Sulfate (S04).--Sulfate is dissolved from many rocks of the earth. Some of the main sources are sulfides of iron, such as pyrite and marcasite, and gypsum. Pyrite is common in many of the limestones of Georgia and also in some of the sands. Water that bBs dissolved gypsum may contain more sulfate than bicarbonate. Sulfate in hard water affects the formation of scale in boilers. Sulfate is usually low or absent in the Ocala limestone in the area of outcrop and for some distance downdip from the outcrop. The maximum amount of sulfate determined in this study was 405 ppm in one of the well waters of the supply of Moultrie. However, water from the abandoned well in Valdosta was reported to contain more than 1,000 ppm. Chloride (Cl).--Chloride is dissolved in small quantities from rocks of the earth. Water that is contaminated by sea water may contain large quantities of chloride. Sewage and industrial wastes may increase the quantity of chloride in some waters. Large quantities of chloride salts in water make the water corrosive. Water that contains excessive amounts of chloride is not suitable for irrigation. 34 Fluoride (F).--Fluoride is present in rocks of the earth in small quantities. In some areas of the eastern United States ground waters contain concentrations of as much as 15 ppm of fluoride, as in parts of the Atlantic Coastal Plain in Virginia and the Carolinas and of the Gulf Coastal Plain in Texas and Arkansas. Only small quantities of fluoride, generally less than 1 ppm, are present in the ground waters of the Coastal Plain in Georgia. According to the U. s. Public Health Service (Dean and others, 1941) about 1.0 ppm in water inhibits dental caries (decay) in the teeth of children. In an evaluation of the fluoridation program of Athens, Ga., Chrietzberg and Lewis (1957) stated, "***A dramatic reduction in dental caries of the permanent teeth can be observed in children up to 13 years of age, with the younger ages showing the greatest benefit". Nitrate (No3 ).--The presence of nitrate in water may result from pollution of water by organic substance, or to solution of nitrate from rocks. Nitrate in small amounts usually can be considered a natural constituent of water, but if it is present in unusual amounts it may indicate pollution of the water. Nitrate is one of the oxidation products of organic matter such as sewage. Nitrate is commonly high in water from dug wells, which are rapidly becoming a thing of the past in some parts of Georgia. Excessive amounts of nitrate in drinking or formula water of infants may cause methemoglobinemia ("blue babies") (Waring, 1949). 35 Hardness.--Hardness of water is the characteristic that is most noticed by all users. It prevents soap from lathering. Hardness is caused principally by calcium and magnesium and is reported in terms of equivalent calcium carbonate (Caco3). The hardness of a water may be calculated by multiplying the parts per million of calcium by 2.5 and that of magnesium by 4.1, the sum of which products represents the hardness as caco3 in parts per million. The hardness caused by calcium and magnesium equivalent to bicarbonate and carbonate in water is called "carbonate hardness". Hardness in excess of that amount is called 11noncarbonate hardness". Hardness of water is objectionable, as it increases consumption of soap and causes scale in boilers which reduces their heat-exchange efHciency. Hardness may be decreased by the addition of lime and soda ash in treatment of water, such as is done at Thomasville, where the hardness in the water is reduced from slightly more than 200 ppm to about 85 ppm (Lohr and Love, 1954). It has been shown (Thomson, Herrick, and Brown, 1956, pl. 3) that hardness of ground waters in Georgia generally increases southward from the Fall Line. Ground waters are classified by the U. S. Geological Survey according to the following scale of hardness: Water class Hardness (ppm) Soft Moderately hard Hard Very hard Less than 60 61 to 120 121 to 180 More than 180 36 The hardness of ground waters in this area ranges from 4 to 448 ppm. The waters from the Upper Cretaceous series are usually very soft, and those from the Tertiary formations are moderately hard to very hard. Dissolved solids.