I. c. 14 S TAT E DI VI S I 0 N C F C 0 NS E RV~ T I 0 N D E P A R T M E N T C' F J:.t1 I N E S, H I N I N G A N D G E C L C' G Y 425 STATE CAPITOL Garland Peyton Director INFC RM~ TIC'N CIRCULAR 14 D C L C M I T E S :~ N D M ;l G N E S I A N L I I.! E S T C N E S I N GECRGIA 'l. I By A. S. Furcron June, 1942 STATE DIVISION OF CONSERVATION DEPARrMENT OF MINES, }:liNING AND GEOLOGY 425 STATE CAPITOL ATLANTA, GEOIDIA DOLOHITES AND 1IAGNESIAN LIMESTONES I N GEOIDIA~~ By A. s. ;Furcron INTRODUCTION Dolomites and magnesian limestones are wide-spread in Georgia but the principal deposits occur in Palezoic rocks of the northwestern part of the State, and in the Whitestone-Marble Hill Belt. This article will discuss very briefly the general location of these rocks. A thorough discussion of the distribution and location of the deposits may be found in the references he~e included, and in the files of the Georgia Department of ~D.ne s, Hining and Geology. Numerous che mical analyses are in our files. Typical analyses of Georgia dolor,utes will be given here. DEFINITION OF DOLOMITE The mineral dolomite (Ca,IJg)co3, when pure, contains 47.9 per cent carbon dioxide (C02), 30.4 per cent lime (CaO), a1n 21.7 per cent magnesia (1~0). In terms of carbonates, this represents calcium carbonate (Caco3), 54.35 per cent, and magnesium carbonate (MgCOJ), 45.65 per cent. Commercial dolomite, however, cannot be expected to be as pure as the above formulae indicate. Our dolomites occur in thick beds interlayered with other forms of stratified rock; they vary in composition with locality and with the formations involved. The per cent magnesium carbonate also exhibits a wide range, so that it is possible to have gradation from pure ~~ ' Revised and reprinted August, 1944. 2 dolomite to magnesian limestone and marbles, or to high calcium lirnestohe and marbles which contain very little magnesium carbonate. 1bstof the rocks. described in this article are magnesian limestones and dolomitic limestones rather than true dolomites. Dolomite may be difficult to distinguish from limestone in the field. 1Nhere cold dilute hydrochloric acid is applied to the limestone, a vigorous effervescence takes place . Dolomite does not effervesce under similar conditions, although an examination with hand lens usually reveals a few bubbles of carbon dioxide izmnediately after the acid is applied to the stone. In the Gainesville Belt, blue mar~l es are low in magnesia; whereas, the light gray stone is usually dolomit~c. In the'White st.one-1~rble Hill ~elt, the white, compact, fine-grained stone is usually dolomite. Pink or coarsely crystalline marbles a r c generally l ovT in magnesia. USES OF DOLOMITE At the pres ent time dolomit e in Georgia is used mostly as ground agricultural liJ:lc. A considerable anount is ground and s old by Willingham.-Little Stone Company of Whitestone, Georgia, and by tho Ladd Lime and Stone Company at Cartersville. The farmers are using more and more ground dolomite upon their land, where it serves to sweeten the soil and make plant f ood available; the magnesia content also adds an element essential t o the plant 's well-being. Certain plants, f or example, t obacco, require considerable maenesia. In order to meet Federal r equirements, farmers who cooperate with the Department of Agriculture are requir ed to use limestone or dol omit e which contains a calcium carbonate equivalent of at least 90 per cent. The calcium carbonate equivalent of a limestone represents the number of pounds of pure calcium carbonate required t o produce t he same amount of neutralization as one hundred pounds of material. F~r example, if the calci um carbonate equivalent .3 of a dolomite or lirnestone i s 85, one hundred pounds of that limestone has the same neutralizing value as 85 pounds of pure calcium carbonate. The Caco3 content of the rock may be determined by multiplying CaO content by 1.7847; 1~0 may be convert ed t o MgC03 if multiplied by 2.0914. The Willingham-Little Company at Whitestone in addition to the above products, markets terraz~o chip aggregate and aggregate for cast stone. The whiteness of the Whitestone dolomite renders it especially applicable to such uses. The fine dust from the dolomite at Whitestone is sold as an asphalt I ' filler, and considerable crushed stone is sold as aggregate for road and co~ crete vmrk. Some of this stone is used for fluxing material at the Atlantic Steel l~lls in Atlanta. lunong other uses for dolomite may be mentioned furnace lining, glass ronufacture, mortars and