--The dissolved-solids content represents the amount of solid mineral matter remaining from a given quantity of water after the water has been evaporated to dryness at 180C. It is approximately equal to the amount of mineral matter dissolved in the water, but may include some water of crystallization or occlusion. According to the U. s. Public Health Service, waters containing less than 500 ppm of dissolved solids are generally suitable for domestic and industrial purposes. Water containing more than 1,000 ppm of dissolved solids generally is not suitable for domestic purposes and many industrial purposes, but may be used for irrigation under certain conditions. 37 6 Specific conductance (K x 10 at 25C).--The specific conductance of water, expressed as microw~os at 25C, is an indication of the dissolvedsolids content, which generally is approximatelY equal to the specific conductance multiplied by a factor of 0.6 to 0.7. Temperature.--The temperatures reported here were taken at the well as the water sample was collected, and are thought to be representative of the temperature of the water in the aquifer from which it was obtained. The temperature of water samples collected from a main or storage tank is affected by the weather and does not represent the temperature of the water in the formation. Temperature of ground water does not vary much throughout the year. The average temperature of ground water in formations near the land surface is usually about the same as the average annual air temperature of the area. Temperature of ground water increases with depth, usually at about 10 F for each 50 to 100 feet of increased depth. The temperature of water collected during this investigation ranged from 67 to 77F. HYdrogen-ion concentration (pH).--The hydrogen ion concentration of water is expressed as the pH. Technically it is the negative exponent of the concentration of hydrogen ions in gram atoms per liter. Water having a pH of 7.0 is neutral on the pH scale. Values less than 7 indicate acidity and values greater than 7 indicate alkalinity. According to Collins, Lamar, and Lohr (1934, p. 8), "*-**determination of pH must be made almost as soon as samples are collected." The pH values reported here were determined in this laboratory at varying times after the samples were collected and may not, therefore, be strictly representative of the water at the well. Conclusions Ground water of excellent quality may be obtained throughout southwestern Georgia. The water from the Tertiary formations is chiefly of the calcium bicarbonate type and is moderately hard to very hard and alkaline. That from the Upper Cretaceous rocks is of the sodium bicarbonate type and is soft and slightly alkaline. Dissolved solids are usually moderate and consist mostly of calcium or sodium and bicarbonate. Ground water from the Ocala limestone usually is low in sulfate near the area of outcrop, but the sulfate increases downdip and in the Valdosta area sulfate is reported to be extremely high. In the vicinity of the Withlacoochee anticline near Thomasville water from a depth of about 1,600 feet was too saline for most uses. The temperature of ground waters in the area ranged from 67 to 77F. The quality of ground water in southwestern Georgia is generally s~itable for municipal, industrial, and irrigational uses of the water, though some softening of the very hard waters is desirable for domestic uses. 39 Selected references Chrietzberg, John E., ru1d Lewis, Fred D., 1957, Evaluation of caries prevalence after five years of fluoridation: Georgia Dept. Public Health, 5 p., 2 tbls., 1 fig. Collins, W. D., Lamar, W. L., and Lohr, E. W., 1934, Industrial utility of public water supplies in the United States, 1932: U. S. Geol. Surve.y Water-Supply Paper 658, 135 p. Collins, W. D., and Riffenburg, H. D., 1923, Contamination of water samples with material dissolved from glass containers: Ind. and Eng. Chemistr.y, v. 15, p. 48-49. Dean, H. T., Jay, Phillip, Arnold, F. A., Jr., and Elvove, Elias {no date), Domestic water and dental caries: Public Health Repts., v. 56, p. 761-792. Lamar, William L., 1942, Industrial quality of public water supplies in Georgia, 1940: U. s. Geol. Surve,y Water-Supply Paper 912, 83 p. Lohr, E. W., and Love, s. K., 1954, The L~dustrial utility of public water supplies in the United States, 1952: U. s. Geol. Survey Water-Supply Paper 1299, Part 1, 639 p. McCallie, S. W., 1898, Preliminary report on the artesian-well s.rstern of Georgia: Georgia Geol. Surv{~ Bull. 7, 214 p. 40 Piper, A. M., and Garrett, A. A., and others, 1953, Native and contaminated ground waters in the Long Beach-Santa Ana area, California: U. s. Geol. Survey Water-Supply Paper 1136, 320 p. Sayre, A. N., and Livingston, Penn, 1945, Ground-water resources of El Paso area, Texas: U. S. Geol. Survey Water-Supply Paper 919, 