plasters, and chemical uses. Dolomite from Pickens County was extensively used in Atlanta as a source of carbon dioxide for carbonated water and soft drinks . It was preferred to limestone because Epson salts (1~S04 o7H2o) could be recovered as a by-product. Later development in the production of carbon dioxide has rendered this process more or loss obsolete. Siliceous limestones and nnrbles are suitable for the manufacture of rock wool. Such rocks should contain around 40 to 65 per cent combined .car- bonates . Too much magnesia makes the glass too viscous. Experiments carried out in the laboratory of the State Division of Mines, Mining and Geology by W. C. Hansard show that ma.gnesia content from .3 to 10 per cent is favorabie f or t he manufacture of rock wool. Dolomite or limestone may be combined sue- cessfully vdth gr~nito waste, fullers earth, slate, shale, etc., in rock wool manufacture~ Since we entered the war there has been renewed interest in dolomite . as a possible source of magnesium salts. Dolomite suitable for such uses 4 should be pure and should contain a high percentage of magnesium carbonate. For exan~le, the ferrosilicon method of producing metallic magnesium recently has revived interest in dolomites which ~re applicable to that process. Several proposed methods for producing magnesium salts and possibly the metal are: (1) Selective calcination of dolomites whereby only the mag- nesium carbonate is decomposed and subsequently dissolved away from the calcium carbonate. (2) Treatment of dolomites with calcium chloride solution whereby magnesium replaces the calcium to produce a magnesium chloride solution from which the metal may be extracted by electrolysis of the fused anhydrous salt. DISTRIBUTION OF DOLOMITE Tho Piedmont and Crystalline areas of the State contain several marble belts within which dolomites arc found. 1vbgnesian limestone and dolomite occur in the Gainesville nurble belt where outcrops may be found from Flower,y Branch in Hall County northeastward through Habersr,am County to the South Carolina line. The marbles of this belt vary considerably vdth locality. In some places, they are schistose and contain considerable silica; in other localities they are dolonlitic but the blue micaceous limestones of the belt usually are low in magnesia. These marbles Yrere burned for lime before and after Civil War times. An .important marble belt enters Georgia in Fannin County in the region of 1lineral Bluff and extends southward east of Blue Ridge, Cherrylog, Ellijay and Talona in Gilmer County; T~lking Rock, Jasper and Tate in Pickens County to the vicinity of Canton in Cherokee Countyo An .isolated occurrence may be found in Haralson County near the Alabama line. In the vicinity of Tate and Harble Hill, famous for the production of Georgia marble, the stone is frequently high in calcium and low in magnesium. In the vicinity of Whitestone, dolomites crop out and are extensively used for agricultural and other 5 purposes l'.Iagnesian limestones and dolomites are comhlon in the Paleozoic areas of nol:"thwest Georgia (S& geologic map of Georgia)~ Shady dolom1te of Lower Cambrian area is medium-grained, coarsely crystalline dolon;itc which cropa out near the eastern borders of the Pale~z.Oi.c nreo.. Exposur~s are uncom.'Tlon and occupy small areas MJ~h of the fornn tion is covered by residual soil. The most wide-spread dolomite, the Knox dolomite (Oznrkian-Ordovician) is thick-bedded, gray dolomite which yields after vteathering large amounts of gray chert in small and large mass es Good out-crops of unweathered dolomite are not cornon but, because this f orm.TIONS Table 6 (Continued) Sample No. 6 7 8 9 10 Uoisture at 100C ...... ...... Gte 0 Loss on ignition Soda (Na20) Potash (!S20) e 37.84 .46 .12 .82 .25 ...... 36 ~ .18 33 ,28 Lime (CaO) 26.74 23.86 27.66 27.90 23.88 Magnesia (lfgO) 16.47 15.46 14.43 15.32 14.60 Alumina (Al203) Ferric oxide (Fe2o3) Ferrous oxide (FeO) ( . ( ( ( ( ( 2.16 ( 3.16 ( 3.28 ( 1.34 ( 2.80 Manganous oxide (Mn.O) ' Titanium dioxide (Ti.02) o Sulphur trioxide (S03) Phosphorus pentoxide (~2o5 ) tr. Carbon dioxide (C02) ,04 o .70 .06 Silica (Sio2) and Insoluble Undetermined 14.68 17.04 15,32 16.54 21,88 39.37 39.37 38.07 1,06 36.17 TOTAL 100,00 100.00 100.00 100,00 100,00 Calcium carbonate Magnesiun carbonate 47.74 42.60 49.36 49.79 42.68 24.74 32.46 30.18 32.04 30.50 6. Limestone. Decatur County. Along the Atl antic Coas t Line Rail way, from 1 to l~ miles southwest of Recovery. 