190 p. Stephenson, L. W., and Veatch, J. 0., 1915, Underground waters of the Coastal Plain of Georgia and a discussion of the quality of waters, by R. B. Dole.:u. s. Geol. Survey Water-Supply Paper 341, 539 p. Thomson, M. T., Herrick, s. M., and Brown, Eugene, 1956, Availability and use of water in Georgia: Georgia Geol. Survey Bull. 65, 416 p. U. s. Salinity Laborator,y Staff, 1954, Saline and alkali soils: U. s. Dept. Agriculture, Agriculture Handbook 60, 160 p. Waring, F. Holman, 1949, Significance of nitrates in water supplies: Am. Water Works Assoc. Jour. v. 72. no. 2. Warren, M.A., 1944, Artesian water in southeastern Georgia, with special reference to the Coastal area: Georgia Geol. Survey Bull. 49, 140 p. 41 APPENDIX Records of chemical analyses and well-construction information. 42 location: Owner: Well No.: Date drilled: Yield: Adel, Cook County MUnicipal City Well 4 June, 1957 1,200 gpm Color: ~ Temperature ( 6 F) : Date of collection: 71 April 18, 1958 GoG.S. No.: pH~ 7.7 Specific conductance (micromhos 25C): 399 Constituents Parts per million ~ilica (SiO':l) 33_ ~on {Fe) .26 ~alcium ( Ca) _5_3_ ~esium MgJ 16 ~odium (NaJ 4.6 Potassium K) l.J!_ ~icarbonate {HCO':lJ 144 parbonate CO':l) 0 Sulfate ( S01, J 87 Chloride (ClJ 4.0 !Fluoride (F) .3 INitrate (NO~) .1 ~issolved solids 289 ~ardness . . Total ascaco3o . . . . Noncarbonate 0 0198 8o EquJ.va.Lents per million 2~ 1.32 .20 .O_li 2.36 .oo 1.81 .11 .02 .oo I( Size inches) 16 12 From (feet) 0 46 Casing record To Depth of well (feet) (feetj 46 'Z76 500 screen setting (feet) L 'Z76- 500!'!1 Aqu1:rer Ocala 1twc~.j.~~~ !/ Open hole in limestone Location: Albany, Dougherty County owner: Municipal Well No.~ City Well 13 Date drilled: December, 1951 Yield: 1.534 gpm TC~oelroart: ~wre~~(~6=2F~)~------~7~3---------- Date of collectiong M&v 15, 1957 G..G..S. No .. : 322 pHg 8.0 Specific conductance (micromhos 25C): Constituents Parts per million ~ilica (SiO~) 26 OC:fon (Fe) .06 Palcium t Ca) 24 Magnesium I Mg) 9.2 Sodium (Na 4'5 Potassium ! K) 2.0 a1carbonate (HCO~) 221 pa.rbonate (CO":lJ 0 Sulfate l S01. J. 9.5 Phloride 1Cl) 6_._8 !Fluoride (FJ .4 INitrate J {NO~ .3 Pissolved solids 2~8 ~ardness Total. as Caco3 e eo e o 0 0 98 Noncarbonate o e 0 0 o e o 0 EqUivaJ.ents per million 1.20 .76 1.96 .05 3.52 .00 .20 lQ .02 ._QQ_ Size 1 From 'inches ) (feet) 26 0 20 0 10 230 Casing record To Depth of well (feet) (feet) 45 250 _9_75> ~ Screen setting {feet) Aqui._fer ZT0-275 290- 00 12- 22 -!1:- :45 :7lj 4C)( -420 430-460 400-490 16-~9 ~I Tallahatta formatioiJ Do. Do. Do. Do. Do. Do. Do. Clayton formation !/ Open hole in limestone 44 !>cation~ Americus, SUmter Countv Owner~ Municip&l Well No. ~ Gray Well Date drilled: __..1""'9.2...7.__ _ _ _ _ __ Yieldg TCeomlpoerrgat-ure3~~(~6=FT)-:---6~9------------Date of collection: April 1. 1958 G.G.So No.: p~eHci:~f~!c-..=:zc-.4o-n~du-c~t-an--c_e ____________ (micromhos 25C): 24o Constituents Parts per million Silica (SiO':l) [Iron lFeJ ~alcium (caJ ~agnesium I MgJ [SodiUin (Na !Potassium IKJ !Bicarbonate (HCO ~ ..QS. 3.02 ._10_ .33 .20. ~ .01 Size 'inches) 12 10 From (feet) ~ ~00 Casing record To Depth of well (feetl (feetj ~00 o6o _900_ Screen settlng lfeetl ------ Aqu1rer ..... (!-rp+_..,..,..nna series 48 U>cation: Bronwood. Terrell Countv Owner: Municipal Well No ~ City Well 2 Date drilled: Novem,ber. 1954 Yieldg 26o gpm TCeomlopre:rat_u_r3e ~(~6-F}-:--_-_-.7-.-..-,-1-..-_-__-~--~-:------ Date of collection: April 8. 1958 4o6 pH: 'le7 specific conductance (micromhos 25 c): __.,c;2,..,2.-.2- - - - Constituents Parts per million Silica (SiO~) ?t:; Iron (FeJ 11 Calcium {Gal ~2 Magnesium l~MgJ 3.4 Sodium (l'la 9.3 Potassium l KJ 2.0 Bicarbonate (HCO~J 116 Qarbonate ( CQ-:t_)_ 0 Sulf'ate ( 801, ) 5.5 Chloride l c~} ?.2 Fluoride {F) .2 Nitrate {NO~ l .o !Dissolved solids 14~ ~ardness as caco3 Total o 0 0 0 0 0 94 Noncarbonate 0 0 0 0 0 0 Equl.va.Lents per million 1hrl .28 Jl.o .05 1.90 .00 .11 .06 .01 .00 Size !(inches) From (feet)_ Casi_ng record To Depth o:r well (feetl (feet)_ Screen setting (feet) Aquifer 8 0 395 4'53 395-453 a/ t'!lav+n.,... ..... .Cn.n !/ Open ho1e in.~.1-stone IDeation: Cairo, Grady County OWner: MUnicipal Well No.~ City Wells 3 and 4 Date drilled: Well 3, Aug., 19%, Well 4, April., 1950 Yieldg G.G.S. No.: Well 3, 141 Well 4, 205 COl.or: 1 T~erat-ure~~(~6 F~)~:--~--7~4------------- Date of collection: MaY 12 1958 pH: 7,7 specific conductance (micromhos 25C): ~8~29""---- Constituents Parts per million ~ilica (SiO':l) 18 OCron U'e) .01 ~&l.cium ( ca) 7'5 Magnesium ~Mg) 36 SOdium (Na 4'5 Potassium ~ KJ ~.7 ~!carbonate (HCQ~l _]_52 parbonate {co":) J 0 SU!f'ate l SOJ, J .255 (ffiloride (Cl.) 42 ,luoride (FJ .'5 ~itrate ( NQ':l J .0 Pissolved s<>lids 6o'5 ~ardness as caeo3 TNoontcaalrbonate 335 0 0 0 0 0 0 0 00 0 0 0 00 00 0 000 .21.0 .l!iQ.Ul.vaJ.ents per million ~.74 2.96 _l.96_ ,OQ _2JI.g_ .00 _531 -- 1..18. .0~ .00 Size inches) 1~ 1!) From (feet) () () Casing record To Depth or well (feet) (feet} !)P.i) ~()() h.OI:\ c;Af; screen $ett1ng (feetl Aqu1f'er 9P.o..h.cts_ _al_ -:.J ':U'l{).. J:\A/:: _, _l_M:lnt'A...A aA...of A a. \ nH .... .c ..... _ru._a_l_a_ __l_a_ 50 Location~ GMU 1a, Mitchell Caunw Owner: MJmicillaJ Well No. ~ City )fell 4 Date drilled: November, 1S57 Yieldg z,ooo iiW' Color~ 1 T~erat-wre~~(~6=F~):----6g~------------ Date of collectiong MAY 8. 1958 G..G..S. No,: 56-4----------------- pH~ :z.B SpecifiC conductance (micromhos 25C): Constituents Parts per million Silica (SiO~) q,4_ Iron (Fe) .01 Calcium l ca} Magnesium I~MgJ 48 .0 ~odium (Na 2 .. 6 IPota.ss_j.um 1 KJ .1.1, ~!carbonate lHCO~) 1 c:;o !Carbonate l co~) 0 ~ulfate (80_1_} .8 Chloride l Cl} 4.0 Fluoride (F) .o [itrate l NO~} 2 ~ ~issolved solids 140 ~ardness . . Total a s Cacoo 3 o " " 0 0 0 "120 . Noncarbonate " 0 0 0 0 0 0 Equl.vaJ.ents per million ~hn ,,J){) .()1 /:;) hh .00 _.02 .ll ,QQ .04 Casing record Size From To Depth of well [(inchesJ Jteetl (feetl (feet) 12 0 150 ~55 Screen settlng l_feetJ l~0.. 3_t:;c:; _a_..L Aquifer 0col'!.1 A_ _J imPc:o+r.....""' J ~/ Open hole in limestone 51 IDeation~ Colquitt, Mj.ller County ower~ Municipal Well No ~ citz Well 2 Date drilled: __;;l""'9_.47.._-.....:4S..;;.__ _ _ _ __ Yield:: 350 gpm 0 _ Color~ T~erat-ure~~(~6 =F~): _ _ _7_0_ _ _ _ _ _ _ _ _ _ _ _ _ Date of collectiong MaY 13. 1958 pSHpegci"'2f7i".=7"c_,.,._c_on-d..-u-c~tan--c-e------- (m.icromhos 25 C)~ __..2l,.Q...__ __ Constituents Parts per million Silica (SiO-:>) 7 .1 Iron lFeJ Calcium {caJ .01 4~ Magnesium Mg) .? aodium {NaJ 2 .. 0 Potassium KJ .1 Bicarbonate (HCO~J .1~0 Carbonate {C0-2) Q_ Sul.!'ate l S01, J .J:i Cliloride l c~ J -~.0. F_!uoride {F) 1 Nitrate l NO~ J ?.5 Dissolved solids 1 ?t; ffardness Total as caco3 0 0 0 ~ 0 0 0 106 Noncarbonate 0 0 0 0 0" " 0 Equivalents per million ? .10 .0? .QQ. .OC\ ? 1~ (\(\ .m nA .m .olJ. Size 1 inchesJ B. From (feet] Casing record To Depth of well (feet) (feet) --- 2~4 Screen setting _(feet) Aquifer - -2a4 s.l '"" C\1"1'1.1 R. 1 ; !/ Open hole in limestone 52 location: Cordele, Crisp Coqpty Owner: Municipal Well No : City Well 4 Date drilled: _ _ _ _ _ __ __,1..,9~5...:.4 Yield: 1,230 gpm Color: 1 _ T~erat-ure~,(~0=F~): ___7_1______________ Date of collection: MaY 14. 1958 G.G.S. No.: 3,90 pH: :z.6 Specific conductance {micromhos 25C): --"26:u.&..J_ _ __ Constituents Parts per million Silica (SiO,_,) 19 ~on (Fe) Calcium (caJ .00 49 ~esium l Mg) l.C:) ~odium (Na 1.< !Potassium ~ K) .o !Bicarbonate (HCO~J 149 Carbonate ( CQ-:tl 0 ~ultate (SO), ) 7.5 ~loride (Cl) 3.t._O !Fluoride (FJ .2 !Nitrate (NO~) .3 !Dissolved solids 160 nardness as caco3 . . Total 130 Noncarbonate 8 EqU1va.Lents per million ~ JJ.c:; J5 .08 .02 2M .00 .J.6 .08 ..01 __...oo_ I( Size inches) 26 20 12 From (teet) 0 0 ?()() Casing record To Deptb o:r well (teet) (feet) 145 ?h.t; 600 screen settlng (teet) Aqu1:rer 270_-~ ~50-~60 375_-385_ 410-420 4~o-46o 490-SlO '58o-S90 1!l..ai_'L Do - - ....... Jkt,_ Do Do. __Do_ Wilcnx ~onn 53 IDeation~ Cuthbert, Rapdalph Count~ Qwnerg Munic:l;paJ Well Noo ~ City Well 3 Date drilled: .Tanua;cy;, 1958 Yieldg 4oo ~ TCo~leorr~at~~5~7(T6-F~)~g--~6~8------------- Date of collectiong April a, 1958 552 pHg 'l 8 Specific conductance (micromhos 25 C): _....2_.5.4_ _ __ Constituents Parts per million ~ilica (SiO~) 17 !Iron {Fe) .2!1 ~alcium ( ca) ~q Magnesium MgJ 8.4 SOdium (Na) L1l Potassium KJ 1.1 [Blcarbonate (HCO~l __147 Parbonate {co.,} :..o SUJ,f'ate l SOJ.) l.2_ PbJ,oride ( Cl.) 2 .. t; !Fluoride {FJ .1 !Nitrate (NO-,) .0 !Dissolved solids 1t;~ ~ardness as caeo3 Totalooooo 0 0 0 0 0 0 0 0 0 132 Noncarbonate 0 0 0 0 0 0 0 0 0 0 12 Eqw.vaJ.ents per million l.Q'i .6Q ..a6_ .0~ _2.lil .00 ..25_ .()7 .01 .1lO. Size inches} 8 From (feet} 0 Casing record To Depth of well (feet) (feet} ?'iO ~r:;o screen settl.ng (feet) Aqu1:rer --.. ! 1"!1 t:~u+""' .P. . .. !I Open Hole in limestone 54 Location~ Dawson. Terrell Chnpt}C Owner~ Munictp&l Well Noo~ City Well 3 Date drilled: December, 1~50 Yield:: Boo gpm TC~oelorra~t-wre3~~(~6 =F~Jg----7~1------------Date of collection:: April 8. 