2/ 7. Limestone, Decatur County. Lot 265 , district 31, 2 miles northwest of Face- ville. Ers . D. B. Bower property, Bainbridge , Georgia. 8. Limestone. Echols County. J. I. Peterson pr operty. Along the Allapaha River, 3t miles belovv the bridge at Statenville, on the west bank of the river. 2/ 9. Same. Analysis by J . Goldstein. 10. Limestone. Grady County, Forest Falls or Limesink, 8 miles north of Whigham. 2./ Soft, white argillaceous limestone with brownish, concentric bands and ap- parently brecciated, hard, white compact limestone in a matrix of s oft, white, argillaceous lililcstonc. Irregular, brovmish bands run through ag- gr egate and matrix Yl:itbt)ut break, 29 MAGNESIAN LIMESTONES IN THE COASTAL PLAIN FORMATIONS Table 6 (Continued) Sample Noe il 12 13 14 15 Moisture at l00C Loss on ignition Soda (Na2o) Potash (K2o) Lime (CaO) Magnesia (MgO) 0 .31 .04 .06 ...... .35 19.44 29. 60 25.26 27.60 28.32 14.08 17'.43 14.95 16.67 1?.10 Alumina (Al2o3) Ferric Oxide(Fe2o3 ) Ferrous oxide (FeO) ~ 2.04 ~ 1.30 ~ 2.00 ~ 1.60 ~ 1.20 Manganous oxide (!mO) ea eoe Titanium dioxide (Ti02) Sulphur trioxide (S03) Phosphorus pentoxide (P2o5) Carbon dioxide (co2) .04 .05 04 .66 tr Silica (Sio ) 2 and Insol. 30~65 7.22 20.12 12.40 10.59 Undete rmined / ToTAL 33.15 44.20 36.97 41.59 42.49 100.00 100.00 Calcium carbonate Ma nesium carbonate 11. Limestone . Grady County. Little Soft, white argillaceous limestone;picolitiC.~tructure; phase of limestone with concretionary structure. . 12. Limestone. Grady County. Jas. Blackshear place, 8 miles south of Cairo, in the escarpment on the east side of Ochlocknee River, 200 yards south of Bonnet Lake.')/ i i 13. Limestone. Thomas County. McKinnon property, 5 miles east of Thomasville, mile south of the 5-mile post on the Boston road and north of the 5-mile post on the Atlantic Coast Line Railroad.2/ 14. Limestone. Thomas County. 1utchell propert11 in the steep slope of an old limesink, 7 miles west of Thomasville and 2 mile north of the ThomasvilleBo~ton public road, near the eastern boundar,y of the Mitchell propcrty.J/ 15. Limestone . Thomas County. R. G. r.u tchell place, ~ milJ west of the Thoma.sville-8pringhill road, 7~ miles south of Thomasvill e.-:..J BIBLIOGRAPHY Additional information and annlyscs of dolo~tes and magnesian linestones of Georgia nay be obtained from the follovnng reports as well as from t he fil es of the Georgia Divisi on of T.:ines, !'.fining and Geology. 1. ;.1cCallie1 S. W. ~ ~rbles of Georgia: Ge "'~ rgia Geol. Survey Bull. 1, 1907, 2nd ed. 126 pp., 52 pl., and 2 naps. (rut of print) 2. J1cCallie, s. w. Roads and Road Building l~aterials of Georgia: Georgia Geol. Survey Bull. 8. 1901. 264 pp., 27 pl., and 1 r.mp . 3. Brantly, J. E. Limestones and I.rarls of the Coastal Plain of Georgia: Georgia Gcol. Survey Bull. 21. 1917. 289 pp., 18 pl., and 1 map. 4. l!cCallie, S. VI. !.!ineral Resources of Georgia: Georgia Geol. Survey Bull. 23. 1910. 164 pp., 20 pl., and 2 maps. (Cut of Print) 5. Veatch, Otto and Stephenson, L. u. Geol ogy of the Coastal Plain of Georgia: Georgia Geol. Survey Bull. 26. 1911. 463 pp., 30 pl., and 2 naps. (Cut of print) 6. I.hynard , T. Poo le. Limestones and Corront IJa.terials of North Georgia: Georgia Geol. Survey 27. 1912. 296 pp., 22 pl., and 1 ~ap. 7. Bayley, Yr. s. Geology of the Tate Quadrangle, Georgia: Georgia Geol. Survey Bull. 43 1928. 170 pp., 22 pl., 2 figs., and 2 maps. 8. Furcron, A.S., Ilinyan, A. c., an~ Snith, R. r;. Rock \Jool- 0pportunities for ?.nnufacturine in Georgia: Georgin Geol. Survey Inform tion Circular 10. 1939. 18 PP 9. Butts, Charles. Geology of the Paleozoic Rocks of Geort;in. IIanuscript in files of the Georg.Ln Division of nnes, :iS.ning nnd Ge0logy. 10. Ha yes, C. 1'.". Rone, Ga.- Aln.: U. S. Geol. Survey Folio 78. 1902. 6, (3) pp., 4 maps. (Cut of print) 11. LaFor ge , Lawrence and Phalen,\',-. C. Ellijay, Gn- N. c. -Tenn.: U.S. Go ol. Survey Folio 187. 1913. 18 pp., 4 maps. l2. l' nynard, T. Poole. Directory of Comr.1ercial !Jinerals in Ge or .r, ia and Alabama .. along the Central of Georgia Rc:tilway: C-entral of Georgia Railway, Industrial Depa rtment. 154 PP 13. Ge or ei a Division of l::ines, :linin~ and Geology. Geol ogic l.~p of Geort;ia. 1939. Scale: ~1~500,000~ 14. Hull, J. P. D., Shearer, H. K. A Prelimina ry RepGrt on a Part c f the P,;rites Depos i ts of Gcoreia: Georeia Geol. Survey Bull. 33 . 1918. 224 pp., 17 pl., and 1 m.1.p. 15. Brantly, J. E. Lincstono a t tho Ladd Quarries near Cartersville, GeorGia. February, 1915. Unpublished manuscript in the files of the Geor[in Division of Hine s, Hinine a nd Go0 locy~