1958 213 1.6 pH:: _ ~eci~f~ic~c-o-nd~u-c~t-an--ce ____________ (micromhos 25C): Constituents Parts per million Silica (SiO':>) 26 Iron (Fe) .08 Calcium {Ca) 40 Magnesium Mg) 3.9 Sodium {NaJ 6.5 PotassiUm. KJ 2.0 !Bicubonate (HCO~J l!f3 ~a.rbonate {CO~) 0 ~uJ.f'ate {SOh } 13 phloride (Cl) 2.0 Fluoride {F) .1 ~itrate {NO~J .o Dissolved solids 164 Hardness Total as caco3 o o o o o 0 0 0 b 0 0 0 0 116 Noncarbonate 0 0 0 0 0 0 0 0 0 0 0 Aq\UvaJ.ents per million 2.00 ''q2 .28 .05 2 ..'~4 .00 .?7 .06 .01 .00 Size l(i.nches) 20 Casing record From To Depth of well (feet)_ (feet1 (feet) 0 345 496 Screen settlng (feet) Aquif'er .-qh.s-h.ah A I -' 1"1Av+nn ..;,_.,.. !/ Open hole in limestone 55 Location~ DoneJdaonv1Jle1 Seminole County ()wnerg MnnicipA] Well Date No o ~ drilled: c-u-~=v-e:l :1-2.=.--------- Yieldg 225 gpm GoGoSo N'Oo g TCo~leorra~ t-~~3~(-6 F=)-g----~-------------Date of collectiong :Jebnery 26, 1958 pSHpgeci~ff~C ~c5on~d~uc~ta~nc-e-------- (micromhos 25Ch -42~50U-.--- Constituents Parts per million Silica (SiO~) _6_~ [ron {Fe} .01 palcium {ca) _50_ Magnesium MgJ .2 Sodium t Na 2.~ !Potassium K} .1 !Bicarbonate (HCO ~oride (C1J ~.'i !Fluoride {F) .0 !Nitrate {NO~) 1.4 !Dissolved solids _Jh,Q ~ardnesa 8B caco3 Total o o o 0 0 0 0 0 0 0 0 0 126 Noncarbonate 0 0 0 0 0 0 0 0 0 0 0 .KquJ.vaJ.ents per million _2_..50_ .02 ._lQ_ .00 2.5J. .oo_ .00 .lQ_ .00 .ill>. Casing record Size From To Depth of well Screen setting 'inches) (feet) (feet) (feet) (feet) A_<1~er A 0 JAn ')]Q 1 An._.,,() t'\i"lRJ a 1 i ..+,.......... !/ Open hole in limestone 56 Location~ Edison, CaJ.houn CountY Owner~ Mnnicipa.] Well Noo~ Ci~ Well 2 Date drilled: July, 1953 Yield~ 250 (Est.) ilW' TCoelmopre~ra.t~u1re~~( 5~F-) g-~_-_.-7.,-.1.-__-_-_ --_--~-- ---- Date of collectiong May 9, 1958 353 pHg 7,.1 Specific conductance (micromhos 25 c)g --'2;..,o5~.~ol_ _ __ Constituents Parts per million Silica (SiP?) 2~ L""''n (Fe ) .1'i palcium l ca.} li ~esium MgJ r:;.o ~odium tNal !Potassium KJ 1!:) 1 a !Bicarbonate (HCO~J 140 Qarbonate CO~l 0 ~ate lSO>.r 9.5 ~loride \Cl.J .o IF'luoride (FJ INitrate (._NO< l ~issolved solids B:ardnese aB caeo3 1 .2 161 Total 108 o o o o 0 0 0 0 0 0 0 0 0 Noncarbonate 0 0 0 .. 0 0 0 0 0 0 0 EQ.'.U.va..ents per million , '75 hl .52 nc: ?h1. .00 .20 .00 .01 .00 I( Size inches} _a_ From (f'eetl _Q Casing record To Depth of well _(teet) (feet) 395 '\lr:; Screen setting _(teet) _Aquifer -- N'i-&:;11:\ ~1 ,., ........,..... - ... ,...... !/ Qpen hole in limestone 57 IDeation: Fort Gaines, Clay County Owner: Municipal Well No o : City Well 3 Date drilled: Mar.;c=ch=-=l:J-9~58~---=~- Yield: 300 gpm pump; 100 gpm flow Color: 4 T~erat~wre~,(~6~F~):----~68~----------- Date of collection: April 8, 1958 G.G.S. No.: pHg 8.3 Specific conductance (micromhos 25C): 4o3 Constituents Parts per million Silica (SiO~) 16 Iron (FeJ .15 Palcium {Ca) __S_._Q Magnesium ~ MgJ 1.5 aodium {Na _90 Potassium ~ KJ 1.7 [Bicarbonate lHCO~J 226 parbonate ( CQ~I 0 Sul-fate l S01, J 12 ICliJ.oride lClJ 15_ !Fluoride (FJ 1.0 INitrate (NO~ J .o ~issolved solids 251 ~ardness Total as Caco3 e 0 0 20 Boncarbonate 0 .l:!:qU1va.J.ents per million .~ .12 _3_~2 .04 3_JO .oo _._25_ .42_ .05 ~oo Size 'inches) 8 From (feet) 0 Casing reco_~ To Depth of well (feet) (feet_} 370 370 Screen se~tlng jfeetl 310-320 ~0-~ A_q~er Upper Cretaceous series Do. Location~ Georgetown. Qu1tmap Coun:t7 Owner: MJmicipo.l. Well No. ~ City Well J. Date drilled: October, 1956 Yieldg lQQ sgm TC~oelroargt-ure~5~(~6=F~)~------------------- Date of collectionx pHg Speci f a, ic 5conductanc~ (micromhos 25 C): _,;;j41;j;19.7 .. - - - - Constituents Parts per million ~ilica (SiO>:)) PL~n U'e) ~alcium (cal ~e:sium Mg) ~odium (Na !Potassium KJ Bicarbonate lHCO~J Carbonate . CO~! Slll4'_ate {S01, r '-'hloride (Cl.J Fluoride {FJ !Nitrate _lNO~ J !Dissolved solids 3 ~srdness as caco Total o o o 0 0 0 0 0 0 0 0 Noncarbonate 0 0 0 0 o- 0 0 0 0 0 1'5 .06 1.6 .0 12._1 2 .. 4 11Q 6 .0 7.0 .7 .o ~26 4 0 .Equ1V&Lents per million .08 .00 5.~'i .oh 'i.?~ .~ .00 .?0 .011 .00 Size !(inches) 6 4 From (feet) 0 ~00 Casing record To Depth of well (feet) (feet) ~00 l ~6'5 l ~h'i Screen setting (feet) Aqui:rer 1 ~9" .1 .0 Fluoride (F) .? Nitrate (N0'2} 1 Dissolved solids 137 Hardness Total as caco3 o a o o .. 0 0 0 0 " 0 0 114 Nonca.rbonate 0 0 0 0 0 0 0 0 0 4 Equiva..ents per million 2c1S .1 ~ .04 .01 ';)_'X) .00 _()7 _()i:; .cu _()() Size ''inches) 8 From (feet) 0 Casing record To Depth of well (feet) (feet) 210 Screen setting (feet) Aqu1f'er t"!l A.ihnl"'n,.. ....,.,........,. 61 IDeation: Merck and Ccar 1, Dougb.erty County OWnller! Priyate. (Merck; Md Cc~ g ) We L10o ~ gmerr Ytl1 l Date drilled: DeCember, 1951 Yield~ l,OOO gpm G.G.S. No.: __.2......~5"-~3------- TC~Oelrora: t-~~2~{~6 F~)~:--~69-------------Date of collection: May 2. 1957 pH: 7.7 Specific conductance (micromhos 25 c): __..2-..~3.9.- - - - - - Constituents Parts per million ~ilica (SiO~) 11 ~n {FeJ .08 ~a:J._cium ( ca) 47 ~esium 1Mg) 1 .1 ~dium. (Na ;>,? !Potassium ! K} .~ !Bicarbonate (HCO~J 1t;O ~arbonate l co~ 1 0 ~l.ll4"_ate ( S01, ) -~ ~oride (ClJ ? .. 0 F]..uoride {F) _() 111trate (NO~J 1 .~ Dissolved solids 1h.~ ~ardness Total ascaco3 0 0 0 0 122 Noncarbonate 0 0 0 0 0 Q .15qw.valents per million ? ~c; ()Q )() .01 ~w:; .00 ()() .Oh {'\(\ ()~ S1ze 'inches) 10 From (feet) Q_ casing record To Depth or well (teetl _(teetl 8o 247 Screen sett1ng {_teet) Aquifer - Bo-247 aL .-.n. . ()I"A1A l_imlll!Ai:nne T.iAhcm .-. !I O,pen hole in limestone 62 wcation: Moultrie. Qg;A,guitt Count: Owner: Municipal . Well No. ~ City Well 3. Date drilled: _ December, 1949 Yieldg Colorg !i Temperat'u_._r.e_...,.(w:oF~}r-:--:z-5- - - - . - - - Date of collection: Agril 9 1958 --= pH: ].B Specific conauctance (micromhos 25C): Constituents - Parts per million ~ilica .( SiO~) [.Iron (Fe) - 24 .10 ~alcium {Ca) 102 Magnesium Mg) 47 Sodium (Na) 38 Potassium KJ S.7 if31carbonate t HCQ-li. 14o Carbonate CO~l 0_ Sulfate {S01, }' 4os Chloride {Cl.J 12 ~uoride {F) 1.2 ~itrate (NO~J .0 ~issolved solids 761 ~ardness as caco3 . . Total o 0 0 ~ . . Noncarbonate 0 0 Q 0 0 448 ~~4 Equi.vaJents per million 5.09 i.87 1.65 .1S 2.29 .00 8.4~ ~4 .Oh .00 I( Size inches) From (feet) Casing record To Depth of well (feet) (feet) Screen setting (feet) Aquifer 16 0 4P'i 7'i? lJ.?t;, .7t;? A_/ ...J t"'H n ...alA_ ]'f1 a.:.,..i &:&f:L '"" !1 Open hole in limestone Location: Newton, BaJter County OWner:: Municipg,l Well No o : City Well 2 Date drilled: ___;;---~------ Yield: T~elmorp~erat~u0re~-(=F~)-: --_7-.-~---~0-"------------...-...-- Date of collection: MaJ 13: 1958 G.G.S. No.: pH: 7.8 Specific conductance (m.icromhos 25 4 C): __.2l.w8oL.-_ __ ~nstituents Parts per 111U1on Silica (SiO':)) 1'1 OCron U'e) .01 c-alcium ( C&) ~6 Magnesium ~Mg) ~.4 SOdium (Nal _6_..o_ Potassium KJ .7 aicarbonate (HCO~} ~u Carbonate (CO-:~ J 0 ~ate (SOJ,) 3.n k.ffiJ,oride {Cl) ~.0 !Fluoride (FJ .1 !Nitrate (NO~) _]_..5_ !Dissolved si5lids 1P7 ~ardness as caeo3 Total 0 0 0 104 Noncarbonate 0 fill 0 () JSq'.!l.?'!Uents per million l.Sn .~ ~ .0!). __2_ l ' i .Of! .D.6._ ...o6. .01 ...Q2. Size inches) R From _(feet} 0 Cas1II.g reco~ To Depth or well (feet) (feetl -- 475 Screen setting lfeetl ~~er - -47'i aL lk-AlA _1_i_n~Aa+n>'IA !I Open hole in limestone 64 Location: Pl1ps. Sgmter Coynty Owner: Mupicipo.J. Well No.: City We1l 2 Date drilled: Jane. 1952 Yield: Color: 3 Temperat-ure~~(~6=F~)-=--~68~------------ Date of collection: April 1, 1958 G.G.S. No.: pH: l3 Specific conductance (micromhos 25 c): ___.1..5... 0~--- Constituents Parts per million Silica (Si00 ) h.a li!'on (Fe) '1, Q_a.lcitm~. _tea) Magnesium MgJ 99 ~.h odium (Na) 9 h. Potassium KJ ~.1 Bicarbonate {HCO~J 76 "'arbonate CO-:t)_ 0 Sul:fate ( S01, ) 12 ghloride (ClJ 2 .. 2 Fluoride {FJ .1 Nitrate (NO~J .5 Dissolved solids l.'U ffardness as caco3 . . Total 0 70 Noncarbonate 0 8 Equl.vaJ.ents per million ] 10 ~(I .10 .. oB 1.21) .00 .91) .06 .01 .01 Casing record Size From To Depth of well Screen setting !(inches) (feet_) (feet) (feet) {feet) Aqul:rer 18 _Q 86 8 6'l 947 _1)14 TI0..1&l 107.. ~-::> 9h7.. 1:\14 _s:,J _, _V"'l ~,.,..,. ............."" ~ l'!] ......... ,...... ~- of,.,..,.,. !/ Open hole in limestone IDeation: Quitman, Brooks county OWner: Mnni cipaJ Well No.: Cit~ Wel 1 3 Date drilled: _ _,...,.~'lol5~:.~~4 _ _ _ _ __ Yield: 700 g,pm o Color: _ T~erat~wre~~(~6=F~):----7-0 ____________ Date of collection: MAY 12, 1958 G.G.S. No.: pH: 15 Specific conductance (micromhos 25C): _,.2,...68w.-_ __ Constituents Parts per million Silica (SiO-::>) ~7 Iron (FeJ Calcium ( ca J .00 4l Magnesium I MgJ 8.1 Sodium(Na 2.5 Potass1um ~ KJ .6 Bicarbonate (HCO~J 162 carbonate _lco~)_ 0 ~ate (SO>, J. 1.2 Cliloride (Cl.J 3.5 F~uoride (FJ .2 Nitrate (NO:d .5 [!issolved ~~lids 154 Hardness Total as Caco3 134 Noncarbonate 1 Equ1vaJ.ents per million -::>.00 .68 .ll .02 2.66 .00 .. 0 2 .10 .01 _.QJ. Size (inches) _l2 From (feet) 0 Cas1ng record To Depth of' well (feet) (feet) 120 ~04 Screen setting {feet) Aquifer - 120-~04 AI u.;,., .......................... nH ..,..,..iaa l\t'alA 1 .,,.,......+.......... !/ Open hole in limestone 66 IDeation: Smithville, Lee County Owner; Municipal Well No.: City Wel1 Date drilled: December, 1950 Yield: TCeomlopre:rat_u_re3~(~F~)-: -~---~:68-=-.,.5-_--_-_--~--~--- Date of collection: At>ril 1. 1958 G.G.S. No.: pH: 6.6 Specific conductance (micromhos 25C): __.u..r.,;;).3- - - - Constituents Parts per million Silica (SiO~;~) l'5 l!l"on (Fe) ca ~alcium ( J ,_02 16 Nagnesium Mg) .5. !Sodium ( Na) c:; ..{. !Potassium K) .1. !Bicarbonate (HCO:d M ,_,arbonate (CO~J 0 ~ulfate (SOt, J .0 !Chloride (ClJ 8.~ !Fluoride (F) .0 !Nitrate (NO~} _5.3. !Dissolved solids Rl ~ardness Total as , Caco3 0 42 Noncarbonate 0 ~ EqU1vaJ.ents per million .13o .oll. .~; ~01 .2SJ_ ,(){) ..oo_ ..23. .00 ....00. Size It inches} 14 8 4 From (feet) 0 0 l4o Casing record To Depth of well (feet) _{feet1 4o 14o 18o 18'5 Screen setting _{_feet_}_ ~ui:f:'er 10'1-140 170-l.Bo Ocala. JAntpa+.n.,..,.., .f!la.iborne_ D"'""nnn IDeation: Sx~veater, Wert;h CQ'Ulilty owner: M!mieipal Well No.: City Well 1 Date drilled: Prior to 192.6 Yield: S4Q p TCeOmlopre:rat~u3re~~( 6~F-)-: --_7-,..1-..-.,._ --_ --_ --_--_--~- Date of collection: April 25" J.Si58 G.G.S. No.: pH: :z:.a Specific conductance (Dlicromhos 25C): __.29,...!+---- Constituents Parts per million ~ilica (Si00 ) [IrOn {Fe) Pal.cium lC&J Magnesium :MgJ ~ium (Na !Potassium j KJ IBlcarbonate {HCQ-:tl tarbonate (co~ J aw.rate {S01, J ~oride ( Cl.) ,luoride {FJ IIitrate (lVO~) !Dissolved solids ~ardness Total as Caco3 Noncarbonate 0 26 .!17_ 415 7J~ ~.'l l.l 199_ 0 1.~~ 3.2 .2 .2 lllO 143 0 Equl.vaJ.ents per million .~.25 ..61 . '1 c; _.03. ~ .. oo _...o!l .09 .oJ. _.oo_ Size inches) 12 From (feetj_ .... Casingrec~ To Depth of well {feet} _(feetj_ .. .. 4oo Screen settlng jfeetj_ Aqu1rer -a.l 01 i ..,..,..,...,..,..... ...... '" ...... 01"A'1Jil. '1 -fm.-P+""'"" !/ Open hole in limestone 68 I.ocation: Thomasville. TbrnnM CountY OWner: Mnni c'Ula1 Well No.: Citf Well 5 Date drilled: Febnm.ry, 1949 Yield: 1,200 iPm Color: 2 Temperat-ure-=--.(""6'=F"~")-:--7-6~------ Date of collection: NaY 8. 1958 G.G.S. No.: pH: 7.8 Specific conductance (micromhos 25C): 418 Constituents Parts per million [ron {Fe) Calcium ( Ca) Magnesium ~ MgJ Sodium {Na} Potassium (KJ Bicarbonate (HCOcation: Tifton. Tift Countv owner: Municipal Well No : City Well 2 ])ate drilled: _ -~.,;9~4oQt.... _ _ _ _ __ Yield: Color: 2 _ T~erat-ure--~(~6~F~)-: ___7_2___________ Date of collection: Agril z8. 1958 G.G.S. No.: 292 pH: 7.9 Specific conductance (micromhos 25C): 271 Constituents Parts per million ~ilica (SiO-:>) 18 ~n (Fe) .14 Oalcimn l CaJ 4o Magnesimn I MgJ 8.~ Sodimn (Na ?.Q Potassimn IKJ .Q Bicarb_onate ( HCO~ )_ 178 Carbonate l CO~ J 0 Sulfate 1S01.t_ l .a ChJ.oride l ClJ ?.A Fluoride (F) .9 Nitrate (NO~} 1 Dissolved solids 1~1 . . Rardness Total as ca co 3 134 Noncarbonate 0 EquivaJ.ents per million 2 .. 00 .hB .1~ .02 9.Q9 .00 .09 .08 .01 .00 Size "inches) 1-:> From (feet) 0 Casing record To Depth of well (feet) (feet) -- '501 screen setting (feet) Aqulrer -'501 a/ Miocene aeries Oli sar.iea !I Qpen hole in limestone 70 location: Valdosta, lowndes County Owner: Well No.: Municipal City Wel1 4 Date drilled: August, 1957 Yield: Color: 34 T~erat~wre~~(~0:F~):------~---------- Date of collection: August 271 1957 G.G.S. No.: 511 pH: 7.3 Specific con~uctance (micromhos 25C): __..l.:z4;:;z.9---- Constituents Parts per million ~ilica (SiO~) J..2 r.rrc>n (Fe) .07 paJ.cium {C&J 2~ Magnesium I:MgJ 2,.8 Sodium (l'la 4.7 Potass1um 1KJ .h. ~!carbonate (HCO-:t! 81 ~arbonate {CO'lJ ~u.J.1"ate 1S01.t_)- 0 ..._8_ Phloride l ClJ 7.A !Fluoride {FJ ~ Nitrate {NO~) .n Dissolved solids 10c:; l{ardness as caeo3 . . Total , . . Noncarbonate , 69 ? EqU1vaJ.ents per million 1 .1 t; .?-:t .?0 .01_ 1 . -:t-:t .00 _n~ .?? n~ .nn I( Size inches) 8 From (teetl 0 Casing record To Depth o:r well (teet} (feet} lQO 400 Screen sett1ng (teet} Aqu1::t"er - 1Q0-4oo a/ 'Min~~n AA'riAa. OH. R~'ri ...lll .l !/ Open hole in limestone 71 IDeation: Vienna, Dool:y County OWner: Municipal Well No.: City Well 2 Date drilled: Yield: 80o gpm. Color: 2 Temperature ( 6 F): Date of collection: 69 Ma.y 14, 1958 143 pHg 7.5 Specific conductance (micromhos 25C): 254 Constituents Parts per million Silica (SiO~) 15 Iron (Fe) .()9 ~alcium {ca} 50 N&gnesium :Mg) .2 aC>dium(Na 1.~ !Potassium j K} .2 [Bicarbonate ( HCO~ }_ l-53 Parbonate {CO'l} 0 SUlfate {SOl, ) - 7.0 ~loride (Cl} 2.0 'luoride {F} .1 !Nitrate (NO~J .2 !Dissolved solids 151 aardness Total asCaco3 e o o oJ.26 Noncarbonate 0 0 0 Equ1vaJ.ents per million 2.50 .02 .o~ .01 2._21 .00 .J,5_ .O_Q .01 .00 Size '1 1nches) 20 10 Casing record From To Depth of well (feet1 (feet) (feet} 0 200 lt11 581 3l Screen sett1ng {feet) 250-260 292-112 322-142 i52-i62 ~80-1go .408-413 566-571 ~~er _C_lai'QQ_me _10!, Do _Do, _Do.... Do _Do_._ W_ilcox a:rouo 72 INDEX Page Ade1 . . . . . 19, 26, 43 Albany 6, 8, 9, 11, 12, 18, 19, 26, 44 Americus 6, 11, 18, 19, 26, 45 Arkansas . . . . . . 35 1\rlington . . . . . . . . . . . . . . . . . . . . . . . . 6 Ashburn . 19, 26, 46 Athens . . . . . 35 Augusta . . . . . . . . . . . . . . . . . . . 6 Bainbridge 16, 18, 19, 26, 47 Baker County . 13, 64 Basal sand . 8, 9, 12 Bashi mar1 . . . . . . . . . . . . . . . . . . . 8 Bicarbonate . . . . . . . . . . . . . . . . . . . . . . 34 Blakely 6, 19, 26, 48 Blufftown formation .. 9 Bronwood . 19, 26, 49 Brooks County .............. 66 Calcium . . . . . . . . . . . . . . . . . . . . . . . . . 33 Calhoun County 9, 11, 13, 57 Cairo . 16, 19, 24, 26, 50 Camilla . 18, 19, 26, 51 Carbonate . . . . . . . . . . . . . . . . . . . . . . . . 34 Carolinas . . . . . . . . . . . . . . . . . . . . . . . . 35 Chattahoochee River 16 Chattahoochee valley 10 Claiborne group 8, 11, 12, 13, 16 Clay County 9, 10, 11, 58 Clayton formation 9, 11, 12, 16, 28 Chloride . . . . . . . . . . . . . . . . . . . . . . . 34 Coll.llllbus . . 6 Colquitt County . 19, 26, 52, 63 Connate water 9, 21 Coquina limestone 6, 9, 11, 12 Cordele 8, 11, 12, 19, 26, 53 Cretaceous . . . . . . . . . . . . . . . . . . . . . . . . 9 Cretaceous, Late . 6 Cretaceous, upper 6, 9, 10, 11, 16, 20, 28, 33, 34, 37, 39 Crisp County 11, 13, 53 Cusseta sand ......... o 6, 9 Cuthbert 19, 26, 54 Dawson ................ 19, 26, 55 Decatur County . 15, 16, 47 Dissolved solids o 37 Donaldsonville 19, 26, 56 Page Dooly County . . . . . . . . . . . . . . . . . . . 72 Dougherty County 6, 8, 9, 10, 11, 12, 13, 44, 61 Dougherty Plain 2, 13, 16 Early County 6, 9, 11, 13, 48 Edison ~ 19, 26, 57 Eocene . . . . . . . . . . . . . . . . . . . . . . 8, 28 Eocene, I.ate . . . . . . 15 Eocene, Upper . 15 Eutaw formation 6, 9, 10 Fall Line . . . . . . . . . . . . . . . . . . . . . . . . . 6 Fall Line Hills 2 Flint River 13, 16 Flint River formation 7 Fluoride . . . . . . . . . . . . . . . . . . . . . . . . . 35 Fort Gaines 10, 19, 24, 26, 58 Fuller's earth . 15 Georgetown 10, 19, 24, 26, 59 Grady County 15, 50 Hardness . . . . . . . . . . . . . . . . . . . . . . 36 Hatchetigbee formation 8 Hawthorn formation 7, 15 Hydrogen-ion concentration (pH) 38 Iron . . . . . . . . . . . . . . . . . . . . . . 32 Irrigation .............. o 25 Jim Woodruff dam 16 ~acy 6 Lee County 9, 11, 13, 60, 67 Leesburg 19, 26, 60 Leslie 19, 26, 61 Lisbon formation 8, 12 Lowndes County 14, 71 Macon 6 Magnes itun 33 Q Map . . 3, 17 Merck and Company 19, 27, 61 Midway group 9 Milledgeville 6 Miller County 13, 52 Miocene 7, 13, 15, 28 Mitchell County 51 Moultrie 14, 16, 18 19, 24, 26, 34, 63 Nanafalia formation . 8 Newton ...... 19, 27, 64 Nitrate 35 o 73 Page Ocala limestone 8, 13, 14, 15, 16, 34, 39 Oligocene . 7, 13, 14, 15, 28 Paleocene . . . . . . . . . . . . . . . . . . . . . . . . . 9 Physiographic provinces . 3 Plains 19, 27, 65 Pleistocene . 7 Potassitun ............ ~. . . . . . . . . 33 Preston . . . . . . . . . . . . . . . . . . . . . . . . . . 11 Principal artesian aquifer 15, 16 Providence sand 6, 9, 10 Ptt..rnpage 16 Quality of water 20 Quaterna.rJ' . . 7 Quitman 16, 19, 27, 59, 66 Quitman County 10 Randolph County 9, 11, 54 Recent . 6, 7 Ripley formation 9 River terrace deposits 7, 16 Salinity . . . . . . . . . . . . . . . . . . . . . . . . . 29 Silica .. 32 Seminole County 13, 56 Smithville . 19, 27, 67 Sodium o 30, 33 Sodium-adsorption-ratio (SAR) 23, 24, 26, 27 Specific conductance 38 Sulfate . . . . . . . . . . . . . . . . . . . . Cl 34 Page Sumter County 6, 11, 12, 45, 61, 65 suwannee limestone . 7 Sylvester l6, 19, 27, 68 Tallahassee syncline 13 Tallahatta formation 8, 12 Tampa limestone 7, 15 Temperature ............... 38 Terrell County 9, 11, 13, 49, 55 Tertiary 7, 8, 9, 10, 20, 33, 37' 39 Texas . . . . . . . . . . . . . . . . . . . . . . . . . . . 35 Thomas County 15, 69 Thomasville 8, 13, 16 18, 19, 21, 27, 36, 39, 69 Tift County 70 Tifton 16, 18, 19, 27, 70 Tifton Upland 2, 13, 14, 15, 16 Turner County 46 Tuscahoma formation 8, 9 Tuscaloosa formation . 6, 9 Valdosta 7, 8, 14, 16, 19, 27, 34, 39, 71 Vienna 12, 19, 27, 72 Virginia . . . . . . . . . . . . . . . . . . . . . . . . 35 Webster ....... 11 Well locations 22 Wilcox. group 8, 12 Withlacoochee anticline 21, 28, 39 Worth County 68